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Peroxy Intermediate Drives Carbon Bond Activation in the Dioxygenase AsqJ J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Dirk Auman, Felix Ecker, Sophie L. Mader, Kevin M. Dorst, Alois Bräuer, Göran Widmalm, Michael Groll, Ville R. I. Kaila
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Identification of the Early Steps in Herbicidin Biosynthesis Reveals an Atypical Mechanism of C-Glycosylation J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Zhang Chen, Shusuke Sato, Yujie Geng, Jiawei Zhang, Hung-wen Liu
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Poly(2,3-Dihydrofuran): A Strong, Biorenewable, and Degradable Thermoplastic Synthesized via Room Temperature Cationic Polymerization J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Scott W. Spring, Jesse H. Hsu, Renee J. Sifri, Szu-Ming Yang, Chloe S. Cerione, Tristan H. Lambert, Christopher J. Ellison, Brett P. Fors
Creation of strong and tough plastics from sustainable and biorenewable resources is a significant challenge in polymer science. This challenge is further complicated when attempting to make these materials using an economically viable process, which is often hindered by the production and availability of chemical feedstocks and the efficiency of the monomer synthesis. Herein, we report the synthesis
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Crystallization-Enabled Henry Reactions: Stereoconvergent Construction of Fully Substituted [N]-Asymmetric Centers J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Pedro De Jesús Cruz, Jeffrey S. Johnson
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Dye-Sensitized Multiple Exciton Generation in Lead Sulfide Quantum Dots J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Zhiyuan Huang, Matthew C. Beard
Multiple exciton generation (MEG), the generation of multiple excitons from the absorption of a single high-energy photon, is a strategy to go beyond the limiting efficiencies that define current-day solar cells by harvesting some of the thermalization energy losses that occur when photons with an energy greater than the semiconductor bandgap are absorbed. In this work, we show that organic dyes can
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Implants with Sensing Capabilities Chem. Rev. (IF 72.087) Pub Date : 2022-08-18 Mladen Veletić, Ehsanul Hoque Apu, Mitar Simić, Jacob Bergsland, Ilangko Balasingham, Christopher H. Contag, Nureddin Ashammakhi
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Atomic-scale Observation of Grain Boundary Dominated Unsynchronized Phase Transition in Polycrystalline Cu2Se Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Hua-Lei Yuan, Kaiwen Wang, Hanwen Hu, Lei Yang, Jie Chen, Kun Zheng
Phase transition is a physical phenomenon that attracts great interest of researchers. Although the theory of second-order phase transition is well-established, their atomic-scale dynamics in polycrystalline materials remains elusive. In this work, second-order phase transitions in polycrystalline Cu2Se at the transition temperature are directly observed by in-situ aberration-corrected transmission
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Generation of Boryl-nitroxide Radicals from a Boraalkene via the Nitroso Ene Reaction Chem. Sci. (IF 9.969) Pub Date : 2022-08-18 Chaohuang Chen, Constantin Gabriel Daniliuc, Sina Klabunde, Michael Ryan Hansen, Gerald Kehr, Gerhard Erker
Examples of isolated boron substituted nitroxide radicals are rare. The reaction of the reactive cyclic boraalkene 3 with nitrosobenzene yields a mixture of the [2+2] cycloaddition product 4, the B-nitroxide radicals 5a and 6a and the azoxybenzene co-product via a bora nitroso ene reaction pathway, the boron analogue of the nitroso ene reaction. The products were separated by flash chromatography and
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A hydrogen-driven biocatalytic approach to recycling synthetic analogues of NAD(P)H Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Holly A Reeve, Jake Nicholson, Farieha Altaf, Thomas H. Lonsdale, Janina Preissler, Lars Lauterbach, Oliver Lenz, Silke Leimkühler, Frank Hollmann, Caroline Emilie Paul, Kylie A Vincent
We demonstrate a recycling system for synthetic nicotinamide cofactor analogues using a soluble hydrogenase with turnover numbers of >1000 for reduction of the cofactor analogues by H2. Coupling this system to an ene-reductase, we show quantitative conversion of N-ethylmaleimide to N-ethylsuccinimide. The biocatalyst system retained >50% activity after 7 h.
