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Enhancing Donor–Acceptor Interaction and Framework Stability by the Povarov Reaction for Photocatalytic H2O2 Production Chem. Mater. (IF 7.2) Pub Date : 2024-09-16 Rui-Cheng Chen, Can-Min Wu, Lai-Hon Chung, Jieying Hu, Mou-Cheng Tang, Zhiqing Lin, Xianghua Yang, Zhengtao Xu, Jun He
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Tuning the Optical Absorption Edge of Vacancy-Ordered Double Perovskites through Metal Precursor and Solvent Selection Chem. Mater. (IF 7.2) Pub Date : 2024-09-16 Alexandra Brumberg, Owen Kuklinski, Greggory T. Kent, Emily E. Morgan, Alexander A. Mikhailovsky, T. Amanda Strom, Michael L. Chabinyc, Ram Seshadri
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The Influence of Reorientational and Vibrational Dynamics on the Mg2+ Conductivity in Mg(BH4)2·CH3NH2 Chem. Mater. (IF 7.2) Pub Date : 2024-09-16 Mads B. Amdisen, Yongqiang Cheng, Niina Jalarvo, Daniel Pajerowski, Craig M. Brown, Torben R. Jensen, Mikael S. Andersson
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Area-Selective Atomic Layer Deposition of Ruthenium via Reduction of Interfacial Oxidation Chem. Mater. (IF 7.2) Pub Date : 2024-09-13 Eun-Hyoung Cho, Dabin Kong, Iaan Cho, Youngchul Leem, Young Min Lee, Miso Kim, Chi Thang Nguyen, Jeong Yub Lee, Bonggeun Shong, Han-Bo-Ram Lee
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Mechanistically Informed Strategies for Site-Selective Atomic Layer Deposition Chem. Mater. (IF 7.2) Pub Date : 2024-09-13 Jessica C. Jones, Ethan P. Kamphaus, Lei Cheng, Cong Liu, Alex B. F. Martinson, Adam S. Hock
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Pentatwinned AuAg Nanorattles with Tailored Plasmonic Properties for Near-Infrared Applications Chem. Mater. (IF 7.2) Pub Date : 2024-09-13 Daniel García-Lojo, Sergio Rodal-Cedeira, Sara Núñez-Sánchez, Daniel Arenas-Esteban, Lakshminarayana Polavarapu, Sara Bals, Jorge Pérez-Juste, Isabel Pastoriza-Santos
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Electrochemical Hydrogenation of Nitrobenzene: From Electrocatalysis to Redox Mediator Catalysis Chem. Mater. (IF 7.2) Pub Date : 2024-09-13 Guo-Feng Liu, Shu Zhang, Chun-Jun Chen, Shu-Ming Xing, Xiao-Yi Zhang, Yue-Jiao Zhang, De-Yin Wu, Jian-Feng Li, Bin Ren, Jia-Jia Chen
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Luminescence Thermometry of Pr3+-Doped Sr3Y2Ge3O12 and Sr3Sc2Ge3O12 Submicron Garnets Spanning the 13–1025 K Range and New Insight to Their Spectroscopy Chem. Mater. (IF 7.2) Pub Date : 2024-09-13 Paulina Bolek, Thomas van Swieten, Justyna Zeler, Andries Meijerink, Eugeniusz Zych
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Europium Lithosilicates Li2EuSi2N4 and Li2EuSiO4─Crystal Structures and Luminescence Chem. Mater. (IF 7.2) Pub Date : 2024-09-12 Kilian M. Rießbeck, Markus Seibald, Christiane Stoll, Hubert Huppertz
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Electrochemical Biomass Depolymerization: Will Complex Catalysts Trigger High Product Selectivity? Chem. Mater. (IF 7.2) Pub Date : 2024-09-12 Lucie M. Lindenbeck, Björn B. Beele, Dirk Ferdinand Lützenkirchen-Hecht, Bruno V. M. Rodrigues, Adam Slabon
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Influence of Aluminum Substitution on Anionic Redox Activation and Stabilization in P′2-Type Na2/3MnO2 for Na/Li Battery Applications Chem. Mater. (IF 7.2) Pub Date : 2024-09-12 Jiaxuan Yin, Yanjia Zhang, Tomohiro Kuriyama, Yongcheng Jin, Naoaki Yabuuchi
