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Fused radical SAM and αKG-HExxH domain proteins contain a distinct structural fold and catalyse cyclophane formation and β-hydroxylation Nat. Chem. (IF 19.2) Pub Date : 2024-09-18 Yohei Morishita, Suze Ma, Eugenio De La Mora, He Li, Heng Chen, Xinjian Ji, Anthony Usclat, Patricia Amara, Ryosuke Sugiyama, Yi Wei Tooh, Gregory Gunawan, Julien Pérard, Yvain Nicolet, Qi Zhang, Brandon I. Morinaka
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A single diiron enzyme catalyses the oxidative rearrangement of tryptophan to indole nitrile Nat. Chem. (IF 19.2) Pub Date : 2024-09-16 Sanjoy Adak, Naike Ye, Logan A. Calderone, Meng Duan, Wilson Lubeck, Rebecca J. B. Schäfer, April L. Lukowski, K. N. Houk, Maria-Eirini Pandelia, Catherine L. Drennan, Bradley S. Moore
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Small-molecule properties define partitioning into biomolecular condensates Nat. Chem. (IF 19.2) Pub Date : 2024-09-13 Sabareesan Ambadi Thody, Hanna D. Clements, Hamid Baniasadi, Andrew S. Lyon, Matthew S. Sigman, Michael K. Rosen
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Stereoselective and site-divergent synthesis of C-glycosides Nat. Chem. (IF 19.2) Pub Date : 2024-09-13 Sheng Xu, Yuanyuan Ping, Minghao Xu, Guozhen Wu, Yang Ke, Rui Miao, Xiaotian Qi, Wangqing Kong
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Isolation of a NHC-stabilized heavier nitrile and its conversion into an isonitrile analogue Nat. Chem. (IF 19.2) Pub Date : 2024-09-10 Martin E. Doleschal, Arseni Kostenko, Jin Yu Liu, Shigeyoshi Inoue
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Reaction-induced unsaturated Mo oxycarbides afford highly active CO2 conversion catalysts Nat. Chem. (IF 19.2) Pub Date : 2024-09-09 Xingtao Sun, Jiafeng Yu, Habib Zada, Yu Han, Ling Zhang, Huaican Chen, Wen Yin, Jian Sun
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Radical-triggered translocation of C–C double bond and functional group Nat. Chem. (IF 19.2) Pub Date : 2024-09-09 Shengchun Wang, Xu Luo, Yuan Wang, Zhao Liu, Yi Yu, Xuejie Wang, Demin Ren, Pengjie Wang, Yi-Hung Chen, Xiaotian Qi, Hong Yi, Aiwen Lei
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Zinc and manganese redox potentials in organic solvents and their influence on nickel-catalysed cross-electrophile coupling Nat. Chem. (IF 19.2) Pub Date : 2024-09-06 Zhi-Ming Su, Ruohan Deng, Shannon S. Stahl
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The eponymous ethyl alcohol Nat. Chem. (IF 19.2) Pub Date : 2024-09-04 Chi Chen, Mahlet Garedew, Stafford W. Sheehan
When one says the word alcohol to a non-chemist, it is typically in reference to ethanol, the first alcohol discovered. Chi Chen, Mahlet Garedew, and Stafford W. Sheehan toast ethanol’s past, present, and future.
