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Disentangling the Catalytic Mechanisms of C60-Buffered Cu/SiO2 Catalyst for DMO-to-EG Conversion ACS Catal. (IF 11.3) Pub Date : 2024-09-20 Jianzhi Xu, Zhen-Chao Long, Zuo-Chang Chen, Chang-Feng Zhu, Hong-Guang Xu, Jian-Wei Zheng, Ewald Janssens, Wei-Jun Zheng, Gao-Lei Hou, Su-Yuan Xie
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Confinement Catalysis of Reaction Intermediates in Ag@Cu2O Cascade Nanoreactors toward Boosted Electrochemical C–C Coupling ACS Catal. (IF 11.3) Pub Date : 2024-09-20 Yonglian Lu, Honglin Li, Hongman Sun, Jiatai Zhao, Yu Zhang, Youhe Wang, Chuanyong Zhu, Dunfeng Gao, Yongxiao Tuo, Jingbin Zeng, De Chen, Zifeng Yan
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Carbon-Chain Elongation by Co-Catalyzed Selective C–C Bond Cleavage and Subsequent Silylperoxylation of Alkene Substrates ACS Catal. (IF 11.3) Pub Date : 2024-09-20 Jia-Hao Xie, Terumasa Kato, Keiji Maruoka
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Mechanistic Insights into CO Reactivity on Iron-Based Catalysts: Role of Surface Atomic Carbon ACS Catal. (IF 11.3) Pub Date : 2024-09-19 Richard Gubo, Daniel García Rodríguez, He Wang, Pengju Ren, Han Xiao, Xiue Li, XueQian Pang, Xin Yu, Jian Xu, Xiao-Dong Wen, Yong Yang, Yong-Wang Li, J.W. Hans Niemantsverdriet, C.J. Kees-Jan Weststrate
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Bifunctional Imine Reductase Cascades for the Synthesis of Saturated N-Heterocycles ACS Catal. (IF 11.3) Pub Date : 2024-09-19 Jeremy I. Ramsden, Bruna Zucoloto da Costa, Rachel S. Heath, James R. Marshall, Sasha R. Derrington, Juan Mangas-Sanchez, Sarah L. Montgomery, Keith R. Mulholland, Sebastian C. Cosgrove, Nicholas J. Turner
Saturated N-heterocycles constitute a vital scaffold for pharmaceutical chemistry but are challenging to access synthetically, particularly asymmetrically. Here, we demonstrate how imine reductases can achieve annulation through tandem inter- and intramolecular reductive amination processes. Imine reductases were used in combination with further enzymes to access unsubstituted, α-substituted, and α
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Traceless Acetal-Directed Catalytic Hydrosilylation of Propargyl Acetates Harnessing the π-Acidic Catalyst ACS Catal. (IF 11.3) Pub Date : 2024-09-19 Udaya Sree Dakarapu, Yao Chung Chang, Thirupataiah Avullala, Suman Das Adhikary, Hiep H. Nguyen, Junha Jeon
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Breaking Oxygen Evolution Limits on Metal Chalcogenide Photocatalysts for Visible-Light-Driven Overall Water-Splitting ACS Catal. (IF 11.3) Pub Date : 2024-09-19 Erling Zhao, Jieqiong Shan, Pengfei Yin, Weiliang Wang, Kun Du, Chueh-Cheng Yang, Jiaxin Guo, Jing Mao, Zhen Peng, Chia-Hsin Wang, Tao Ling
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Fully Exposed Nickel Clusters for Semihydrogenation of Acetylene ACS Catal. (IF 11.3) Pub Date : 2024-09-19 Chengquan Sui, Huan Ma, Fei Huang, Maolin Wang, Xiangbin Cai, Jiangyong Diao, Pengju Ren, Xiaodong Wen, Li Jin, Guoqing Wang, Ding Ma, Hongyang Liu
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Theoretical Design of the Electrocatalytic Urea Synthesis from Carbon Dioxide and Nitric Oxides ACS Catal. (IF 11.3) Pub Date : 2024-09-18 Jun Long, Dong Luan, Xiaoyan Fu, Huan Li, Jianping Xiao
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Sub-2 nm Ternary Metallic Alloy Encapsulated within Montmorillonite Interlayers for Efficient Hydrogen Generation from Ammonia Borane Hydrolysis ACS Catal. (IF 11.3) Pub Date : 2024-09-18 Jiafu Li, Yanran Feng, Xingyun Li, Tianjun Zhang, Xia Liu, Ning Wang, Qiming Sun
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Covalently Anchored Molecular Catalyst onto a Graphitic Carbon Nitride Surface for Photocatalytic Epoxidation of Olefins ACS Catal. (IF 11.3) Pub Date : 2024-09-18 Sebastiano Gadolini, Rachel N. Kerber, Riho T. Seljamäe-Green, Wenming Tong, Pau Farràs, Elena C. Corbos
