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A focus on detection of polymorphs by dynamic nuclear polarization solid-state nuclear magnetic resonance spectroscopy Chem. Sci. (IF 8.4) Pub Date : 2023-09-28 Yunhua Chen, Jiashan Mi, Aaron J. Rossini
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General acid-mediated aminolactone formation using unactivated alkenes Chem. Sci. (IF 8.4) Pub Date : 2023-09-28 David Just, Carlos R. Gonçalves, Uroš Vezonik, Daniel Kaiser, Nuno Maulide
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A focus on computer vision for non-contact monitoring of catalyst degradation and product formation kinetics Chem. Sci. (IF 8.4) Pub Date : 2023-09-27 Niklaas J. Buurma, Scott W. Bagley
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Catalytic olefin metathesis in blood Chem. Sci. (IF 8.4) Pub Date : 2023-09-27 Igor Nasibullin, Hiromasa Yoshioka, Akari Mukaimine, Akiko Nakamura, Yuriko Kusakari, Tsung-Che Chang, Katsunori Tanaka
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Competing quantum effects in heavy-atom tunnelling through conical intersections Chem. Sci. (IF 8.4) Pub Date : 2023-09-27 Wei Fang, Eric R. Heller, Jeremy O. Richardson
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A focus on harnessing big data and artificial intelligence: revolutionizing drug discovery from traditional Chinese medicine sources Chem. Sci. (IF 8.4) Pub Date : 2023-09-26 Mingyu Li, Jian Zhang
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Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex Chem. Sci. (IF 8.4) Pub Date : 2023-09-26 Kurtis M. Carsch, Sasha C. North, Ida M. DiMucci, Andrei Iliescu, Petra Vojáčková, Thomas Khazanov, Shao-Liang Zheng, Thomas R. Cundari, Kyle M. Lancaster, Theodore A. Betley
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Correction: Improving time-resolution and sensitivity of in situ X-ray photoelectron spectroscopy of a powder catalyst by modulated excitation Chem. Sci. (IF 8.4) Pub Date : 2023-09-25 M. Roger, L. Artiglia, A. Boucly, F. Buttignol, M. Agote-Arán, J. A. van Bokhoven, O. Kröcher, D. Ferri
Correction for ‘Improving time-resolution and sensitivity of in situ X-ray photoelectron spectroscopy of a powder catalyst by modulated excitation’ by M. Roger et al., Chem. Sci., 2023, 14, 7482–7491, https://doi.org/10.1039/D3SC01274C.
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Ligand entry pathways control the chemical space recognized by GPR183 Chem. Sci. (IF 8.4) Pub Date : 2023-09-25 Viktoria Madeline Skovgaard Kjær, Tomasz Maciej Stępniewski, Brian Medel-Lacruz, Lisa Reinmuth, Marija Ciba, Elisabeth Rexen Ulven, Massimiliano Bonomi, Jana Selent, Mette Marie Rosenkilde
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A tunable family of CAAC-ruthenium olefin metathesis catalysts modularly derived from a large-scale produced ibuprofen intermediate Chem. Sci. (IF 8.4) Pub Date : 2023-09-22 Adrian Sytniczuk, Filip Struzik, Karol Grela, Anna Kajetanowicz
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On the σ-complex character of bis(gallyl)/digallane transition metal species Chem. Sci. (IF 8.4) Pub Date : 2023-09-22 Till L. Kalkuhl, Lei Qin, Lili Zhao, Gernot Frenking, Terrance J. Hadlington
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PDI–trityl dyads as photogenerated molecular spin qubit candidates Chem. Sci. (IF 8.4) Pub Date : 2023-09-22 Maximilian Mayländer, Kevin Kopp, Oliver Nolden, Michael Franz, Philipp Thielert, Andreas Vargas Jentzsch, Peter Gilch, Olav Schiemann, Sabine Richert
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Correction: Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic NiII, PdII and PtII tetrathiolate bridges Chem. Sci. (IF 8.4) Pub Date : 2023-09-21 Manuel Quiroz, Molly M. Lockart, Shan Xue, Dakota Jones, Zachary Martinez, Yisong Guo, Brad S. Pierce, Kim R. Dunbar, Michael B. Hall, Marcetta Y. Darensbourg
Correction for ‘Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic NiII, PdII and PtII tetrathiolate bridges’ by Manuel Quiroz et al., Chem. Sci., 2023, 14, 9167–9174, https://doi.org/10.1039/D3SC01546G.
