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Chromium Nitride Umpolung Tuned by the Locus of Oxidation J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Diego Martelino, Samyadeb Mahato, Warren VandeVen, Nicholas M. Hein, Ryan M. Clarke, Gregory A. MacNeil, Fabrice Thomas, Tim Storr
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Continuous-Flow Reactor Synthesis for Homogeneous 1 nm-Sized Extremely Small High-Entropy Alloy Nanoparticles J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Hiroki Minamihara, Kohei Kusada, Dongshuang Wu, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Loku Singgapulige Rosantha Kumara, Koji Ohara, Osami Sakata, Shogo Kawaguchi, Yoshiki Kubota, Hiroshi Kitagawa
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Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO2 Reduction Catalyzed by Iron Porphyrins J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Jeffrey S. Derrick, Matthias Loipersberger, Sepand K. Nistanaki, Aila V. Rothweiler, Martin Head-Gordon, Eva M. Nichols, Christopher J. Chang
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An Artificial Metalloenzyme Based on a Copper Heteroscorpionate Enables sp3 C–H Functionalization via Intramolecular Carbene Insertion J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Corentin Rumo, Alina Stein, Juliane Klehr, Ryo Tachibana, Alessandro Prescimone, Daniel Häussinger, Thomas R. Ward
The selective functionalization of sp3 C–H bonds is a versatile tool for the diversification of organic compounds. Combining attractive features of homogeneous and enzymatic catalysts, artificial metalloenzymes offer an ideal means to selectively modify these inert motifs. Herein, we report on a copper(I) heteroscorpionate complex embedded within streptavidin that catalyzes the intramolecular insertion
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Oxygen Vacancy-Mediated Selective C–N Coupling toward Electrocatalytic Urea Synthesis J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Xiaoxiao Wei, Xiaojian Wen, Yingying Liu, Chen Chen, Chao Xie, Dongdong Wang, Mengyi Qiu, Nihan He, Peng Zhou, Wei Chen, Jun Cheng, Hongzhen Lin, Jianfeng Jia, Xian-Zhu Fu, Shuangyin Wang
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Palladium Mediated Synthesis of Protein–Polyarene Conjugates J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Jacob Rodriguez, Heemal H. Dhanjee, Bradley L. Pentelute, Stephen L. Buchwald
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Intrinsically Re-curable Photopolymers Containing Dynamic Thiol-Michael Bonds J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Connor J. Stubbs, Anissa L. Khalfa, Viviane Chiaradia, Joshua C. Worch, Andrew P. Dove
The development of photopolymers that can be depolymerized and subsequently re-cured using the same light stimulus presents a significant technical challenge. A bio-sourced terpenoid structure, l-carvone, inspired the creation of a re-curable photopolymer in which the orthogonal reactivity of an irreversible thioether and a dynamic thiol-Michael bond enables both photopolymerization and thermally driven
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Reversible Structural Isomerization of Nature’s Water Oxidation Catalyst Prior to O–O Bond Formation J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Yu Guo, Johannes Messinger, Lars Kloo, Licheng Sun
Photosynthetic water oxidation is catalyzed by a manganese–calcium oxide cluster, which experiences five “S-states” during a light-driven reaction cycle. The unique “distorted chair”-like geometry of the Mn4CaO5(6) cluster shows structural flexibility that has been frequently proposed to involve “open” and “closed”-cubane forms from the S1 to S3 states. The isomers are interconvertible in the S1 and
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Structural Basis for Dityrosine-Mediated Inhibition of α-Synuclein Fibrillization J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Cagla Sahin, Eva Christina Østerlund, Nicklas Österlund, Joana Costeira-Paulo, Jannik Nedergaard Pedersen, Gunna Christiansen, Janni Nielsen, Anne Louise Grønnemose, Søren Kirk Amstrup, Manish K. Tiwari, R. Shyama Prasad Rao, Morten Jannik Bjerrum, Leopold L. Ilag, Michael J. Davies, Erik G. Marklund, Jan Skov Pedersen, Michael Landreh, Ian Max Møller, Thomas J. D. Jørgensen, Daniel Erik Otzen