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Improved Near-Neutral Hydrogen Evolution Reaction Kinetics through Electrolyte Engineering with the Efficient Hydrogen Source NH4+ ACS Catal. (IF 11.3) Pub Date : 2024-09-17 Xiusong Huang, Junjie Xu, Xuefei Xu, Shujuan Wang
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A High-Throughput Screening Platform for Engineering Poly(ethylene Terephthalate) Hydrolases ACS Catal. (IF 11.3) Pub Date : 2024-09-17 Thomas M. Groseclose, Erin A. Kober, Matilda Clark, Benjamin Moore, Shounak Banerjee, Victoria Bemmer, Gregg T. Beckham, Andrew R. Pickford, Taraka T. Dale, Hau B. Nguyen
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Rhodium-Catalyzed [5 + 1 + 2] Cycloaddition of Yne-3-acyloxy-1,4-enynes (YACEs) and Carbon Monoxide: Reaction Development and Mechanism ACS Catal. (IF 11.3) Pub Date : 2024-09-17 Qi Cui, Pan Zhang, Bing-Wen Li, Yi Jin, Qianwei Zhang, Hong-Xi Bai, Zhi-Xiang Yu
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Kinetic and Substrate Specificity Determination of Bacterial LPMOs ACS Catal. (IF 11.3) Pub Date : 2024-09-17 Alan Carletti, Florian Csarman, Marco Sola, Gianantonio Battistuzzi, Roland Ludwig, Giulia Di Rocco
Lytic polysaccharide monooxygenases (LPMOs) are copper enzymes discovered in the past decade. Their importance in the degradation of recalcitrant substrates in sustainable processes is now well established; however, the catalytic peroxygenase mechanism has yet to be fully understood. This is also because the study of reaction kinetics has to deal with multiple variables, including the nature of the
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Enhanced Radical Dehydrogenation over Carbon Monoxide-Decorated Palladium Sites for Linear α-Olefin Production from Biomass-Derived Fatty Acids ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Genheng Li, Juntao Ren, Zhipeng Huang, Jianyu Han, Nengchao Luo, Yanming Hu, Feng Wang
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Acridine/Lewis Acid Complexes as Powerful Photocatalysts: A Combined Experimental and Mechanistic Study ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Dillon R. L. Rickertsen, Joshua L. Crow, Tamal Das, Ion Ghiviriga, Jennifer S. Hirschi, Daniel Seidel
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Dual O2-Mediated Reactivity of a Mononuclear Cobalt Complex with Amyloid-β Peptides ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Jong-Min Suh, Wooyeol Ryu, Eunju Nam, Nam Kwon, Kyungmin Kim, Dongwook Kim, Jaeheung Cho, Kiyoung Park, Mi Hee Lim
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Comparison of the Efficiency of B–O and B–C Bond Formation Pathways in Borane-Catalyzed Carbene Transfer Reactions Using α-Diazocarbonyl Precursors: A Combined Density Functional Theory and Machine Learning Study ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Kaveh Farshadfar, Kari Laasonen
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Fe-Based Materials for Photocatalytic Nitrogen Reduction to Ammonia: Unique Advantages, Challenges, and Perspectives ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Tong Hu, Xiaodi Cheng, Jie Luo, Yupeng Yan, Qin Zhang, Yang Li
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Suppressing H2 Evolution with Sterically Encumbered Proton Sources to Improve the Faradaic Efficiency for CO2 Reduction to Formate ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Andrew D. Cypcar, Kathleen M. Bui, Jenny Y. Yang
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Ni-Phthalocyanine Derived Electrocatalysts for Oxygen Reduction Reaction and Hydrogen Evolution Reaction: Active Sites Formation and Electrocatalytic Activity ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Seyed Ariana Mirshokraee, Mohsin Muhyuddin, Nicolò Pianta, Enrico Berretti, Laura Capozzoli, Jacopo Orsilli, Francesco D’Acapito, Rosanna Viscardi, Alessio Cosenza, Plamen Atanassov, Carlo Santoro, Alessandro Lavacchi
