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Strain-Driven Solid–Solid Crystal Conversion in Chiral Hybrid Pseudo-Perovskites with Paramagnetic-to-Ferromagnetic Transition J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-02 Haining Zheng, Rongrong Zhang, Xiao Wu, Qihan Zhang, Zhenyue Wu, Walter P. D. Wong, Jingsheng Chen, Qing-Hua Xu, Kian Ping Loh
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Synthesis of Arynes via Formal Dehydrogenation of Arenes J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-02 Riley A. Roberts, Bryan E. Metze, Aleksandra Nilova, David R. Stuart
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ortho-Methoxycarbonylethynylphenyl Thioglycosides (MCEPTs): Versatile Glycosyl Donors Enabled by Electron-Withdrawing Substituents and Catalyzed by Gold(I) or Cu(II) Complexes J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-02 Hui Liu, Zhi-Fen Liang, Han-Jian Liu, Jin-Xi Liao, Li-Jun Zhong, Yuan-Hong Tu, Qing-Ju Zhang, Bin Xiong, Jian-Song Sun
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Water-Immiscible Coacervate as a Liquid Magnetic Robot for Intravascular Navigation J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-02 Pengchao Zhao, Fuyang Qu, Hao Fu, Jianyang Zhao, Jiaxin Guo, Jiankun Xu, Yi-Ping Ho, Michael K. Chan, Liming Bian
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Formation of Long-Lived Dark States during Electronic Relaxation of Pyrimidine Nucleobases Studied Using Extreme Ultraviolet Time-Resolved Photoelectron Spectroscopy J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Yuta Miura, Yo-ichi Yamamoto, Shutaro Karashima, Natsumi Orimo, Ayano Hara, Kanae Fukuoka, Tatsuya Ishiyama, Toshinori Suzuki
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Dissecting the Ultrafast Stepwise Bidirectional Proton Relay in a Blue-Light Photoreceptor J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Zijing Chen, Xiu-Wen Kang, Yalin Zhou, Zhongneng Zhou, Siwei Tang, Shuhua Zou, Kailin Wang, Jiulong Huang, Bei Ding, Dongping Zhong
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Structure and Site Evolution of Framework Ni Species in MIL-127 MOFs for Propylene Oligomerization Catalysis J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Benjamin Yeh, Saumil Chheda, Steven D. Prinslow, Adam S. Hoffman, Jiyun Hong, Jorge E. Perez-Aguilar, Simon R. Bare, Connie C. Lu, Laura Gagliardi, Aditya Bhan
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Controlled Synthesis of a Homopolymer Network Using a Well-Defined Single-Component Diels–Alder Cyclopentadiene Monomer J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Thi M. Tran, Javier Read de Alaniz
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Unraveling Sequential Oxidation Kinetics and Determining Roles of Multi-Cobalt Active Sites on Co3O4 Catalyst for Water Oxidation J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Wanchao Kang, Ruifang Wei, Heng Yin, Dongfeng Li, Zheng Chen, Qinge Huang, Pengfei Zhang, Huanwang Jing, Xiuli Wang, Can Li
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Light-Activated Assembly of Connexon Nanopores in Synthetic Cells J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Ahmed Z. Sihorwala, Alexander J. Lin, Jeanne C. Stachowiak, Brian Belardi
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Photoinduced Nickel-Catalyzed Selective N-Demethylation of Trialkylamines Using C(sp2)–Bromides as HAT Reagents J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Xiao Zhang, Yangyang Shen, Tomislav Rovis
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Enzymatic cis-Decalin Formation in Natural Product Biosynthesis J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Masao Ohashi, Dan Tan, Jiayan Lu, Cooper S. Jamieson, Daiki Kanayama, Jiahai Zhou, K. N. Houk, Yi Tang
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Cationic Single-Unit Monomer Insertion (cSUMI): From Discrete Oligomers to the α-/ω-End and In-Chain Sequence-Regulated Polymers J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Wei Tao, Wei He, Xuepu Feng, Guoqin Liu, Qiangqiang Shi, Jiajia Tan, Jinming Hu, Sheng Yang, Guhuan Liu, Ronghua Yang