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A nanoplatform for mild-temperature photothermal and type I & II photodynamic therapy in NIR-II biowindow Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Bing Lu, Zhecheng Zhang, Huang Yuying, Yuehua Zhang, Jin Wang, Yue Ding, Yang Wang, Yong Yao
Herein we synthesized an A−D−A small molecule photosensitizer DPTTIC and a new amphiphilic pillararene WP5-8C-2PEG, which were used to construct a novel nanoparticle DPTTIC NPs with NIR II absorption. under a 980 nm laser irradiation, DPTTIC NPs performed well in mild-temperature photothermal and type I & II photodynamic combined therapy for tumors.
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Bimetallic Effect Promotes the Activity of Rh in Catalyzed Selective Hydrogenation of Phenol Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Shiwei Li, Huachao Zhao, Wei Ran, Jing-fu Liu, Rui Liu
Au@RhPd ultrathin nanowires is designed as highly reactive and selective catalyst for the hydrogenation of phenol under ambient conditions. Au NWs modulates the electronic state of Rh atoms to enhance the adsorption of phenol and desorption of cyclohexanone. Pd works as cocatalyst to activate H2 into H* and spillover to Rh sites. This new catalyst shows turnover frequency up to 560 h-1 for a wide spectrum
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Correction: Diastereoselective synthesis of tetrahydrobenzo[b]azocines by Lu(OTf)3-catalyzed [4+4] cycloaddition of donor–acceptor cyclobutanes with anthranils Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Meifeng Hou, Jiajun Li, Fucai Rao, Zuliang Chen, Yingjing Wei
Correction for ‘Diastereoselective synthesis of tetrahydrobenzo[b]azocines by Lu(OTf)3-catalyzed [4+4] cycloaddition of donor–acceptor cyclobutanes with anthranils’ by Meifeng Hou et al., Chem. Commun., 2022, 58, 5865–5868, https://doi.org/10.1039/D2CC00829G.
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CO2-driven reversible transfer of the amine-functionalized ZIF-90 between organic and aqueous phases Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Xiaoyan Pei, Chunyu Tian, Yanning Wang, Zhenzhen Li, Zhiyang Xiong, Huiyong Wang, Xiantao Ma, Xinhua Cao, Zhiyong Li
Phase transfer of metal-organic frameworks is highly desired in many areas, which remains a challenge. Herein, we firstly presented a CO2-driven reversible transfer of the amine-functionalized ZIF-90 between organics and water. Mechanism study showed that the switching is ascribed to the reversible generation of hydrophilic ammonium salts from the reaction of CO2 with the amines on the ZIF-90. The
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Genetically Encoded Fluorescent Unnatural Amino Acids and FRET Probes for Detecting Deubiquitinase Activities Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Manjia Li, Feifei Wang, Long Yan, Minghao Lu, Yuqing Zhang, Tao Peng
Herein we present the genetic encoding of 7-aminocoumarin-based lysine derivatives, ACouK and AFCouK, into proteins in both bacterial and mammalian cells and the characterization of FRET pairs comprising of ACouK or AFCouK as the donor and GFP as the acceptor. We further report the application of the FRET pairs to construct fully genetically encoded ratiometric probes for detecting deubiquitinases
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Rapid Identification of Short-lived Intermediates in Alternating-Current Electrolysis by Mass Spectrometry Chem. Commun. (IF 6.065) Pub Date : 2022-08-18 Xiao-Jun Xi, Jun Hu, Hong-Yuan Chen, Jing-Juan Xu