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Chemodivergence in Pd-catalyzed desymmetrization of allenes: enantioselective [4+3] cycloaddition, desymmetric allenylic substitution and enynylation Chem. Sci. (IF 8.4) Pub Date : 2023-09-21 Pengfei Luo, Long Li, Xinfang Mao, Zheng Sun, Yingcheng Wang, Fangzhi Peng, Zhihui Shao
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A cell-active cyclic peptide targeting the Nrf2/Keap1 protein–protein interaction Chem. Sci. (IF 8.4) Pub Date : 2023-09-20 Jessica Iegre, Sona Krajcovicova, Anders Gunnarsson, Lisa Wissler, Helena Käck, Anna Luchniak, Stefan Tångefjord, Frank Narjes, David R. Spring
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High and fast: NMR protein–proton side-chain assignments at 160 kHz and 1.2 GHz Chem. Sci. (IF 8.4) Pub Date : 2023-09-20 Morgane Callon, Dominique Luder, Alexander A. Malär, Thomas Wiegand, Václav Římal, Lauriane Lecoq, Anja Böckmann, Ago Samoson, Beat H. Meier
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Rare-earth hydroxide/MXene hybrid: a promising agent for near-infrared photothermy and magnetic resonance imaging Chem. Sci. (IF 8.4) Pub Date : 2023-09-20 Mingjun Bai, Linawati Sutrisno, Junhong Duan, Hao Wan, Gen Chen, Xiaohe Liu, Renzhi Ma
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π-Extended benzo[1,2:4,5]di[7]annulene bis(dicarboximide)s – a new class of non-alternant polycyclic aromatic dicarboximides Chem. Sci. (IF 8.4) Pub Date : 2023-09-20 Jonas Spengler, Chongwei Zhu, Kazutaka Shoyama, Frank Würthner
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Directing group assisted para-selective C–H alkynylation of unbiased arenes enabled by rhodium catalysis Chem. Sci. (IF 8.4) Pub Date : 2023-09-20 Uttam Dutta, Gaurav Prakash, Kirti Devi, Kongkona Borah, Xinglong Zhang, Debabrata Maiti
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Photo-caged 2-butene-1,4-dial as an efficient, target-specific photo-crosslinker for covalent trapping of DNA-binding proteins Chem. Sci. (IF 8.4) Pub Date : 2023-09-19 Jiahui Li, Zenghui Cui, Chaochao Fan, Yifei Zhou, Mengtian Ren, Chuanzheng Zhou
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Greater transferability and accuracy of norm-conserving pseudopotentials using nonlinear core corrections Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Wan-Lu Li, Kaixuan Chen, Elliot Rossomme, Martin Head-Gordon, Teresa Head-Gordon
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Rh(III)-catalyzed highly site- and regio-selective alkenyl C–H activation/annulation of 4-amino-2-quinolones with alkynes via reversible alkyne insertion Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Naohiro Hirako, Takeshi Yasui, Yoshihiko Yamamoto
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Supramolecular alternating copolymers with highly efficient fluorescence resonance energy transfer Chem. Sci. (IF 8.4) Pub Date : 2023-09-19 Anwesha Chakraborty, Pradipta Kumar Das, Biman Jana, Suhrit Ghosh
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Asymmetric Friedel−Crafts reaction of unsaturated carbonyl-tethered heteroarenes via vinylogous activation of Pd0-π-Lewis base catalysis Chem. Sci. (IF 8.4) Pub Date : 2023-09-19 Bo Jiang, Wu-Tao Gui, Hao-Tian Wang, Ke Xie, Zhi-Chao Chen, Lei Zhu, Qin Ouyang, Wei Du, Ying-Chun Chen
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Evolutionary adaptation from hydrolytic to oxygenolytic catalysis at the α/β-hydrolase fold Chem. Sci. (IF 8.4) Pub Date : 2023-09-18 Soi Bui, Sara Gil-Guerrero, Peter van der Linden, Philippe Carpentier, Matteo Ceccarelli, Pablo G. Jambrina, Roberto A. Steiner
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Post-synthetic benzylation of the mRNA 5′ cap via enzymatic cascade reactions Chem. Sci. (IF 8.4) Pub Date : 2023-09-18 N. V. Cornelissen, R. Mineikaitė, M. Erguven, N. Muthmann, A. Peters, A. Bartels, A. Rentmeister
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Dimerization of confined Brønsted acids in enantioselective organocatalytic reactions Chem. Sci. (IF 8.4) Pub Date : 2023-09-18 Ingolf Harden, Frank Neese, Giovanni Bistoni
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Metal-coding assisted serological multi-omics profiling deciphers the role of selenium in COVID-19 immunity Chem. Sci. (IF 8.4) Pub Date : 2023-09-18 Ying Zhou, Shuofeng Yuan, Fan Xiao, Hongyan Li, Ziwei Ye, Tianfan Cheng, Cuiting Luo, Kaiming Tang, Jianpiao Cai, Jianwen Situ, Siddharth Sridhar, Wing-Ming Chu, Anthony Raymond Tam, Hin Chu, Chi-Ming Che, Lijian Jin, Ivan Fan-Ngai Hung, Liwei Lu, Jasper Fuk-Woo Chan, Hongzhe Sun
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Direct conversion of amino acids to oxetanol bioisosteres via photoredox catalysis Chem. Sci. (IF 8.4) Pub Date : 2023-09-15 Avelyn Mae V. Delos Reyes, Christopher S. Nieves Escobar, Alberto Muñoz, Maya I. Huffman, Derek S. Tan