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Spin-Crossover Solids as Phase-Change Materials to Actuate Strain in 2D MoS2 Chem. Mater. (IF 7.2) Pub Date : 2024-09-12 Tao Yuwen, Ruiquan Yang, Assel Aitkaliyeva, Charles J Hages, Daniel R. Talham
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Hybrid Rare-Earth Double Perovskite Ferroic with Near-Infrared Light-Emitting Property Chem. Mater. (IF 7.2) Pub Date : 2024-09-11 Hua-Kai Li, Li-Ping Wang, Na Wang, Zong-Ze Cui, Liang-Liang Zou, Le-Ping Miao, Heng-Yun Ye, Chao Shi
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Emerging Anion Disorder in CaTi1–xFexO3–x/2 Perovskites by X-ray Spectroscopy and Neutron Total Scattering Chem. Mater. (IF 7.2) Pub Date : 2024-09-11 Bryce G. Mullens, Frederick P. Marlton, Matilde Saura-Múzquiz, Maria K. Nicholas, Ahmadi J. Permana, Bruce C. Cowie, Valerie Mitchell, Cheng Li, Zhaoming Zhang, Brendan J. Kennedy
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Surface-Initiated Synergistic Disassembly of Metal-Phenolic Networks by Redox and Hydrolytic Reactions Chem. Mater. (IF 7.2) Pub Date : 2024-09-11 Wenting Liao, Bohan Cheng, Chenyu Wang, Joseph J. Richardson, Mitsuru Naito, Kanjiro Miyata, Hirotaka Ejima
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Crystal Orientation, Strain, and Microstrain of Perovskite Films in a Complex Compositional Parameter Space Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Filippo Tavormina, Eleonora Quadrivi, Paolo Biagini, Riccardo Po, Rosamaria Marrazzo, Maria Antonietta Loi, Luisa Barba, Norberto Masciocchi, Antonietta Guagliardi
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Energy-Induced Phase-Control Syntheses of Single-Phase NixRu1–x Solid Solutions and Active-Moderate-Sites Synergy in the Oxygen Evolution Reaction Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Yuhan Liu, Wenfang Zhai, Panpan Cui, Lei Li, Zhengfei Dai, Bo Huang
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Deciphering the Unusual Pressure-Induced Electron Transfer in the Molecular Switch {[Fe(Tp)(CN)3]2[Co(vbik)2]2}·(BF4)2·2MeOH Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Buqin Xu, Yanling Li, Benoît Baptiste, Lise-Marie Chamoreau, Damian Paliwoda, Shiteng Mi, Gábor Molnár, Kamel Boukheddaden, Rodrigue Lescouëzec
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Proapoptotic Peptide-Templated Au Nanoclusters Selectively Enhance Radiosensitivity of Cancer Cells Chem. Mater. (IF 7.2) Pub Date : 2024-09-09 Ying Shi, Zhenlong Liang, Min Jiang, Jingyi Qin, Xingshu Fei, Yingting Chen, Xinke Yu, Kefeng Pu, Xiaochuan Ma
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Platinum Selenide Nanoparticle Synthesis and Reaction with Butyllithium Breaking the Long-Range Ordering Structure Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Victor Secco Lemos, Daniel Angeli de Moraes, Iara de Lacerda Pataca, Olavo Fiamencini Verruma, Carolina Pirogini Torres, Angela Albuquerque, Ingrid Rodríguez-Gutiérrez, Danilo Biazon Janes, Felipe Crasto de Lima, Flavio Leandro Souza, Edson Roberto Leite, Adalberto Fazzio, João Batista Souza Junior