α-Synuclein (α-Syn) is an intrinsically disordered protein which self-assembles into highly organized β-sheet structures that accumulate in plaques in brains of Parkinson’s disease patients. Oxidative stress influences α-Syn structure and self-assembly; however, the basis for this remains unclear. Here we characterize the chemical and physical effects of mild oxidation on monomeric α-Syn and its aggregation
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Inherent Minor Conformer of Bordetella Effector BteA Directs Chaperone-Mediated Unfolding J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Adi Yahalom, Hadassa Shaked, Sharon Ruthstein, Jordan H. Chill
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Ultralow-Loading Pt/Zn Hybrid Cluster in Zeolite HZSM-5 for Efficient Dehydroaromatization J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Genwei Chen, Lingzhe Fang, Tao Li, Yizhi Xiang
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Conformational Flexibility as a Tool for Enabling Site-Selective Functionalization of Unactivated sp3 C–O Bonds in Cyclic Acetals J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Ciro Romano, Laura Talavera, Enrique Gómez-Bengoa, Ruben Martin
A dual catalytic manifold that enables site-selective functionalization of unactivated sp3 C–O bonds in cyclic acetals with aryl and alkyl halides is reported. The reaction is triggered by an appropriate σ*–p orbital overlap prior to sp3 C–O cleavage, thus highlighting the importance of conformational flexibility in both reactivity and site selectivity. The protocol is characterized by its excellent
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Synergistic Stimulation of Metal–Organic Frameworks for Stable Super-cooled Liquid and Quenched Glass J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Zheng Yin, Yingbo Zhao, Shuang Wan, Jian Yang, Zhaolin Shi, Si-Xu Peng, Ming-Zhu Chen, Tian-Yi Xie, Teng-Wu Zeng, Osamu Yamamuro, Masami Nirei, Hiroshi Akiba, Yue-Biao Zhang, Hai-Bin Yu, Ming-Hua Zeng
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In Situ Mechanistic Insights for the Oxygen Reduction Reaction in Chemically Modulated Ordered Intermetallic Catalyst Promoting Complete Electron Transfer J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Soumi Mondal, Debabrata Bagchi, Mohd Riyaz, Shreya Sarkar, Ashutosh Kumar Singh, C. P. Vinod, Sebastian C. Peter
The well-known limitation of alkaline fuel cells is the slack kinetics of the cathodic half-cell reaction, the oxygen reduction reaction (ORR). Platinum, being the most active ORR catalyst, is still facing challenges due to its corrosive nature and sluggish kinetics. Many novel approaches for substituting Pt have been reported, which suffer from stability issues even after mighty modifications. Designing
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Structural Basis of Pyridostatin and Its Derivatives Specifically Binding to G-Quadruplexes J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Liu-Yi Liu, Tian-Zhu Ma, You-Liang Zeng, Wenting Liu, Zong-Wan Mao
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Ligand-Field Spectroscopy of Co(III) Complexes and the Development of a Spectrochemical Series for Low-Spin d6 Charge-Transfer Chromophores J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-24 Jonathan T. Yarranton, James K. McCusker
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Detection of Few Hydrogen Peroxide Molecules Using Self-Reporting Fluorescent Nanodiamond Quantum Sensors J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-23 Yingke Wu, Priyadharshini Balasubramanian, Zhenyu Wang, Jaime A. S. Coelho, Mateja Prslja, Reiner Siebert, Martin B. Plenio, Fedor Jelezko, Tanja Weil
