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Photocatalytic generation of alkyl carbanions from aryl alkenes Nat. Catal. (IF 42.8) Pub Date : 2024-10-23 Milena L. Czyz, Tyra H. Horngren, Andrew J. Kondopoulos, Liam J. Franov, José A. Forni, Le Nhan Pham, Michelle L. Coote, Anastasios Polyzos
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Catalytic Strategies for the Selective Synthesis of α- and β-Functionalized Amines via Hydrofunctionalization of Enamides Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Rui Sun, Xiao Yang
α- and β-functionalized amines are two classes of important compounds, whose structural units are widely present in approved drugs. The hydrofunctionalization of enamides is the most direct and efficient method for constructing these two types of compounds. The regioselectivity was the focus of this conversion, which is largely influenced by the catalytic mode. Therefore, in order to selectively synthesize
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Direct Synthesis of 3,4-Disubstituted Quinolines and 2-Acylquinolines from Amines and Epoxides Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Xueyan Lv, Shichen Li, Shuai Fang, Xiaotian Wu, Bingchuan Yang, Chen Ma
Herein, we present a protocol starting from styrene oxide reacting with o-acylaniline and o-alkenylaniline derivatives to obtain 3,4-disubstituted quinoline and 2-acylquinoline derivatives, respectively, in 32-92% yields under specific conditions. Preliminary research outcomes underscore the versatility of our approach, as exemplified by its scalability for large-scale synthesis, downstream derivatization
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Copper-Catalyzed Dearomative Cyclization of Indolyl Ynamides for Synthesis of Pentacyclic Spiroindolines Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Miao Xu, Jia-Tian Jiang, Hao-Xuan Dong, Guang-Hui Wang, Bo Zhou, Longwu Ye
The dearomatization of indoles with ynamides is a convenient access towards polycyclic spiroindolines, which can be initiated by α- and β-additions of ynamides. Currently, the related β-addition initiated dearomative cyclization requires noble-metal catalyst or stoichiometric oxidant. Herein, we report a copper-catalyzed dearomative cyclization of aryl-substituted indolyl ynamides through regioselective
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Borane-Catalyzed Selective Transformation of Levulinic Acid and Hydrazines into Hexahydropyridazines and Tetrahydropyridazin-3(2H)-ones Using Hydrosilane Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Lijin Xu, Zhenli Luo, Jianbo Yang, Ji Yang, Zhen Yao, Zhenni He, Kai Liu, Qian Shi
Abstract. Borane-catalyzed one-pot tandem cyclization/hydrosilylation of levulinic acid and other γ-ketoacids with hydrazines for selective access to hexahydropyridazines and tetrahydropyridazin-3(2H)-ones has been developed. The combination of B(C6F5)3 and Et3SiH allows for synthesis of various hexahydropyridazines and tetrahydropyridazin-3(2H)-ones in 67-97% yields with tolerance towards various
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Role of High-Valence Metal Dissolution in Oxygen Evolution Kinetics of the Advanced FeNiOx Catalysts ACS Catal. (IF 11.3) Pub Date : 2024-10-22 Jun Ke, Jiaxi Zhang, Longhai Zhang, Shunyi He, Chengzhi Zhong, Li Du, Huiyu Song, Xiaoming Fang, Zhengguo Zhang, Zhiming Cui
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Cu-Albumin Artificial Enzymes with Peroxidase and Oxidase Activity for Stereoselective Oxidations ACS Catal. (IF 11.3) Pub Date : 2024-10-22 Maham Liaqat, Emma McDonald, Robert Jervine Valdez Ortega, Aaron Lopes, Flavia Codreanu, Hannah Carlisle, Challa V. Kumar, Xudong Yao, James F. Rusling, Jie He
