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Biological Polymers: Evolution, Function, and Significance Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-05 Kavita Matange, Eliav Marland, Moran Frenkel-Pinter, Loren Dean Williams
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Near-Infrared-II Fluorescent Probes for Analytical Applications: From In Vitro Detection to In Vivo Imaging Monitoring Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-05 Sha Liu, Wenhong Dong, Hui-quan Gao, Zhaorui Song, Zhen Cheng
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Microfluidics-Assembled Nanovesicles for Nucleic Acid Delivery Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-04 Xuanyu Li, Zhiliang Qin, Saijie Wang, Lingmin Zhang, Xingyu Jiang
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Catalytic Hydrogenolysis of Lignin into Serviceable Products. Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-05 Shuizhong Wang,Xiancheng Li,Rumin Ma,Guoyong Song
ConspectusLignin, a major component of lignocellulosic biomass, accounts for nearly 30% of organic carbon on Earth, making it the most abundant renewable source of aromatic carbon. The valorization of lignin beyond low-value heat and power has been one of the foremost challenges for a long time. On the other hand, aromatic compounds, constituting a substantial segment of the chemical industry and projected
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Physical Phenomena in Porous Frameworks Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-04 Thomas Heine, Mircea Dinca, Guangshan Zhou
Porous materials are characterized by a high internal surface area and significant pore volume. Natural examples, such as microporous zeolites, have been known to humanity since ancient times, but their systematic investigation only started in the 1930s and flourished with the discovery of synthetic zeolites and their critical role in modern catalysis, molecular sieving, and ion exchange. The broader
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Indirect Construction of Chiral Metal–Organic Frameworks for Enantioselective Luminescence Sensing Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-02 Zongsu Han, Kun-Yu Wang, Mengmeng Wang, Wei Shi
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Dibenzothiophenium Salts: Practical Alternatives to Hypervalent I(III)-Based Reagents Acc. Chem. Res. (IF 16.4) Pub Date : 2025-02-02 Manuel Alcarazo
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Dirhodium-Catalyzed Asymmetric Transformations of Alkynes via Carbene Intermediates Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-31 Rui Wu, Zurong Xu, Dong Zhu, Shifa Zhu
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Strategies and Prospects for Engineering a Stable Zn Metal Battery: Cathode, Anode, and Electrolyte Perspectives Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-29 Kang Zhou, Xiaomeng Yu, Xiaoli Dong, Ziyang Guo, Yonggang Wang
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Aerolysin Nanopore Electrochemistry Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-28 Jun-Ge Li, Yi-Lun Ying, Yi-Tao Long
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Skeletal Editing through Cycloaddition and Subsequent Cycloreversion Reactions Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-28 Pengwei Xu, Armido Studer
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Heterogeneous Frustrated Lewis Pair Catalysts: Rational Structure Design and Mechanistic Elucidation Based on Intrinsic Properties of Supports Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-28 Jiasi Li, Guangchao Li, Shik Chi Edman Tsang
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Symmetry Breaking: Case Studies with Organic Cage-Racemates Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-28 Chenhao Chen, Shaodong Zhang
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Computational Modeling of Electrocatalysts for CO2 Reduction: Probing the Role of Primary, Secondary, and Outer Coordination Spheres Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-27 Christina M. Zeng, Julien A. Panetier
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Development of PFAS-Free Locally Concentrated Ionic Liquid Electrolytes for High-Energy Lithium and Aluminum Metal Batteries Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-26 Xu Liu, Cheng Xu, Henry Adenusi, Yuping Wu, Stefano Passerini
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Elucidating the Origins of High Capacity in Iron-Based Conversion Materials: Benefit of Complementary Advanced Characterization toward Mechanistic Understanding Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-24 Ryan C. Hill, Kenneth J. Takeuchi
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Crystalline Covalent Triazine Frameworks and 2D Triazine Polymers: Synthesis and Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-24 Yumei Ren, Shuai Yang, Yuxi Xu
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Catalytic Asymmetric Dehydrogenative Si–H/X–H Coupling toward Si-Stereogenic Silanes Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-22 Yicong Ge, Jie Ke, Chuan He
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Bistable Functions and Signaling Motifs in Systems Chemistry: Taking the Next Step Toward Synthetic Cells Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-22 Indrajit Maity, Nathaniel Wagner, Dharm Dev, Gonen Ashkenasy
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Exploring Singlet Carbyne Anions and Related Low-Valent Carbon Species Utilizing a Cyclic Phosphino Substituent Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-22 Chaopeng Hu, Xin-Feng Wang, Chenyang Hu, Rui Wei, Hongyu Wang, Liu Leo Liu
