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Oxidative Self-Assembly of Au/Ag/Pt Alloy Nanoparticles into High-Surface Area, Mesoporous, and Conductive Aerogels for Methanol Electro-oxidation Chem. Mater. (IF 9.811) Pub Date : 2022-06-24 Rajib Sarkar, Ahmed A. Farghaly, Indika U. Arachchige
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Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence Chem. Mater. (IF 9.811) Pub Date : 2022-06-24 Jiarong Lv, Yanyan Qian, Qun Jing, Xinmei Wang, Ming-Hsien Lee, Zhaohui Chen
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Physicochemical Screen Effect of Li Ions in Oxygen Redox Cathodes for Advanced Sodium-Ion Batteries Chem. Mater. (IF 9.811) Pub Date : 2022-06-24 Sangeon Park, Gwanghyeon Choi, Jongbeom Kim, Jaewoon Lee, Hyungjun Kim, Maenghyo Cho, Duho Kim
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Chemical Considerations for Colloidal Nanocrystal Synthesis† Chem. Mater. (IF 9.811) Pub Date : 2022-06-24 Jonathan De Roo
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Synthesis of In-Plane Oriented Tin Sulfides by Organosulfur-Mediated Sulfurization of Ultrathin SnO2 Films Chem. Mater. (IF 9.811) Pub Date : 2022-06-23 Bhobnibhit Chatmaneerungcharoen, Mathias Fraccaroli, François Martin, Cyril Guedj, Emmanuel Nolot, Denis Rouchon, Nicolas Vaxelaire, Roselyne Templier, Adeline Grenier, Anne-Marie Papon, Hervé Roussel, Laetitia Rapenne, Hubert Renevier, Stéphane Cadot
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MnTa2N4: A Ternary Nitride Spinel with a Strong Magnetic Frustration Chem. Mater. (IF 9.811) Pub Date : 2022-06-24 Rafael Trócoli, Carlos Frontera, Judith Oró-Solé, Clemens Ritter, Pere Alemany, Enric Canadell, M. Rosa Palacín, Josep Fontcuberta, Amparo Fuertes
Magnetic frustration results from competing magnetic interactions and leads to unusual ground states, ranging from non-collinear magnetic orders to spin liquids (SLs), opening the path to new physics and emerging properties. We report the engineered magnetic interaction design and synthesis of the new ternary nitride MnTa2N4 with a normal spinel structure, where the magnetic cations Mn2+ occupy exclusively
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Distinctive Formation of Bifunctional ZnCoS-rGO 3D Hollow Microsphere Flowers with Excellent Energy Storage Performances Chem. Mater. (IF 9.811) Pub Date : 2022-06-23 Peng Chen, Chao Yang, Peng Gao, Xuli Chen, Ya-Jun Cheng, Jilei Liu, Kunkun Guo
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Tuning Au–Cu Janus Structures through Strong Ligand-Mediated Interfacial Energy Control Chem. Mater. (IF 9.811) Pub Date : 2022-06-23 Xu Fan, Senyuan An, Jia Jia, Wenjia Xu, Xiaoying Wu, Jianpeng Zong, Yun Wang, Hongyu Chen, Yuhua Feng
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pH-Responsive Gelation in Metallo-Supramolecular Polymers Based on the Protic Pyridinedicarboxamide Ligand Chem. Mater. (IF 9.811) Pub Date : 2022-06-23 Mostafa Ahmadi, Farhad Panahi, Naeimeh Bahri-Laleh, Mohammad Sabzi, Gerard Pareras, Bruno N. Falcone, Albert Poater
Pyridinedicarboxamide (PDCA) ligands have been widely integrated into different polymer chemistries and provided promising self-healing properties in bulk upon adding specific metal ions. However, their application in the development of synthetic hydrogels is limited due to the lack of clear kinetics and thermodynamic data. To fill this gap, we study the dynamics of polymer hydrogels formed by the
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Selective CO2 Reduction to Formate on a Zn-Based Electrocatalyst Promoted by Tellurium Chem. Mater. (IF 9.811) Pub Date : 2022-06-22 Xue Teng, Jianmin Lu, Yanli Niu, Shuaiqi Gong, Mingze Xu, Thomas J. Meyer, Zuofeng Chen