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Improved Stability and Performance of an n-Type Depletion Mode Poly(benzodifurandione) Based Organic Electrochemical Transistor via Electrolyte Selection Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Xihu Wu, Haoran Tang, Zhongliang Zhou, Teddy Salim, Cindy G. Tang, Fei Huang, Wei Lin Leong
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How Size and Composition of Cobalt Doped Iron Oxide Nanoparticle Tracers Enhance Magnetic Particle Imaging Performance Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Ashkan Abdibastami, Lucy Gloag, Jhair P. Prada, Hong Thien Kim Duong, Saeed Shanehsazzadeh, Scott A. Sulway, Soshan Cheong, Haira Hackbarth, Nicholas M. Bedford, Guy N. L. Jameson, Andre Bongers, J. Justin Gooding, Richard D. Tilley
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Proton Conduction in Paddlewheel-type Dinuclear Platinum(III) Complex System Including Neutral and Protonated 1,2,4-Triazole Chem. Mater. (IF 7.2) Pub Date : 2024-09-10 Peng-Hao Wang, Yukihiro Yoshida, Tomoya Ito, Yoshiaki Nakano, Hiroshi Kitagawa
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Second Phases and Dislocations to Boost the Thermoelectric Properties of CuInTe2 by Sb Doping at In Site Chem. Mater. (IF 7.2) Pub Date : 2024-09-09 Erkuo Yang, Lifeng Yu, Guangshu Li, Wen Zhang, Xinghui Wang, Rongchun Chen, Huijun Kang, Zongning Chen, Enyu Guo, Tongmin Wang
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Concentration-Dependent Layer-Stacking and the Influence on Phase-Conversion in Colloidally Synthesized WSe2 Nanocrystals Chem. Mater. (IF 7.2) Pub Date : 2024-09-09 Jessica Q. Geisenhoff, Yuanhui Pan, Hang Yin, Francesco Paesani, Alina M. Schimpf
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Dynamic Disorder in Monolayer and Multilayer 2D Ruddlesden–Popper Lead Iodide Perovskites: Evidence from Solid-State Nuclear Magnetic Resonance and Ultrafast Optical Spectroscopy Chem. Mater. (IF 7.2) Pub Date : 2024-09-06 Noemi Landi, Daniela Marongiu, Silvia Borsacchi, Lucia Calucci, Elena Maurina, Stefano Lai, Riccardo Pau, Angelica Simbula, Michele Saba, Marco Geppi, Elisa Carignani
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Copper Doping Blueshifts the Lowest-Energy Optical Transition of PbS Nanocrystals Chem. Mater. (IF 7.2) Pub Date : 2024-09-06 Patrick Y. Yee, Sarah Brittman, Paul D. Cunningham, Rhonda M. Stroud, Katherine D. Burgess, Steven C. Erwin, John L. Lyons, Michael H. Stewart, Barbara A. Marcheschi, Brandon Durant, Chase T. Ellis, Janice E. Boercker
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Hydrophilic vs Hydrophobic: Exploring Facet-Dependent Proton Transport Channels in Single Crystal of Ring-Shaped Trimeric Isopolytungstate Chem. Mater. (IF 7.2) Pub Date : 2024-09-06 Mengnan Yang, Lijuan Xiong, Shiyan Ji, Yao Zhang, Weixia Shi, Huafeng Li, Pengtao Ma, Jingping Wang, Jingyang Niu
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Atomic-Scale and Nanoscale Structural Changes in LiCoO2 Due to Irreversible Delithiation Accompanied by Oxygen Release Chem. Mater. (IF 7.2) Pub Date : 2024-09-05 Kei Nakayama, Shunsuke Kobayashi, Ryo Ishikawa, Akihide Kuwabara, Yuichi Ikuhara
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Two Nanoparticle Populations Simultaneously Directed Using Triptych Triblock Terpolymers Chem. Mater. (IF 7.2) Pub Date : 2024-09-05 Mengxue Zhang, Xiaomeng Li, Chuanbing Tang, Morgan Stefik