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Fullerene on non-iron cluster-matrix co-catalysts promotes collaborative H2 and N2 activation for ammonia synthesis Nat. Chem. (IF 19.2) Pub Date : 2024-09-04 Yangyu Zhang, Xuanbei Peng, Han-Rui Tian, Bo Yang, Zuo-Chang Chen, Jiejie Li, Tianhua Zhang, Mingyuan Zhang, Xiaocong Liang, Zhiyang Yu, Yanliang Zhou, Lirong Zheng, Xiuyun Wang, Jian-Wei Zheng, Yu Tang, Chak-tong Au, Lilong Jiang, Su-Yuan Xie
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Balancing volumetric and gravimetric capacity for hydrogen in supramolecular crystals Nat. Chem. (IF 19.2) Pub Date : 2024-09-03 Ruihua Zhang, Hilal Daglar, Chun Tang, Penghao Li, Liang Feng, Han Han, Guangcheng Wu, Benjie N. Limketkai, Yong Wu, Shuliang Yang, Aspen X.-Y. Chen, Charlotte L. Stern, Christos D. Malliakas, Randall Q. Snurr, J. Fraser Stoddart
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Chemoproteomic profiling unveils binding and functional diversity of endogenous proteins that interact with endogenous triplex DNA Nat. Chem. (IF 19.2) Pub Date : 2024-09-02 Hongzhan Xu, Jing Ye, Kui-Xing Zhang, Qingxi Hu, Tongxiao Cui, Chong Tong, Mengqi Wang, Huichao Geng, Kun-Ming Shui, Yan Sun, Jian Wang, Xiaomeng Hou, Kai Zhang, Ran Xie, Yafei Yin, Nan Chen, Jia-Yu Chen
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A metalloenzyme platform for catalytic asymmetric radical dearomatization Nat. Chem. (IF 19.2) Pub Date : 2024-08-28 Wenzhen Fu, Yue Fu, Yunlong Zhao, Huanan Wang, Peng Liu, Yang Yang
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A new research group’s first conferences Nat. Chem. (IF 19.2) Pub Date : 2024-08-27 Shira Joudan
Going to conferences to share and learn about the latest science is a key part of being a researcher. Shira Joudan reflects on presenting their group’s research for the first time and guiding students through their first conference experiences.
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Monitoring the formation of infinite-layer transition metal oxides through in situ atomic-resolution electron microscopy Nat. Chem. (IF 19.2) Pub Date : 2024-08-27 Yaolong Xing, Inhwan Kim, Kyeong Tae Kang, Jinho Byun, Woo Seok Choi, Jaekwang Lee, Sang Ho Oh
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Shape-persistent ladder molecules exhibit nanogap-independent conductance in single-molecule junctions Nat. Chem. (IF 19.2) Pub Date : 2024-08-26 Xiaolin Liu, Hao Yang, Hassan Harb, Rajarshi Samajdar, Toby J. Woods, Oliver Lin, Qian Chen, Adolfo I. B. Romo, Joaquín Rodríguez-López, Rajeev S. Assary, Jeffrey S. Moore, Charles M. Schroeder
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Digital skills in chemical education Nat. Chem. (IF 19.2) Pub Date : 2024-08-23 Andrew R. McCluskey, Miguel Rivera, Antonia S. J. S. Mey
The role of computers in the chemical sciences is changing. Previously the domain of the theoretical or computational chemist, advanced digital skills, including data analysis, automation and simulation, are becoming extremely relevant to all. Here, we discuss the importance of integrating digital skills into an undergraduate chemistry programme and highlight some work currently being carried out to
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Expanding the diversity of lithium electrolytes Nat. Chem. (IF 19.2) Pub Date : 2024-08-23 Jooha Park, Kyoungoh Kim, Kisuk Kang
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‘Living’ anionic polymerization through reversible activation of C–H bonds with a base catalyst Nat. Chem. (IF 19.2) Pub Date : 2024-08-21