Zn-based materials represent a class of low-cost, promising electrocatalysts for CO2 reduction but the tuning of catalytic activity and selectivity by varying composition and nanostructure is a challenge. Herein, a ZnTe/ZnO heterostructured material supported on N-doped carbon nanosheets (ZnTe/ZnO@C) is prepared with a novel ZnTe metal–organic framework (MOF). The hybrid material exhibits greatly enhanced
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Comment on “Size Dependent Optical Properties and Structure of ZnS Nanocrystals Prepared from a Library of Thioureas” Chem. Mater. (IF 9.811) Pub Date : 2022-06-22 Tangi Aubert, Aleksandr A. Golovatenko, Anna V. Rodina, Zeger Hens
In their recent article, Owen et al. published a new data set for ZnS quantum dots, linking an optical band gap with a nanocrystal diameter. (1) Such band gap/size data sets have been very helpful in the field of quantum dots to build calibration or sizing curves. These sizing curves are widely used to quickly determine nanocrystal sizes from absorption measurements, and they have been reported for
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First-Principles Computational Design and Discovery of Solid-Oxide Proton Conductors Chem. Mater. (IF 9.811) Pub Date : 2022-06-22 Md Shafiqul Islam, Shuo Wang, Alex T. Hall, Yifei Mo
Solid-oxide proton-conducting materials are key components for hydrogen-based energy devices, including solid-oxide fuel cells, electrolyzers, hydrogen separation membranes, and novel electronic computing devices. The further development of these devices requires proton-conducting materials with high proton conductivity and good stability with hydrogen and water under the device-operating environment
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Regulating the Helical Chirality of Racemic Polyacetylene by Chiral Polylactide for Realizing Full-Color and White Circularly Polarized Luminescence Chem. Mater. (IF 9.811) Pub Date : 2022-06-21 Xinhui Gao, Jing Wang, Kai Yang, Biao Zhao, Jianping Deng
Exploring the generation and transfer of chirality at different hierarchical levels has always been a significant research subject. The present contribution reports our success in inducing and regulating the helical chirality of achiral macromolecules (racemic polyacetylene) by using a chiral helical macromolecule (chiral polylactide); helical chirality is sufficiently transferred between two types
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In Situ Engineering of a Metal Oxide Protective Layer into Pt/Carbon Fuel-Cell Catalysts by Atomic Layer Deposition Chem. Mater. (IF 9.811) Pub Date : 2022-06-21 Woo-Jae Lee, Susanta Bera, HyunJae Woo, Hyun Gu Kim, Ji-Hu Baek, Woongpyo Hong, Jung-Yeon Park, Seung-Jeong Oh, Se-Hun Kwon
Degradation of polymer electrolyte membrane fuel cell (PEMFC) systems has emerged as a critical issue. A thin metal oxide layer coated with Pt/carbon via ALD (atomic layer deposition) is one of the potential approaches for preserving electrochemical activity; however, the exact interfacial effects of metal oxide on enhancing PEMFC durability are unclear. Herein, interfacial engineering of the TiO2
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Network Size Control in Coordination Polymer Glasses and Its Impact on Viscosity and H+ Conductivity Chem. Mater. (IF 9.811) Pub Date : 2022-06-21 Tomohiro Ogawa, Kazuki Takahashi, Takuya Kurihara, Sanjog S. Nagarkar, Koji Ohara, Yusuke Nishiyama, Satoshi Horike