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Twisted Acceptor Core Molecular Design with Phenoxazine and Phenothiazine Donors Enabled Yellow Thermally Activated Delayed Fluorescent Emitters/Sensitizers for Long-Lifetime Solution-Processed Organic Light-Emitting Diodes Exceeding 31% External Quantum Efficiency Chem. Mater. (IF 7.2) Pub Date : 2024-09-04 Md Intekhab Alam, Mangey Ram Nagar, Jwo-Huei Jou, Sivakumar Vaidyanathan
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Challenges Reconciling Theory and Experiments in the Prediction of Lattice Thermal Conductivity: The Case of Cu-Based Sulvanites Chem. Mater. (IF 7.2) Pub Date : 2024-09-04 Irene Caro-Campos, Marta María González-Barrios, Oscar J. Dura, Erik Fransson, Jose J. Plata, David Ávila, Javier Fdez Sanz, Jesús Prado-Gonjal, Antonio M. Márquez
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Engineering a Surfactant Trap via Postassembly Modification of an Imine Cage Chem. Mater. (IF 7.2) Pub Date : 2024-09-04 María Pérez-Ferreiro, Quinn M. Gallagher, Andrea B. León, Michael A. Webb, Alejandro Criado, Jesús Mosquera
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Chemical Instability of CsPbBr3 Nanocrystals and the Reversible Transformation between CsPbBr3 and Cs4PbBr6 Nanocrystals as Driven by Synthetic Precursors Chem. Mater. (IF 7.2) Pub Date : 2024-09-04 Huan Tian, Yi Liu, Feng-Lei Jiang
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In Operando X-ray Diffraction Study of Thermoelectric Cu2Se Chem. Mater. (IF 7.2) Pub Date : 2024-09-03 Rasmus B. Stubkjær, Peter S. Thorup, Lasse R. Jo̷rgensen, Martin Roelsgaard, Karl F. F. Fischer, Ann-Christin Dippel, Bo Brummerstedt Iversen
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Unleashing the Potential of Fast Charging Batteries: Leveraging Anion Redox Chemistry in Ni- and Co-Free Cathodes Chem. Mater. (IF 7.2) Pub Date : 2024-09-03 Sudhan Nagarajan, Subhayan Roychoudhury, Conan Weiland, Debora Motta Meira, Mahalingam Balasubramanian, David Prendergast, Sooyeon Hwang, Leela Mohana Reddy Arava
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FeSi4P4 and CoSi3P3: Hidden Gems of Ternary Tetrel Pnictides with Outstanding Nonlinear Optical Properties Chem. Mater. (IF 7.2) Pub Date : 2024-09-03 Ernesto Soto, Shannon J. Lee, Andrew P. Porter, Gayatri Viswanathan, Georgiy Akopov, Nethmi Hewage, Kui Wu, Victor Trinquet, Guillaume Brunin, Geoffroy Hautier, Gian-Marco Rignanese, Aaron J. Rossini, Kirill Kovnir
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Sono-Assembly of Polyphenol–Protein Capsules for Enhanced Biocatalytic Cascades Chem. Mater. (IF 7.2) Pub Date : 2024-09-01 Xiaomiao Cui, Zhiliang Gao, Kaijie Zhao, Ning Wang, Qun Yu, Muthupandian Ashokkumar, Jingcheng Hao, Jiwei Cui
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Dual-Channel Control of Ferroelasticity in a Soft Molecular Crystal Induced by Perfluorinated Substitution Chem. Mater. (IF 7.2) Pub Date : 2024-09-02 Long-Xing Zhou, Wei-Xin Mao, Jin-Fei Lan, Xin Deng, Yan Qin, Han-Yue Zhang
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Rationalizing the Influence of Small-Molecule Dopants on Guanine Crystal Morphology Chem. Mater. (IF 7.2) Pub Date : 2024-09-01 Avital Wagner, Adam Hill, Tali Lemcoff, Eynav Livne, Noam Avtalion, Nicola Casati, Benson M. Kariuki, Ellen R. Graber, Kenneth D. M. Harris, Aurora J. Cruz-Cabeza, Benjamin A. Palmer