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Emerging chiral two-dimensional materials Nat. Chem. (IF 19.2) Pub Date : 2024-08-21 Jinqiao Dong, Yan Liu, Yong Cui
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Generating synthetic gap junctions using supramolecular amphiphilic giant nanotubes Nat. Chem. (IF 19.2) Pub Date : 2024-08-20 Ai Kohata, Kazushi Kinbara
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Synthetic model interfaces for the study of intermolecular charge-transfer states Nat. Chem. (IF 19.2) Pub Date : 2024-08-20
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Synthesis of model heterojunction interfaces reveals molecular-configuration-dependent photoinduced charge transfer Nat. Chem. (IF 19.2) Pub Date : 2024-08-20 Jeroen Royakkers, Hanbo Yang, Alexander J. Gillett, Flurin Eisner, Pratyush Ghosh, Daniel G. Congrave, Mohammed Azzouzi, Zahra Andaji-Garmaroudi, Anastasia Leventis, Akshay Rao, Jarvist Moore Frost, Jenny Nelson, Hugo Bronstein
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Neural-network-based molecular dynamics simulations reveal that proton transport in water is doubly gated by sequential hydrogen-bond exchange Nat. Chem. (IF 19.2) Pub Date : 2024-08-20 Axel Gomez, Ward H. Thompson, Damien Laage
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Machine learning trims the peptide drug design process to a sweet spot Nat. Chem. (IF 19.2) Pub Date : 2024-08-16 Chloe E. Markey, Daniel Reker
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Sulfone cross-coupling outcompetes proton transfer Nat. Chem. (IF 19.2) Pub Date : 2024-08-15 Chloe D. Wong, Elizabeth R. Jarvo
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Dynamic-to-static switch of hydrogen bonds induces a metal–insulator transition in an organic–inorganic superlattice Nat. Chem. (IF 19.2) Pub Date : 2024-08-14 Zhenkai Xie, Rui Luo, Tianping Ying, Yurui Gao, Boqin Song, Tongxu Yu, Xu Chen, Munan Hao, Congcong Chai, Jiashu Yan, Zhiheng Huang, Zhiguo Chen, Luojun Du, Chongqin Zhu, Jiangang Guo, Xiaolong Chen
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Discovery of the selenium-containing antioxidant ovoselenol derived from convergent evolution Nat. Chem. (IF 19.2) Pub Date : 2024-08-14 Chase M. Kayrouz, Kendra A. Ireland, Vanessa Y. Ying, Katherine M. Davis, Mohammad R. Seyedsayamdost
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Multi-tiered chemical proteomic maps of tryptoline acrylamide–protein interactions in cancer cells Nat. Chem. (IF 19.2) Pub Date : 2024-08-13 Evert Njomen, Rachel E. Hayward, Kristen E. DeMeester, Daisuke Ogasawara, Melissa M. Dix, Tracey Nguyen, Paige Ashby, Gabriel M. Simon, Stuart L. Schreiber, Bruno Melillo, Benjamin F. Cravatt
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Author Correction: Repurposing a plant peptide cyclase for targeted lysine acylation. Nat. Chem. (IF 19.2) Pub Date : 2024-09-01 Fabian B H Rehm,Tristan J Tyler,Yan Zhou,Yen-Hua Huang,Conan K Wang,Nicole Lawrence,David J Craik,Thomas Durek
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Dynamic structural twist in metal–organic frameworks enhances solar overall water splitting Nat. Chem. (IF 19.2) Pub Date : 2024-08-12 Kang Sun, Yan Huang, Fusai Sun, Qingyu Wang, Yujie Zhou, Jingxue Wang, Qun Zhang, Xusheng Zheng, Fengtao Fan, Yi Luo, Jun Jiang, Hai-Long Jiang
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Get to Know NO Nat. Chem. (IF 19.2) Pub Date : 2024-08-08 Pokhraj Ghosh, Timothy H. Warren
Nitric oxide is at the heart of myriad environmental and biological processes. Pokhraj Ghosh and Timothy Warren explore the molecular interconnections and wide-ranging impacts of this molecule which is critical for the health of our planet.
