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Vanadium-Based Cathodes for Aqueous Zinc-Ion Batteries: Mechanisms, Challenges, and Strategies Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-16 Kaiyue Zhu, Weishen Yang
Zinc-ion batteries (ZIBs) are highly promising for large-scale energy storage because of their safety, high energy/power density, low cost, and eco-friendliness. Vanadium-based compounds are attractive cathodes because of their versatile structures and multielectron redox processes (+5 to +3), leading to high capacity. Layered structures or 3-dimensional open tunnel frameworks allow easy movement of
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Kinetic Studies of CO2 Insertion into Metal–Element σ-Bonds Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-13 Nilay Hazari
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Atomic Spalling of a van der Waals Nanomembrane Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-12 Ji-Yun Moon, Sang-Hoon Bae, Jae-Hyun Lee
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Conductive Framework Materials for Chemiresistive Detection and Differentiation of Toxic Gases Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-11 Georganna Benedetto, Katherine A. Mirica
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Thinking Outside the Energetic Box: Stabilizing and Greening High-Energy Materials with Reticular Chemistry Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-12 Qi Lai, Yangyang Long, Ping Yin, Jean’ne M. Shreeve, Siping Pang
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Steric and Electronic Influence of Excited-State Decay in Cu(I) MLCT Chromophores Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-11 Felix N. Castellano, Michael C. Rosko
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Chemical Quantum Dots in Bell Laboratories Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-05 Louis Brus
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Recent Advances in Electrochemical Carboxylation with CO2 Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-03 Guo-Quan Sun, Li-Li Liao, Chuan-Kun Ran, Jian-Heng Ye, Da-Gang Yu
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From Coherence to Function: Exploring the Connection in Chemical Systems Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-02 Shahnawaz R. Rather, Gregory D. Scholes, Lin X. Chen
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The Once and Future Catalysts: How the Challenges of First-Row Transition-Metal Catalysis Grew to Become Strengths Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-03 Mary P. Watson, Daniel J. Weix
Some of the first synthetically useful metal-catalyzed reactions reported involved first-row transition metals and the complexity of their reactivity was evident even 60 years ago, but it is only recently that homogeneous catalysis with first-row transition metals has become the focus of academic research and industrial synthesis efforts. On the other hand, the development of second- and third-row
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Spin States Matter─from Fundamentals toward Synthetic Methodology Development and Drug Discovery Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-02 Claire Empel, Quoc Hoang Pham, Rene M. Koenigs
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Dynamic Chemistry of DNA-Based Nanoassemblies in Living Cells Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-30 Nachuan Song, Hongjin Li, Chi Yao, Dayong Yang
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2D Carbonaceous Materials for Molecular Transport and Functional Interfaces: Simulations and Insights Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-27 Yujing Tong, Sheng Dai, De-en Jiang
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Synthesis at the Interface of Chemistry and Biology Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-28 Peter G. Schultz
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Design of Highly Electrophilic and Stable Metal Nitrido Complexes Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-28 Jing Xiang, Huatian Shi, Wai-Lun Man, Tai-Chu Lau
Metal oxo (M═O) and nitrido (M≡N) complexes are two important classes of high-valent transition metal complexes. The use of M═O as oxidants in chemical and biological systems has been extensively investigated. Nature makes use of M═O in enzymes such as cytochrome P450 to oxidize a variety of substrates. Highly oxidizing oxo species have also been synthesized and they have been shown to oxidize organic
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Toward Accurate Photoluminescence Nanothermometry Using Rare-Earth Doped Nanoparticles for Biomedical Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-27 Miao Liu, Jinyang Liang, Fiorenzo Vetrone
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Making 2D Materials Sparkle in Energy Storage via Assembly Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-27 Yu Long, Ying Tao, Wei Lv, Quan-Hong Yang
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Toward the Use of Methyl-Coenzyme M Reductase for Methane Bioconversion Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-27 Thuc-Anh Dinh, Kylie D. Allen
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Confinement-Driven Dimethyl Ether Carbonylation in Mordenite Zeolite as an Ultramicroscopic Reactor Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-27 Wei Chen, Zhiqiang Liu, Xianfeng Yi, Anmin Zheng
The conversion of C1 molecules to methyl acetate through the carbonylation of dimethyl ether in mordenite zeolite is an appealing reaction and a crucial step in the industrial coal-to-ethanol process. Mordenite zeolite has large 12-membered-ring (12MR) channels (7.0 × 6.5 Å2) and small 8MR channels (5.7 × 2.6 Å2) connected by a side pocket (4.8 × 3.4 Å2), and this unique pore architecture supplies
