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Modular Synthesis of α-Aryl-α-Heteroaryl α-Amino Acid Derivatives via a Copper-Catalyzed Cross-Dehydrogenative-Coupling Reaction Using Air as the Sole Oxidant Org. Lett. (IF 5.2) Pub Date : 2023-09-28 Xiangxiang Kong, Jing Ren, Jinlong Li, Yu Liu, Kaizhi Li
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Boron-Assisted Cobalt-Catalyzed C–H Methylation Using CO2 and H2 Org. Lett. (IF 5.2) Pub Date : 2023-09-28 Qin Shi, Haiyan Hu, Minxing Du, Yajun Sun, Yudong Li, Yuehui Li
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Synthesis of Polysubstituted Furans via Rh(II)-Catalyzed [2 + 3] Annulation of N-Sulfonyl-1,2,3-triazoles with Enaminones Org. Lett. (IF 5.2) Pub Date : 2023-09-28 Xiaoqiang Lei, Juan Feng, Qinglan Guo, Yuanhe Li, Jiangong Shi
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Electrooxidative Fluorofunctionalization of Arylcyclopropanes Org. Lett. (IF 5.2) Pub Date : 2023-09-28 Yanni Yue, Yang Song, Shuaishuai Zhao, Chi Zhang, Chuan Zhu, Chao Feng
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Fluoride-Catalyzed Cross-Coupling of Carbamoyl Fluorides and Alkynylsilanes Org. Lett. (IF 5.2) Pub Date : 2023-09-28 Dusty Cadwallader, Dmytro Shevchuk, Tristan R. Tiburcio, Christine M. Le
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Dehalogenative Arylation of Unactivated Alkyl Halides via Electroreduction Org. Lett. (IF 5.2) Pub Date : 2023-09-28 Jinping Lan, Weijie Yu, Ke You, Mengyu Xu, Bin Zhang, Yuanquan Wang, Tao Wang, Jin Luo
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Visible-Light-Enabled Lanthanum-Mediated Intramolecular Epoxy-Ring Opening/Dehydrogenative Lactonization Org. Lett. (IF 5.2) Pub Date : 2023-09-27 Lina Cai, Qihong Lai, Lele Zhang, Guotao Xue, Yirui Zhang, Na He, Mingqiang Huang, Shirong Hu, Shunyou Cai
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Pd-Catalyzed Regioselective Hydroformylation of Olefins with HCO2H and Its Derivatives Org. Lett. (IF 5.2) Pub Date : 2023-09-27 Wenlong Ren, Jinzi Huang, Yian Shi
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Total Synthesis of a Linear Tetrasaccharide Repeating Unit of Vibrio vulnificus MO6-24 Org. Lett. (IF 5.2) Pub Date : 2023-09-27 Antara Ghosh, Suvarn S. Kulkarni
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Catalytic Enantioselective Alkylation of Aldehydes with 3-Bromooxindoles Org. Lett. (IF 5.2) Pub Date : 2023-09-27 Zhen Li, Xiao-Ming Zhang, Fu-Min Zhang, Yong-Qiang Tu
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Cobalt-Promoted Electroreductive Cross-Coupling of Prop-2-yn-1-yl Acetates with Chloro(vinyl)silanes Org. Lett. (IF 5.2) Pub Date : 2023-09-27 Chong-Hui Xu, Zhi-Qiang Xiong, Jing-Hao Qin, Xin-Hua Xu, Jin-Heng Li
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Site-Selective Nitration of Aryl Germanes at Room Temperature Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Amit Dahiya, Avetik G. Gevondian, Aymane Selmani, Franziska Schoenebeck
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Core-Labeling (Radio) Synthesis of Phenols Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Colin F. Lynch, Joseph W. Downey, Yongliang Zhang, Jacob M. Hooker, Mark D. Levin
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Fluorine-Activated and -Directed Allene Cycloadditions with Nitrile Oxides and Imine Oxides: Synthesis of Ring-Fluorinated Isoxazole Derivatives Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Kohei Fuchibe, Kazuki Sakon, Kyosuke Suto, Reo Eto, Sho Nakazono, Junji Ichikawa