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Carrier-Induced Metal-to-Insulator Transition in Electrostatically Doped VO2 Chem. Mater. (IF 7.2) Pub Date : 2024-08-31 Debasish Mondal, Smruti Rekha Mahapatra, Shubham Kumar Parate, Pavan Nukala, Naga Phani B. Aetukuri
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Synthetic Organic Materials for Targeting Immunotherapies to Lymph Nodes Chem. Mater. (IF 7.2) Pub Date : 2024-08-30 Christopher J. Bridgeman, Ruochen Shen, Ryan A. McIlvaine, Camilla Edwards, Marian A. Ackun-Farmmer, Christopher M. Jewell
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Discharging of Ramsdellite MnO2 Cathode in a Lithium-Ion Battery Chem. Mater. (IF 7.2) Pub Date : 2024-08-30 Woongkyu Jee, Alexey A. Sokol, Cyril Xu, Bruno Camino, Xingfan Zhang, Scott M. Woodley
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Thermodynamic and Kinetic Properties of the Lithium–Silver System Chem. Mater. (IF 7.2) Pub Date : 2024-08-30 Jeremiah Thomas, Sesha Sai Behara, Anton Van der Ven
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Resorcinol–Azodianiline Covalent Organic Framework Supported FeOOH Quantum Dot-Catalyzed Electrochemical Ammonia Synthesis under Ambient Conditions Chem. Mater. (IF 7.2) Pub Date : 2024-08-29 Pragalbh Shekhar, Kento Kosugi, Himan Dev Singh, Rinku Kushwaha, Deepak Rase, Takumi Matsuzaki, Chitvan Jain, Piyush Singh, Yashraj Singh, Chathakudath Prabhakaran Vinod, Mio Kondo, Shigeyuki Masaoka, Ramanathan Vaidhyanathan
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Two-Dimensional Acid–Base Hydrogen-Bonded Organic Framework toward a Highly Conductive Proton Exchange Membrane Chem. Mater. (IF 7.2) Pub Date : 2024-08-29 Chen Wang, Zhirong Yang, Wenjia Wu, Chongchong Chen, Yifan Li, Runnan Zhang, Wenpeng Li, Kun Dai, Jingtao Wang
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Understanding the Self-Healing Electrostatic Shield Mechanism at the Lithium–Metal Anode Surface Chem. Mater. (IF 7.2) Pub Date : 2024-08-29 Samuel Bertolini, Arnaud Delcorte, Pedro Venezuela
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Unveiling the Potential of Redox Chemistry to Form Size-Tunable, High-Index Silicon Particles Chem. Mater. (IF 7.2) Pub Date : 2024-08-28 Megan A. Parker, Safa Khaddad, Nicolas Fares, Anissa Ghoridi, David Portehault, Sébastien Bonhommeau, Yacine Amarouchene, Patrick Rosa, Mathieu Gonidec, Glenna L. Drisko
Silicon particles of intermediate sizes (75–200 nm) scatter visible wavelengths, making them promising candidates for optical devices. The solution synthesis of silicon particles in this size range, however, has proved challenging for chemists over the past few decades. Here, a solution-phase synthesis provides a pathway toward reaching size tunability between 45 and 230 nm via changing the reactant
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Polymorphism within the Quasi-One-Dimensional Au2MP2 (M = Tl, Pb, Pb/Bi, and Bi) Series Chem. Mater. (IF 7.2) Pub Date : 2024-08-28 Scott B. Lee, Jonathan S. Van Buskirk, Fatmagül Katmer, Suchismita Sarker, Daniel C. Fredrickson, Leslie M. Schoop
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Atom-Knotting Enables High-Performance Intrinsically Stretchable Polymer Semiconductors Chem. Mater. (IF 7.2) Pub Date : 2024-08-28 Mingliang Zhu, Yifan Li, Chengyu Wang, Zhihao Shao, Wenkang Shi, Jinyang Chen, Zhao Yang, Yangshuang Bian, Mingcong Qin, Zhiheng Zhu, Zhiyuan Zhao, Hanlin Wang, Yunlong Guo, Yunqi Liu