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Cobalt-Catalyzed Regiodivergent Heck-Type Reaction of Simple Unactivated Alkenes ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Chunyang Zhao, Chao Dong, Wenxuan Ma, Lili Shi, Dezhi Liu, Xiaoxuan Zhang, Zhoufeng Cui, Zhiwei Wang, Junkai Fu
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Iron(I) Tetraphenylporphyrin Is an Active Catalyst in Reductive Deoxygenation when Switching from CO2 to Isoelectronic N2O ACS Catal. (IF 11.3) Pub Date : 2024-09-16 Camille Chartier, Rana Deeba, Alexandra Collard, Sylvie Chardon-Noblat, Cyrille Costentin
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State-of-the-Art Advancements in Synthesis of Nitriles from Primary Alcohols ACS Catal. (IF 11.3) Pub Date : 2024-09-15 Pengfei Wu, Xiaomin Zhang, Jifeng Pang, Guoqiang Wei, Mingyuan Zheng, Tao Zhang
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Single-Site Catalysts for the Oxygen Reduction Reaction: Why Iron Is Better than Platinum ACS Catal. (IF 11.3) Pub Date : 2024-09-14 Alessandro Facchin, Daniel Forrer, Mirco Zerbetto, Francesco Cazzadori, Andrea Vittadini, Christian Durante
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Recent Progress on the Stability of Electrocatalysts under High Current Densities toward Industrial Water Splitting ACS Catal. (IF 11.3) Pub Date : 2024-09-14 Shumin Gong, Yao Meng, Zeying Jin, Hsien-Yi Hsu, Minshu Du, Feng Liu
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Room-Temperature Secondary Ammonium Salt-Catalyzed Enantioselective Halogenation via Hydrogen-Bonded Ion Pair ACS Catal. (IF 11.3) Pub Date : 2024-09-14 Zhihuang Chen, Zhipeng Wu, Qinghai Zhou, Peng Yang, Xing Li, Xiaodong Xiong
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A Chemoenzymatic Hydroaminomethylation Strategy for the Selective Synthesis of Linear Primary Amines from Olefins by Sequential and Tandem Processes ACS Catal. (IF 11.3) Pub Date : 2024-09-13 Jenna L. Manske, Jeremy Nicolai, Brandon J. Bloomer, Douglas S. Clark, John F. Hartwig
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Regulating Steric Effect of Cobalt Corroles for Promoted Oxygen Electrocatalysis ACS Catal. (IF 11.3) Pub Date : 2024-09-13 Yuhan Xu, Xiaotong Jin, Jieling Zhang, Haonan Qin, Benxing Mei, Tao Liu, Siyu Lei, Shen Li, Yongyi Bo, Xialiang Li, Rui Cao
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Nonadiabatic Proton-Coupled Electron Transfer at a Graphitic Surface Immobilized Cobalt Porphyrin ACS Catal. (IF 11.3) Pub Date : 2024-09-13 Phillips Hutchison, Alexander V. Soudackov, Sharon Hammes-Schiffer
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Role of Surface Hydrogen Coverage in C–C Coupling Process for CO2 Electroreduction on Ni-Based Catalysts ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Haowen Ding, Shisheng Zheng, Xinzhe Yang, Junjie Pan, Zhefeng Chen, Mingzheng Zhang, Shunning Li, Feng Pan
Research into electrochemical CO2 reduction reaction (CO2RR) toward multicarbon products has long been dominated by the investigation of Cu-based catalyst system. Yet, several recent studies have documented competitive catalytic performance on Ni-based alloys and compounds, which can trigger C–C coupling for producing long-chain hydrocarbons. To develop an in-depth understanding of how Ni-based catalysts
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Isotopic Studies of Reaction Pathways within Propylene Epoxidation over Promoted Silver Catalysts ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Joseph Esposito, Aditya Bhan
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Pt Atom-Substituted MoC Single-Atom Catalyst for Enhancing H2 Production ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Nanfang Tang, Dongyuan Liu, Shuai Chen, Zhenyu Wang, Yuxia Ma, Qi Li, Yunshuai Li, Guoliang Xu, Chuntian Wu, Liqun Kang, Wenhao Luo, Botao Qiao, Houyu Zhu, Yu Cong
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Suppressing Metal-Support Interaction Enhances Photothermal CO2 Methanation on the Ru/CeO2 Catalysts ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Yun Zhou, Peng Zheng, Jiajian Gao, Wenqing Xu, Yang Yang, Lili Zhang, Tingyu Zhu, Guangwen Xu, Ziyi Zhong, Fabing Su