We herein report a design of artificial enzymes by incorporating a synthetic copper complex into noncatalytic bovine serum albumin (Cu-BSA) to carry out stereoselective oxidation. This Cu-BSA catalyst with stably bound Cu complex as a cofactor shows peroxidase-like activity to catalyze epoxidation of styrene with high chiral selectivity (>99%) to R-styrene epoxide. With the electrochemical conversion
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Merging Consecutive PET Processes within a Metal–Organic Cage for Abiotic–Biotic Combined Photocatalytic Biomass Reforming ACS Catal. (IF 11.3) Pub Date : 2024-10-22 Zhefan Li, Junkai Cai, Lingxiao Wang, Chunying Duan
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Electron-withdrawing effect of polyoxometalates in Cu(I)-based metal–organic frameworks for enhanced azide-alkyne “click” reaction J. Catal. (IF 6.5) Pub Date : 2024-10-22 Bing-Bing Lu, Ji-Qiang Guan, Yu-Tong Wu, Si-Yi An, Ying Fu, Fei Ye
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Water-Stable Perovskite Nanocrystals to Overcome the Photocatalysis–Stability Trade-Off in Aqueous Photo-RAFT Polymerization ACS Catal. (IF 11.3) Pub Date : 2024-10-22 Mengqiang Zhang, Jingyi Hao, Chengli Wang, Yue Zhang, Xiaomeng Zhang, Zhe Cui, Peng Fu, Minying Liu, Ge Shi, Xiaoguang Qiao, Yajing Chang, Yanjie He, Xinchang Pang
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Direct Detection of Key Intermediates during the Product Release in Rhenium Bipyridine-Catalyzed CO2 Reduction Reaction ACS Catal. (IF 11.3) Pub Date : 2024-10-22 Samir Chattopadhyay, Mun Hon Cheah, Reiner Lomoth, Leif Hammarström
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Virtual Ligand-Assisted Optimization: A Rational Strategy for Ligand Engineering ACS Catal. (IF 11.3) Pub Date : 2024-10-21 Wataru Matsuoka, Taihei Oki, Ren Yamada, Tomohiko Yokoyama, Shinichi Suda, Carla M. Saunders, Bastian Bjerkem Skjelstad, Yu Harabuchi, Natalie Fey, Satoru Iwata, Satoshi Maeda
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Transformative ligand effects in Fe-photocatalyzed Giese-type additions Chem Catal. (IF 11.5) Pub Date : 2024-10-22 Michael S. Crocker, Jung-Ying Lin, Reem Nsouli, Nathan D. McLaughlin, Djamaladdin G. Musaev, Aliyeh Mehranfar, Ernesto R. Lopez, Laura K.G. Ackerman-Biegasiewicz
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Fine-tuning catalytic selectivity by modulating catalyst-environment interactions: CO2 hydrogenation over Pd-based catalysts Chem Catal. (IF 11.5) Pub Date : 2024-10-22 Hong Zhang, Ping Liu
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Electrochemical CO2 fixation with amines to synthesize α-amino acids Chem Catal. (IF 11.5) Pub Date : 2024-10-22 Yimeng Cao, Jun Chen, Chunmei Ding, Ying Zhang, Haibo Chi, Yan Liu, Can Li
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Photoredox-catalysed amidyl radical insertion to bicyclo[1.1.0]butanes Nat. Catal. (IF 42.8) Pub Date : 2024-10-22 Chetan C. Chintawar, Ranjini Laskar, Debanjan Rana, Felix Schäfer, Nele Van Wyngaerden, Subhabrata Dutta, Constantin G. Daniliuc, Frank Glorius
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Dual C2 Synthon Strategy for the Synthesis of Pyrimidines: Copper‐Catalyzed Aerobic α,β‐C(sp3)‐H Bond Difunctionalization of Tertiary Alkylamines Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Ramachandra Reddy Putta, Junhwa Hong, Seung Hyun Choi, Jinwoo Lee, Honghui Lee, Seok Beom Lee, Suckchang Hong