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Modulation Excitation Spectroscopy: A Powerful Tool to Elucidate Active Species and Sites in Catalytic Reactions Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-26 Jakob Weyel, Leon Schumacher, Marc Ziemba, Maximilian Pfeiffer, Christian Hess
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Interplay of Phonon Directionality and Emission Polarization in Two-Dimensional Layered Metal Halide Perovskites Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-21 Roman Krahne, Miao-Ling Lin, Ping-Heng Tan
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Electron Transport over 2D Molecular Materials and Assemblies Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-20 Shu Seki, Rajendra Prasad Paitandi, Wookjin Choi, Samrat Ghosh, Takayuki Tanaka
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The Role of London Dispersion Interactions in Modern Chemistry Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-20 Stefan Grimme, Peter R. Schreiner
The intricate and subtle forces governing molecular interactions have long captivated the scientific community. This special issue of Accounts of Chemical Research highlights the efforts of several leaders in the field who have made significant strides in elucidating the profound impact of London dispersion interactions in molecular chemistry. These contributions offer fresh perspectives and innovative
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Examining the Importance of Hydrogen Bonding and Proton Transfer in Iron Porphyrin-Mediated Carbon Dioxide Upconversion Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-20 Jeffrey J. Warren
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Heavy Metal-Based Toxic Oxo-Pollutants Sequestration by Advanced Functional Porous Materials for Safe Drinking Water Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-20 Subhajit Dutta, Sahel Fajal, Sujit K. Ghosh
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Reversible Fluorescent Probes for Dynamic Imaging of Liver Ischemia-Reperfusion Injury Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-20 Wen Zhang, Jihong Liu, Ping Li, Xin Wang, Bo Tang
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Engineering the Interfacing of Molecules with 2D Transition Metal Dichalcogenides: Enhanced Multifunctional Electronics Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-19 Bin Han, Paolo Samorì
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Van der Waals Electrides Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-19 Jun Zhou, Jing-Yang You, Yi-Ming Zhao, Yuan Ping Feng, Lei Shen
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Regulating Charge Transfer in Cyanine Dyes: A Universal Methodology for Enhancing Cancer Phototherapeutic Efficacy Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-17 Xueze Zhao, Jianjun Du, Wen Sun, Jiangli Fan, Xiaojun Peng
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Friends not Foes: Exfoliation of Non-van der Waals Materials Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-16 Mulan Yang, Leslie M. Schoop
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From π-Conjugated Rods to Shape-Persistent Rings, Wheels, and Ladders: The Question of Rigidity Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-16 Sigurd Höger, John M. Lupton
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Single-Crystal Structural Analysis of 2D Metal–Organic Frameworks and Covalent Organic Frameworks by Three-Dimensional Electron Diffraction Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-15 Qichen Chen, Guojun Zhou, Zhehao Huang
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Understanding the Role of Layered Minerals in the Emergence and Preservation of Proto-Proteins and Detection of Traces of Early Life Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-14 Sarah V. Stewart, Valentina Erastova
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Materials Design and Mechanistic Understanding of Tellurium and Tellurium–Sulfur Cathodes for Rechargeable Batteries Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-13 Yue Zhang, Jian Liu
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On-Water Surface Synthesis of Two-Dimensional Polymer Membranes for Sustainable Energy Devices Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-10 Feng Ni, Zhiyong Wang, Xinliang Feng
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Correction to “Molecular Coping Mechanisms: Reprogramming tRNAs to Regulate Codon-Biased Translation of Stress Response Proteins” Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-09 Michelle M. Mitchener, Thomas J. Begley, Peter C. Dedon
The authors regret the omission of a critical source of funding for this article. We gratefully acknowledge support from the Singapore National Medical Research Council Open Fund (MOH-000645) to Prof. Kimberly Kline at Nanyang Technological Institute of Singapore and the University of Geneva. The Acknowledgments section should now as shown herein. The authors thank all past and present RNA scientists
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Carboxylate-Based Metal–Organic Framework and Coordination Polymer Glasses: Progress and Perspectives Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-09 Minhyuk Kim, Yelim Lee, Hoi Ri Moon
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Oxidative and Reductive Manipulation of C1 Resources by Bio-Inspired Molecular Catalysts to Produce Value-Added Chemicals Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-08 Tomoya Ishizuka, Takahiko Kojima