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Base-Promoted Tandem Synthesis of 2-Substituted Indoles and N-Fused Polycyclic Indoles Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Fan Zhou, Huimin Jin, Yuanhang Zhang, Jie Li, Patrick J. Walsh, Shengzhang Lin
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Net Intermolecular Silyloxypyrone-Based (5+2) Cycloadditions Utilizing Amides as Enabling and Cleavable Tethers Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Susanna N. Angles, Wentao Guo, Kwabena Darko, Marymoud Erzuah, Kenneth G. Pauley, Ifeanyichukwu E. Promise, John R. Goodell, Dean J. Tantillo, T. Andrew Mitchell
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[Cp*IrCl2]2-Catalyzed Amidocarbonation of Olefins with Sulfoxonium Ylides toward Functionalized Isoindolin-1-ones Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Qi Yang, Junxue Bai, Han Yang, Yang Yao, Yingming Yao, Jianwei Sun, Song Sun
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Rh(III)-Catalyzed [3 + 2] Annulation/Pinacol Rearrangement Reaction of Enaminones with Iodonium Ylides: Direct Synthesis of 2-Spirocyclo-pyrrol-3-ones Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Mingshuai Zhang, Longkun Chen, Haifeng Sun, Zhuoyuan Liu, Sheng-Jiao Yan, Fuchao Yu
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Asymmetric Formal Coupling of β-Ketoesters with Quinones Promoted by a Chiral Bifunctional N-Heterocyclic Olefin Org. Lett. (IF 5.2) Pub Date : 2023-09-26 Sijing Wang, Jia Yang, Hongkun Zeng, Yuqiao Zhou, Fei Wang, Xiaoming Feng, Shunxi Dong
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Hard–Soft Cooperativity of an Allosteric Tweezer Org. Lett. (IF 5.2) Pub Date : 2023-09-25 Suk-il Kang, Hyun Lee, Sungryul Bae, Dongwhan Lee
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Synthesis of α-Hydroxyl and α-Amino Pyridinyl Esters via Photoreductive Dual Radical Cross-Coupling Org. Lett. (IF 5.2) Pub Date : 2023-09-25 Xian-Chao Cui, Hu Zhang, Hao Zhang, Yi-Ping Wang, Jian-Ping Qu, Yan-Biao Kang
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Synthesis of Tetrasubstituted 1,4-Dicarbonyl (Z)-2,3-Dihaloalkenes via Electrophilic Halogenation of Alkynyl Hydrazones Org. Lett. (IF 5.2) Pub Date : 2023-09-25 Akashdeep Sharma, Paru Jamwal, Ramani Gurubrahamam
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Construction of Highly Functionalized C4-Oxyacylated and Aminated Pyrazolines Org. Lett. (IF 5.2) Pub Date : 2023-09-25 Vikram Singh, Bal Krishna Mishra, Deepak Kumar, Bhoopendra Tiwari
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Rh(III)-Catalyzed C–H Activation of Benzamides and Chemodivergent Annulation with Benzoxazinanones: Substrate Controlled Selectivity Org. Lett. (IF 5.2) Pub Date : 2023-09-25 Danqing Ji, Xingwei Li
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Synthesis of (±)-Angustatin A: Assembly of the Phenanthrene Moiety Despite Increasing Ring Strain Org. Lett. (IF 5.2) Pub Date : 2023-09-25 Hoang D. Doan, Christian Rugen, Christopher Golz, Manuel Alcarazo
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Correction to “Regioselective Synthesis of Highly Functionalized Pyrazoles from N-Tosylhydrazones” Org. Lett. (IF 5.2) Pub Date : 2023-09-21 Qian Zhang, Meng Tang
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C(sp)–C(sp3) Bond Formation through Ligand- and Additive-Free CuO-Mediated Decarboxylative Direct Cross-Coupling of Coumarin-/Chromone-3-carboxylic Acids and Terminal Alkynes Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Anindita Bhowmick, Goutam Brahmachari