Hydrogen peroxide (H2O2) plays an important role in various signal transduction pathways and regulates important cellular processes. However, monitoring and quantitatively assessing the distribution of H2O2 molecules inside living cells requires a nanoscale sensor with molecular-level sensitivity. Herein, we show the first demonstration of sub-10 nm-sized fluorescent nanodiamonds (NDs) as catalysts
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Identifying the Real Chemistry of the Synthesis and Reversible Transformation of AuCd Bimetallic Clusters J. Am. Chem. Soc. (IF 15.419) Pub Date : 2022-06-23 Huixin Xiang, Hao Yan, Jiaohu Liu, Ranran Cheng, Cong-Qiao Xu, Jun Li, Chuanhao Yao
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Graphene Hydrogels Implanted onto Carbon Cloth for Polypyrrole Electrodeposition toward High-Performance Supercapacitor Electrodes ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-22 Yu Zhang, Yan Yu, Aizhen Xu, Wen Li, Yujun Qin
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Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Carlos Yelamos, Estefania del Horno, Jesus Jover, Miguel Mena, Adrian Perez-Redondo
Reaction of [TiCp*Cl3] (Cp* = η5-C5Me5) with one equivalent of magnesium in tetrahydrofuran at room temperature affords the paramagnetic trinuclear complex [{TiCp*(μ-Cl)}3(μ3-Cl)], which reacts with dinitrogen under ambient conditions to give the diamagnetic derivative [{TiCp*(μ-Cl)}3(μ3-η1:η2:η2-N2)] and the titanium(III) dimer [{TiCp*Cl(μ-Cl)}2]. The structure of the trinuclear mixed-valence complexes
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Explaining Regio-Divergent Vinylations with Vinylbenziodoxolones Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Ester Maria Di Tommaso, Per-Ola Norrby, Berit Olofsson
Vinylbenziodoxolones have recently been identified as efficient hypervalent iodine(III) reagents for electrophilic vinylations under transition metal-free conditions. Their unique reactivity allows synthesis of either internal or terminal alkenes, depending on the nucleophile class. This paper constitutes the first mechanistic investigation of VBX vinylations, and makes use of NMR studies, deuterium
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Spontaneous Ammonia Activation Through Coordination Induced Bond Weakening in Molybdenum Complexes of a Dianionic Pentadentate Ligand Platform Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 C. Christopher Almquist, Nicole Removski, Thayalan Rajeshkumar, Benjamin Gelfand, Warren Piers, Laurent Maron
Ammonia oxidation catalyzed by molecular compounds is of current interest as a carbon free source of dihydrogen. Activation of N-H bonds through coordination to transition metal centers is a key reaction in this process. We report the substantial activation of ammonia via reaction with low valent molybdenum complexes of a diborate pentadentate ligand system. Spontaneous loss of hydrogen atoms from
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Redox-Active Crystalline Coordination Catalyst for Hybrid Electrocatalytic Full Reaction Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Sheng-Nan Sun, Long-Zhang Dong, Jia-Ru Li, Jing-Wen Shi, Jiang Liu, Yi-Rong Wang, Qing Huang, Ya-Qian Lan
Hybrid CO 2 electroreduction in which carbon dioxide reduction reaction (CO 2 RR) is coupled with a thermodynamically more favorable anodic oxidation reaction is recognized as a very important strategy to improve the total value of redox products and energy conversion efficiency. In this work, a coordination catalyst model system for hybrid electrocatalytic full reaction, including Ni 8 -TET with active
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Fast A-Site Cation Cross-exchange at Room Temperature: Single-to Double- and Triple-Cation Halide Perovskite Nanocrystals Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Clara Otero-Martínez, Muhammad Imran, Nadine J. Schrenker, Junzhi Ye, Kangyu Ji, Akshay Rao, Samuel D. Stranks, Robert L. Z. Hoye, Sara Bals, Liberato Manna, Jorge Pérez-Juste, Lakshminarayana Polavarapu
We report here fast A-site cation cross-exchange between APbX 3 perovskite nanocrystals (NCs) made of different A-cations (Cs (Cesium), FA (formamidinium), and MA (methylammonium)) at room temperature. Surprisingly, the A-cation cross-exchange proceeds as fast as the halide (X=Cl, Br, or I) exchange with the help of free A-oleate complexes present in the freshly prepared colloidal perovskite NC solutions
