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Bismuth radical catalysis in the activation and coupling of redox-active electrophiles Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Mauro Mato, Davide Spinnato, Markus Leutzsch, Hye Won Moon, Edward J. Reijerse, Josep Cornella
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D3+ formation through photoionization of the molecular D2–D2 dimer Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Yonghao Mi, Enliang Wang, Zack Dube, Tian Wang, A. Y. Naumov, D. M. Villeneuve, P. B. Corkum, André Staudte
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Multistep, site-selective noncovalent synthesis of two-dimensional block supramolecular polymers Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Norihiko Sasaki, Jun Kikkawa, Yoshiki Ishii, Takayuki Uchihashi, Hitomi Imamura, Masayuki Takeuchi, Kazunori Sugiyasu
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Expanding the substrate scope of pyrrolysyl-transfer RNA synthetase enzymes to include non-α-amino acids in vitro and in vivo Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Riley Fricke, Cameron V. Swenson, Leah Tang Roe, Noah Xue Hamlish, Bhavana Shah, Zhongqi Zhang, Elise Ficaretta, Omer Ad, Sarah Smaga, Christine L. Gee, Abhishek Chatterjee, Alanna Schepartz
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Why charging Li–air batteries with current low-voltage mediators is slow and singlet oxygen does not explain degradation Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Sunyhik Ahn, Ceren Zor, Sixie Yang, Marco Lagnoni, Daniel Dewar, Tammy Nimmo, Chloe Chau, Max Jenkins, Alexander J. Kibler, Alexander Pateman, Gregory J. Rees, Xiangwen Gao, Paul Adamson, Nicole Grobert, Antonio Bertei, Lee R. Johnson, Peter G. Bruce
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Opportunities and challenges with hyperpolarized bioresponsive probes for functional imaging using magnetic resonance Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Goran Angelovski, Ben J. Tickner, Gaoji Wang
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Ultrafast formation dynamics of D3+ from the light-driven bimolecular reaction of the D2–D2 dimer Nat. Chem. (IF 24.274) Pub Date : 2023-06-01 Lianrong Zhou, Hongcheng Ni, Zhejun Jiang, Junjie Qiang, Wenyu Jiang, Wenbin Zhang, Peifen Lu, Jin Wen, Kang Lin, Meifang Zhu, Reinhard Dörner, Jian Wu
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Polymeric protagonists for biological processes Nat. Chem. (IF 24.274) Pub Date : 2023-05-29 Alana P. Gudinas, Danielle J. Mai
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Selecting aptamers with programmed affinities Nat. Chem. (IF 24.274) Pub Date : 2023-05-29 Ping Song, Chunhai Fan
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Illuminating enzyme design using deep learning Nat. Chem. (IF 24.274) Pub Date : 2023-05-29 Christian Dallago, Kevin K. Yang
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Fragmentation and [4 + 3] cycloaddition in sodorifen biosynthesis Nat. Chem. (IF 24.274) Pub Date : 2023-05-29 Houchao Xu, Lukas Lauterbach, Bernd Goldfuss, Gregor Schnakenburg, Jeroen S. Dickschat
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Route to complex colloidal crystals through entropy compartmentalization Nat. Chem. (IF 24.274) Pub Date : 2023-05-25
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Fibril formation and ordering of disordered FUS LC driven by hydrophobic interactions Nat. Chem. (IF 24.274) Pub Date : 2023-05-25 Daria Maltseva, Sayantan Chatterjee, Chun-Chieh Yu, Mateusz Brzezinski, Yuki Nagata, Grazia Gonella, Anastasia C. Murthy, Jeanne C. Stachowiak, Nicolas L. Fawzi, Sapun H. Parekh, Mischa Bonn
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Entropy compartmentalization stabilizes open host–guest colloidal clathrates Nat. Chem. (IF 24.274) Pub Date : 2023-05-25 Sangmin Lee, Thi Vo, Sharon C. Glotzer
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A trivalent 4f complex with two bis-silylamide ligands displaying slow magnetic relaxation Nat. Chem. (IF 24.274) Pub Date : 2023-05-25 Dylan Errulat, Katie L. M. Harriman, Diogo A. Gálico, Alexandros A. Kitos, Akseli Mansikkamäki, Muralee Murugesu