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Rapid prediction of full spin systems using uncertainty-aware machine learning Chem. Sci. (IF 8.4) Pub Date : 2023-09-15 Jake Williams, Eric Jonas
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Macroscopic handedness inversion of terbium coordination polymers achieved by doping homochiral ligand analogues Chem. Sci. (IF 8.4) Pub Date : 2023-09-15 Chang-Yu Wang, Jia-Ge Jia, Guo-Guo Weng, Ming-Feng Qin, Kui Xu, Li-Min Zheng
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N-Acyloxymethyl-phthalimides deliver genotoxic formaldehyde to human cells Chem. Sci. (IF 8.4) Pub Date : 2023-09-15 Vicki L. Emms, Liam A. Lewis, Lilla Beja, Natasha F. A. Bulman, Elisabete Pires, Frederick W. Muskett, James S. O. McCullagh, Lonnie. P. Swift, Peter J. McHugh, Richard J. Hopkinson
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Magainin 2-derived stapled peptides derived with the ability to deliver pDNA, mRNA, and siRNA into cells Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Motoharu Hirano, Hidetomo Yokoo, Chihiro Goto, Makoto Oba, Takashi Misawa, Yosuke Demizu
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Correction: Liquid electrolyte chemistries for solid electrolyte interphase construction on silicon and lithium-metal anodes Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Sewon Park, Saehun Kim, Jeong-A Lee, Makoto Ue, Nam-Soon Choi
Correction for ‘Liquid electrolyte chemistries for solid electrolyte interphase construction on silicon and lithium-metal anodes’ by Sewon Park et al., Chem. Sci., 2023, https://doi.org/10.1039/d3sc03514j.
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On-DNA hydroalkylation of N-vinyl heterocycles via photoinduced EDA-complex activation Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Mohammed Sharique, Bianca Matsuo, Albert Granados, Saegun Kim, Mahwish Arshad, Hyunjung Oh, Victoria E. Wu, Minxue Huang, Adam Csakai, Lisa A. Marcaurelle, Gary A. Molander
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Accessing unusual heterocycles: ring expansion of benzoborirenes by formal cycloaddition reactions Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Marvin Sindlinger, Markus Ströbele, Jörg Grunenberg, Holger F. Bettinger
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Ionomer degradation in catalyst layers of anion exchange membrane fuel cells Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Qihao Li, Meixue Hu, Chuangxin Ge, Yao Yang, Li Xiao, Lin Zhuang, Héctor D. Abruña
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Cu/Pd-catalyzed arylboration of a 1-silyl-1,3-cyclohexadiene for stereocontrolled and diverse cyclohexane/ene synthesis Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Phillip F. Crook, Alan R. Lear, Suman Das, M. Kevin Brown
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Divergent total syntheses of ITHQ-type bis-β-carboline alkaloids by regio-selective formal aza-[4 + 2] cycloaddition and late-stage C–H functionalization Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Qixuan Wang, Fusheng Guo, Jin Wang, Xiaoguang Lei
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Record release of tetramethylguanidine using a green light activated photocage for rapid synthesis of soft materials Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Kun-You Chung, Ain Uddin, Zachariah A. Page
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Peptide conjugates with polyaromatic hydrocarbons can benefit the activity of catalytic RNAs Chem. Sci. (IF 8.4) Pub Date : 2023-09-12 Kevin J. Sweeney, Tommy Le, Micaella Z. Jorge, Joan G. Schellinger, Luke J. Leman, Ulrich F. Müller
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Time-resolved enantiomer-exchange probed by using the orbital angular momentum of X-ray light Chem. Sci. (IF 8.4) Pub Date : 2023-09-11 Xiang Jiang, Yeonsig Nam, Jérémy R. Rouxel, Haiwang Yong, Shaul Mukamel
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Acyl-caged rhodamines: photo-controlled and self-calibrated generation of acetyl radicals for neural function recovery in early AD mice Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Xiao Luo, Zhonghui Zhang, Jie Wang, Xueli Wang, Yani Zhang, Jinquan Chen, Guangbo Ge, Wen Yang, Xuhong Qian, Yang Tian, Youjun Yang
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Carbon–carbon bond activation by Mg, Al, and Zn complexes Chem. Sci. (IF 8.4) Pub Date : 2023-09-14 Joseph M. Parr, Mark R. Crimmin
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The challenge of balancing model sensitivity and robustness in predicting yields: a benchmarking study of amide coupling reactions Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Zhen Liu, Yurii S. Moroz, Olexandr Isayev