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Solvent-Dependent Supramolecular Host-Guest Assemblies of Platinum(II) Tweezers and a Guest System: From Discrete Molecules to High-Ordered Oligomers Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Jenny Yuk-Wa Yeung, Fred Ka-Wai Kong, Franky Ka-Wah Hau, Michael Ho-Yeung Chan, Maggie Ng, Ming-Yi Leung, Vivian W. W. Yam
A series of platinum(II) calix[4]arene-based molecular tweezers was synthesized. The studies of the host-guest association with a charge-neutral cyclometalated platinum(II) complex showed a drastic color change and the turning on of near-infrared emission resulting from Pt⋯Pt and π−π interactions. Control of the host-guest assembly process by varying the solvent composition can lead to a change from
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The Impact of Boron Hybridisation on Photocatalytic Processes Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Alessandro Marotta, Callum E. Adams, John Molloy
Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the forefront of organic synthesis resulting in the development of new technologies to access complex (non)borylated frameworks. Central to the success of this combination is control of boron hybridisation. Contingent on the photoactivation mode, boron as its neutral planar form or tetrahedral boronate can be used
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Luminescence and Length Control in Nonchelated d8-Metallosupramolecular Polymers through Metal-Metal Interactions Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Jonas Matern, Ivan Maisuls, Cristian A. Strassert, Gustavo Fernandez
Supramolecular polymers (SPs) of d 8 transition metal complexes have received considerable attention by virtue of their rich photophysical properties arising from metal-metal interactions. However, thus far, the molecular design is restricted to complexes with chelating ligands due to their advantageous preorganization and strong ligand fields. Herein, we demonstrate unique pathway-controllable me
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Magneto-Orientation of Magnetic Double Stacks for Patterned Anisotropic Hydrogels with Multiple Responses and Modulable Motions Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Chen Fei Dai, Olena Khoruzhenko, Chengqian Zhang, Qing Li Zhu, Dejin Jiao, Miao Du, Josef Breu, Peng Zhao, Qiang Zheng, Zi Liang Wu
Reported here is a multi-response anisotropic poly(N-isopropylacrylamide) hydrogel developed by using a rotating magnetic field to align magnetic double stacks (MDSs) that are fixed by polymerization. The magneto-orientation of MDSs originates from the unique structure with g-Fe2O3 nanoparticles sandwiched by two silicate nanosheets. The resultant gels not only exhibit anisotropic optical and mechanical
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Cis-Trans Reisomerization Precedes Reprotonation of the Retinal Chromophore in the Photocycle of Schizorhodopsin 4 Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Kouhei Hayashi, Misao Mizuno, Hideki Kandori, Yasuhisa Mizutani
Recent discoveries of light-driven inward proton-pumping rhodopsins have opened new avenues to exploring the mechanism of unidirectional transport because these proteins transport protons in the opposite direction to conventional proton-pumping rhodopsins, despite their similar protein structure and membrane topology. Schizorhodopsin (SzR) is a newly discovered rhodopsin family of light-driven inward
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One-Step Thermophoretic AND Gate Operation on Extracellular Vesicles Improves Diagnosis of Prostate Cancer Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Jinqi Deng, Shuai Zhao, Junhong Li, Yangchang Cheng, Chao Liu, Zheng Liu, Lele Li, Fei Tian, Bo Dai, Jiashu Sun
