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Gold Nanorods: The Most Versatile Plasmonic Nanoparticles Chem. Rev. (IF 60.622) Pub Date : 2021-09-27 Jiapeng Zheng, Xizhe Cheng, Han Zhang, Xiaopeng Bai, Ruoqi Ai, Lei Shao, Jianfang Wang
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Ionic Liquid Electrolyte with Enhanced Li+ Transport Ability Enables Stable Li Deposition for High-Performance Li-O2 Batteries Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 Yichao Cai, Qiu Zhang, Yong Lu, Zhimeng Hao, Youxuan Ni, Jun Chen
Bis(trifluoromethanesulfonyl)imide-based ionic liquid (TFSI-IL) electrolyte could endow Li-O 2 batteries with low charging overpotential. However, the weak Li + transport ability (LTA) leads to non-uniform Li deposition. Herein, guided by Sand formula, the LTA of TFSI-IL electrolyte is greatly enhanced to realize robust Li deposition through introducing hydrofluoroether (HFE) and optimizing electrolyte
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Enhanced ribozyme-catalyzed recombination and oligonucleotide assembly in peptide-RNA condensates Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 Kristian Kyle Le Vay, Emilie Yeonwha Song, Basusree Ghosh, T-Y Dora Tang, Hannes Mutschler
The ability of RNA to catalyze RNA ligation is critical to its central role in many prebiotic model scenarios, in particular the copying of information during self-replication. Prebiotically plausible ribozymes formed from short oligonucleotides can catalyze reversible RNA cleavage and ligation reactions, but harsh conditions or unusual scenarios are often required to promote folding and drive the
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NMR spectroscopy of the main protease of SARS-CoV-2 and fragment-based screening identify three protein hotspots and an antiviral fragment Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 François-Xavier Cantrelle, Emmanuelle Boll, Lucile Brier, Danai Moschidi, Sandrine Belouzard, Valérie Landry, Florence Leroux, Frédérique Dewitte, Isabelle Landrieu, Jean Dubuisson, Benoit Deprez, Julie Charton, Xavier Hanoulle
The main protease (3CLp) of the SARS-CoV-2, the causative agent for the COVID-19 pandemic, is one of the main targets for drug development. To be active, 3CLp relies on a complex interplay between dimerization, active site flexibility, and allosteric regulation. The deciphering of these mechanisms is a crucial step to enable the search for inhibitors. In this context, using NMR spectroscopy, we studied
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Angewandte Chemie Launches Scientific Perspectives and Viewpoint Articles Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 Pilar Calleja, Eric Castro, Kim Meyer, Lisa Pecher, Rachel Schmidt-Radde, Mathias Wiechen
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Corrigendum: Mechanistic Investigation on Copper–Arylacetylide Polymerization and Sensing Applications Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 Quanduo Liang, Xiaoyong Chang, Ya-qiong Su, Samuel M. Mugo, Qiang Zhang
Two corresponding authors must be added to the author list of this Research Article: Prof. Zheng Bian, Prof. Guangshan Zhu Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education, Faculty of Chemistry Northeast Normal University (P. R. China) E-mail: bianz070@nenu.edu.cn E-mail: zhugs100@nenu.edu.cn In the article main text on page 18015, right column, the word
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Corrigendum: Beyond the Polysulfide Shuttle and Lithium Dendrite Formation: Addressing the Sluggish Sulfur Redox Kinetics for Practical High-Energy Li-S Batteries Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 Chen Zhao, Gui-Liang Xu, Tianshou Zhao, Khalil Amine
In this Research Article, Figure 2 and Figure 3 were swapped during the publication process. Therefore, the position of Figure 2 and Figure 3 needs to be switched, while the Figure captions remain unchanged.