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Flash-within-flash synthesis of gram-scale solid-state materials Nat. Chem. (IF 19.2) Pub Date : 2024-08-08 Chi Hun ‘William’ Choi, Jaeho Shin, Lucas Eddy, Victoria Granja, Kevin M. Wyss, Bárbara Damasceno, Hua Guo, Guanhui Gao, Yufeng Zhao, C. Fred Higgs, Yimo Han, James M. Tour
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Triplet carbenes with transition-metal substituents Nat. Chem. (IF 19.2) Pub Date : 2024-08-05 Ze-Jie Lv, Kim A. Eisenlohr, Robert Naumann, Thomas Reuter, Hendrik Verplancke, Serhiy Demeshko, Regine Herbst-Irmer, Katja Heinze, Max C. Holthausen, Sven Schneider
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Enantiospecific cross-coupling of cyclic alkyl sulfones Nat. Chem. (IF 19.2) Pub Date : 2024-08-05 Roberto Nolla-Saltiel, Zachary T. Ariki, Stefanie Schiele, Jana Alpin, Yasuyo Tahara, Daisuke Yokogawa, Masakazu Nambo, Cathleen M. Crudden
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Using dimethylsulfonium to identify readers of methylation Nat. Chem. (IF 19.2) Pub Date : 2024-07-30 Xiang Li, Xiang David Li
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Single-electron transfer between sulfonium and tryptophan enables site-selective photo crosslinking of methyllysine reader proteins Nat. Chem. (IF 19.2) Pub Date : 2024-07-30 Feng Feng, Yingxiao Gao, Qun Zhao, Ting Luo, Qingyun Yang, Nan Zhao, Yihang Xiao, Yusong Han, Jinheng Pan, Shan Feng, Lihua Zhang, Mingxuan Wu
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Direct nanoscopic imaging of the hydrated nanoparticle–ligand interface Nat. Chem. (IF 19.2) Pub Date : 2024-07-25 Taylor J. Woehl, Damien Alloyeau
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Magnetic fields reveal signatures of triplet-pair multi-exciton photoluminescence in singlet fission Nat. Chem. (IF 19.2) Pub Date : 2024-07-25 Jiale Feng, Parisa Hosseinabadi, Damon M. de Clercq, Ben P. Carwithen, Michael P. Nielsen, Matthew W. Brett, Shyamal K. K. Prasad, Adam A. D. Farahani, Hsiu L. Li, Samuel N. Sanders, Jonathon E. Beves, N. J. Ekins-Daukes, Jared H. Cole, Pall Thordarson, David M. Huang, Murad J. Y. Tayebjee, Timothy W. Schmidt
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Phosphorus-mediated hydrogenation catalysis Nat. Chem. (IF 19.2) Pub Date : 2024-07-24 Josh Abbenseth
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Light strikes gold to purify water Nat. Chem. (IF 19.2) Pub Date : 2024-07-24 Zhipeng Yu, Lifeng Liu
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Collisional alignment and molecular rotation control the chemi-ionization of individual conformers of hydroquinone with metastable neon Nat. Chem. (IF 19.2) Pub Date : 2024-07-19 L. Ploenes, P. Straňák, A. Mishra, X. Liu, J. Pérez-Ríos, S. Willitsch
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Protein semisynthesis reveals plasticity in HECT E3 ubiquitin ligase mechanisms Nat. Chem. (IF 19.2) Pub Date : 2024-07-19 Hanjie Jiang, Bryant D. Miller, Thibault Viennet, Hyojeon Kim, Kwangwoon Lee, Haribabu Arthanari, Philip A. Cole
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An evolved artificial radical cyclase enables the construction of bicyclic terpenoid scaffolds via an H-atom transfer pathway Nat. Chem. (IF 19.2) Pub Date : 2024-07-19 Dongping Chen, Xiang Zhang, Anastassia Andreevna Vorobieva, Ryo Tachibana, Alina Stein, Roman P. Jakob, Zhi Zou, Damian Alexander Graf, Ang Li, Timm Maier, Bruno E. Correia, Thomas R. Ward