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Activity-based directed evolution of a membrane editor in mammalian cells Nat. Chem. (IF 24.274) Pub Date : 2023-05-22 Reika Tei, Saket R. Bagde, J. Christopher Fromme, Jeremy M. Baskin
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Arenes participate in 1,3-dipolar cycloaddition with in situ-generated diazoalkenes Nat. Chem. (IF 24.274) Pub Date : 2023-05-22 Shubhangi Aggarwal, Alexander Vu, Dmitry B. Eremin, Rudra Persaud, Valery V. Fokin
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In vitro selection of macrocyclic peptide inhibitors containing cyclic γ2,4-amino acids targeting the SARS-CoV-2 main protease Nat. Chem. (IF 24.274) Pub Date : 2023-05-22 Takashi Miura, Tika R. Malla, C. David Owen, Anthony Tumber, Lennart Brewitz, Michael A. McDonough, Eidarus Salah, Naohiro Terasaka, Takayuki Katoh, Petra Lukacik, Claire Strain-Damerell, Halina Mikolajek, Martin A. Walsh, Akane Kawamura, Christopher J. Schofield, Hiroaki Suga
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Spin-dependent reactivity and spin-flipping dynamics in oxygen atom scattering from graphite Nat. Chem. (IF 24.274) Pub Date : 2023-05-22 Zibo Zhao, Yingqi Wang, Ximei Yang, Jiamei Quan, Bastian C. Krüger, Paula Stoicescu, Reed Nieman, Daniel J. Auerbach, Alec M. Wodtke, Hua Guo, G. Barratt Park
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Making a start on the tenure track Nat. Chem. (IF 24.274) Pub Date : 2023-05-18 Shira Joudan
Getting started at a new institution and building a research programme can be an exciting period, but there is much to do in a short space of time. Shira Joudan reflects on her first month as an assistant professor, discussing the stresses of setting up a new lab and how it’s easier with a little help from your (new) friends.
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Multi-site programmable functionalization of alkenes via controllable alkene isomerization Nat. Chem. (IF 24.274) Pub Date : 2023-05-18 Zhengxing Wu, Jingjie Meng, Huikang Liu, Yunyi Li, Xiao Zhang, Wanbin Zhang
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Real-time monitoring of reaction stereochemistry through single-molecule observations of chirality-induced spin selectivity Nat. Chem. (IF 24.274) Pub Date : 2023-05-15 Chen Yang, Yanwei Li, Shuyao Zhou, Yilin Guo, Chuancheng Jia, Zhirong Liu, Kendall N. Houk, Yonatan Dubi, Xuefeng Guo
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Not all catenanes with oriented rings are topologically chiral Nat. Chem. (IF 24.274) Pub Date : 2023-05-11
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A catenane that is topologically achiral despite being composed of oriented rings Nat. Chem. (IF 24.274) Pub Date : 2023-05-11 Noel Pairault, Federica Rizzi, David Lozano, Ellen M. G. Jamieson, Graham J. Tizzard, Stephen M. Goldup
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In vivo metallophilic self-assembly of a light-activated anticancer drug Nat. Chem. (IF 24.274) Pub Date : 2023-05-11 Xue-Quan Zhou, Peiyuan Wang, Vadde Ramu, Liyan Zhang, Suhua Jiang, Xuezhao Li, Selda Abyar, Panagiota Papadopoulou, Yang Shao, Ludovic Bretin, Maxime A. Siegler, Francesco Buda, Alexander Kros, Jiangli Fan, Xiaojun Peng, Wen Sun, Sylvestre Bonnet
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Chloride in the battery pool Nat. Chem. (IF 24.274) Pub Date : 2023-05-05 Adam Weingarten
The researchers synthesized Li3TiCl6 from LiCl and TiCl3 and, with electrochemical testing, found room-temperature ionic conductivities above 1 mS cm–1. This is a relatively high value that enables positive electrode formulation in which the active material comprises 95 wt% of the solid composite electrode, a greater proportion than the <80 wt% in most solid-state cells. X-ray diffraction and bond-valance
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Looking into luciferin Nat. Chem. (IF 24.274) Pub Date : 2023-05-05 Vadim R. Viviani
Organisms that glow are perhaps eerie. Vadim Viviani ponders on the luciferin–luciferase systems responsible for their intriguing bioluminescence.