Herein, we report the rapid mass spectrometric identification of short-lived intermediates generated under AC electrolysis via combining bipolar electrochemistry with nanoelectrospray ionization in a hybrid ultramicroelectrode/ion emitter. The key reactive intermediates involved in the C-O/O-H cross-metathesis between 4-alkoxy anilines and alcohols were successfully captured and identified for the
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Closed Aromatic Tubes - Capsularenes Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Radoslav Z. Pavlović, Lei Zhiquan, Tyler J. Finnegan, Christopher A. Waudby, Xiuze Wang, Vageesha W. Liyana Gunawardana, Xingrong Zhu, Curt M. Wong, Taylor Hamby, Curtis E. Moore, Nicole Hoefer, David W McComb, Christo S. Sevov, Jovica D Badjic
In this study, we describe a synthetic method for incorporating arenes into closed tubes that we name capsularenes. First, we prepared vase-shaped molecular baskets 4-7. The baskets comprise a benzene base fused to three bicyclo[2.2.1]heptane rings that extend into phthalimide (4), naphthalimide (6), and anthraceneimide sides (7), each carrying a dimethoxyethane acetal group. In the presence of catalytic
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Large Room Temperature Anomalous Transverse Thermoelectric Effect in Kagome Antiferromagnet YMn6Sn6 Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Subhajit Roychowdhury, Andrew M. Ochs, Satya N. Guin, Kartik Samanta, Jonathan Noky, Chandra Shekhar, Maia G. Vergniory, Joshua E. Goldberger, Claudia Felser
Kagome magnets possess several novel non-trivial topological features owing to the strong correlation between topology and magnetism, that extends to their applications in the field of thermoelectricity. Conventional thermoelectric (TE) devices use the Seebeck effect to convert heat into electrical energy. In contrast, transverse thermoelectric devices based on the Nernst effect are attracting recent
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Super-Linear-Threshold-Switching Selector with Multiple Jar-Shaped Cu-Filaments in the Amorphous Ge3Se7 Resistive Switching Layer in a Cross-Point Synaptic Memristor Array Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Hea-Jee Kim, Dae-Seong Woo, Soo-Min Jin, Hyo-Jun Kwon, Ki-Hyun Kwon, Dong-Won Kim, Dong-Hyun Park, Dong-Eon Kim, Hong-Uk Jin, Hyun-Do Choi, Tae-Hun Shim, Jea-Gun Park
The learning and inference efficiencies of an artificial neural network represented by a cross-point synaptic memristor array can be achieved using a selector (1S), with high selectivity (Ion/Ioff) and sufficient death region, stacked vertically on a synaptic memristor (1 M). This can prevent a sneak current in the memristor array. A selector with multiple jar-shaped conductive Cu filaments in the
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Prospects for Simultaneously Capturing Carbon Dioxide and Harvesting Water from Air Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Matthew N. Dods, Simon C. Weston, Jeffrey R. Long
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Versatile Sequential Casting Processing for Highly Efficient and Stable Binary Organic Photovoltaics (Adv. Mater. 33/2022) Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Chengliang He, Youwen Pan, Guanghao Lu, Baohua Wu, Xinxin Xia, Chang-Qi Ma, Zeng Chen, Haiming Zhu, Xinhui Lu, Wei Ma, Lijian Zuo, Hongzheng Chen
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Bioinspired Stretchable Transducer for Wearable Continuous Monitoring of Respiratory Patterns in Humans and Animals (Adv. Mater. 33/2022) Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Yasin Cotur, Selin Olenik, Tarek Asfour, Michael Bruyns-Haylett, Michael Kasimatis, Ugur Tanriverdi, Laura Gonzalez-Macia, Hong Seok Lee, Andrei S. Kozlov, Firat Güder