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Using NMR Spectroscopy to Evaluate Metal–Ligand Bond Covalency for the f Elements Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-22 Trevor W. Hayton, Jochen Autschbach
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Self-Assembling Peptides, Conjugates, and Mimics: A Versatile Platform for Materials and Beyond Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-21 Honggang Cui, Matthew Tirrell
Peptides are fundamental components of biological systems that are also readily synthesized chemically. Alongside polypeptides, proteins, and their mimics, peptides have emerged over the past few decades as versatile and indispensable molecular building blocks for creating myriad functional materials. While early studies on peptide assembly focused primarily on their pathological roles, such as the
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Recent Advances in Asymmetric Organometallic Electrochemical Synthesis (AOES) Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-19 Cong Ma, Jian-Feng Guo, Shi-Shuo Xu, Tian-Sheng Mei
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Homo-Mannich Reaction of Cyclopropanols: A Versatile Tool for Natural Product Synthesis Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-17 Tao Zhou, Qiuyuan Tan, Dan Jiang, Ling He, Min Zhang
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Photochromic Sodalites: From Natural Minerals to Advanced Applied Materials Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-16 Tangui Le Bahers, Mika Lastusaari, Mark Weller, Henrik Friis, Ludo van Goethem
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Nanoscale Structure and Interfacial Electrochemical Reactivity of Moiré-Engineered Atomic Layers Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-16 Madeline Van Winkle, Kaidi Zhang, D. Kwabena Bediako
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Adjustment of Molecular Sorption Equilibrium on Catalyst Surface for Boosting Catalysis Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-15 Hai Wang, Hangjie Li, Jindi Duan, Liang Wang, Feng-Shou Xiao
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Unraveling the Meaning of Effective Uptake Coefficients in Multiphase and Aerosol Chemistry Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-13 Ryan S. Reynolds, Kevin R. Wilson
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Molecular Photoelectrocatalysis for Radical Reactions Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-13 Peng Xiong, Hai-Chao Xu
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Ion Networks in Water-based Li-ion Battery Electrolytes Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-11 Kyungwon Kwak, Jonggu Jeon, So Yeon Chun, Minhaeng Cho
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Selecting Initial Conditions for Trajectory-Based Nonadiabatic Simulations Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-09 Jiří Janoš, Petr Slavíček, Basile F. E. Curchod
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Correction to “Tuning Reactive Crystallization Pathways for Integrated CO2 Capture, Conversion, and Storage via Mineralization” Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-09 Prince Ochonma, Xun Gao, Greeshma Gadikota
The Conflict of Interest statement and additional Acknowledgments have been added as shown below. In Table 1, the Pb content is 24.8 ppm. The authors are also very grateful to Hassnain Asgar for the discussions on reactive carbon dioxide capture and mineralization and metal recovery. This article has not yet been cited by other publications.
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Sequence-Defined DNA Polymers: New Tools for DNA Nanotechnology and Nucleic Acid Therapy Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-08 Muhammad Ghufran Rafique, Quentin Laurent, Michael D. Dore, Hassan H. Fakih, Tuan Trinh, Felix J. Rizzuto, Hanadi F. Sleiman
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Biocompatible 2D Material Inks Enabled by Supramolecular Chemistry: From Synthesis to Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-08 Khaled Parvez, Cinzia Casiraghi
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Tripodal Triptycenes as a Versatile Building Block for Highly Ordered Molecular Films and Self-Assembled Monolayers Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-07 Michael Zharnikov, Yoshiaki Shoji, Takanori Fukushima
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Visible-Light-Fueled Polymerizations for 3D Printing Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-06 Lynn M. Stevens, Nirvana T. Almada, Hyeong Seok Kim, Zachariah A. Page
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Mass Spectrometry-Based Protein Footprinting for Protein Structure Characterization Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-05 Ming Cheng, Michael L. Gross
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Intermediate Control: Unlocking Hitherto Unknown Reactivity and Selectivity in N-Conjugated Allenes and Alkynes Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-03 Tapas R. Pradhan, Jin Kyoon Park
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Rare Earth Complex-Based Functional Materials: From Molecular Design and Performance Regulation to Unique Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-02 Pingru Su, Fujia Song, Jing Cao, Chun-Hua Yan, Yu Tang