Herein, we describe a two‐component methodology developed for the synthesis of pyrimidine derivatives using tertiary alkylamines and amidines. Tertiary alkylamines serve as dual C2 synthons through copper‐catalyzed aerobic difunctionalization of the α,β‐C(sp3)‐H bonds. The process operates under mild conditions and uses atmospheric oxygen as the oxidant. Notably, this methodology yields up to 85% and
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Stereodivergent Synthesis of Chiral Hydrobenzofuranpyrrolidines by Catalytic Asymmetric Dearomative Cyclization and Controlled Epimerization Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Wei Liu, Yeting Huang, Ziqiang Dai, Min Yu, Xuangan Liu, Weijun Yao, Xiaoyu Han
A rapid and straightforward way to access stereoisomeric sets of products bearing multiple stereogenic centers is still a significant challenge in asymmetric catalysis. We present herein our experimental studies on the stereodivergent synthesis of chiral hydrobenzofuran‐fused pyrrolidines with three stereogenic centers via organocatalytic asymmetric dearomative cyclization and epimerization process
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Investigation of AMA Synthase from Pyrenophora teres f. teres 0‐1 for the Synthesis of Aspergillomarasmine A Analogues and Non‐canonical Amino Acids Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Zhixi Zhu, Yue Ma, Xiaoying Xie, Zhiyuan Wang, Lu Han, Jingwu Song, Yuzong Liang, Gerrit Poelarends, Yijun Chen, Meiling Lu, Jielin Zhang
The fungal natural product aspergillomarasmine A (AMA) is an inhibitor of metallo‐β‐lactamases and a promising co‐drug candidate for reversing bacterial β‐lactam resistance. The biosynthesis of AMA from L‐Asp and O‐phospho‐L‐serine is catalyzed by AMA synthase, which possesses high synthetic potential for the biocatalytic preparation of AMA and related aminopolycarboxylic acids. Here, we identified
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Ruthenium(II)‐Catalyzed Pyridyl‐Directed Tryptophan C‐H Acylmethylation with α‐Chloro Ketones Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Shulei Hu, Yong Wang, Xiong Xie, Renwen Liang, Hong Liu, Jiang Wang
A ruthenium(Ⅱ)‐catalyzed C‐H acylmethylation of Trp‐containing peptides with α‐chloro ketones has been reported. This reaction features good C‐2 selectivity and chemoselectivity,making it suitable for the late‐stage modification of Trp‐containing peptides. Low‐cost metal ruthenium as a catalyst enables the reaction to be conducted on a gram scale. This report also discusses the synthetic applications
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Revisiting the Synthetic Utility of 4,5‐Dehydro[2.2]paracyclophane Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-22 Jumpei Taguchi, Yuta Omoto, Konami Uto, Hitomi Tabuchi, Hidehiro Uekusa, Takashi Niwa, Takamitsu Hosoya
4,5‐Dehydro[2.2]paracyclophane, an aryne species of [2.2]paracyclophane ([2.2]PCP) was reported more than half a century ago. However, despite its potential usefulness for preparing [2.2]PCP derivatives, this species is rarely considered in synthetic applications, probably because the efficiency of aryne generation and reaction with arynophiles are low under harsh reaction conditions of classical methods
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Bimodal mesoporous AlMCM-41 supported NiMo catalysts for efficient hydrodesulfurization of 4,6-dimethyldibenzothiophene J. Catal. (IF 6.5) Pub Date : 2024-10-19 Hao Zhang, Qing Zhang, Guang-Ren Qian, Hong Liu, Yang Yue
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Abundant interfacial and intrinsic oxygen vacancies enabling small nickel/ceria nanocrystal efficient CO2 methanation J. Catal. (IF 6.5) Pub Date : 2024-10-19 Chaoyang Yang, Junlei Zhang, Weiping Liu, Xueyi Yang, Yuwen Wang, Wanglei Wang
