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Phototriggered Guest Release from a Nonporous Organic Crystal: Remarkable Single-Crystal-to-Single-Crystal Transformation of a Binary Cocrystal Solvate to a Ternary Cocrystal J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Shweta P. Yelgaonkar; Gonzalo Campillo-Alvarado; Leonard R. MacGillivray
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Rationally Designed Redox-Active Au(I) N-Heterocyclic Carbene: An Immunogenic Cell Death Inducer J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Sajal Sen; Stephanie Hufnagel; Esther Y. Maier; Isaiah Aguilar; Jayaraman Selvakumar; Jennie E. DeVore; Vincent M. Lynch; Kuppuswamy Arumugam; Zhengrong Cui; Jonathan L. Sessler; Jonathan F. Arambula
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A Förster Resonance Energy Transfer-Based Sensor of Steric Pressure on Membrane Surfaces J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Justin R. Houser; Carl C. Hayden; D. Thirumalai; Jeanne C. Stachowiak
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NaZnCO3(OH): A High-Performance Carbonate Ultraviolet Nonlinear Optical Crystal Derived from KBe2BO3F2 J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Guang Peng; Chensheng Lin; Ning Ye
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Solvent Choice in Metal–Organic Framework Linker Exchange Permits Microstructural Control J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Ryan A. Dodson; Andre P. Kalenak; Adam J. Matzger
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Reciprocal Coupling in Chemically Fueled Assembly: A Reaction Cycle Regulates Self-Assembly and Vice Versa J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Brigitte A. K. Kriebisch; Alexander Jussupow; Alexander M. Bergmann; Fabian Kohler; Hendrik Dietz; Ville R. I. Kaila; Job Boekhoven
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α-Halo Ketone for Polyhedral Perovskite Nanocrystals: Evolutions, Shape Conversions, Ligand Chemistry, and Self-Assembly J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Suman Bera; Rakesh Kumar Behera; Narayan Pradhan
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Catalytic Oxidative Deamination by Water with H2 Liberation J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Shan Tang; Michael Rauch; Michael Montag; Yael Diskin-Posner; Yehoshoa Ben-David; David Milstein
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Copper-Catalyzed Formal Dehydrogenative Coupling of Carbonyls with Polyfluoroarenes Leading to β-C–H Arylation J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 Weilong Xie; Dongwook Kim; Sukbok Chang
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Spotlights on Recent JACS Publications J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-25 ACS Contributing Correspondents
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Solute–Solvent Interactions in Modern Physical Organic Chemistry: Supramolecular Polymers as a Muse J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Mathijs F. J. Mabesoone; Anja R. A. Palmans; E. W. Meijer
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Time-Resolved Changes in Dielectric Constant of Metal Halide Perovskites under Illumination J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-13 Min Ji Hong; Liangdong Zhu; Cheng Chen; Longteng Tang; Yen-Hung Lin; Wen Li; Rose Johnson; Shirsopratim Chattopadhyay; Henry J. Snaith; Chong Fang; John G. Labram
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High Throughput Screening with SAMDI Mass Spectrometry for Directed Evolution J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Adam J. Pluchinsky; Daniel J. Wackelin; Xiongyi Huang; Frances H. Arnold; Milan Mrksich
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Two-Dimensional Coordination Networks from Cyclic Dipeptides J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Yuanyuan Guo; Ajiguli Nuermaimaiti; Niels Due Kjeldsen; Kurt V. Gothelf; Trolle R. Linderoth
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Enantioselective Iron-Catalyzed Cross-[4+4]-Cycloaddition of 1,3-Dienes Provides Chiral Cyclooctadienes J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Elena Braconi; Alissa C. Götzinger; Nicolai Cramer
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Triplet Sensitization and Photon Upconversion Using InP-Based Quantum Dots J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Runchen Lai; Youbao Sang; Yang Zhao; Kaifeng Wu