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Multimodal-Responsive Circularly Polarized Luminescence Security Materials J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Qi Guo, Mingjiang Zhang, Zhi Tong, Shanshan Zhao, Yajie Zhou, Yaxin Wang, Shan Jin, Jie Zhang, Hong-Bin Yao, Manzhou Zhu, Taotao Zhuang
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Catalytic Cross-Metathesis Reactions That Afford E- and Z-Trisubstituted Alkenyl Bromides: Scope, Applications, and Mechanistic Insights J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Tobias Koengeter, Can Qin, Binh Khanh Mai, Qinghe Liu, Yucheng Mu, Peng Liu, Amir H. Hoveyda
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Correction to “Aerobic Photobiocatalysis Enabled by Combining Core–Shell Nanophotoreactors and Native Enzymes” J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-02-01 Wenxin Wei, Francesca Mazzotta, Ingo Lieberwirth, Katharina Landfester, Calum T. J. Ferguson, Kai A. I. Zhang
Page 7324. The following was omitted from the Acknowledgments in the original publication. Open access funded by Max Planck Society. F.M. acknowledges financial support from the SuperCol project that received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No. 860914. This article has not yet been cited by other publications
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Experimentally Validated Ab Initio Crystal Structure Prediction of Novel Metal–Organic Framework Materials J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-01-31 Yizhi Xu, Joseph M. Marrett, Hatem M. Titi, James P. Darby, Andrew J. Morris, Tomislav Friščić, Mihails Arhangelskis
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Z-Trisubstituted α,β-Unsaturated Esters and Acid Fluorides through Stereocontrolled Catalytic Cross-Metathesis J. Am. Chem. Soc. (IF 16.383) Pub Date : 2023-01-31 Can Qin, Tobias Koengeter, Fengyue Zhao, Yucheng Mu, Fang Liu, K. N. Houk, Amir H. Hoveyda
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Recent Development of Halide Perovskite Materials and Devices for Ionizing Radiation Detection Chem. Rev. (IF 72.087) Pub Date : 2023-02-02 Xiaoyu He, Yao Deng, Decai Ouyang, Na Zhang, Jing Wang, Akshay A. Murthy, Ioannis Spanopoulos, Saiful M. Islam, Qing Tu, Guichuan Xing, Yuan Li, Vinayak P. Dravid, Tianyou Zhai
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2D II–VI Semiconductor Nanoplatelets: From Material Synthesis to Optoelectronic Integration Chem. Rev. (IF 72.087) Pub Date : 2023-02-01 Benjamin T. Diroll, Burak Guzelturk, Hong Po, Corentin Dabard, Ningyuan Fu, Lina Makke, Emmanuel Lhuillier, Sandrine Ithurria
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Understanding Nanocellulose–Water Interactions: Turning a Detriment into an Asset Chem. Rev. (IF 72.087) Pub Date : 2023-02-01 Laleh Solhi, Valentina Guccini, Katja Heise, Iina Solala, Elina Niinivaara, Wenyang Xu, Karl Mihhels, Marcel Kröger, Zhuojun Meng, Jakob Wohlert, Han Tao, Emily D. Cranston, Eero Kontturi
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Predicting accidental release of engineered nanomaterials to the environment Nat. Nanotechnol. (IF 40.523) Pub Date : 2023-02-02 Fadri Gottschalk, Bruno Debray, Fred Klaessig, Barry Park, Jean-Marc Lacome, Alexis Vignes, Vicenç Pomar Portillo, Socorro Vázquez-Campos, Christine Ogilvie Hendren, Stephen Lofts, Samuel Harrison, Claus Svendsen, Ralf Kaegi
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How France became the unlikely home of the insect-farming industry Nature (IF 69.504) Pub Date : 2023-02-02
The country is known for its love of meat. Could the growing insect industry help to reduce agricultural carbon emissions?
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Fluffball foxes wander thousands of kilometres to find a home Nature (IF 69.504) Pub Date : 2023-02-01
The Arctic fox, which weighs less than many house cats, covers long distances in the frigid north.
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Pill for a skin disease also curbs excessive drinking Nature (IF 69.504) Pub Date : 2023-02-01
The drug apremilast reduces alcohol intake in mice bred to imbibe to excess and in humans with alcohol-use disorder.