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Highly stable and electron-rich Ni single atom catalyst for directed electroreduction of CO2 to CO J. Catal. (IF 6.5) Pub Date : 2024-10-21 Fengwei Zhang, Jijie Li, Shuai Chen, Jingjing Li, Ruimin Zhang, Yangyang Zhao, Wen-Yan Zan, Yawei Li
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Stability of supported Pd-based ethanol oxidation reaction electrocatalysts in alkaline media J. Catal. (IF 6.5) Pub Date : 2024-10-21 Tuani C. Gentil, Maria Minichova, Valentín Briega-Martos, Victor S. Pinheiro, Felipe M. Souza, João Paulo C. Moura, Júlio César M. Silva, Bruno L. Batista, Mauro C. Santos, Serhiy Cherevko
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Anion intercalation of NiMn-LDH accelerating urea electrooxidation on trivalent nickel J. Catal. (IF 6.5) Pub Date : 2024-10-21 Qian Zheng, Yuandong Yan, Shaonan Zhang, Shicheng Yan, Zhigang Zou
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Plasmon and N-vacancy synergistically enhanced tubular carbon nitride-based S-scheme heterojunction photocatalyst with one stone five birds function: Pathways, DFT calculation and mechanism insight J. Catal. (IF 6.5) Pub Date : 2024-10-21 Feng Sun, Qian Xu, Haiyang Liu, Da Xu, Xinxing Wang, Chuan Luo, Tianqi Wang, Hui Yu, Wensheng Yu, Xiangting Dong
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Plasma-driven non-oxidative coupling of methane to ethylene and hydrogen at mild temperature over CuxO/CeO2 catalyst J. Catal. (IF 6.5) Pub Date : 2024-10-19 Rui Liu, Shangkun Li, Qian Chen, Dongxing Li, Jiasong Zhao, Chuang Li, Xiaoxia Gao, Wenping Zhao, Li Wang, Chong Peng, Annemie Bogaerts, Hongchen Guo, Yanhui Yi
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Diverse Mechanisms for the Aromatic Hydroxylation: Insights into the Mechanisms of the Coumarin Hydroxylation by CYP2A6 ACS Catal. (IF 11.3) Pub Date : 2024-10-21 Zhenjia Gan, Jianqiang Feng, Jiabin Yin, Juping Huang, Binju Wang, John Z.H. Zhang
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Copper-catalyzed 1,4-aminohydroxylation and aminothiolation of 1,3-dienes by carbonyl-assisted migration Chem Catal. (IF 11.5) Pub Date : 2024-10-21 Noah H. Watkins, Yungeun Kwon, Qiu Wang
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Modulator engineering of bifunctional metal-organic framework for synergistic catalysis Chem Catal. (IF 11.5) Pub Date : 2024-10-21 Jing Ouyang, Hongyi Tao, Zhiyi Yang, Yim Kwan Wong, Wei Shen Aik, Herman Ho-Yung Sung, Ian Williams, Yangjian Quan
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Unveiling Intrinsic Charge Transfer Dynamics in Bone-Joint S-Scheme Heterostructures To Promote Photocatalytic Hydrogen Peroxide Generation ACS Catal. (IF 11.3) Pub Date : 2024-10-21 Yuhui Liu, Xiaoxu Deng, Yi Wang, Qin Luo, Yunxia Liu, Shuang-Feng Yin, Peng Chen
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Synergistic regulation of g-C3N4 band structure by phosphorus and sodium doping to enhance photocatalytic hydrogen peroxide production efficiency J. Catal. (IF 6.5) Pub Date : 2024-10-18 Yuting Wang, Mengxiang Wang, Xuya Zhang, Xinru Pan, Yongpeng Cui, Daoqing Liu, Yajun Wang, Wenqing Yao
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1,6-Conjugate hydrogenation of para-quinone methides to phenol-containing diaryl- and triarylmethanes under atmospheric pressure catalyzed by a metal–ligand bifunctional iridium catalyst J. Catal. (IF 6.5) Pub Date : 2024-10-20 Guoqiang Zhao, Xiangchao Xu, Jin Zhang, Beixuan Dong, Wenli Wang, Wenbo Zhou, Qixun Shi, Feng Li