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Corrigendum: Imidazotetrazines as Weighable Diazomethane Surrogates for Esterifications and Cyclopropanations Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-09-27 Riley L. Svec, Paul J. Hergenrother
Temozolomide (TMZ) was FDA approved for treatment of glioblastoma (GBM) in 1995 and is a life-extending (and sometimes life-saving1) drug for GBM and other cancers.2 TMZ has been administered to thousands of patients and has been shipped around the world for over three decades; patients typically ingest grams of TMZ during a standard treatment regimen.3 We recently reported the use of TMZ as a reagent
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Metagenome-Guided Analogue Synthesis Yields Improved Gram-Negative-Active Albicidin- and Cystobactamid-Type Antibiotics Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-05 Zongqiang Wang, Amanda Kasper, Rabia Mehmood, Melinda Ternei, Shaogang Li, Joel S. Freundlich, Sean F. Brady
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Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-07-28 Daniels Posevins, Aitor Bermejo-López, Jan-E. Bäckvall
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Construction of Co–Mn Prussian Blue Analog Hollow Spheres for Efficient Aqueous Zn-ion Batteries Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-07-27 Yinxiang Zeng, Xue Feng Lu, Song Lin Zhang, Deyan Luan, Sheng Li, Xiong Wen (David) Lou
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Photoresponsive Palladium and Nickel Catalysts for Ethylene Polymerization and Copolymerization Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-07-26 Dan Peng, Changle Chen
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Rhodium(I) Complexes Bearing an Aryl-Substituted 1,3,5-Hexatriene Chain: Catalysts for Living Polymerization of Phenylacetylene and Potential Helical Chirality of 1,3,5-Hexatrienes Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-05 Shiori Sakamoto, Tsuyoshi Taniguchi, Yoko Sakata, Shigehisa Akine, Tatsuya Nishimura, Katsuhiro Maeda
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Nγ-Hydroxyasparagine: A Multifunctional Unnatural Amino Acid That is a Good P1 Substrate of Asparaginyl Peptide Ligases Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-15 Yiyin Xia, Janet To, Ning-Yu Chan, Side Hu, Heng Tai Liew, Seetharamsing Balamkundu, Xiaohong Zhang, Julien Lescar, Surajit Bhattacharjya, James P. Tam, Chuan-Fa Liu
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Polymer Topology Reinforced Synergistic Interactions among Nanoscale Molecular Clusters for Impact Resistance with Facile Processability and Recoverability Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-10 Jia-Fu Yin, Haiyan Xiao, Peidong Xu, Junsheng Yang, Zhiwei Fan, Yubin Ke, Xikai Ouyang, Geng Xin Liu, Tao Lin Sun, Liqun Tang, Stephen Z. D. Cheng, Panchao Yin
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Truce–Smiles Rearrangements by Strain Release: Harnessing Primary Alkyl Radicals for Metal-Free Arylation Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-09 David M. Whalley, Jayasree Seayad, Michael F. Greaney
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Enantioselective Lactonization by π-Acid-Catalyzed Allylic Substitution: A Complement to π-Allylmetal Chemistry Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-22 Arun Raj Kizhakkayil Mangadan, Ji Liu, Aaron Aponick
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Three-Dimensional Radical Covalent Organic Frameworks as Highly Efficient and Stable Catalysts for Selective Oxidation of Alcohols Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-13 Fengqian Chen, Xinyu Guan, Hui Li, Jiehua Ding, Liangkui Zhu, Bin Tang, Valentin Valtchev, Yushan Yan, Shilun Qiu, Qianrong Fang
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Catalytic Asymmetric Darzens-Type Epoxidation of Diazoesters: Highly Enantioselective Synthesis of Trisubstituted Epoxides Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Dong Guk Nam, Su Yong Shim, Hye-Min Jeong, Do Hyun Ryu