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Field-linked resonances of polar molecules Nature (IF 69.504) Pub Date : 2023-02-01 Xing-Yan Chen, Andreas Schindewolf, Sebastian Eppelt, Roman Bause, Marcel Duda, Shrestha Biswas, Tijs Karman, Timon Hilker, Immanuel Bloch, Xin-Yu Luo
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Measurement of the axial vector form factor from antineutrino–proton scattering Nature (IF 69.504) Pub Date : 2023-02-01 T. Cai, M. L. Moore, A. Olivier, S. Akhter, Z. Ahmad Dar, V. Ansari, M. V. Ascencio, A. Bashyal, A. Bercellie, M. Betancourt, A. Bodek, J. L. Bonilla, A. Bravar, H. Budd, G. Caceres, M. F. Carneiro, G. A. Díaz, H. da Motta, J. Felix, L. Fields, A. Filkins, R. Fine, A. M. Gago, H. Gallagher, S. M. Gilligan, R. Gran, E. Granados, D. A. Harris, S. Henry, D. Jena, S. Jena, J. Kleykamp, A. Klustová, M.
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Pseudospin-selective Floquet band engineering in black phosphorus Nature (IF 69.504) Pub Date : 2023-02-01 Shaohua Zhou, Changhua Bao, Benshu Fan, Hui Zhou, Qixuan Gao, Haoyuan Zhong, Tianyun Lin, Hang Liu, Pu Yu, Peizhe Tang, Sheng Meng, Wenhui Duan, Shuyun Zhou
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Fish fossil unfolds clues to vertebrate brain evolution Nature (IF 69.504) Pub Date : 2023-02-01 Hugo Dutel, Matteo Fabbri
A 319-million-year-old tissue is the oldest known vertebrate brain.
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Fieldwork: how to gain access to research participants Nature (IF 69.504) Pub Date : 2023-02-01
It took experience and emotional investment to improve my ability to get close to research participants. Here’s how I did it, says Anna Lena Bercht.
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Light-activated catalysts point the way to sustainable chemistry Nature (IF 69.504) Pub Date : 2023-02-01 Emiliano Cortés
Earth-abundant plasmonic catalysts for ammonia decomposition.
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Could solar panels in space supply Earth with clean energy? Nature (IF 69.504) Pub Date : 2023-02-01
As a prototype prepares for tests in orbit, Nature looks at five of the biggest challenges for space-based solar power.
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The next generation of coronavirus vaccines: a graphical guide Nature (IF 69.504) Pub Date : 2023-02-01
New technologies might provide more potent or broader immunity — but will have to fight for market share.
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Light tailors the electronic properties of a model semiconductor Nature (IF 69.504) Pub Date : 2023-02-01 Alberto Crepaldi
Time-dependent engineering of irradiated black phosphorus.
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For optimal antibody effectiveness, sometimes less is more Nature (IF 69.504) Pub Date : 2023-02-01 Christoph Wülfing, Simon J. Dovedi
Modulating receptor-binding affinity influences antibody effectiveness.
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How a grisly historical accident set one neuroscientist on the road to writing a book Nature (IF 69.504) Pub Date : 2023-02-01
A psychology class about railway engineer Phineas Gage’s behaviour change after a metal rod speared his brain in 1848 led Chantel Prat, author of The Neuroscience of You, switching disciplines.
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The surprising chemicals used to embalm Egyptian mummies Nature (IF 69.504) Pub Date : 2023-02-01
Resins used to prepare bodies for the afterlife are found in vessels in an ancient workshop.
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Daily briefing: ‘De-extinction’ company wants to bring back the dodo Nature (IF 69.504) Pub Date : 2023-02-01
Colossal Biosciences says its genetic technologies could revive the extinct bird. Plus, how scientists are rethinking the origins of depression and visual guide to the next generation of COVID-19 vaccines.
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Studying spin physics with moving molecules Nature (IF 69.504) Pub Date : 2023-02-01
Dipolar interactions between rotating molecules in motion can be tuned to give rise to rich dynamics.
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Recipes and ingredients for ancient Egyptian mummification Nature (IF 69.504) Pub Date : 2023-02-01 Salima Ikram
Analysis of labelled pots offers insights into embalming methods.
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Ultracold molecules find the sweet spot for collisions Nature (IF 69.504) Pub Date : 2023-02-01 Sebastian Will, Tanya Zelevinsky
Resonances used to enhance molecular reactions.
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When will COVID stop being a global emergency? Nature (IF 69.504) Pub Date : 2023-02-01
The World Health Organization has decided the crisis isn’t over yet — but it’s at a transition point.
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Scientists — counter lobbyists to shape environment policy Nature (IF 69.504) Pub Date : 2023-01-31
Letter to the Editor
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Where infectious diseases erupt, and more — this week’s best science graphics Nature (IF 69.504) Pub Date : 2023-01-31
Three charts from the world of research, selected by Nature editors.