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Iron‐Catalyzed Reductive Coupling of Nitro Compounds with Grignard and Organozinc Reagents for Synthesis of Functionalized Secondary Amines Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-21 Takeshi Hata, Koki Nishi, Daiki Goto, Yuta Tatsumi, Shoma Kobayashi, Masayuki Shigeta, Hirokazu Urabe
The treatment of nitro compounds with Grignard reagents in the presence of a catalytic amount of FeCl2/4 t‐BuMgCl produced various types of secondary amines in good yields. This reductive coupling most likely involves the compatibility of functional groups such as chlorine, benzyl ether, olefin, and acetylene. Moreover, the corresponding poly‐substituted amines were not observed under these conditions
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Arylation of Secondary Phosphines with Diaryliodonium Salts under Metal‐Free and Non‐Photochemical Conditions Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-21 Ajit Jha, SUDEEP SARKAR, Kacper Szczepanski, Marcin Kalek
A new, efficient, as well as metal‐ and irradiation‐free approach for the direct arylation of secondary phosphines has been developed. The reaction employs diaryliodonium salts as electrophilic aryl‐transfer reagents, effecting the P–Ar bond‐formation in a single step, under mild conditions, using t‐BuOK as a base and DMSO as a solvent, at room temperature. The protocol furnishes expedient access to
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Molybdenum‐Catalyzed Direct Synthesis of Pyrroles from Nitroarenes with Glycols as Reductants Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-21 Sara Gómez Gil, Samuel Suárez-Pantiga, María R. Pedrosa, Roberto Sanz
A molybdenum‐catalyzed synthesis of N‐(hetero)aryl pyrroles directly from inexpensive and commonly available (hetero)nitroarenes via reduction with pinacol and annulation with 1,4‐dicarbonyls or cyclobutane‐1,2‐diols has been described. The process does not require an inert atmosphere and tolerates the presence of air and water. This non‐noble catalytic system shows high chemoselectivity, allowing
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Bioactive Molecules from Lignocellulose‐derived Platform Chemicals Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-21 Guorui Qiang, Mohd Farhan Ansari, Zhuohua Sun, Saravanakumar Elangovan
The ever‐increasing prevalence of diseases and inadequate resources on Earth are threats to society. Biomass is an abundant resource, and bioactive compounds produced from biomass are environmentally benign in contrast to conventional chemical synthesis methods, which frequently depend on non‐renewable resources. In addition, the functionalized monomers from biomass allow the atom economical synthesis
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Regulating the d-Band Center of Metal–Organic Frameworks for Efficient Nitrate Reduction Reaction and Zinc-Nitrate Battery ACS Catal. (IF 11.3) Pub Date : 2024-10-18 Yuanhui Yao, Xiaofei Wei, Haiqiao Zhou, Kai Wei, Bin Kui, Fangfang Wu, Liang Chen, Wei Wang, Fangna Dai, Peng Gao, Nana Wang, Wei Ye
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Water-assisted preparation of Ni/La(OH)3 catalyst for efficient catalytic C-O bond hydrogenolysis of tetrahydrofuran-dimethanol J. Catal. (IF 6.5) Pub Date : 2024-10-19 Xinyu Yao, Dong Liu, Junhong Fu, Jian Wang, Mengle Shen, Zuoyi Xiao, Qingda An, Jiahui Huang
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Artificial Peroxidase Based on the Biotin–Streptavidin Technology that Rivals the Efficiency of Natural Peroxidases ACS Catal. (IF 11.3) Pub Date : 2024-10-19 Manjistha Mukherjee, Valerie Waser, Elinor F. Morris, Nico V. Igareta, Alec H. Follmer, Roman P. Jakob, Dilbirin Üzümcü, Timm Maier, Thomas R. Ward