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Influence of Ring Strain on the Formation of Rearrangement vs Cyclization Isotwistane Products in the Acyl Radical Reaction of Bicyclo[2.2.2]octanone Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Chih-Ming Chen, Sheng-Kuo Lin, Chi-Tien Hsieh, Julakanti Satyanarayana Reddy, Yi Ning Teoh, Mu-Jeng Cheng, Hsing-Pang Hsieh
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Engineering of Dual-Function Vitreoscilla Hemoglobin: A One-Pot Strategy for the Synthesis of Unnatural α-Amino Acids Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Fengxi Li, Yaning Xu, Yuelin Xu, Hanqing Xie, Junhao Wu, Chunyu Wang, Zhengqiang Li, Zhi Wang, Lei Wang
Despite a well-developed and growing body of work on the directed evolution of hemoproteins, the potential of hemoproteins to catalyze non-natural reactions remains underexplored. This paper reports a new biocatalytic strategy for the one-pot synthesis of unnatural α-amino acids. Engineered variants of dual-function Vitreoscilla hemoglobin were found to efficiently catalyze N–H insertion and C–H sp3
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β-l-Rhamnosylation and β-d-Mannosylation Mediated by 4-O-Ester Groups in a Weakly Nucleophilic Environment Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Yongliang Zhang, Changsheng Chen, Yongtao Gao, Min Yang, Zehuan He, Bangzhi Zhang, Guofeng Gu, Bencan Tang, Feng Cai
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Divergent Synthesis of Pyrazolo[1,5-a]pyridines and Imidazo[1,5-a]pyridines via Reagent-Controlled Cleavage of the C–N or C–C Azirine Bond in 2-Pyridylazirines Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Anastasiya V. Agafonova, Artem A. Golubev, Ilia A. Smetanin, Alexander F. Khlebnikov, Dar’ya V. Spiridonova, Mikhail S. Novikov
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Visible-Light-Promoted Aryl Cation Formation: Aromatic SN1 Reactions of Areneazo-2-(2-nitro)propanes Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Dilip V. Patil, Karu Ramesh, Hun Young Kim, Kyungsoo Oh
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DABCO-Catalyzed DMSO-Promoted Sulfurative 1,2-Diamination of Phenylacetylenes with Elemental Sulfur and o-Phenylenediamines: Access to Quinoxaline-2-thiones Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Thi Minh Chau Tran, Nang Duy Lai, Thai Thanh Thu Bui, Dinh Hung Mac, Thi Thu Tram Nguyen, Pascal Retailleau, Thanh Binh Nguyen
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Retraction of: Ruthenium-Catalyzed Brook Rearrangement Involved Domino Sequence Enabled by Acylsilane–Aldehyde Corporation Org. Lett. (IF 5.2) Pub Date : 2023-09-22 Xiunan Lu, Jian Zhang, Liangyao Xu, Wenzhou Shen, Feifei Yu, Liyuan Ding, Guofu Zhong
The authors retract this article after attempts to reproduce the work show that the compounds are silyl indenes, not siloxy indenes. Errors were made in high-resolution mass spectrometry analysis, which has been confirmed by a crystal structure of compound 3aa (CCDC 2285656). The alkylation/carbocyclization/Brook rearrangement proposed in the Letter has not been achieved. The original letter was published
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Synthetically Useful Transformations of Olefins via Cationic 1,2-Oxazetium Intermediates Org. Lett. (IF 5.2) Pub Date : 2023-09-21 G. Sudhakar Reddy, E. J. Corey
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Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines Org. Lett. (IF 5.2) Pub Date : 2023-09-21 Yifeng Guo, Zhe Zhuang, Xiaoying Feng, Quanyu Ma, Ningning Li, Chaochao Jin, Hiroto Yoshida, Jiajing Tan
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Photocatalytic C–C Bond Cleavage and Fluorosulfonylation of Strained Cycloalkanols for Carbonyl-Containing Aliphatic Sulfonyl Fluorides Org. Lett. (IF 5.2) Pub Date : 2023-09-20 Zhi-Min Yan, Lin Qi, Hui-Jie Du, Zi-Qiang Zhao, Jia-Li Liu, Yi-Chen Dong, Wei Li, Li-Jing Wang