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Single crystals of purely organic free-standing two-dimensional woven polymer networks Nat. Chem. (IF 19.2) Pub Date : 2024-07-18 Ding Xiao, Zhitong Jin, Guan Sheng, Liya Chen, Xuedong Xiao, Tianyu Shan, Jiao Wang, Rahul Navik, Jianping Xu, Lin Zhou, Qing-Hui Guo, Guangfeng Li, Yihan Zhu, J. Fraser Stoddart, Feihe Huang
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Template-based copying in chemically fuelled dynamic combinatorial libraries Nat. Chem. (IF 19.2) Pub Date : 2024-07-16 Christine M. E. Kriebisch, Ludwig Burger, Oleksii Zozulia, Michele Stasi, Alexander Floroni, Dieter Braun, Ulrich Gerland, Job Boekhoven
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Heterotrimeric collagen helix with high specificity of assembly results in a rapid rate of folding Nat. Chem. (IF 19.2) Pub Date : 2024-07-15 Carson C. Cole, Douglas R. Walker, Sarah A. H. Hulgan, Brett H. Pogostin, Joseph W. R. Swain, Mitchell D. Miller, Weijun Xu, Ryan Duella, Mikita Misiura, Xu Wang, Anatoly B. Kolomeisky, George N. Philips, Jeffrey D. Hartgerink
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Molecular-docking electrolytes enable high-voltage lithium battery chemistries Nat. Chem. (IF 19.2) Pub Date : 2024-07-15 Baochen Ma, Haikuo Zhang, Ruhong Li, Shuoqing Zhang, Long Chen, Tao Zhou, Jinze Wang, Ruixin Zhang, Shouhong Ding, Xuezhang Xiao, Tao Deng, Lixin Chen, Xiulin Fan
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Isolation and characterization of a two-coordinate phosphinidene oxide Nat. Chem. (IF 19.2) Pub Date : 2024-07-15 Chenyang Hu, Nicolas H. Rees, Maren Pink, Jose M. Goicoechea
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Engineering a nanoscale liposome-in-liposome for in situ biochemical synthesis and multi-stage release Nat. Chem. (IF 19.2) Pub Date : 2024-07-15 Colin P. Pilkington, Ignacio Gispert, Suet Y. Chui, John. M. Seddon, Yuval Elani
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Fast and facile synthesis of amidine-incorporated degradable lipids for versatile mRNA delivery in vivo Nat. Chem. (IF 19.2) Pub Date : 2024-07-09 Xuexiang Han, Mohamad-Gabriel Alameh, Ningqiang Gong, Lulu Xue, Majed Ghattas, Goutham Bojja, Junchao Xu, Gan Zhao, Claude C. Warzecha, Marshall S. Padilla, Rakan El-Mayta, Garima Dwivedi, Ying Xu, Andrew E. Vaughan, James M. Wilson, Drew Weissman, Michael J. Mitchell
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The many phases of biomolecular condensates Nat. Chem. (IF 19.2) Pub Date : 2024-07-08
In this issue we feature several articles that explore advances in the study of phase separation. They highlight some recently reported mechanistic features and progress in the methodology used to study it within cells, and they delve into the implications that phase separation has for select cellular functions.
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In the pink with bismuth subsalicylate Nat. Chem. (IF 19.2) Pub Date : 2024-07-08 A. Ken Inge
A. Ken Inge pores over the history and applications of bismuth subsalicylate, from dispelling digestive distress to breaching bacterial biodefences.
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Phase by phase through a condensate researcher's career path Nat. Chem. (IF 19.2) Pub Date : 2024-07-08 Stacey-Lynn Paiva
Tanja Mittag talks to Nature Chemistry about how her path in research led to her work in phase separation and her thoughts about the future of the field.
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Establishing the origin of Marcus-inverted-region behaviour in the excited-state dynamics of cobalt(III) polypyridyl complexes Nat. Chem. (IF 19.2) Pub Date : 2024-07-04 Atanu Ghosh, Jonathan T. Yarranton, James K. McCusker