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Furan-Based HTCC/In2S3 Heterojunction Achieves Fast Charge Separation To Boost the Photocatalytic Generation of H2O2 in Pure Water ACS Catal. (IF 11.3) Pub Date : 2024-10-19 Xiaolong Tang, Changlin Yu, Jiaming Zhang, Kaiwei Liu, Debin Zeng, Fang Li, Feng Li, Guijun Ma, Yanbin Jiang, Yongfa Zhu
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Enantioselective Synthesis of Helically Chiral Molecules Enabled by Asymmetric Organocatalysis ACS Catal. (IF 11.3) Pub Date : 2024-10-19 Qingqin Huang, Yu-Ping Tang, Chao-Gang Zhang, Zhen Wang, Lei Dai
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Kinetics, Mechanism, and Thermodynamics of Ceria-Zirconia Reduction ACS Catal. (IF 11.3) Pub Date : 2024-10-18 Andrew Hwang, Andrew “Bean” Getsoian, Enrique Iglesia
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Production of docosahexaenoic acid through enzymatic hydrolysis of Omega-3 rich oil J. Catal. (IF 6.5) Pub Date : 2024-10-18 Ernestina García-Quinto, Raquel Aranda-Cañada, Jose M. Guisan, Gloria Fernandez-Lorente
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Electronic and geometric features controlling the reactivity of Mg-vanadate and V2O5 surfaces toward the initial C–H activation of C1–C3 alkanes – A DFT+U study J. Catal. (IF 6.5) Pub Date : 2024-10-18 Hansel Montalvo-Castro, Álvaro Loaiza-Orduz, Randall J. Meyer, Craig Plaisance, David Hibbitts
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Boosting the catalytic performance of core-shell structured Ru@Pd/SBA-15 in 2-ethyl-anthraquinone hydrogenation by tuning d-band center J. Catal. (IF 6.5) Pub Date : 2024-10-15 Yue Zhang, Rongrong Zhang, Guozhu Liu, Li Wang, Zhiyong Pan
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Electrochemically driven nonheme iron complex-catalyzed oxidation reactions using water as an oxygen source J. Catal. (IF 6.5) Pub Date : 2024-10-16 Songgang Huang, Yan Wang, Si Si, Mei Yan, Weimin Zhang, Wenhua Ji, Jie Chen, Wonwoo Nam, Bin Wang
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Leveraging Atomic-Scale Synergy for Selective CO2 Electrocatalysis to CO over CuNi Dual-Atom Catalysts ACS Catal. (IF 11.3) Pub Date : 2024-10-18 Bin Chen, Dehuan Shi, Renxia Deng, Xin Xu, Wenxia Liu, Yang Wei, Zheyuan Liu, Shenghong Zhong, Jianfeng Huang, Yan Yu
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Regulation of the Properties of Hydrogen Dissociation and Transfer in the Presence of S Atoms for Efficient Hydrogenations ACS Catal. (IF 11.3) Pub Date : 2024-10-18 Xiaoyan Liu, Mingyuan Zhang, Xin Liu, Jiali Liu, Huicong Dai, Wenhao Luo, Jian Liu, Rui Gao, Qihua Yang
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Regulating the Electrochemical Microenvironment of Ni(OH)2 by Cr Doping for Highly Efficient Methanol Electrooxidation ACS Catal. (IF 11.3) Pub Date : 2024-10-18 Hongye Qin, Yukun Ye, Guangliang Lin, Jinyang Zhang, Wenqi Jia, Wei Xia, Lifang Jiao
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Molybdenum-Catalyzed Reductive Ortho-Allylation of Nitroarenes with 1,3-Dienes ACS Catal. (IF 11.3) Pub Date : 2024-10-17 Jin-Liang Lu, Zhi Zhang, Jing-Tong Deng, Jin-Bao Peng
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P450DA Monooxygenase-Catalyzed Chemoselective and Enantiodivergent Epoxidation of Unactivated Alkenes ACS Catal. (IF 11.3) Pub Date : 2024-10-17 Jia-Jing Li, Xiao-Jian Zhou, Juan Ao, Jin-Tao Gao, An-Ni Wang, Zhuang-Lin Shen, Yang Gu, Jia-Hai Zhou, Yong-Zheng Chen