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Chemical Programming of Solubilizing, Nonequilibrium Active Droplets Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-08 Kueyoung E. Kim, Rebecca V. Balaj, Lauren D. Zarzar
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Kinetic Resolution as a General Approach to Enantioenrichment in Prebiotic Chemistry Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-08 Min Deng, Jinhan Yu, Donna G. Blackmond
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Flexible Metal–Organic Frameworks: From Local Structural Design to Functional Realization Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-08 Na Li, Jiandong Pang, Feifan Lang, Xian-He Bu
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Correction to “Quantum Chemical Interrogation of Reactions Promoted by Dirhodium Tetracarboxylate Catalysts─Mechanism, Selectivity, and Nonstatistical Dynamic Effects” Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-08 Dean J. Tantillo
The following text (in the “Setting the Stage” section) was modified to better represent the work described: In the seminal work of Taber and co-workers, extended molecular mechanics calculations were shown to be capable of reproducing the sense of diastereoselectivity for several Rh2(OAc)4 catalyzed intramolecular C–H insertion reactions.7 These computations made use of constrained distances and angles
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Advancing Electrically Conductive Metal–Organic Frameworks for Photocatalytic Energy Conversion Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-07 Xiaoyu Fang, Ji Yong Choi, Michael Stodolka, Hoai T. B. Pham, Jihye Park
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Electronic Structure and Functions of Carbon Nitride in Frontier Green Catalysis Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-06 Jingkai Lin, Wenjie Tian, Huayang Zhang, Hongqi Sun, Shaobin Wang
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Photophysics in Biomembranes: Computational Insight into the Interaction between Lipid Bilayers and Chromophores Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-06 S. Osella, S. Knippenberg
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Design of Cr-Based Molecular Electrocatalyst Systems for the CO2 Reduction Reaction Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-06 Megan E. Moberg, Charles W. Machan
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Protocellular Heme and Iron–Sulfur Clusters Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-05 Daniele Rossetto, Nemanja Cvjetan, Peter Walde, Sheref S. Mansy
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Resistive Gas Sensors Based on 2D TMDs and MXenes Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-05 Ali Mirzaei, Jin-Young Kim, Hyoun Woo Kim, Sang Sub Kim
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Borozenes: Benzene-Like Planar Aromatic Boron Clusters Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-03 Lai-Sheng Wang
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Engineering Cells for Cancer Therapy Acc. Chem. Res. (IF 16.4) Pub Date : 2024-08-02 Peixin Liu, Quanyin Hu
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Chemical Antiquity in Metabolism Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-31 Natalia Mrnjavac, Loraine Schwander, Max Brabender, William F. Martin
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Fabricating Large-Area Thin Films of 2D Conductive Metal–Organic Frameworks Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-29 Hyebeen Jeong, Geunchan Park, Jaemin Jeon, Sarah S. Park
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Reactive Carbon Capture: Cooperative and Bifunctional Adsorbent-Catalyst Materials and Process Integration for a New Carbon Economy Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-26 Khaled Baamran, Shane Lawson, Fateme Rezaei, Ali. A. Rownaghi
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Mechanism of the Terahertz Wave–MXene Interaction and Surface/Interface Chemistry of MXene for Terahertz Absorption and Shielding Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-26 Tao Zhao, Hujie Wan, Tianze Zhang, Xu Xiao
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Physicochemical Methods for the Structuring and Assembly of MOF Crystals Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-26 Tolga Zorlu, Daniel Hetey, Michael R. Reithofer, Jia Min Chin
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Modulating the Photophysical Properties of Twisted Donor–Acceptor–Donor π-Conjugated Molecules: Effect of Heteroatoms, Molecular Conformation, and Molecular Topology Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-24 Youhei Takeda
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Nucleophilic Aromatic Substitution of Halobenzenes and Phenols with Catalysis by Arenophilic π Acids Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-23 Kai Chen, Hang Shi
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Construction of Porous Aromatic Frameworks with Specifically Designed Motifs for Charge Storage and Transport Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-23 Yuyang Tian, Fengchao Cui, Zheng Bian, Xin Tao, Hengguo Wang, Ning Zhang, Guangshan Zhu
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Fullertubes: A 30-Year Story of Prediction, Experimental Validation, and Applications for a Long-Missing Family of Soluble Carbon Molecules Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-23 Steven Stevenson, Harry C. Dorn
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New Opportunities for Organic Synthesis with Superheated Flow Chemistry Acc. Chem. Res. (IF 16.4) Pub Date : 2024-07-23 Pauline Bianchi, Jean-Christophe M. Monbaliu