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High-voltage lithium-metal batteries enabled by ethylene glycol bis(propionitrile) ether-LiNO3 synergetic additives Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Shaopeng Li, Kangsheng Huang, Langyuan Wu, Dewei Xiao, Jiang Long, Chenhui Wang, Hui Dou, Pu Chen, Xiaogang Zhang
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Hybrid bronzes: mixed-valence organic–inorganic metal oxides as a tunable material platform Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 W. Lakna N. Dayaratne, Raúl Torres-Cadena, Bennett P. Schmitt, Emma M. Westrick, Adam Jaffe
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From random to rational: improving enzyme design through electric fields, second coordination sphere interactions, and conformational dynamics Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Shobhit S. Chaturvedi, Daniel Bím, Christo Z. Christov, Anastassia N. Alexandrova
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Generative organic electronic molecular design informed by quantum chemistry Chem. Sci. (IF 8.4) Pub Date : 2023-09-13 Cheng-Han Li, Daniel P. Tabor
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Resolving a guanine-quadruplex structure in the SARS-CoV-2 genome through circular dichroism and multiscale molecular modeling Chem. Sci. (IF 8.4) Pub Date : 2023-09-11 Luisa D'Anna, Tom Miclot, Emmanuelle Bignon, Ugo Perricone, Giampaolo Barone, Antonio Monari, Alessio Terenzi
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Electron count and ligand composition influence the optical and chiroptical signatures of far-red and NIR-emissive DNA-stabilized silver nanoclusters Chem. Sci. (IF 8.4) Pub Date : 2023-09-11 Rweetuparna Guha, Anna Gonzàlez-Rosell, Malak Rafik, Nery Arevalos, Benjamin B. Katz, Stacy M. Copp
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–SR removal or –R removal? A mechanistic revisit on the puzzle of ligand etching of Au25(SR)18 nanoclusters during electrocatalysis Chem. Sci. (IF 8.4) Pub Date : 2023-09-11 Fang Sun, Lubing Qin, Zhenghua Tang, Guocheng Deng, Megalamane S. Bootharaju, Zidong Wei, Qing Tang, Taeghwan Hyeon
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Room temperature stable E,Z-diphosphenes: their isomerization, coordination, and cycloaddition chemistry Chem. Sci. (IF 8.4) Pub Date : 2023-09-11 Jieli Lin, Shihua Liu, Jie Zhang, Hansjörg Grützmacher, Cheng-Yong Su, Zhongshu Li
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Selective thiazoline peptide cyclisation compatible with mRNA display and efficient synthesis Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Minglong Liu, Richard Morewood, Ryoji Yoshisada, Mirte N. Pascha, Antonius J. P. Hopstaken, Eliza Tarcoveanu, David A. Poole, Cornelis A. M. de Haan, Christoph Nitsche, Seino A. K. Jongkees
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The rise of automated curiosity-driven discoveries in chemistry Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Latimah Bustillo, Teodoro Laino, Tiago Rodrigues
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Room temperature ionic liquids with two symmetric ions Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Daniel Rauber, Frederik Philippi, Daniel Schroeder, Bernd Morgenstern, Andrew J. P. White, Marlon Jochum, Tom Welton, Christopher W. M. Kay
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Deaminative ring contraction for the synthesis of polycyclic heteroaromatics: a concise total synthesis of toddaquinoline Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Emily K. Kirkeby, Zachary T. Schwartz, Myles A. Lovasz, Andrew G. Roberts
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Masked cerulenin enables a dual-site selective protein crosslink Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Ziran Jiang, Aochiu Chen, Jeffrey Chen, Arman Sekhon, Gordon V. Louie, Joseph P. Noel, James J. La Clair, Michael D. Burkart
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Acid–base responsive multifunctional poly(formyl sulfide)s through a facile catalyst-free click polymerization of aldehyde-activated internal diynes and dithiols Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Baixue Li, Xue Wang, Die Huang, Mingzhao Li, Anjun Qin, Yusheng Qin, Ben Zhong Tang
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Biomimetic design of an α-ketoacylphosphonium-based light-activated oxygenation auxiliary Chem. Sci. (IF 8.4) Pub Date : 2023-09-08 Ryoto Oya, Kenji Ota, Masaaki Fuki, Yasuhiro Kobori, Masahiro Higashi, Kazunori Nagao, Hirohisa Ohmiya
更新日期：2023-09-28
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