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A Single-Dot Perovskite Spectrometer (Adv. Mater. 33/2022) Adv. Mater. (IF 32.086) Pub Date : 2022-08-18 Linqi Guo, Haoxuan Sun, Min Wang, Meng Wang, Liangliang Min, Fengren Cao, Wei Tian, Liang Li
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Simultaneous Photoactivation of cGAS-STING Pathway and Pyroptosis by Pt(II)-Triphenylamine Complexes for Cancer Immunotherapy Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Yu-Yi Ling, Xiao-Yu Xia, Liang Hao, Wen-Jin Wang, Hang Zhang, Liu-Yi Liu, Wenting Liu, Zhi-Yuan Li, Cai-Ping Tan, Zong-Wan Mao
Activation of the cyclic GMP-AMP synthase-stimulator of interferon gene (cGAS-STING) pathway is a potent anticancer immunotherapeutic strategy, and the induction of pyroptosis is a feasible way to stimulate the anticancer immune responses. Herein, two Pt(II) complexes (Pt1 and Pt2) were designed as photoactivators of the cGAS-STING pathway. In response to light irradiation, Pt1 and Pt2 could damage
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A Long-Circulating Vector for Aptamers Based upon Polyphosphodiester-Backboned Molecular Brushes Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Yuyan Wang, Dali Wang, Jiachen Lin, Zidi Lyu, Peiru Chen, Tingyu Sun, Chenyang Xue, Mehrnaz Mojtabavi, Armin Vedadghavami, Zheyu Zhang, Ruimeng Wang, Lei Zhang, Christopher Park, Gyu Seong Heo, Yongjian Liu, Sijia S. Dong, Ke Zhang
Aptamers face challenges for use outside the ideal conditions in which they are developed. These difficulties are most palpable in vivo due to nuclease activities, rapid clearance, and off-target binding. Herein, we demonstrate that a polyphosphodiester-backboned molecular brush can suppress enzymatic digestion, reduce non-specific cell uptake, enable long blood circulation, and rescue the bioactivity
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Single-Fluorophore-Based Organic Crystals with Distinct Conformers Enabling Wide-Range Excitation-Dependent Emissions Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Rongrong Huang, Chao Wang, Davin Tan, Kai Wang, Bo Zou, Yangtao Shao, Taihong Liu, Haonan Peng, Xiaogang Liu, Yu Fang
Achieving wide-range tunable emission colors, especially in the solid state of single-fluorophore materials, remains a significant challenge. Herein, we report a molecular design strategy that affords wide-range excitation-dependent emissions spanning over ~230 nm in crystalline states. Under the donor-π-acceptor configuration, we judiciously choose a rotatable acceptor fragment, o -carborane, to enrich
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Missing-linker Defects in Covalent Organic Framework Membranes for Efficient CO2 Separation Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Zheyuan Guo, Hong Wu, Yu Chen, Shiyi Zhu, Haifei Jiang, Shuqing Song, Yanxiong Ren, Yuhan Wang, Xu Liang, Guangwei He, Yonghong Li, Zhongyi Jiang
Covalent organic framework (COF) membranes with tunable ordered channels and free organic groups hold great promise in molecular separations owing to the synergy of physical and chemical microenvironments. Herein, we develop a defect engineering strategy to fabricate COF membranes for efficient CO 2 separation. Abundant amino groups are in situ generated on the COF nanosheets arising from the missing-linker
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Space-Confined Donor-Acceptor Strategy Enables Fast Spin-Flip of Multiple Resonance Emitters for Suppressing Efficiency Roll-Off Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Yang Liu, Xin Xiao, Zhenmei Huang, Dezhi Yang, Dongge Ma, Junjie Liu, Bowen Lei, Zhengyang Bin, Jingsong You