Circulating extracellular vesicles (EVs) have emerged as a valuable source of cancer biomarkers. However, the high degree of EV heterogeneity and the complexity of clinical samples pose a challenge in the sensitive identification of tumor-derived EVs. Here we introduce a one-step thermophoretic AND gate operation (Tango) assay that integrates polyethylene glycol (PEG)-enhanced thermophoretic accumulation
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Amine-directed Formation of B–N Bonds for BN-fused Polycyclic Aromatic Multiple Resonance Emitters with Narrowband Emission Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2022-06-24 Guoyun Meng, Hengyi Dai, Tianyu Huang, Jinbei Wei, Jianping Zhou, Xiao Li, Xiang Wang, Xiangchen Hong, Chen Yin, Xuan Zeng, Yuewei Zhang, Dezhi Yang, Dongge Ma, Guomeng Li, Dongdong Zhang, Lian Duan
Despite the remarkable multiple resonances (MR) optoelectronic properties of organic nanographenes with boron and nitrogen atoms disposed para to each other, the synthetic procedures are sophisticated with low yields and the molecular skeletons are limited. Here, a new paradigm of easy-to-access MR emitter is constructed by simplifying the multiborylation through the amine-directed formation of B-N
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Computational Fluid Dynamics–Discrete Element Method Studies on Dynamics and Segregation in Spouted Bed with Polydispersed Particles Ind. Eng. Chem. Res. (IF 3.72) Pub Date : 2022-06-24 Ritesh Raman, Palash Kumar Mollick, Partha S. Goswami
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Modeling Drainage in Periodic Separation Ind. Eng. Chem. Res. (IF 3.72) Pub Date : 2022-06-24 Jens Abildskov, Sten Bay Jørgensen
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Polyhedral Organic Silsesquioxane Cage Structures Formed via Reaction of Methylchlorosilanes with Re/CeO2 in Catalytic Oxygen Depletion–Regeneration Cycle Ind. Eng. Chem. Res. (IF 3.72) Pub Date : 2022-06-24 Robert T. Larsen, Matthew McLaughlin, Dimitris E. Katsoulis
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Rare Earth Magnets and Limescale: Analysis of Magnetic Water Treatment Using a Dynamic Scale Rig Ind. Eng. Chem. Res. (IF 3.72) Pub Date : 2022-06-23 Jean Lombard, Leané D. van Zijl, Luca Bertossi, Shane Smith, Elaine Barnard, Sean J. O’Kennedy, Anthony Turton
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Improved High-Temperature Electrical Properties of Polymeric Material by Grafting Modification ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Chao Yuan, Yao Zhou, Yujie Zhu, Shixun Hu, Jiajie Liang, Zhen Luo, Bing Gao, Tan Zeng, Yaru Zhang, Juan Li, Shangshi Huang, Zhifei Han, Xiao Yang, Yang Yang, Pengfei Meng, Jun Hu, Jinliang He, Hao Yuan, Qi Li
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Co7Fe3 Nanoparticles Confined in N-Doped Carbon Nanocubes for Highly Efficient, Rechargeable Zinc–Air Batteries ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Teng-xiu Tu, Xiao Zhou, Peng-fang Zhang, Liang Tan, Zhi-feng Xu, Meng-qin Liu, Wen-yi Li, Xiao-min Kang, Yi-jin Wu, Jian-zhong Zheng
Active component management and microengineering of metal nanoparticles are significant challenges for efficient M/N/C electrocatalysts, as a crucial electrode material for reversible zinc–air batteries, because of the lack of a multifunctional structural strategy in the electrocatalytic preparation process. Here, a convenient, one-step pyrolysis method was introduced into the preparation process of
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Synthesis of a Thermally and Hydrothermally Stable Copper-Based Catalyst via Alloying of Cu with Ni and Zn for Catalyzing Conversion of Furfural into Cyclopentanone ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Yuewen Shao, Kai Sun, Mengjiao Fan, Guoming Gao, Junzhe Wang, Lijun Zhang, Shu Zhang, Xun Hu
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Stabilizing Zinc Anodes by a Cotton Towel Separator for Aqueous Zinc-Ion Batteries ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Penghui Cao, Haochen Zhou, Xiangyang Zhou, Qing Du, Jingjing Tang, Juan Yang