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DFT Study of a Missing Piece in Brasilane-Type Structure Biosynthesis: An Unusual Skeletal Rearrangement J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-10-30 Hajime Sato; Takahiro Hashishin; Junichiro Kanazawa; Kazunori Miyamoto; Masanobu Uchiyama
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Arginine Forks Are a Widespread Motif to Recognize Phosphate Backbones and Guanine Nucleobases in the RNA Major Groove J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Sai Shashank Chavali; Chapin E. Cavender; David H. Mathews; Joseph E. Wedekind
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Path-Dependent Morphological Evolution of Se–Te Mesostructures Prepared by Inorganic Phototropic Growth J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Kathryn R. Hamann; Azhar I. Carim; Madeline C. Meier; Nathan S. Lewis
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Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of Unactivated Alkenes J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Yue Li; Feng-Ping Zhang; Rong-Hua Wang; Shao-Long Qi; Yu-Xin Luan; Mengchun Ye
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Shape-Selective Synthesis of Pentacene Macrocycles and the Effect of Geometry on Singlet Fission J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Harrison M. Bergman; Gavin R. Kiel; Ryan J. Witzke; David P. Nenon; Adam M. Schwartzberg; Yi Liu; T. Don Tilley
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LaIII and ZnII Cooperatively Template a Metal–Organic Capsule J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Dong Yang; Jake L. Greenfield; Tanya K. Ronson; Larissa K. S. von Krbek; Le Yu; Jonathan R. Nitschke
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In Crystallo Snapshots of Rh2-Catalyzed C–H Amination J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Anuvab Das; Chen-Hao Wang; Gerard P. Van Trieste III; Cheng-Jun Sun; Yu-Sheng Chen; Joseph H. Reibenspies; David C. Powers
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Asymmetric Total Synthesis of the Highly Strained 4β-Acetoxyprobotryane-9β,15α-diol J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Wen Zhang; Zi-Xiong Zhou; Xu-Jiang Zhu; Zhang-Hua Sun; Wei-Min Dai; Chuang-Chuang Li
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Molecular Complexes Featuring Unsupported Dispersion-Enhanced Aluminum–Copper and Gallium–Copper Bonds J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Kristian L. Mears; Cary R. Stennett; Elina K. Taskinen; Caroline E. Knapp; Claire J. Carmalt; Heikki M. Tuononen; Philip P. Power
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Unprecedented Reactivities of Highly Reactive Manganese(III)–Iodosylarene Porphyrins in Oxidation Reactions J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-13 Lina Zhang; Yong-Min Lee; Mian Guo; Shunichi Fukuzumi; Wonwoo Nam
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Vibrationally Hot and Cold Triplets. Sensitizer-Dependent Dynamics and Localized Vibrational Promotion of a Di-π-methane Rearrangement J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Kai-Yuan Kuan; Daniel A. Singleton
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Hydrodeoxygenative Cyclotetramerization of Carbon Monoxide by a Trinuclear Titanium Polyhydride Complex J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Shaowei Hu; Takanori Shima; Zhaomin Hou
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Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-13 Jennifer Morvan; François Vermersch; Ziyun Zhang; Laura Falivene; Thomas Vives; Vincent Dorcet; Thierry Roisnel; Christophe Crévisy; Luigi Cavallo; Nicolas Vanthuyne; Guy Bertrand; Rodolphe Jazzar; Marc Mauduit
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Cyclopropenylidenes as Strong Carbene Anchoring Groups on Au Surfaces J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Evan A. Doud; Rachel L. Starr; Gregor Kladnik; Anastasia Voevodin; Enrique Montes; Narendra P. Arasu; Yaping Zang; Percy Zahl; Alberto Morgante; Latha Venkataraman; Héctor Vázquez; Dean Cvetko; Xavier Roy
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Thiosquaramide-Based Supramolecular Polymers: Aromaticity Gain in a Switched Mode of Self-Assembly J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-16 Victorio Saez Talens; Joyal Davis; Chia-Hua Wu; Zhili Wen; Francesca Lauria; Karthick Babu Sai Sankar Gupta; Raisa Rudge; Mahsa Boraghi; Alexander Hagemeijer; Thuat T. Trinh; Pablo Englebienne; Ilja K. Voets; Judy I. Wu; Roxanne E. Kieltyka