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Catalytic enantioselective nucleophilic desymmetrization of phosphonate esters Nat. Chem. (IF 24.274) Pub Date : 2023-05-01 Michele Formica, Tatiana Rogova, Heyao Shi, Naoto Sahara, Branislav Ferko, Alistair J. M. Farley, Kirsten E. Christensen, Fernanda Duarte, Ken Yamazaki, Darren J. Dixon
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Precision native polysaccharides from living polymerization of anhydrosugars Nat. Chem. (IF 24.274) Pub Date : 2023-04-27 Lianqian Wu, Zefeng Zhou, Devavrat Sathe, Junfeng Zhou, Shoshana Dym, Zhensheng Zhao, Junpeng Wang, Jia Niu
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Spatiotemporal and global profiling of DNA–protein interactions enables discovery of low-affinity transcription factors Nat. Chem. (IF 24.274) Pub Date : 2023-04-27 An-Di Guo, Ke-Nian Yan, Hao Hu, Linhui Zhai, Teng-Fei Hu, Haixia Su, Yijia Chi, Jinyin Zha, Yechun Xu, Dongxin Zhao, Xiaojie Lu, Yong-Jiang Xu, Jian Zhang, Minjia Tan, Xiao-Hua Chen
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Advances in single-molecule junctions as tools for chemical and biochemical analysis Nat. Chem. (IF 24.274) Pub Date : 2023-04-27 Essam M. Dief, Paul J. Low, Ismael Díez-Pérez, Nadim Darwish
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Regio- and enantioselective remote dioxygenation of internal alkenes Nat. Chem. (IF 24.274) Pub Date : 2023-04-27 Xiaonan Li, Tilong Yang, Jiayuan Li, Xiang Li, Pinhong Chen, Zhenyang Lin, Guosheng Liu
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The implicit bias impeding chemistry Nat. Chem. (IF 24.274) Pub Date : 2023-04-24 Bruce C. Gibb
Bifurcating the population as either verbal or visual thinkers is one of the simplest ways to classify intelligence. Bruce Gibb argues that visual thinking is key to chemistry, and that teaching and testing must focus on this type of thinking rather than traditional approaches promoting verbal thinking skills.
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Accurate structure models and absolute configuration determination using dynamical effects in continuous-rotation 3D electron diffraction data Nat. Chem. (IF 24.274) Pub Date : 2023-04-20 Paul B. Klar, Yaşar Krysiak, Hongyi Xu, Gwladys Steciuk, Jung Cho, Xiaodong Zou, Lukas Palatinus
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Uniform segmented platelet micelles with compositionally distinct and selectively degradable cores Nat. Chem. (IF 24.274) Pub Date : 2023-04-20 Zaizai Tong, Yujie Xie, Maria C. Arno, Yifan Zhang, Ian Manners, Rachel K. O’Reilly, Andrew P. Dove
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A liquid quasicrystal of columns Nat. Chem. (IF 24.274) Pub Date : 2023-04-17 Marianne Impéror-Clerc
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Spatiotemporal functional assembly of split protein pairs through a light-activated SpyLigation Nat. Chem. (IF 24.274) Pub Date : 2023-04-17 Emily R. Ruskowitz, Brizzia G. Munoz-Robles, Alder C. Strange, Carson H. Butcher, Sebastian Kurniawan, Jeremy R. Filteau, Cole A. DeForest
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Synthesis of planar chiral ferrocenes via enantioselective remote C–H activation Nat. Chem. (IF 24.274) Pub Date : 2023-04-17 Lan Zhou, Hong-Gang Cheng, Lisha Li, Kevin Wu, Jing Hou, Chengkang Jiao, Shuang Deng, Zirui Liu, Jin-Quan Yu, Qianghui Zhou
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Emulsion-oriented assembly for Janus double-spherical mesoporous nanoparticles as biological logic gates Nat. Chem. (IF 24.274) Pub Date : 2023-04-13 Tiancong Zhao, Liang Chen, Minchao Liu, Runfeng Lin, Weiluo Cai, Chin-Te Hung, Shangfeng Wang, Linlin Duan, Fan Zhang, Ahmed Elzatahry, Xiaomin Li, Dongyuan Zhao
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Modular enantioselective access to β-amino amides by Brønsted acid-catalysed multicomponent reactions Nat. Chem. (IF 24.274) Pub Date : 2023-04-13 Jun Wei, Jian Zhang, Jun Kee Cheng, Shao-Hua Xiang, Bin Tan
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Growth of single-crystal imine-linked covalent organic frameworks using amphiphilic amino-acid derivatives in water Nat. Chem. (IF 24.274) Pub Date : 2023-04-10 Zhipeng Zhou, Lei Zhang, Yonghang Yang, Iñigo J. Vitorica-Yrezabal, Honglei Wang, Fanglin Tan, Li Gong, Yuyao Li, Pohua Chen, Xin Dong, Zihao Liang, Jing Yang, Chao Wang, Yuexian Hong, Yi Qiu, Armin Gölzhäuser, Xudong Chen, Haoyuan Qi, Sihai Yang, Wei Liu, Junliang Sun, Zhikun Zheng
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Indole-5,6-quinones display hallmark properties of eumelanin Nat. Chem. (IF 24.274) Pub Date : 2023-04-10 Xueqing Wang, Lilia Kinziabulatova, Marco Bortoli, Anju Manickoth, Marisa A. Barilla, Haiyan Huang, Lluís Blancafort, Bern Kohler, Jean-Philip Lumb
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Nature-inspired methylated polyhydroxybutyrates from C1 and C4 feedstocks Nat. Chem. (IF 24.274) Pub Date : 2023-04-06 Zhiyao Zhou, Anne M. LaPointe, Timothy D. Shaffer, Geoffrey W. Coates
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A C–H activation-based enantioselective synthesis of lower carbo[n]helicenes Nat. Chem. (IF 24.274) Pub Date : 2023-04-06 Shu-Min Guo, Soohee Huh, Max Coehlo, Li Shen, Grégory Pieters, Olivier Baudoin
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Electrochemical synthesis of propylene from carbon dioxide on copper nanocrystals Nat. Chem. (IF 24.274) Pub Date : 2023-04-06 Jing Gao, Alimohammad Bahmanpour, Oliver Kröcher, Shaik M. Zakeeruddin, Dan Ren, Michael Grätzel
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Giving the green light Nat. Chem. (IF 24.274) Pub Date : 2023-03-30 Jane Liao, Allie C. Obermeyer
Jane Liao and Allie C. Obermeyer explore the discovery, modification and applications of green fluorescent protein, best known for its use as a tool to cast light on cellular processes.