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Electrochemical Synthesis of 4‐Selenylated Oxazolones via Oxyselenylation of Ynamides Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-19 Jinhui Cai, Kaili Cen, Weishuang Li, Hongyi Lin, Haixia Zhang
Electrosynthesis of selenylated‐oxazolone derivatives via cascade selenylation/cyclization of ynamides was disclosed. A series of diaryl diselenides, dialkyl diselenides, and heteroaryl‐substituted ynamides was tolerated in this protocol and delivered 4‐selenyloxazolones in 28‐83% yield. The scale‐up reaction and the oxidation of selenylated‐oxazolones was performed to showcase the practicability of
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1,3‐Propanediol, An Exemplary Bio‐Renewable Organic Platform Chemical. Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-19 Andrew Marr
This opinionated review underlines the increasing production of 1,3‐propanediol (1,3‐PDO) by whole cell biocatalytic fermentation of biomass and highlights how production has transitioned from petrochemicals to bio‐renewables. Current uses of 1,3‐PDO are listed. Some future prospects for evolving the current technology and expanding the chemical uses of 1,3‐PDO use are discussed, with emphasis on catalytic
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Generation of Sulfamoyl Radicals via Visible‐Light Mediated Fixation of Sulfur Dioxide for the Synthesis of Sulfonamides Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-19 Thaís Rodrigues Arroio, Jan Philipp Nau, Kamil Hofman, Christoph Förster, Stephanie L. Faber, Sabine Becker, Katja Heinze, Giuliano Cesar Clososki, Georg Manolikakes
. Herein, we report a new approach for the light‐mediated generation of sulfamoyl radicals using sulfur dioxide as key building block and the direct application of these radicals in the synthesis of sulfonamides. In the presence of different photoredox catalysts, sulfamoyl radicals can be generated directly from SO2 or the SO2 surrogate DABSO (1,4‐diazabicyclo[2.2.2]octane·bis (sulfur dioxide) adduct)
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Introduction of Phosphinine Ring into Aromatic Systems via Alkyne Cyclization Adv. Synth. Catal. (IF 4.4) Pub Date : 2024-10-19 Eliška Mizerová, Martin Kos, Martin Jakubec, Marek Pavlica, Vladimír Církva, Jaroslav Zadny, Jan Storch, Tomáš Beránek
Recently developed synthetic protocols for the preparation of λ3‐phosphanaphthalenes have broadened the general scope of organophosphorus chemistry, but a versatile protocol is still missing. Here, we describe a scalable synthetic approach for the construction of various substituted phosphanaphthalenes. We have obtained 11 derivatives through rigorous study and have demonstrated the robustness of this
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Descriptors for Electrochemical CO2 Reduction in Imidazolium-Based Electrolytes ACS Catal. (IF 11.3) Pub Date : 2024-10-17 Federico Dattila, Alessia Fortunati, Federica Zammillo, Hilmar Guzmán, Núria López, Simelys Hernández
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Pore-Structure Engineering of Hierarchical β Zeolites for the Enhanced Hydrocracking of Waste Plastics to Liquid Fuels ACS Catal. (IF 11.3) Pub Date : 2024-10-17 Muhammad Usman Azam, Auguste Fernandes, Maria João Ferreira, Waheed Afzal, Inês Graça
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Boosting Enzyme Activity in Biomass Conversion by Modulating the Hydrolysis Process of Cellobiohydrolases ACS Catal. (IF 11.3) Pub Date : 2024-10-16 Han Liu, Yu Ding, Scott Mazurkewich, Wenwen Pei, Xiuxin Wei, Johan Larsbrink, Christophe Chipot, Zhangyong Hong, Wensheng Cai, Zhiyou Zong