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High-Performance Ultraviolet Organic Light-Emitting Diode Enabled by High-Lying Reverse Intersystem Crossing Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-13 Han Zhang, Ganggang Li, Xiaomin Guo, Kai Zhang, Bing Zhang, Xuecheng Guo, Yuxuan Li, Jianzhong Fan, Zhiming Wang, Dongge Ma, Ben Zhong Tang
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Double Double to Double Perovskite Transformations in Quaternary Manganese Oxides Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-09 Kunlang Ji, Khalid N. Alharbi, Elena Solana-Madruga, Gessica T. Moyo, Clemens Ritter, J. Paul Attfield
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Near-Infrared-Excited Multicolor Afterglow in Carbon Dots-Based Room-Temperature Afterglow Materials Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-13 Yihao Zheng, Haopeng Wei, Ping Liang, Xiaokai Xu, Xingcai Zhang, Huihong Li, Chenlu Zhang, Chaofan Hu, Xuejie Zhang, Bingfu Lei, Wai-Yeung Wong, Yingliang Liu, Jianle Zhuang
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Preparation of Bulk-Phase Nitride Perovskite LaReN3 and Topotactic Reduction to LaNiO2-Type LaReN2 Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-06 Simon D. Kloß, Martin L. Weidemann, J. Paul Attfield
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A Lamellar MXene (Ti3C2Tx)/PSS Composite Membrane for Fast and Selective Lithium-Ion Separation Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-11 Zong Lu, Ying Wu, Li Ding, Yanying Wei, Haihui Wang
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Forrestiacids A and B, Pentaterpene Inhibitors of ACL and Lipogenesis: Extending the Limits of Computational NMR Methods in the Structure Assignment of Complex Natural Products Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-10 Juan Xiong, Peng-Jun Zhou, Hao-Wen Jiang, Ting Huang, Yu-Hang He, Ze-Yu Zhao, Yi Zang, Yeun-Mun Choo, Xiaojuan Wang, Amar G. Chittiboyina, Pankaj Pandey, Mark T. Hamann, Jia Li, Jin-Feng Hu
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Electronic Modulation Caused by Interfacial Ni-O-M (M=Ru, Ir, Pd) Bonding for Accelerating Hydrogen Evolution Kinetics Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-23 Liming Deng, Feng Hu, Mingyue Ma, Shao-Chu Huang, Yixing Xiong, Han-Yi Chen, Linlin Li, Shengjie Peng
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Fabrication of Integrated Copper-Based Nanoparticles/Amorphous Metal–Organic Framework by a Facile Spray-Drying Method: Highly Enhanced CO2 Hydrogenation Activity for Methanol Synthesis Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-11 Yuko Mitsuka, Naoki Ogiwara, Megumi Mukoyoshi, Hiroshi Kitagawa, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Masaaki Haneda, Shogo Kawaguchi, Yoshiki Kubota, Hirokazu Kobayashi
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Dihydrogen Activation by Lithium- and Sodium-Aluminyls Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-16 Matthew J. Evans, Mathew D. Anker, Claire L. McMullin, Sam E. Neale, Martyn P. Coles
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Probing the Extremes of Covalency in M−Al bonds: Lithium and Zinc Aluminyl Compounds Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-15 Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge
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In-Situ Encapsulation of Protein into Nanoscale Hydrogen-Bonded Organic Frameworks for Intracellular Biocatalysis Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Jiakang Tang, Ji Liu, Qizhen Zheng, Wenting Li, Jinhan Sheng, Lanqun Mao, Ming Wang
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Key Features of Polyimide-Derived Carbon Molecular Sieves Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Wulin Qiu, Johannes E. Leisen, Zhongyun Liu, Wenying Quan, William J. Koros
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Facet-Dependent Oxidative Strong Metal-Support Interactions of Palladium–TiO2 Determined by In Situ Transmission Electron Microscopy Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-05 Min Tang, Songda Li, Shiyuan Chen, Yang Ou, Matsumoto Hiroaki, Wentao Yuan, Beien Zhu, Hangsheng Yang, Yi Gao, Ze Zhang, Yong Wang