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Bioinspired Interface-Guided Conformal Janus Membranes with Enhanced Adhesion for Flexible Multifunctional Electronics Chem. Mater. (IF 9.811) Pub Date : 2022-06-21 Xueyu Wang, Shan Li, Peng Xiao, Jiang He, Wei Zhou, Qiling Wang, Shengqian Zhu, Peng Wei, Tao Chen
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High-Pressure Synthesis of β- and α-In2Se3-Like Structures in Ga2S3 Chem. Mater. (IF 9.811) Pub Date : 2022-06-21 Samuel Gallego-Parra, Rosario Vilaplana, Oscar Gomis, Plácida Rodríguez-Hernández, Alfonso Muñoz, Jesus Antonio González, Juan Angel Sans, Catalin Popescu, Francisco Javier Manjón
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Nucleation of Porous Crystals from Ion-Paired Prenucleation Clusters Chem. Mater. (IF 9.811) Pub Date : 2022-06-16 Nick Pellens, Nikolaus Doppelhammer, Sambhu Radhakrishnan, Karel Asselman, C. Vinod Chandran, Dries Vandenabeele, Bernhard Jakoby, Johan A. Martens, Francis Taulelle, Erwin K. Reichel, Eric Breynaert, Christine E. A. Kirschhock
Current nucleation models propose manifold options for the formation of crystalline materials. Exploring and distinguishing between different crystallization pathways on the molecular level however remain a challenge, especially for complex porous materials. These usually consist of large unit cells with an ordered framework and pore components and often nucleate in complex, multiphasic synthesis media
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Non-Aqueous One-Pot SnO2 Nanoparticle Inks and Their Use in Printable Perovskite Solar Cells Chem. Mater. (IF 9.811) Pub Date : 2022-06-16 T. A. Nirmal Peiris, Hasitha C. Weerasinghe, Manoj Sharma, Jueng-Eun Kim, Monika Michalska, Naresh Chandrasekaran, Dimuthu C. Senevirathna, Hanchen Li, Anthony S. R. Chesman, Doojin Vak, Jacek J. Jasieniak
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Donor–Acceptor Conjugated Copolymers Containing Transition-Metal Complex: Intrachain Magnetic Exchange Interactions and Magneto-Optical Activity Chem. Mater. (IF 9.811) Pub Date : 2022-06-16 Xunshan Liu, Jiaze Xie, Jens Niklas, Emigdio E. Turner, Dafei Yuan, John S. Anderson, Jeffrey J. Rack, Oleg G. Poluektov, Luping Yu
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Tough Antibacterial Metallopolymer Double-Network Hydrogels via Dual Polymerization Chem. Mater. (IF 9.811) Pub Date : 2022-06-15 JiHyeon Hwang, Yujin Cha, Luis Ramos, Tianyu Zhu, Leman Buzoglu Kurnaz, Chuanbing Tang
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HSIL-Based Synthesis of Ultracrystalline K,Na-JBW, a Zeolite Exhibiting Exceptional Framework Ordering and Flexibility Chem. Mater. (IF 9.811) Pub Date : 2022-06-15 Karel Asselman, Sambhu Radhakrishnan, Nick Pellens, C. Vinod Chandran, Maarten Houlleberghs, Yijue Xu, Johan A. Martens, Sreeprasanth Pulinthanathu Sree, Christine E.A. Kirschhock, Eric Breynaert
A reproducible synthesis strategy for ultracrystalline K,Na-aluminosilicate JBW zeolite is reported. The synthesis uses a Na-based hydrated silicate ionic liquid (HSIL) as a silicon source and gibbsite as the aluminum source. 27Al and 23Na NMR spectra exhibit crystalline second-order quadrupole patterns in the hydrated as well as dehydrated states and distinct resonances for different T-sites demonstrating
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Understanding and Utilizing Reactive Oxygen Reservoirs in Atomic Layer Deposition of Metal Oxides with Ozone Chem. Mater. (IF 9.811) Pub Date : 2022-06-15 Joel R. Schneider, Camila de Paula, Nathaniel E. Richey, Jon G. Baker, Solomon T. Oyakhire, Stacey F. Bent