Multi-resonance boron-nitrogen-containing thermally activated delayed fluorescence (MR-TADF) emitters have experienced great success in assembling narrowband organic light-emitting diodes (OLEDs). However, the slow reverse intersystem crossing rate (kRISC) of MR-emitters (103-105 s-1) that will lead to severe device efficiency roll-off has received extensive attention and remains a challenging issue
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Halogen Atom Participation in Guiding the Stereochemical Outcomes of Acetal Substitution Reactions Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Krystyna M. Demkiw, Wouter A. Remmerswaal, Thomas Hansen, Gijsbert A. van der Marel, Jeroen D. C. Codée, Keith Woerpel
Acetal substitution reactions of α-halogenated five- and six-membered rings can be highly stereoselective. Erosion of stereoselectivity occurs as nucleophilicity increases, which is consistent with additions to a halogen-stabilized oxocarbenium ion, not a three-membered-ring halonium ion. Computational investigations confirmed that the open-form oxocarbenium ions are the reactive intermediates involved
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Simultaneous Generation of Methyl Esters and CO in Lignin Transformation Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Mingyang Liu, Buxing Han, Paul J. Dyson
Lignin is an abundant renewable carbon source. Due to its complex structure, utilization of lignin is very challenging. Herein, we describe an efficient strategy for the simultaneous utilization of lignin, in which the methoxy groups in lignin react with carboxylic acids to generate methyl carboxylates and the other alkyl and phenyl carbons react with oxygen to predominantly form CO that can be used
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Fano Resonance in Single-molecule Junctions Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Yan Zheng, Ping Duan, Yu Zhou, Chuan Li, Dahai Zhou, Yaping Wang, Li-Chuan Chen, Zhiyu Zhu, Xiaohui Li, Jie Bai, Kai Qu, Tengyang Gao, Jia Shi, Junyang Liu, Qian-Chong Zhang, Zhong-Ning Chen, Wenjing Hong
The Fano resonance in single-molecule junctions could be created by interaction with discrete and continuous molecular orbitals and enables effective electron transport modulation between constructive and destructive interference within a small energy range. However, direct observation of Fano resonance remains unexplored because of the disappearance of discrete orbitals by molecule-electrode coupling
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Self-Assembled Aza-Boron-Dipyrromethene for Ferroptosis-Boosted Sonodynamic Therapy Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-18 Changwen You, Xingguang Li, Dongqiong Wang, Hongzhong Chen, Lei Liang, Yu Chen, Yanli Zhao, Huijing Xiang
The presence of apoptosis inhibition proteins renders the cancer cells resistant to apoptosis, severely compromising the antitumor efficacy of sonodynamic therapy (SDT). Here, an intelligent anticancer nanoplatform based on an Aza-boron-dipyrromethene dye (denoted as Aza-BDY) is elaborately established for ferroptosis augmented SDT through cysteine (Cys) starvation. After endocytosis by tumor cells
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In-Situ Analysis of Anionic Coordination Polymerizations by Electrospray-Ionization Mass Spectrometry Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-17 Friedrich Kreyenschmidt, Niklas F. Eisele, Valentin Hevelke, Rene Rahrt, Anne-Kathrin Kreyenschmidt, Konrad Koszinowski