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Fluoride-Ion Conduction by Synergic Rotation of the Anion Sublattice for Tl4.5SnF8.5 Analogues Chem. Mater. (IF 7.2) Pub Date : 2024-08-28 Tsuyoshi Takami, Nozomu Yasufuku, Mariia Ivonina, Tomofumi Tada, Kazuki Tani, Chanachai Pattanathummasid, Kazuhiro Mori
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Temperature-Induced Lattice Defects and Surface Reconstruction in BaTiO3 Nanocubes Chem. Mater. (IF 7.2) Pub Date : 2024-08-27 Kouichi Nakashima, Atsuya Toi, Reira Kuribara, Mikitaka Yoshida, Natsune Hasegawa, Tomoya Kobayashi, Ken Yamaguchi, Kotaro Hata
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Triple Magnetic Stacking in an Iron-Containing Cuprate with Cu–Fe–Cu Magnetic Blocks Chem. Mater. (IF 7.2) Pub Date : 2024-08-27 Sara A. López-Paz, Dita P. Sari, Jorge Sánchez-Marcos, Leandro Liborio, Simone Sturniolo, Clemens Ritter, Adrian D. Hillier, Miguel A. Alario-Franco
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Role of CeNiSi2 and BaNiSn3 Structure Types in the Emergent Magnetism of the Homologous Series Lnn+1MnX3n+1:Ce4Fe3Ge10 Chem. Mater. (IF 7.2) Pub Date : 2024-08-27 Alexis Dominguez Montero, Sebastian A. Stoian, Gregory T. McCandless, Ryan E. Baumbach, Julia Y. Chan
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Realization of Extreme Nonstoichiometry in Gadolinium Aluminate Garnets by Glass Crystallization Synthesis Chem. Mater. (IF 7.2) Pub Date : 2024-08-27 Xue Fang, Victor Castaing, Ana Isabel Becerro, Weiwei Cao, Emmanuel Veron, Didier Zanghi, Matthew S. Dyer, Cécile Genevois, Mathieu Allix, Michael J. Pitcher
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One-Step Solvothermal Synthesis of Perovskite-Type Li3xLa2/3–x□1/3–2xTiO3 Nanomaterials Chem. Mater. (IF 7.2) Pub Date : 2024-08-26 Michael A. Dato, Linhua Hu, Dan McElheny, Jordi Cabana
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Predicted High-Pressure Hot Superconductivity in Li2CaH16 and Li2CaH17 Phases that Resemble the Type-II Clathrate Structure Chem. Mater. (IF 7.2) Pub Date : 2024-08-26 Morgan Redington, Eva Zurek
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Reviewing Li-Rich Disordered Rocksalts as Next-Generation High-Energy Cathode Material Chem. Mater. (IF 7.2) Pub Date : 2024-08-21 Sayandeep Guin, Subham Ghosh, Susim Sabuj Sarkar, Urmimala Maitra
To keep up with the ever increasing demand for improved energy storage technologies, huge improvements in the capacity and energy density of intercalated cathode materials used in lithium batteries are required. Due to their crystal structure and chemistry, current layered and spinel-type cathodes can reversibly cycle only a maximum of one Li+ per formula unit (pfu). Radical improvements are needed
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Electrical Double Layers Modulate the Growth of Solid–Electrolyte Interphases† Chem. Mater. (IF 7.2) Pub Date : 2024-08-19 Jaehyeon Kim, Fujia Zhao, Lalith Krishna Samanth Bonagiri, Qian Ai, Yingjie Zhang
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Distinct Mechanical Properties and Photomechanical Response from Isostructural, yet Chemically Different Molecular Crystal Actuators Chem. Mater. (IF 7.2) Pub Date : 2024-08-24 Jiawei Lin, Jianmin Zhou, Liang Li, Ibrahim Tahir, Songgu Wu, Panče Naumov, Junbo Gong