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Repurposing Templates for Zeolite Synthesis from Simulations and Data Mining Chem. Mater. (IF 9.811) Pub Date : 2022-06-14 Daniel Schwalbe-Koda, Omar A. Santiago-Reyes, Avelino Corma, Yuriy Román-Leshkov, Manuel Moliner, Rafael Gómez-Bombarelli
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Enhanced Hardening Effects on Molybdenum-Doped WB2 and WB2–SiC/B4C Composites Chem. Mater. (IF 9.811) Pub Date : 2022-06-14 Lisa E. Pangilinan, Shanlin Hu, Christopher L. Turner, Jinyuan Yan, Abby Kavner, Reza Mohammadi, Sarah H. Tolbert, Richard B. Kaner
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Accelerated Mining of 2D Van der Waals Heterojunctions by Integrating Supervised and Unsupervised Learning Chem. Mater. (IF 9.811) Pub Date : 2022-06-14 An Chen, Zhilong Wang, Xu Zhang, Letian Chen, Xu Hu, Yanqiang Han, Junfei Cai, Zhen Zhou, Jinjin Li
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Cooperative Protonation Underlying the Acid Response of Metal–Organic Frameworks Chem. Mater. (IF 9.811) Pub Date : 2022-06-14 Yan Xu, Shuai-Liang Yang, Gen Li, Ran Bu, Xiao-Yan Liu, En-Qing Gao
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Laminar Flow-Assisted Metal Etching for the Preparation of High-Quality Transfer-Free Graphene Chem. Mater. (IF 9.811) Pub Date : 2022-06-13 Fang-Chi Ding, Cheng-Yu Dai, Chun-Lung Yao, Cheuk Yui Lai, Chiao-Chen Chen
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Energy Landscape of the Sugar Conformation Controls the Sol-to-Gel Transition in Self-Assembled Bola Glycolipid Hydrogels Chem. Mater. (IF 9.811) Pub Date : 2022-06-13 Alexandre Poirier, Patrick Le Griel, Thomas Zinn, Petra Pernot, Sophie L. K. W. Roelants, Wim Soetaert, Niki Baccile
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Double Doping of a Low-Ionization-Energy Polythiophene with a Molybdenum Dithiolene Complex Chem. Mater. (IF 9.811) Pub Date : 2022-06-13 Emmy Järsvall, Till Biskup, Yadong Zhang, Renee Kroon, Stephen Barlow, Seth R. Marder, Christian Müller
Doping of organic semiconductors is crucial for tuning the charge-carrier density of conjugated polymers. The exchange of more than one electron between a monomeric dopant and an organic semiconductor allows the polaron density to be increased relative to the number of counterions that are introduced into the host matrix. Here, a molybdenum dithiolene complex with a high electron affinity of 5.5 eV
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Scalable Fabrication of Metal Halide Perovskites for Direct X-ray Flat-Panel Detectors: A Perspective† Chem. Mater. (IF 9.811) Pub Date : 2022-06-10 Yuki Haruta, Mioko Kawakami, Yuui Nakano, Soumya Kundu, Shinji Wada, Takumi Ikenoue, Masao Miyake, Tetsuji Hirato, Makhsud I. Saidaminov
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Ion-Pairs in Aluminosilicate-Alkali Synthesis Liquids Determine the Aluminum Content and Topology of Crystallizing Zeolites Chem. Mater. (IF 9.811) Pub Date : 2022-06-10 Karel Asselman, Nick Pellens, Barbara Thijs, Nikolaus Doppelhammer, Mohamed Haouas, Francis Taulelle, Johan A. Martens, Eric Breynaert, Christine E.A. Kirschhock
Using hydrated silicate ionic liquids, phase selection and framework silicon-to-aluminum ratio during inorganic zeolite synthesis were studied as a function of batch composition. Consisting of homogeneous single phasic liquids, this synthesis concept allows careful control of crystallization parameters and evaluation of yield and sample homogeneity. Ternary phase diagrams were constructed for syntheses
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Pseudomorphic Replacement in the Transformation between Metal–Organic Frameworks toward Three-Dimensional Hierarchical Nanostructures Chem. Mater. (IF 9.811) Pub Date : 2022-06-10 Lei Shao, Fuqiang Fan, Xueya Dai, Hongxin Fu, Wenze Li, Wei Qi, Fan-Bao Meng, Yu Fu