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Dispensing Essential Oil Components through Cocrystallization: Sustainable and Smart Materials for Food Preservation and Agricultural Applications ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Fabio Montisci, Paolo P. Mazzeo, Claudia Carraro, Michele Prencipe, Paolo Pelagatti, Fabio Fornari, Federica Bianchi, Maria Careri, Alessia Bacchi
The ever-increasing attention on environmental problems and sustainability has highlighted several problems related to the use of conventional pesticides in the agricultural industry, e.g., toxic residues in the soil and hazards to the environment and human health. In the search for natural antimicrobial and insecticide alternatives, essential oils (EOs) and their active components have emerged as
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Gold Nanoparticle/Carbon Fiber Hybrid Structure from the Eco-Friendly and Energy-Efficient Process for Electrochemical Biosensing ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Taehwan Lim, Seoyeon Won, In-Woo Nam, Jae Shik Choi, Chae Hwa Kim, Tae Hee Kim, Jung Han Kim, Sang Young Yeo, Huanan Zhang, Byeong Jin Yeang
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Integrated Approach to Extract and Purify Proteins from Honey by Ionic Liquid-Based Three-Phase Partitioning ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Matheus M. Pereira, Sónia N. Pedro, Maria V. Quental, Aminou Mohamadou, João A. P. Coutinho, Mara G. Freire
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Characterization of a Dual Cellulolytic/Xylanolytic AA9 Lytic Polysaccharide Monooxygenase from Thermothelomyces thermophilus and its Utilization Toward Nanocellulose Production in a Multi-Step Bioprocess ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-24 Koar Chorozian, Anthi Karnaouri, Antonis Karantonis, Maria Souli, Evangelos Topakas
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Agar-Based Composite Films as Effective Biodegradable Sound Absorbers ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Surendra Kumar, Kousar Jahan, Abhishek Verma, Manan Agarwal, C. Chandraprakash
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A SiCl4-Assisted Roasting Approach for Recovering Spent LiCoO2 Cathode ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Mengting Li, Beilei Zhang, Xin Qu, Muya Cai, Dongxu Liu, Fengyin Zhou, Hongwei Xie, Shuaibo Gao, Huayi Yin
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Mesoporous NaxMnOy-Supported Platinum–Cobalt Bimetallic Single-Atom Catalysts with Good Sulfur Dioxide Tolerance in Propane Oxidation ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Xiuqing Hao, Jiguang Deng, Yuxi Liu, Lin Jing, Jia Wang, Zhiwei Wang, Hongxing Dai
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Sustainable Poly(butylene adipate-co-furanoate) Composites with Sulfated Chitin Nanowhiskers: Synergy Leading to Superior Robustness and Improved Biodegradation ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Truong Vu Thanh, Lam Tan Hao, Ha-Young Cho, Hyeri Kim, Seul-A Park, Minkyung Lee, Hyo Jeong Kim, Hyeonyeol Jeon, Sung Yeon Hwang, Jeyoung Park, Dongyeop X. Oh, Jun Mo Koo
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Sustainable Synthesis of Amides from Carboxylic Acids and Equivalent Amounts of Amines Using a Reusable Brønsted Acidic Ionic Liquid as a Catalyst and a Solvent ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Lin Zhang, Jian Jiang, Linlin Li, Qian Chen, Ling Zhang, Hao Sun, Chun Li
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Sustainable Nutrient Substrates for Enhanced Seedling Development in Hydroponics ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Zhitong Zhao, Tao Xu, Xiaoyong Pan, Susanti, Jason C. White, Xiao Hu, Yansong Miao, Philip Demokritou, Kee Woei Ng
Sustainable agriculture can be achieved by upcycling and repurposing organic wastes for high-value applications. Keratin and cellulose are two natural biopolymers which are plentiful in biowastes such as hair, poultry feathers, wood shavings, and vegetable trimmings. In this study, these waste-derived biopolymers are converted into bioactive nutrient substrates that can support crop development in