Anionic coordination polymerizations proceed via highly reactive intermediates, whose in-situ analysis has remained difficult. Here, we show that electrospray-ionization mass spectrometry is a promising method to obtain detailed information on the polymerization process. Focusing on polymerization reactions of 1,3-dienes initiated by CoCl2/RLi (R = Me, nBu, tBu, Ph), we directly observe the growing
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Engineering Supramolecular Binding Sites in a Chemically Stable Metal−Organic Framework for Simultaneous High C2H2 Storage and Separation Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-17 Kai Shao, Hui-Min Wen, Cong-Cong Liang, Xiaoyan Xiao, Xiao-Wen Gu, Banglin Chen, Guodong Qian, Bin Li
Developing porous materials to overcome the trade-off between adsorption capacity and selectivity for C2H2/CO2separation remains a challenge. Herein, we report a stable HKUST-1-like MOF (ZJU-50a), featuring large cages decorated with high density of supramolecular binding sites to achieve both high C2H2 storage and selectivity. ZJU-50a exhibits one of the highest C2H2 storage capacity (192 cm3 g−1)
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Formation and Reactivity of a Fleeting Ni(III) Bisphenoxyl Diradical Species Angew. Chem. Int. Ed. (IF 16.823) Pub Date : 2022-08-17 Ayushi Awasthi, Isaac F. Leach, Silène Engbers, Rakesh Kumar, Raju Eerlapally, Sikha Gupta, Johannes E. M. N. Klein, Apparao Draksharapu
Cytochrome P450s and Galactose Oxidases exploit redox active ligands to form reactive high valent intermediates for oxidation reactions. This strategy works well for the late 3d metals where accessing high valent states is rather challenging. Herein, we report the oxidation of NiII(salen) (salen = N,N’-bis(3,5-di-tert-butyl-salicylidene)-1,2-cyclohexane-(1R,2R)-diamine) with mCPBA (meta-chloroperoxybenzoic
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Porous Polymer Cubosomes with Ordered Single Primitive Bicontinuous Architecture and Their Sodium–Iodine Batteries J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Luoxing Xiang, Siqi Yuan, Faxing Wang, Zhihan Xu, Xiuhong Li, Feng Tian, Liang Wu, Wei Yu, Yiyong Mai
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Graphene Infrared Radiation Management Targeting Photothermal Conversion for Electric-Energy-Free Crude Oil Collection J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Yi Cheng, Shuting Cheng, Bingbing Chen, Jun Jiang, Ce Tu, Wenjuan Li, Yuyao Yang, Kewen Huang, Kun Wang, Hao Yuan, Junliang Li, Yue Qi, Zhongfan Liu
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Transamidation-Driven Molecular Pumps J. Am. Chem. Soc. (IF 16.383) Pub Date : 2022-08-18 Lorna Binks, Chong Tian, Stephen D. P. Fielden, Iñigo J. Vitorica-Yrezabal, David A. Leigh
We report a new class of synthetic molecular pumps that use a stepwise information ratchet mechanism to achieve the kinetic gating required to sequester their macrocyclic substrates from bulk solution. Threading occurs as a result of active template reactions between the pump terminus amine and an acyl electrophile, whereby the bond-forming reaction is accelerated through the cavity of a crown ether
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Emerging Electrochromic Materials and Devices for Future Displays Chem. Rev. (IF 72.087) Pub Date : 2022-08-18 Chang Gu, Ai-Bo Jia, Yu-Mo Zhang, Sean Xiao-An Zhang
With the rapid development of optoelectronic fields, electrochromic (EC) materials and devices have received remarkable attention and have shown attractive potential for use in emerging wearable and portable electronics, electronic papers/billboards, see-through displays, and other new-generation displays, due to the advantages of low power consumption, easy viewing, flexibility, stretchability, etc