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Iron-Catalyzed Reductive Cyclization by Hydromagnesiation: A Modular Strategy Towards N-Heterocycles Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-18 Joachim Loup, Egor M. Larin, Mark Lautens
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Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear PtII→GeIV Complex Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-16 Mohammadjavad Karimi, Elham S. Tabei, Remi Fayad, Mohamed R. Saber, Evgeny O. Danilov, Cameron Jones, Felix N. Castellano, François P. Gabbaï
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Discrete Heteropolynuclear Yb/Er Assemblies: Switching on Molecular Upconversion Under Mild Conditions Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Jie Wang, Yue Jiang, Jiao-Yang Liu, Hai-Bing Xu, Yue-Xing Zhang, Xu Peng, Mohamedally Kurmoo, Seik Weng Ng, Ming-Hua Zeng
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A Borondifluoride-Complex-Based Photothermal Agent with an 80 % Photothermal Conversion Efficiency for Photothermal Therapy in the NIR-II Window Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-07-20 Zhiyong Jiang, Changli Zhang, Xiaoqing Wang, Ming Yan, Zongxin Ling, Yuncong Chen, Zhipeng Liu
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A Tale of Two Isomers: Enhanced Antiaromaticity/Diradical Character versus Deleterious Ring-Opening of Benzofuran-fused s-Indacenes and Dicyclopenta[b,g]naphthalenes Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Joshua E. Barker, Tavis W. Price, Lucas J. Karas, Ryohei Kishi, Samantha N. MacMillan, Lev N. Zakharov, Carlos J. Gómez-García, Judy I. Wu, Masayoshi Nakano, Michael M. Haley
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Palladium-Catalyzed Cascade Carbonylation to α,β-Unsaturated Piperidones via Selective Cleavage of Carbon–Carbon Triple Bonds Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Yao Ge, Fei Ye, Ji Yang, Anke Spannenberg, Haijun Jiao, Ralf Jackstell, Matthias Beller
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Tertiary Chiral Nanostructures from C−H⋅⋅⋅F Directed Assembly of Chiroptical Superatoms Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Hui Shen, Zhen Xu, Lingzheng Wang, Ying-Zi Han, Xianhu Liu, Sami Malola, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng
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Restriction of Intramolecular Vibration in Aggregation-Induced Emission Luminogens: Applications in Multifunctional Luminescent Metal–Organic Frameworks Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-03 Yuan Yuan Liu, Xin Zhang, Kai Li, Qiu Chen Peng, Yu Jing Qin, Hong Wei Hou, Shuang Quan Zang, Ben Zhong Tang
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Bending for Better: Flexible Organic Single Crystals with Controllable Curvature and Curvature-Related Conductivity for Customized Electronic Devices Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-10 Yifu Chen, Zewei Chang, Jiaxing Zhang, Junbo Gong
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Ionic Functionalization of Multivariate Covalent Organic Frameworks to Achieve an Exceptionally High Iodine-Capture Capacity Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-24 Yaqiang Xie, Tingting Pan, Qiong Lei, Cailing Chen, Xinglong Dong, Youyou Yuan, Jie Shen, Yichen Cai, Chunhui Zhou, Ingo Pinnau, Yu Han
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Controlling Coagulation in Blood with Red Light Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-07-22 Patricia Müller, Marlen Sahlbach, Simone Gasper, Günter Mayer, Jens Müller, Bernd Pötzsch, Alexander Heckel
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A Congruent-Melting Mid-Infrared Nonlinear Optical Vanadate Exhibiting Strong Second-Harmonic Generation Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark G. Humphrey, Chi Zhang
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Regio-controllable Cobalt-Catalyzed Sequential Hydrosilylation/Hydroboration of Arylacetylenes Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Zhaoyang Cheng, Jun Guo, Yufeng Sun, Yushan Zheng, Zhehong Zhou, Zhan Lu