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Catalyst-Free Approach for the Degradation of Bio- and CO2-Sourced Polycarbonates: A Step toward a Circular Plastic Economy ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Fabiana Siragusa, Thomas Habets, Raphael Méreau, Gwilherm Evano, Bruno Grignard, Christophe Detrembleur
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Simultaneous Removal of Toluene in Gas and Electricity Production by Using a Single-Chamber Microbial Fuel Cell-Biotricking Filter System ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Fang Wang, Yinchi Xu, Wenyue Dai, Fangzheng Su, Juexiu Li, Changsen Zhang, Ruiqin Zhang, Panpan Liu
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Accelerated Non-Enzymatic Fatty Acid Esterification during Microdroplet Collision: A Method for Enhanced Sustainability ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Pallab Basuri, Jenifer Shantha Kumar, Subhashree Das, Thalappil Pradeep
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Oxygen Corrosion Engineering of Nonprecious Ternary Metal Hydroxides toward Oxygen Evolution Reaction ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Yang Xiao, Kamran Dastafkan, Yibing Li, Tingwen Zhao, Zhen Su, Huiqian Qi, Chuan Zhao
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Sustainable Indicators Based on Furfural-Derived Colorant-Doped Biobased Polyurethane to Improve Food Safety ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23 Shenglin Zhou, Li Wang, Yazhou Wang, Hao Ma, Bin Yan, Kai Guo, Qiang Yan, Haojun Fan, Jun Xiang
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Importance of Green and Sustainable Chemistry in the Chemical Industry ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-23
This article references 14 other publications. This article has not yet been cited by other publications. This article references 14 other publications.
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Gel-like Ag-Dicyandiamide Metal–Organic Supramolecular Network-Derived g-C3N4 for Photocatalytic Hydrogen Generation ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-22 Hepsiba Niruba Catherine, Wei-Lun Chiu, Lee-Lee Chang, Kuo-Lun Tung, Chechia Hu
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Highly Integrated Precursor-Derived FePO4/P-Doped C 2D Nanofilm-Encapsulated Ni2P@NC Matrix as an Electrocatalyst for Energy-Saving Hydrogen Production ACS Sustain. Chem. Eng. (IF 8.198) Pub Date : 2022-06-22 Yanru Feng, Wenjuan Xu, Zejun Sun, Chengrui Li, Liutao Guo, Hong Li, Junli Xu, Hong-bin Sun
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Advantages of Tandem versus Simultaneous Operation: The case of Isomerization/Hydrogenation of Terpinolene Epoxide to Terpinen-4-ol Using a Ni/TiO2-SiO2 Bifunctional Catalyst Chem. Eng. Sci. (IF 4.311) Pub Date : 2022-06-24 Jie Liu, Jianhao Cui, Lei Chen, Jingjing Chen, Huidong Zheng, S. Ted Oyama
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An open-source topology optimization modeling framework for the design of passive micromixer structure Chem. Eng. Sci. (IF 4.311) Pub Date : 2022-06-23 Jian Na, Hong Li, Peng Yan, Xingang Li, Xin Gao
In the microfluidic systems, the structure of micromixer is one of the important influence factors for the mixing performance. The traditional trial-and-error method for the optimization design of micromixer structure is difficult to consider both the mixing performance and power dissipation. Here we show the topology optimization method of designing the passive micromixer with the minimum power dissipation
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Intrusive sampling of dust deposition in a granular bed filter-cyclone coupled separator Chem. Eng. Sci. (IF 4.311) Pub Date : 2022-06-23 Ming Chang, Yiping Fan, Chunxi Lu
A separator coupling cyclone with a built-in granular bed filter is proposed for gas purification. Due to the complicated mutual influences between the outer cyclone shell and the inner granular bed, the dust deposition is different from that in the traditional granular bed filter. By using the intrusive sampling method, the dusts deposited in the bed are sampled under varying inlet dust concentrations