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Are science and technology friends or foes? Nat. Chem. (IF 24.274) Pub Date : 2023-03-30 Ksenija D. Glusac, Radomir N. Saicic
Does the pursuit of scientific research based on a well-defined technological outcome hamper our ability to be creative? And does it limit opportunities to explore and develop fundamental areas of science that may ultimately lead to applications we hadn’t even thought of yet?
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OregonFluor enables quantitative intracellular paired agent imaging to assess drug target availability in live cells and tissues Nat. Chem. (IF 24.274) Pub Date : 2023-03-30 Lei G. Wang, Antonio R. Montaño, Jason R. Combs, Nathan P. McMahon, Allison Solanki, Michelle M. Gomes, Kai Tao, William H. Bisson, Dani A. Szafran, Kimberley S. Samkoe, Kenneth M. Tichauer, Summer L. Gibbs
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Rings of power Nat. Chem. (IF 24.274) Pub Date : 2023-03-27 Adam Weingarten
The team synthesized a family of substituted tetraquinolines starting from a difunctionalized quinoline. Following chemoselective methyl ester formation and Suzuki–Miyaura coupling with a 2-aminophenylboronic acid, Kumagai and co-workers obtained the cyclic dimer via two-fold amidation. Treatment with an aryl alkyne, trifluoromethanesulfonic anhydride, and pyridine resulted in poor tetraquinoline yields;
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How many roads must a woman walk down? Nat. Chem. (IF 24.274) Pub Date : 2023-03-27 Anne Pichon
Zafra Lerman talks to Nature Chemistry about embedding art in science education, and science in the pursuit of peace on Earth.
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Illuminating anti-ageing Nat. Chem. (IF 24.274) Pub Date : 2023-03-27 Yunjie Xu, Jong Seung Kim, Mingle Li
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Catalytic undirected borylation of tertiary C–H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes Nat. Chem. (IF 24.274) Pub Date : 2023-03-27 Isaac F. Yu, Jenna L. Manske, Alejandro Diéguez-Vázquez, Antonio Misale, Alexander E. Pashenko, Pavel K. Mykhailiuk, Sergey V. Ryabukhin, Dmitriy M. Volochnyuk, John F. Hartwig
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Isolation of a californium(II) crown–ether complex Nat. Chem. (IF 24.274) Pub Date : 2023-03-27 Todd N. Poe, Harry Ramanantoanina, Joseph M. Sperling, Hannah B. Wineinger, Brian M. Rotermund, Jacob Brannon, Zhuanling Bai, Benjamin Scheibe, Nicholas Beck, Brian N. Long, Samantha Justiniano, Thomas E. Albrecht-Schönzart, Cristian Celis-Barros
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Isolation, bonding and reactivity of a monomeric stibine oxide Nat. Chem. (IF 24.274) Pub Date : 2023-03-23 John S. Wenger, Monica Weng, Graham N. George, Timothy C. Johnstone
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A columnar liquid quasicrystal with a honeycomb structure that consists of triangular, square and trapezoidal cells Nat. Chem. (IF 24.274) Pub Date : 2023-03-23 Xiangbing Zeng, Benjamin Glettner, Ute Baumeister, Bin Chen, Goran Ungar, Feng Liu, Carsten Tschierske