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Orientation-Controlled Anisotropy in Single Crystals of Quasi-1D BaTiS3 Chem. Mater. (IF 9.811) Pub Date : 2022-06-10 Boyang Zhao, Md Shafkat Bin Hoque, Gwan Yeong Jung, Hongyan Mei, Shantanu Singh, Guodong Ren, Milena Milich, Qinai Zhao, Nan Wang, Huandong Chen, Shanyuan Niu, Sang-Jun Lee, Cheng-Tai Kuo, Jun-Sik Lee, John A. Tomko, Han Wang, Mikhail A. Kats, Rohan Mishra, Patrick E. Hopkins, Jayakanth Ravichandran
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Bright Green Emission from Self-Trapped Excitons Triggered by Sb3+ Doping in Rb4CdCl6 Chem. Mater. (IF 9.811) Pub Date : 2022-06-10 Jiance Jin, Yinghui Peng, Yuting Xu, Kai Han, Anran Zhang, Xiao-Bao Yang, Zhiguo Xia
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Correction to “Surface Stabilization with Fluorine of Layered Ultrahigh-Nickel Oxide Cathodes for Lithium-Ion Batteries” Chem. Mater. (IF 9.811) Pub Date : 2022-06-10 Lalit Sharma, Michael Yi, Eunmi Jo, Hugo Celio, Arumugam Manthiram
The original article had an error in the Table of Contents (TOC) and Abstract figure. The y-axis label has to be changed from “Voltage (V)” to “Specific capacity (mA h g–1)” as given in the corrected TOC figure below. We note that this error has no impact in the results and final conclusions. However, the correct image should be displayed for posterity. The authors are sorry for the error and any consequent
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Construction of Dual-Atom Fe via Face-to-Face Assembly of Molecular Phthalocyanine for Superior Oxygen Reduction Reaction Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Anuj Kumar, Kai Sun, Xinxuan Duan, Shubo Tian, Xiaoming Sun
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Insight into the Fergusonite–Scheelite Phase Transition of ABO4-Type Oxides by Density Functional Theory: A Case Study of the Subtleties of the Ground State of BiVO4 Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Taifeng Liu, Xingfan Zhang, Jingcheng Guan, C. Richard A. Catlow, Aron Walsh, Alexey A. Sokol, John Buckeridge
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Uncovering the Kagome Ferromagnet within a Family of Metal–Organic Frameworks Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Samuel A. Ivko, Katherine Tustain, Tristan Dolling, Aly Abdeldaim, Otto H. J. Mustonen, Pascal Manuel, Chennan Wang, Hubertus Luetkens, Lucy Clark
Kagome networks of ferromagnetically or antiferromagnetically coupled magnetic moments represent important models in the pursuit of a diverse array of novel quantum and topological states of matter. Here, we explore a family of Cu2+-containing metal–organic frameworks (MOFs) bearing kagome layers pillared by ditopic organic linkers with the general formula Cu3(CO3)2(x)3·2ClO4 (MOF-x), where x is 1
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Temperature-Dependent Reaction Pathways in FeS2: Reversibility and the Electrochemical Formation of Fe3S4 Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Grace Whang, David S. Ashby, Aliya S. Lapp, Yi-Chieh Hsieh, Danielle M. Butts, Igor V. Kolesnichenko, Pu-Wei Wu, Timothy N. Lambert, A. Alec Talin, Bruce S. Dunn
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Correlating Structural Disorder to Li+ Ion Transport in Li4–xGe1–xSbxS4 (0 ≤ x ≤ 0.2) Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Bianca Helm, Nicolò Minafra, Björn Wankmiller, Matthias T. Agne, Cheng Li, Anatoliy Senyshyn, Michael Ryan Hansen, Wolfgang G. Zeier