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Base-Activated Latent Heteroaromatic Sulfinates as Nucleophilic Coupling Partners in Palladium-Catalyzed Cross-Coupling Reactions Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-02 Xinlan A. F. Cook, Loïc R. E. Pantaine, David C. Blakemore, Ian B. Moses, Neal W. Sach, Andre Shavnya, Michael C. Willis
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Steric Hindrance Drives the Boron-Initiated Polymerization of Dienyltriphenylarsonium Ylides to Photoluminescent C5-Polymers Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-13 Xin Wang, Nikos Hadjichristidis
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Rapid Access to Ordered Mesoporous Carbons for Chemical Hydrogen Storage Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Uiseok Jeong, HyeonJi Kim, Sreerangappa Ramesh, Nesibe A. Dogan, Sirinapa Wongwilawan, Sungsu Kang, Jungwon Park, Eun Seon Cho, Cafer T. Yavuz
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Radical Trifluoroacetylation of Alkenes Triggered by a Visible-Light-Promoted C–O Bond Fragmentation of Trifluoroacetic Anhydride Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-07-21 Kun Zhang, David Rombach, Nicolas Yannick Nötel, Gunnar Jeschke, Dmitry Katayev
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An Open-Shell Coronoid with Hybrid Chichibabin–Schlenk Conjugation Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Bibek Prajapati, Duy-Khoi Dang, Piotr J. Chmielewski, Marcin A. Majewski, Tadeusz Lis, Carlos J. Gómez-García, Paul M. Zimmerman, Marcin Stępień
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Dynamic Constitutional Frameworks as Antibacterial and Antibiofilm Agents Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Andrei Diaconu, Tom Coenye, Mihail Barboiu, Stéphane P. Vincent
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Activity Trends and Mechanisms in Peroxymonosulfate-Assisted Catalytic Production of Singlet Oxygen over Atomic Metal-N-C Catalysts Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-13 Yun Gao, Tongwei Wu, Chengdong Yang, Chao Ma, Zhenyang Zhao, Zihe Wu, Sujiao Cao, Wei Geng, Yi Wang, Yongyi Yao, Yanning Zhang, Chong Cheng
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Polyoxometalate-Based Metal–Organic Framework as Molecular Sieve for Highly Selective Semi-Hydrogenation of Acetylene on Isolated Single Pd Atom Sites Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-09 Yiwei Liu, Bingxue Wang, Qiang Fu, Wei Liu, Yu Wang, Lin Gu, Dingsheng Wang, Yadong Li
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Ordered Conformation-Regulated Vesicular Membrane Permeability Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-14 Yi Zheng, Zuojie Wang, Zifen Li, Hang Liu, Jing Wei, Chuan Peng, Yeqiang Zhou, Jianshu Li, Qiang Fu, Hong Tan, Mingming Ding
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Feedback and Communication in Active Hydrogel Spheres with pH Fronts: Facile Approaches to Grow Soft Hydrogel Structures Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-04 Indrajit Maity, Charu Sharma, Francisco Lossada, Andreas Walther
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O-to-S Substitution Enables Dovetailing Conflicting Cyclizability, Polymerizability, and Recyclability: Dithiolactone vs. Dilactone Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-23 Yanchao Wang, Maosheng Li, Jinlong Chen, Youhua Tao, Xianhong Wang
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18.77 % Efficiency Organic Solar Cells Promoted by Aqueous Solution Processed Cobalt(II) Acetate Hole Transporting Layer Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-21 Huifeng Meng, Chentong Liao, Min Deng, Xiaopeng Xu, Liyang Yu, Qiang Peng
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A Family of Heterobimetallic Cubes Shows Spin-Crossover Behaviour Near Room Temperature Angew. Chem. Int. Ed. (IF 15.336) Pub Date : 2021-08-12 Matthias Hardy, Jacopo Tessarolo, Julian J. Holstein, Niklas Struch, Norbert Wagner, Ralf Weisbarth, Marianne Engeser, Johannes Beck, Shinnosuke Horiuchi, Guido H. Clever, Arne Lützen
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