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Daily briefing: Coffee works by borrowing your energy Nature (IF 69.504) Pub Date : 2023-01-31
Caffeine blocks a brain receptor to stave off the drowsy feeling — but it can return with a vengeance. Plus, pandemic school closures cost children one-third of a year’s learning and how machines could spot alien signals that humans miss.
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Why we have nothing to fear from the decolonization of mathematics Nature (IF 69.504) Pub Date : 2023-01-31
Maths made the modern world — and everyone stands to gain from the acknowledgment that the world made maths.
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Asia faces weather whiplash as Earth warms Nature (IF 69.504) Pub Date : 2023-01-30
Floods followed by droughts, or droughts followed by floods, will rise in frequency in a warming world.
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Bacterial defence repurposed to fight blight Nature (IF 69.504) Pub Date : 2023-01-30 Andrew Mitchinson
Natural products that protect plants from a common disease.
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Assigning 1H Chemical Shifts in Paramagnetic Mono and Bimetallic Surface Sites using DFT: a Case Study on the Union Carbide Polymerization Catalyst Chem. Sci. (IF 9.969) Pub Date : 2023-02-02 Anna Nobile, David Trummer, Zach Berkson, Michael Wörle, Christophe Coperet, Pierre-Adrien Payard
The Union Carbide (UC) ethylene polymerization catalyst, based on silica-supported chromocene, is one of the first industrial catalysts prepared by surface organometallic chemistry, though the structure of the surface sites remains elusive. Recently, our group reported that monomeric and dimeric Cr (II) sites as well as Cr(III) hydride sites are present and that their proportion varies as a function
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Mechanochemical Solid State Single Electron Transfer from Reduced Organic Hydrocarbon for Catalytic Aryl-halide Bond Activation Chem. Sci. (IF 9.969) Pub Date : 2023-02-02 Amit Biswas, Anup Bhunia, Swadhin K Mandal
Solid-state radical generation is an attractive but underutilized methodology in the catalytic strong bond activation process, such as the aryl-halide bond. Traditionally, such a process of strong bond activation relied upon the use of transition metal complexes or strongly reducing photocatalysts in organic solvents. The generation of the aryl radical from aryl halides in the absence of transition-metal
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Intramolecular trapping of the spiro radicals to unusual cyclization products from the usual migration substrates Chem. Sci. (IF 9.969) Pub Date : 2023-02-02 Jingming Zhang, Chengkou Liu, Yaqi Qiao, Minghui Wei, Wenjing Guan, Ziren Mao, Hong Qin, Zheng Fang, Kai Guo
A conceptually new methodology to give unusual cyclization products from the usual migration substrates was disclosed. The highly complex and structurally important and valuable spirocyclic compounds were produced through radical addition, intramolecular cyclization and ring-opening instead of usual migration to the di-functionalization products of olefins. Furthermore, a plausible mechanism was proposed
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Unraveling deposition/dissolution chemistry of MnO2 for high-energy aqueous batteries Energy Environ. Sci. (IF 39.714) Pub Date : 2023-02-01 Xiaolin Ye, Daliang Han, Guangyi Jiang, Changjun Cui, Yong Guo, Yaogang Wang, Zhicheng Zhang, Zhe Weng, Quanhong Yang
Aqueous rechargeable batteries based on the deposition/dissolution of MnO2 are drawing significant attention because of their record-high theoretical capacity and redox potential in addition to their low cost and high safety. However, the deposition/dissolution chemistry of MnO2 remains elusive, which must be overcome for it to be used in batteries. Herein, we used an in situ electrochemical quartz
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Charge and Mass Transport Mechanisms in Two-Dimensional Covalent Organic Frameworks (2D COFs) for Electrochemical Energy Storage Devices Energy Environ. Sci. (IF 39.714) Pub Date : 2023-02-01 Hanyin Zhang, Yubo Geng, Jin Huang, Zixiao Wang, Kun Du, Haoyuan Li
The development of smartphones and electric cars calls for electrochemical energy storage devices with higher capacities, faster charging rates, and improved safety. A key to developing these devices is the discovery of better electrode and electrolyte materials. Over the past few years, a new type of organic materials, two-dimensional covalent organic frameworks (2D COFs), have attracted increasing