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Biosynthesis and characterization of fuscimiditide, an aspartimidylated graspetide Nat. Chem. (IF 24.274) Pub Date : 2022-08-18 Hader E. Elashal, Joseph D. Koos, Wai Ling Cheung-Lee, Brian Choi, Li Cao, Michelle A. Richardson, Heather L. White, A. James Link
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Do protons have intrinsic charm? New evidence suggests yes Nature (IF 69.504) Pub Date : 2022-08-17
Hear the biggest stories from the world of science | 17 August 2022
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Post-translational control of beige fat biogenesis by PRDM16 stabilization Nature (IF 69.504) Pub Date : 2022-08-17 Qiang Wang, Huixia Li, Kazuki Tajima, Anthony R. P. Verkerke, Zachary H. Taxin, Zhishuai Hou, Joanne B. Cole, Fei Li, Jake Wong, Ichitaro Abe, Rachana N. Pradhan, Tadashi Yamamuro, Takeshi Yoneshiro, Joel N. Hirschhorn, Shingo Kajimura
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In vivo single-molecule analysis reveals COOLAIR RNA structural diversity Nature (IF 69.504) Pub Date : 2022-08-17 Minglei Yang, Pan Zhu, Jitender Cheema, Rebecca Bloomer, Pawel Mikulski, Qi Liu, Yueying Zhang, Caroline Dean, Yiliang Ding
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Saccorhytus is an early ecdysozoan and not the earliest deuterostome Nature (IF 69.504) Pub Date : 2022-08-17 Yunhuan Liu, Emily Carlisle, Huaqiao Zhang, Ben Yang, Michael Steiner, Tiequan Shao, Baichuan Duan, Federica Marone, Shuhai Xiao, Philip C. J. Donoghue
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Endocytosis in the axon initial segment maintains neuronal polarity Nature (IF 69.504) Pub Date : 2022-08-17 Kelsie Eichel, Takeshi Uenaka, Vivek Belapurkar, Rui Lu, Shouqiang Cheng, Joseph S. Pak, Caitlin A. Taylor, Thomas C. Südhof, Robert Malenka, Marius Wernig, Engin Özkan, David Perrais, Kang Shen
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Formation of moiré interlayer excitons in space and time Nature (IF 69.504) Pub Date : 2022-08-17 David Schmitt, Jan Philipp Bange, Wiebke Bennecke, AbdulAziz AlMutairi, Giuseppe Meneghini, Kenji Watanabe, Takashi Taniguchi, Daniel Steil, D. Russell Luke, R. Thomas Weitz, Sabine Steil, G. S. Matthijs Jansen, Samuel Brem, Ermin Malic, Stephan Hofmann, Marcel Reutzel, Stefan Mathias
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MYB orchestrates T cell exhaustion and response to checkpoint inhibition Nature (IF 69.504) Pub Date : 2022-08-17 Carlson Tsui, Lorenz Kretschmer, Svenja Rapelius, Sarah S. Gabriel, David Chisanga, Konrad Knöpper, Daniel T. Utzschneider, Simone Nüssing, Yang Liao, Teisha Mason, Santiago Valle Torres, Stephen A. Wilcox, Krystian Kanev, Sebastian Jarosch, Justin Leube, Stephen L. Nutt, Dietmar Zehn, Ian A. Parish, Wolfgang Kastenmüller, Wei Shi, Veit R. Buchholz, Axel Kallies
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Self-oscillating pump in a topological dissipative atom–cavity system Nature (IF 69.504) Pub Date : 2022-08-17 Davide Dreon, Alexander Baumgärtner, Xiangliang Li, Simon Hertlein, Tilman Esslinger, Tobias Donner
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Live-seq enables temporal transcriptomic recording of single cells Nature (IF 69.504) Pub Date : 2022-08-17 Wanze Chen, Orane Guillaume-Gentil, Pernille Yde Rainer, Christoph G. Gäbelein, Wouter Saelens, Vincent Gardeux, Amanda Klaeger, Riccardo Dainese, Magda Zachara, Tomaso Zambelli, Julia A. Vorholt, Bart Deplancke
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Continental configuration controls ocean oxygenation during the Phanerozoic Nature (IF 69.504) Pub Date : 2022-08-17 Alexandre Pohl, Andy Ridgwell, Richard G. Stockey, Christophe Thomazo, Andrew Keane, Emmanuelle Vennin, Christopher R. Scotese