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Expanding Horizons in Quantum Chemical Studies: The Versatile Power of MRSF-TDDFT Acc. Chem. Res. (IF 16.4) Pub Date : 2025-01-01 Seunghoon Lee, Woojin Park, Cheol Ho Choi
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Reactivity of Anomalous Aziridines for Versatile Access to High Fsp3 Amine Chemical Space Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-30 Elijah T. Marris, Daniel S. Rampon, Jennifer M. Schomaker
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Thermodynamics and Modeling of Collective Effects in the Organic Ligand Shell of Colloidal Quantum Dots Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-30 Jason J. Calvin, Amanda S. Brewer, A. Paul Alivisatos
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Organic Iono-Optoelectronics: From Electrochromics to Artificial Retina Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-25 Ke Chen, Inho Song, Liyan You, Jianguo Mei
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Development of New Methods of Studying Catalyst and Materials Surfaces with Ambient Pressure Photoelectron Spectroscopy Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-23 Franklin Tao
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Do-Nothing Prebiotic Chemistry: Chemical Kinetics as a Window into Prebiotic Plausibility Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-19 Skyla B. White, Paul B. Rimmer
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Transforming Highly Oxidized and Reduced Carbon Feedstocks: Strategies for Catalytic CO2 and CH4 Valorization Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-17 Nilay Hazari, Hannah S. Shafaat, Jenny Y. Yang
Carbon is a ubiquitous element in society as a critical component of materials, medicines, commodity chemicals, and fuels. A primary reason for the broad utility of carbon-containing compounds is the redox and chemical versatility of carbon. Remarkably, a carbon atom can span 9 oxidation states (+4 to −4), with fuels typically consisting of highly reduced carbon-based compounds (−1 to −4), (1) biological
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From the Chemistry of Life’s Emergence to the Chemistry of Life Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-17 Claudia Bonfio, Martina Preiner
Enzymes catalyze cellular chemistry, ultimately enabling life to exist. They are complex and specialized protein catalysts formed by millions of years of evolution. In modern cells, enzymes, and the metabolic reactions accelerated by them, are often localized within highly specialized and organized membrane-bound or membrane-less cellular compartments. In short, catalysis and compartmentalization are
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Use of Intramolecular Quinol Redox Couples to Facilitate the Catalytic Transformation of O2 and O2-Derived Species Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-17 Byron H. Farnum, Christian R. Goldsmith
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Lipid Trafficking in Diverse Bacteria Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-16 Jonathan Chiu-Chun Chou, Laura M. K. Dassama
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Triftosylhydrazone in Single-Atom Skeletal Editing Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-16 Zhaohong Liu, Xiaolong Zhang, Paramasivam Sivaguru, Xihe Bi
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Space Exploration of Metal–Organic Frameworks in the Mesopore Regime Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-13 Gaoli Hu, Qi Liu, Hexiang Deng
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Electroreductive Cross-Coupling Reactions: Carboxylation, Deuteration, and Alkylation Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-13 Pengfei Li, Yanwei Wang, Hanying Zhao, Youai Qiu
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Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-12 Xuehua Dong, Ling Huang, Guohong Zou
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Photoresponsive Chemistries for User-Directed Hydrogel Network Modulation to Investigate Cell–Matrix Interactions Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-12 Monica L. Ohnsorg, Ella A. Hushka, Kristi S. Anseth
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N-Acyl-N-alkyl/aryl Sulfonamide Chemistry Assisted by Proximity for Modification and Covalent Inhibition of Endogenous Proteins in Living Systems Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-11 Tomonori Tamura, Itaru Hamachi
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Physics and Chemistry of Two-Dimensional Triangulene-Based Lattices Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-10 Hongde Yu, Yu Jing, Thomas Heine
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Enhancing Biocatalysis: Metal–Organic Frameworks as Multifunctional Enzyme Hosts Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-28 Fanrui Sha, Xiaoliang Wang, Kent O. Kirlikovali, Omar K. Farha
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Bioinspired Total Synthesis of Natural Products Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-27 Lijun Chen, Peng Chen, Yanxing Jia
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Controlling Hydrogen Evolution and CO2 Reduction at Transition Metal Hydrides Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-26 Andrew D. Cypcar, Jenny Y. Yang
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All-in-One CO2 Capture and Transformation: Lessons from Formylmethanofuran Dehydrogenases Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-25 Olivier N. Lemaire, Tristan Wagner