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Divergent Trideuteromethylthiolation and Aminotrideuteromethylthiolation of Alkenes with N-Fluorobenzenesulfonimide and CD3SSO3Na Org. Lett. (IF 5.2) Pub Date : 2023-09-21 Wenting Wang, Lin Zhao, Hui Wu, Youqing He, Ge Wu
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Cobalt(II)-Catalyzed Enantioselective Propargyl Claisen Rearrangement: Access to Allenyl-Substituted Quaternary β-Ketoesters Org. Lett. (IF 5.2) Pub Date : 2023-09-21 Ya-Ping Wang, Xing-Ping Zhang, Ming-Sheng Xie, Hai-Ming Guo
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Iodide-Dependent Selective Dehydroaromatization Affording Maleimide-Fused 9,10-Phenanthrenes and Their Analogues Org. Lett. (IF 5.2) Pub Date : 2023-09-21 Shuowen Wang, Zhuohao Chen, Shanping Chen, Wen Shao, Ya Chen, Guo-Jun Deng
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Correction to “Brominated B1-Polycyclic Aromatic Hydrocarbons for the Synthesis of Deep-Red to Near-Infrared Delayed Fluorescence Emitters” Org. Lett. (IF 5.2) Pub Date : 2023-09-19 Kang Yuan, Abhishek Kumar Gupta, Changfeng Si, Marina Uzelac, Eli Zysman-Colman, Michael James Ingleson
A Data Availability Statement is added to include the data underpinning the calculations and photophysics described in this paper. The research data supporting this publication can be accessed at 10.17630/fd1c4863-0606-4595-9c89-f40ef45fef4d. This article has not yet been cited by other publications.
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Hydrazine Hydrate in Asymmetric Synthesis: A Bifunctional Squaramide Catalytic Approach toward Fused Pyrazolines Org. Lett. (IF 5.2) Pub Date : 2023-09-20 Dipankar Das, Chandan Kamilya, Prasanta Ghorai
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Stereoselective Synthesis of α-Disubstituted β-Homoprolines Org. Lett. (IF 5.2) Pub Date : 2023-09-20 Arianna Quintavalla, Davide Carboni, Maria Simeone, Marco Lombardo
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Nickel/Titanocene-Catalyzed Electrophilic Acylation Coupling of Styrene Oxides Org. Lett. (IF 5.2) Pub Date : 2023-09-19 Jincan Li, Chang Cao, Haihong Wu, Kaiwu Dong
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Total Synthesis of Guajavadimer A via Lewis Acid-Catalyzed Cascade Double Hetero-Diels–Alder Reactions Org. Lett. (IF 5.2) Pub Date : 2023-09-19 Shengfu Duan, Xing Zhang, Xiangxin Li, Zhiyong Chi, Zhixiang Xie
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Visible-Light-Induced, Catalyst-Free Monofluoromethyl Sulfonylation of Alkenes with Iodine(III) Reagent and DABSO Org. Lett. (IF 5.2) Pub Date : 2023-09-19 Zhi-Peng Ye, Jing-Song Yang, Si-Jia Yang, Meng Guo, Chu-Ping Yuan, Yong-Qing Ye, Hong-Bin Chen, Hao-Yue Xiang, Kai Chen, Hua Yang
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Chiral-Boron-Complex Catalyzed Asymmetric Inverse-Electron-Demand Aza-Diels–Alder Reaction of β-Trifluoromethyl α,β-Unsaturated Ketones with Cyclic N-Sulfonyl Ketimines Org. Lett. (IF 5.2) Pub Date : 2023-09-18 Guo-Li Chai, Xiao Wang, Ya-Jing Hou, Wen-Hui Ren, Junbiao Chang
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Organoelectrophotocatalytic Generation of Acyl Radicals from Formamides and Aldehydes: Access to Acylated 3-CF3-2-Oxindoles Org. Lett. (IF 5.2) Pub Date : 2023-09-18 Hong He, Qinhui Wan, Zhong-Wei Hou, Quan Zhou, Lei Wang
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Cobalt’s Dual Role in Promoting C3-Glycosylation of Indoles: Unraveling Mechanistic Insights Org. Lett. (IF 5.2) Pub Date : 2023-09-18 Qiu-Qi Mu, Ao-Xin Guo, Xin Cai, Yang-Yang Qin, Xing-Le Liu, Fang-Zhen Ye, Hui-Jie Yang, Xiong Xiao, Xue-Wei Liu