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The Role of Ligands and Silver(I) Additives in the Ligand-Promoted Divergent α,β-Dehydrogenation of Aliphatic Acids ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Zhewei Li, Yanhui Tang, Ming Lei
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Molecular Basis for the P450-Catalyzed sp3 C–N Glycosidic Bond Formation in Staurosporine Biosynthesis ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Fei Xiao, Tai-Ping Zhou, Sheng Dong, Tong Li, Cai-Hong Yun, Yingang Feng, Qiu Cui, Kui Hong, Binju Wang, Wenli Li
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Imine Reductases and Reductive Aminases in Organic Synthesis ACS Catal. (IF 11.3) Pub Date : 2024-09-12 Godwin A. Aleku
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Unexpected Main-Chain-Mediated and Neutral-Intermediate-Involved Catalytic Reaction in a High-Fidelity ent-Neoabietadiene Synthase ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Ke Gao, Kangwei Xu, Pengcheng Lin, Jianxun Zhu, Ruibo Wu, Jiachen Zi
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Hydrogen Peroxide Generation and Hydrogen Oxidation Reaction on Pt/Co/Pt(111) and Pt/Co/Pt(100) Single-Crystal Model Catalyst Surface ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Kenta Hayashi, Takeru Tomimori, Yoshihiro Chida, Naoto Todoroki, Toshimasa Wadayama
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Effect of Iron Doping in Ordered Nickel Oxide Thin Film Catalyst for the Oxygen Evolution Reaction ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Ane Etxebarria, Mauricio Lopez Luna, Andrea Martini, Uta Hejral, Martina Rüscher, Chao Zhan, Antonia Herzog, Afshan Jamshaid, David Kordus, Arno Bergmann, Helmut Kuhlenbeck, Beatriz Roldan Cuenya
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Incorporating Coverage-Dependent Reaction Barriers into First-Principles-Based Microkinetic Models: Approaches and Challenges ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Michelle A. Nolen, Carrie A. Farberow, Stephanie Kwon
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Interception of Transient anti-Allyl–Ir Species with Cu–Azomethine Ylide: Mechanistic Origins of Z-Selectivity in an Asymmetric Allylation Reaction ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Hui Xu, Xinxin Niu, Yanfeng Dang
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Chemoselective Cu-Catalyzed Cross-Nucleophile Alkylarylation of Alkenes ACS Catal. (IF 11.3) Pub Date : 2024-09-11 SangHyun Lee, Jianyang D. Yu, Alex L. Monterde, Sarah E. Tung, Ya-Nong Wang, Brittany L. Gay, Kami L. Hull
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Size Dependent Photocatalytic Activity of Mesoporous ZnIn2S4 Nanocrystal Networks ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Evangelos K. Andreou, Ioannis Vamvasakis, Andreas Douloumis, Georgios Kopidakis, Gerasimos S. Armatas
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Intramolecular C–H Oxidation in Iron(V)-oxo-carboxylato Species Relevant in the γ-Lactonization of Alkyl Carboxylic Acids ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Andrea Álvarez-Núñez, Rudraditya Sarkar, Valeria Dantignana, Jin Xiong, Yisong Guo, Josep M. Luis, Miquel Costas, Anna Company
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Photoredox/Nickel Dual Catalysis for C(sp2)–C(sp3) Cross-Electrophile Coupling Reaction of Mesylates of Phenols and Primary Alcohols ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Sayan K. Jana, Rayan Bhattacharya, Purusattam Dey, Sunit Chakraborty, Biplab Maji
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Chiral Phosphate-Catalyzed Enantiodivergent Oxa-Diels–Alder Reaction of Trifluoropyruvate and Simple Dienes ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Chunming Yang, Shengkun Hu, Talin Li, Long Zhang, Sanzhong Luo