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All-Magnetic Slabs and Multiferroism in (Bi2–xO2)(MF4) Aurivillius Oxyfluorides (M = Fe and Ni) Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Olivier Mentré, Miguel A. Juárez-Rosete, Marie Colmont, Clemens Ritter, François Fauth, Mathieu Duttine, Marielle Huvé, Christine Terryn, Victor Duffort, Ángel M. Arévalo-López
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Molecular Engineering of Robust Starburst-Based Organic Photosensitizers for Highly Efficient Photocatalytic Hydrogen Generation from Water Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Yan-Yi Kwok, Po-Yu Ho, Ying Wei, Zhong Zheng, Sze-Chun Yiu, Cheuk-Lam Ho, Shuping Huang
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Construction of Hydrazone-Linked Macrocycle-Enriched Covalent Organic Frameworks for Highly Efficient Photocatalysis Chem. Mater. (IF 9.811) Pub Date : 2022-06-09 Meng-Hao Li, Zhiqiang Yang, Zheng Li, Jia-Rui Wu, Bing Yang, Ying-Wei Yang
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Understanding the Role of Charge Storage Mechanisms in the Electrochromic Switching Kinetics of Metal Oxide Nanocrystals Chem. Mater. (IF 9.811) Pub Date : 2022-06-08 Hsin-Che Lu, Benjamin Z. Zydlewski, Bharat Tandon, Sofia A. Shubert-Zuleta, Delia J. Milliron
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Enhanced Surface Passivation of Lead Sulfide Quantum Dots for Short-Wavelength Photodetectors Chem. Mater. (IF 9.811) Pub Date : 2022-06-08 Shichen Yin, Carr Hoi Yi Ho, Shuo Ding, Xiangyu Fu, Liping Zhu, Julian Gullett, Chen Dong, Franky So
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Enhanced H2O2 Production via Photocatalytic O2 Reduction over Structurally-Modified Poly(heptazine imide) Chem. Mater. (IF 9.811) Pub Date : 2022-06-08 Pankaj Sharma, Thomas J. A. Slater, Monika Sharma, Michael Bowker, C. Richard A. Catlow
Solar H2O2 produced by O2 reduction provides a green, efficient, and ecological alternative to the industrial anthraquinone process and H2/O2 direct-synthesis. We report efficient photocatalytic H2O2 production at a rate of 73.4 mM h–1 in the presence of a sacrificial donor on a structurally engineered catalyst, alkali metal-halide modulated poly(heptazine imide) (MX → PHI). The reported H2O2 production
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CeO2 Aerogel-Induced Resilience of Catalytic Ni(OH)2 under Oxidizing Conditions Chem. Mater. (IF 9.811) Pub Date : 2022-06-08 Travis G. Novak, Paul A. DeSario, Michelle D. Johannes, Todd H. Brintlinger, Ryan H. DeBlock, Jeffrey W. Long, Christopher N. Chervin, Rhonda M. Stroud, Debra R. Rolison
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ScSI: A New Exfoliatable Semiconductor Chem. Mater. (IF 9.811) Pub Date : 2022-06-08 Austin M. Ferrenti, Maxime A. Siegler, Shiyuan Gao, Nicholas Ng, Tyrel M. McQueen
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Trihalide Mixing by Size-Flexible H– Ions in Layered Ba2H3 (Cl, Br, I) Chem. Mater. (IF 9.811) Pub Date : 2022-06-08 Hiroki Ubukata, Fumitaka Takeiri, Cédric Tassel, Shintaro Kobayashi, Shogo Kawaguchi, Takashi Saito, Takashi Kamiyama, Shunsuke Kobayashi, Genki Kobayashi, Hiroshi Kageyama
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Spatiotemporal Route to Understanding Metal Halide Perovskitoid Crystallization Chem. Mater. (IF 9.811) Pub Date : 2022-06-07 Mansoor Ani Najeeb Nellikkal, Rodolfo Keesey, Margaret Zeile, Venkateswaran Shekar, Zhi Li, Nicholas Leiby, Matthias Zeller, Emory M. Chan, Joshua Schrier, Alexander J. Norquist