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A condensate dynamic instability orchestrates actomyosin cortex activation Nature (IF 69.504) Pub Date : 2022-08-17 Victoria Tianjing Yan, Arjun Narayanan, Tina Wiegand, Frank Jülicher, Stephan W. Grill
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When and where to protect forests Nature (IF 69.504) Pub Date : 2022-08-17 Ian H. Luby, Steve J. Miller, Stephen Polasky
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Spatial profiling of chromatin accessibility in mouse and human tissues Nature (IF 69.504) Pub Date : 2022-08-17 Yanxiang Deng, Marek Bartosovic, Sai Ma, Di Zhang, Petra Kukanja, Yang Xiao, Graham Su, Yang Liu, Xiaoyu Qin, Gorazd B. Rosoklija, Andrew J. Dwork, J. John Mann, Mina L. Xu, Stephanie Halene, Joseph E. Craft, Kam W. Leong, Maura Boldrini, Gonçalo Castelo-Branco, Rong Fan
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Floating perovskite-BiVO4 devices for scalable solar fuel production Nature (IF 69.504) Pub Date : 2022-08-17 Virgil Andrei, Geani M. Ucoski, Chanon Pornrungroj, Chawit Uswachoke, Qian Wang, Demetra S. Achilleos, Hatice Kasap, Katarzyna P. Sokol, Robert A. Jagt, Haijiao Lu, Takashi Lawson, Andreas Wagner, Sebastian D. Pike, Dominic S. Wright, Robert L. Z. Hoye, Judith L. MacManus-Driscoll, Hannah J. Joyce, Richard H. Friend, Erwin Reisner
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Ordered and deterministic cancer genome evolution after p53 loss Nature (IF 69.504) Pub Date : 2022-08-17 Timour Baslan, John P. Morris, Zhen Zhao, Jose Reyes, Yu-Jui Ho, Kaloyan M. Tsanov, Jonathan Bermeo, Sha Tian, Sean Zhang, Gokce Askan, Aslihan Yavas, Nicolas Lecomte, Amanda Erakky, Anna M. Varghese, Amy Zhang, Jude Kendall, Elena Ghiban, Lubomir Chorbadjiev, Jie Wu, Nevenka Dimitrova, Kalyani Chadalavada, Gouri J. Nanjangud, Chaitanya Bandlamudi, Yixiao Gong, Mark T. A. Donoghue, Nicholas D. Socci
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A compute-in-memory chip based on resistive random-access memory Nature (IF 69.504) Pub Date : 2022-08-17 Weier Wan, Rajkumar Kubendran, Clemens Schaefer, Sukru Burc Eryilmaz, Wenqiang Zhang, Dabin Wu, Stephen Deiss, Priyanka Raina, He Qian, Bin Gao, Siddharth Joshi, Huaqiang Wu, H.-S. Philip Wong, Gert Cauwenberghs
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Observation of Rabi dynamics with a short-wavelength free-electron laser Nature (IF 69.504) Pub Date : 2022-08-17 Saikat Nandi, Edvin Olofsson, Mattias Bertolino, Stefanos Carlström, Felipe Zapata, David Busto, Carlo Callegari, Michele Di Fraia, Per Eng-Johnsson, Raimund Feifel, Guillaume Gallician, Mathieu Gisselbrecht, Sylvain Maclot, Lana Neoričić, Jasper Peschel, Oksana Plekan, Kevin C. Prince, Richard J. Squibb, Shiyang Zhong, Philipp V. Demekhin, Michael Meyer, Catalin Miron, Laura Badano, Miltcho B. Danailov
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LACC1 bridges NOS2 and polyamine metabolism in inflammatory macrophages Nature (IF 69.504) Pub Date : 2022-08-17 Zheng Wei, Joonseok Oh, Richard A. Flavell, Jason M. Crawford
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Preservation of high-pressure volatiles in nanostructured diamond capsules Nature (IF 69.504) Pub Date : 2022-08-17 Zhidan Zeng, Jianguo Wen, Hongbo Lou, Xin Zhang, Liuxiang Yang, Lijie Tan, Benyuan Cheng, Xiaobing Zuo, Wenge Yang, Wendy L. Mao, Ho-kwang Mao, Qiaoshi Zeng
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A biochemical timer phases condensates in and out in cells Nature (IF 69.504) Pub Date : 2022-08-17 Guillaume Charras, Martin Lenz
Dynamic mechanism avoids clumping of the cell's actin cytoskeleton.