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Progress in Enzyme-Catalyzed C(sp3)–H Amination ACS Catal. (IF 11.3) Pub Date : 2024-09-11 Wei-Nan Xu, Ya-Dong Gao, Ping Su, Luqi Huang, Zhao-Lin He, Li-Cheng Yang
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Optimizing Reaction Kinetics and Thermodynamics for Photocatalytic CO2 Reduction through Spin Polarization Manipulation ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Mingyang Li, Shiqun Wu, Dongni Liu, Zhicheng Ye, Chengxuan He, Jinlong Wang, Xiaoyi Gu, Zehan Zhang, Huizi Li, Jinlong Zhang
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Advancing CO2RR with O-Coordinated Single-Atom Nanozymes: A DFT and Machine Learning Exploration ACS Catal. (IF 11.3) Pub Date : 2024-09-09 Hao Sun, Jing-yao Liu
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Mechanistic Insights into the Dealumination of an H-ZSM-5 Zeolite Using Reactive Molecular Dynamics Simulations ACS Catal. (IF 11.3) Pub Date : 2024-09-10 E. Grajales-González, M. Monge-Palacios, Sirio Brunialti, S. Mani Sarathy
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Effects of Acid Sites and Formaldehyde Decomposition on the Catalyst Lifetime for Methanol-to-Olefins over Ca-Modified HZSM-5 ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Jinsong Luo, Tianci Xiao, Wu Wen, Jun Bao, Chengyuan Liu, Yang Pan
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On the Structure Sensitivity of CO2 Hydrogenation over Cu/ZrO2: Insights into the Role of the Support and the Active Sites ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Tomás Vergara, Daviel Gómez, Lucas Warmuth, Annika E. Enss, Martin Peterlechner, Rodrigo Pallacán, Vlad Martin Diaconescu, Laura Simonelli, Felix Studt, Patricia Concepción, Romel Jiménez, Alejandro Karelovic
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Ni-Catalyzed Deoxygenative Cross-Coupling of Alcohols with Aryl Chlorides via an Organic Photoredox Process ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Weikang Xiong, Tengfei Kang, Fei Li, Huijuan Liao, Yonggang Yan, Jianyang Dong, Gang Li, Dong Xue
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Saccharide-Assisted Resolution of Bioactive Chiral Carboxylic Acids via NHC-Catalyzed Regioselective Transesterification ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Shuolu Dai, Juan Zou, Haiqi Wang, Min Xu, Erjuan Xu, Jia Song, Yu Hong, Shaojun Li, Wen-Xin Lv, Yonggui Robin Chi
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Iridium-Catalyzed Asymmetric Cascade Allylation/[1,4]-Phospha-Brook Rearrangement Reaction ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Zhi-Yuan Yi, Hui Xu, Xin Chang, Yanfeng Dang, Xiu-Qin Dong, Chun-Jiang Wang
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Metallaphotoredox Synthesis of Axially Chiral Tetrasubstituted Allenes through Regio- and Enantioselective 1,4-Carbocyanation of 1,3-Enynes ACS Catal. (IF 11.3) Pub Date : 2024-09-10 Keyi Peng, Ya-Sheng Cao, Quanyuan Wang, Ziwei Xia, Ya Chen, Yixin Lu, Guo-Jun Deng
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Enhanced Light Alkane Oxidation under Impurity-Containing Conditions by Low-Coordinated Co–O Structures Boosting C–H Bond Activation ACS Catal. (IF 11.3) Pub Date : 2024-09-09 Fan Dang, Zeyu Jiang, Yadi Wang, Jialei Wan, Chunli Ai, Mingjiao Tian, Yanfei Jian, Han Xu, Reem Albilali, Jiaguo Yu, Chi He
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Correction to “Double Asymmetric Hydrogenation of α-Iminoketones: Facile Synthesis of Enantiopure Vicinal Amino Alcohols” ACS Catal. (IF 11.3) Pub Date : 2024-09-09 Jiang Wang, Xin Lin, Pan-Lin Shao, Jingyuan Song, Jialin Wen, Xumu Zhang
Our follow-up studies have revealed that the previously used ligand in the double asymmetric hydrogenation of several substrates was not (Sc,Rp)-DuanPhos, but instead was (RC,Sp)-Duanphos. We also regret other mistakes in the original article. The scientific discoveries and conclusions in the original paper are not affected. A corrected version of the Supporting Information is provided. We sincerely