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Pseudo-Polymorphism in Layered FeS Intercalates: A Competition between Charged and Neutral Guest Species Chem. Mater. (IF 9.811) Pub Date : 2022-06-07 Colin P. Harmer, Saeed Kamali, Oleg I. Lebedev, Shannon J. Lee, Raquel A. Ribeiro, Paul C. Canfield, Kirill Kovnir
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Zero-Thermal-Quenching Layered Metal Halide Perovskite Chem. Mater. (IF 9.811) Pub Date : 2022-06-07 Joo Hyeong Han, N. S. M. Viswanath, Yong Min Park, Han Bin Cho, Sung Woo Jang, Jeong Wan Min, Won Bin Im
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Effect of Relaxations on the Conductivity of La1/2+1/2xLi1/2–1/2xTi1–xAlxO3 Fast Ion Conductors Chem. Mater. (IF 9.811) Pub Date : 2022-06-06 Keti Vezzù, Ester García-González, Gioele Pagot, Esteban Urones-Garrote, Maria Eugenia Sotomayor, Alejandro Varez, Vito Di Noto
Perovskite-type solid-state electrolytes, Li3xLa2/3–xTiO3 (LLTO), are considered among the most promising candidates for the development of all-solid-state batteries based on lithium metal. Their high bulk ionic conductivity can be modulated by substituting part of the atoms hosted in the A- or B-site of the LLTO structure. In this work, we investigate the crystal structure and the long-range charge
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Nonheteroepitaxial CsPbBr3/Cs4PbBr6 Interfaces Result in Nonpassivated Bright Bromide Vacancies Chem. Mater. (IF 9.811) Pub Date : 2022-06-06 Eyal Cohen, Alina Nagel, Marc Fouchier, Larisa Popilevsky, Yaron Kauffmann, Sasha Khalfin, Shaked Dror, Yehonadav Bekenstein
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Formulation of Poly(ionic liquids)@COF Nanotrap for Efficient Perrhenate Sequestration from Alkaline Nuclear Waste Chem. Mater. (IF 9.811) Pub Date : 2022-06-06 Zhao-Fei Liu, Kun Liu, Xin-Jing Zheng, Yu-Han Wang, Xiao-Xiao Sun, Peng-Chong Xue, Cheng-Peng Li, Miao Du
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Controlling Defects to Achieve Reproducibly High Ionic Conductivity in Na3SbS4 Solid Electrolytes Chem. Mater. (IF 9.811) Pub Date : 2022-06-06 Masaki Shimoda, Mayu Maegawa, Suguru Yoshida, Hirofumi Akamatsu, Katsuro Hayashi, Prashun Gorai, Saneyuki Ohno
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Direct Visualization of Supramolecular Binding and Separation of Light Hydrocarbons in MFM-300(In) Chem. Mater. (IF 9.811) Pub Date : 2022-06-06 Lixia Guo, Mathew Savage, Joe H. Carter, Xue Han, Ivan da Silva, Pascal Manuel, Svemir Rudić, Chiu C. Tang, Sihai Yang, Martin Schröder
The purification of light olefins is one of the most important chemical separations globally and consumes large amounts of energy. Porous materials have the capability to improve the efficiency of this process by acting as solid, regenerable adsorbents. However, to develop translational systems, the underlying mechanisms of adsorption in porous materials must be fully understood. Herein, we report
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Interfacial Electron Delocalization in Engineering Nanosized Anti-Perovskite Nitride for Efficient CO2 Electroreduction Chem. Mater. (IF 9.811) Pub Date : 2022-06-03 Qian Liang, Yu Zhao, Jian-de Chen, Jia-jun Dai, Xingyu Ding, Zhen Tong, Shi-jun Xie, Jing Zhang, Zhe-hui Zhou, Jun-Tao Li, Jian-Feng Li, Yao Zhou
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Solution-Processable Naphthalene Diimide-Based Conjugated Polymers as Organocatalysts for Photocatalytic CO2 Reaction with Extremely Stable Catalytic Activity for Over 330 Hours Chem. Mater. (IF 9.811) Pub Date : 2022-06-03 Shih-Hao Wang, Farheen Khurshid, Pin-Zhen Chen, Ying-Ren Lai, Cheng-Wei Cai, Po-Wen Chung, Michitoshi Hayashi, Ru-Jong Jeng, Syang-Peng Rwei, Leeyih Wang