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An Efficient High-entropy Perovskite-type Air Electrode for Reversible Oxygen Reduction and Water Splitting in Protonic Ceramic Cells Adv. Mater. (IF 32.086) Pub Date : 2023-02-01 Fan He, Yucun Zhou, Tong Hu, Yangsen Xu, Mingyang Hou, Feng Zhu, Dongliang Liu, Hua Zhang, Kang Xu, Meilin Liu, Yu Chen
Reversible protonic ceramic electrochemical cells (R-PCECs) are emerging as ideal devices for highly efficient energy conversion (generating electricity) and storage (producing H2) at intermediate temperatures (400-700°C). However, their commercialization is largely hindered by the development of highly efficient air electrodes for oxygen reduction and water-splitting reactions. Here we report our
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Near Zero-threshold Voltage P-N Junction Diodes Based on Super-semiconducting Nanostructured Ag/Al Arrays Adv. Mater. (IF 32.086) Pub Date : 2023-02-01 Zhigang Li, Jiteng Li, Weike Wang, Qijie Yan, Yongrui Zhou, Luping Zhu, Bingqiang Cao, Bingqing Wei
Semiconductor devices are currently one of the most common energy consumption devices. Significantly reducing the energy consumption of semiconductor devices with advanced energy-efficient technologies is highly desirable. The discovery of super-semiconductors (SSCs) based on metallic bi-layer shell arrays provides an opportunity to realize ultra-low-power consumption semiconductors devices. As an
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Effect of Phosphorus Modulation in Iron Single-Atom Catalysts for Peroxidase Mimicking Adv. Mater. (IF 32.086) Pub Date : 2023-02-01 Shichao Ding, Jordan Alysia Barr, Zhaoyuan Lyu, Fangyu Zhang, Maoyu Wang, Peter Tieu, Xin Li, Mark H. Engelhard, Zhenxing Feng, Scott P. Beckman, Xiaoqing Pan, Jin-cheng Li, Dan Du, Yuehe Lin
Fe-N-C single-atom catalysts (SACs) exhibit excellent peroxidase (POD)-like catalytic activity, owing to their well-defined isolated iron active sites on the carbon substrate, which effectively mimic the Fe-Nx active site's structure of natural peroxidase. To further meet the requirements of diverse biosensing applications, SACs POD-like activity still needs to be continuously enhanced. Herein, we
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Enzymatically Crosslinked Collagen as Versatile Matrix for In Vitro and In Vivo Co-Engineering of Blood and Lymphatic Vasculature Adv. Mater. (IF 32.086) Pub Date : 2023-02-01 Dominic Rütsche, Monica Nanni, Simon Rüdisser, Thomas Biedermann, Marcy Zenobi-Wong
Adequate vascularization is required for the successful translation of many in vitro engineered tissues. This study presents a novel collagen derivative that harbors multiple recognition peptides for orthogonal enzymatic crosslinking based on sortase A and Factor XIII. Sortase A-mediated crosslinking enables the rapid co-engineering of human blood and lymphatic microcapillaries and mesoscale capillaries
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Energy Efficient Neuro-inspired Phase Change Memory Based on Ge4Sb6Te7 as a Novel Epitaxial Nanocomposite Adv. Mater. (IF 32.086) Pub Date : 2023-01-31 Asir Intisar Khan, Heshan Yu, Huairuo Zhang, John R. Goggin, Heungdong Kwon, Xiangjin Wu, Christopher Perez, Kathryn M. Neilson, Mehdi Asheghi, Kenneth E Goodson, Patrick M. Vora, Albert Davydov, Ichiro Takeuchi, Eric Pop
Phase change memory (PCM) is a promising candidate for neuro-inspired, data-intensive artificial intelligence applications, which relies on the physical attributes of PCM materials including gradual change of resistance states and multilevel operation with low resistance drift. However, achieving these attributes simultaneously remains a fundamental challenge for PCM materials such as Ge2Sb2Te5, the
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Hierarchical Composite Self-Sorted Supramolecular Gel Noodles Adv. Mater. (IF 32.086) Pub Date : 2023-01-31 Libby J. Marshall, Matthew Wallace, Najet Mahmoudi, Giuseppe Ciccone, Claire Wilson, Massimo Vassalli, Dave J. Adams
Multicomponent supramolecular systems can be used to achieve different properties and new behaviors compared to their corresponding single component systems. Here, we use a two-component system, showing that a non-gelling component modifies the assembly of the gelling component, allowing access to co-assembled structures that cannot be formed from the gelling component alone. We characterize the systems