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Divergent Synthesis of Trifluoromethyl-Substituted 1,2-Dihydroquinoxalines and Diimines by Cascade Reactions of CF3–Imidoyl Sulfoxonium Ylides with Azo Compounds Org. Lett. (IF 5.2) Pub Date : 2023-09-18 Guangming Wei, Dongling Zheng, Chen Li, Zhengkai Chen, Xiao-Feng Wu
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Catalytic Asymmetric Reverse Prenylation of Indol-2-one Enabled a Synthesis of (−)-Debromoflustramine A Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Yi Hou, Jiyou Huo, Ruoxin Li, Jun Hou, Pan Lei, Hongbo Wei, Weiqing Xie
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Pd-Catalyzed Regioselective (Markovnikov) Addition of Aryl Boronic Acids to Terminal Alkynes of 1,3-Dicarbonyl Compounds and Cyclization/Debenzoylation of Olefinic Dicarbonyl: Access to Arylated Pyran and (E)-4-Methylene-1,6-diphenylhex-5-en-1-one Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Jivan Shinde, Veerababurao Kavala, Ching-Fa Yao
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Amine-Directed Regioselective Pyridyl Csp2–H Aminovinylation Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Zhongfeng Luo, Chengjie Wang, Huanfeng Jiang, Wei Zeng
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Nickel-Catalyzed Asymmetric Decarboxyarylation with NHP Esters of α-Amino Acid to Chiral Benzylamines Org. Lett. (IF 5.2) Pub Date : 2023-09-14 Cheng-Yu Wang, Yu-Ling Huang, Wei-Cheng Xu, Qian Gao, Peng Liu, Yu-Xiang Bi, Guo-Kai Liu, Xi-Sheng Wang
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Experimental and Theoretical Studies on Cobalt-Catalyzed Regioselective Hydrosilylation of Tetrafluorinated Cyclohexa-1,3-dienes Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Kento Nagai, Suguru Morishitabara, Yuji Nishi, Chihiro Kajimoto, Motohiro Yasui, Takashi Yumura, Shigeyuki Yamada, Tsutomu Konno
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Synthesis of Multisubstituted Aromatics via 3-Triazenylarynes Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Jumpei Taguchi, Takumi Okuyama, Satomi Tomita, Takashi Niwa, Takamitsu Hosoya
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Nickel-Catalyzed Metathesis between Carboxylic Acids and Thioesters: A Direct Access to Thioesters Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Qiumin Xie, Anhui Wei, Ziding Liu, Qian Yan, Xiuli Zhang, Bao Gao
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Enantioselective C–H Arylation for Axially Chiral Heterobiaryls Org. Lett. (IF 5.2) Pub Date : 2023-09-14 Ziyue Liu, Ben Gao, Konstantin Chernichenko, He Yang, Sébastien Lemaire, Wenjun Tang
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Chemoselective Methods for Labeling and Modification of Peptides and Proteins Org. Lett. (IF 5.2) Pub Date : 2023-09-15 Margaret A. Brimble, Lutz Ackermann, Yan-Mei Li, Monika Raj
Research in peptide and protein modification originated in the early 20th century with the groundbreaking work of chemists such as Emil Fischer and Robert Robinson. Their contributions were pivotal in elucidating the structure, reactivity, and synthesis of peptides, establishing the fundamental principles that have shaped subsequent advancements. These early explorations not only laid the foundation
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Double Bond Geometric Isomers of Pentaketide Ansamycins from Streptomyces sp. S008 Org. Lett. (IF 5.2) Pub Date : 2023-09-14 Shengliang Zhao, Chunhua Lu, Haoxin Wang, Yaoyao Li, Yuemao Shen