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Molecular Engineering of Chromophores to Enable Triplet–Triplet Annihilation Upconversion J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Kealan J. Fallon; Emily M. Churchill; Samuel N. Sanders; James Shee; John L. Weber; Rinat Meir; Steffen Jockusch; David R. Reichman; Matthew Y. Sfeir; Daniel N. Congreve; Luis M. Campos
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Monodisperse CdSe Quantum Dots Encased in Six (100) Facets via Ligand-Controlled Nucleation and Growth J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-13 Liulin Lv; Jiongzhao Li; Yonghong Wang; Yufei Shu; Xiaogang Peng
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Hydrogen–Deuterium Exchange within Adenosine Deaminase, a TIM Barrel Hydrolase, Identifies Networks for Thermal Activation of Catalysis J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Shuaihua Gao; Emily J. Thompson; Samuel L. Barrow; Wenju Zhang; Anthony T. Iavarone; Judith P. Klinman
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Uncoupling the Folding-Function Paradigm of Lytic Peptides to Deliver Impermeable Inhibitors of Intracellular Protein–Protein Interactions J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Stephen E. Miller; Kohei Tsuji; Rachel P.M. Abrams; Terrence R. Burke, Jr.; Joel P. Schneider
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Shape-Shifting Peptide Nanomaterials: Surface Asymmetry Enables pH-Dependent Formation and Interconversion of Collagen Tubes and Sheets J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Andrea D. Merg; Gavin Touponse; Eric van Genderen; Thorsten B. Blum; Xiaobing Zuo; Alisina Bazrafshan; Hew Ming Helen Siaw; Arthur McCanna; R. Brian Dyer; Khalid Salaita; Jan Pieter Abrahams; Vincent P. Conticello
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Using Visible Light to Tune Boronic Acid–Ester Equilibria J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Joseph V. Accardo; Emily R. McClure; Martín A. Mosquera; Julia A. Kalow
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Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Tzu-Sen Su; Felix Thomas Eickemeyer; Michael A. Hope; Farzaneh Jahanbakhshi; Marko Mladenović; Jun Li; Zhiwen Zhou; Aditya Mishra; Jun-Ho Yum; Dan Ren; Anurag Krishna; Olivier Ouellette; Tzu-Chien Wei; Hua Zhou; Hsin-Hsiang Huang; Mounir Driss Mensi; Kevin Sivula; Shaik M. Zakeeruddin; Jovana V. Milić; Anders Hagfeldt; Ursula Rothlisberger; Lyndon Emsley; Hong Zhang; Michael Grätzel
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Structure and Properties of Cs7(H4PO4)(H2PO4)8: A New Superprotonic Solid Acid Featuring the Unusual Polycation (H4PO4)+ J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Louis S. Wang; Sawankumar V. Patel; Sheel S. Sanghvi; Yan-Yan Hu; Sossina M. Haile
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Unifying Conceptual Density Functional and Valence Bond Theory: The Hardness–Softness Conundrum Associated with Protonation Reactions and Uncovering Complementary Reactivity Modes J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Thijs Stuyver; Sason Shaik
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Controlled Diffusion of Photoswitchable Receptors by Binding Anti-electrostatic Hydrogen-Bonded Phosphate Oligomers J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Thomas S. C. MacDonald; Ben L. Feringa; William S. Price; Sander J. Wezenberg; Jonathon E. Beves
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New Mechanism for Cinchona Alkaloid-Catalysis Allows for an Efficient Thiophosphorylation Reaction J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Nastaran Salehi Marzijarani; Yu-hong Lam; Xiao Wang; Artis Klapars; Ji Qi; Zhiyan Song; Benjamin D. Sherry; Zhijian Liu; Yining Ji
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Aryl Amination Using Soluble Weak Base Enabled by a Water-Assisted Mechanism J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-12 Sii Hong Lau; Peng Yu; Liye Chen; Christina B. Madsen-Duggan; Michael J. Williams; Brad P. Carrow
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Overlap-Driven Splitting of Triplet Pairs in Singlet Fission J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-15 Elliot J. Taffet; David Beljonne; Gregory D. Scholes
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Enantioselective Construction of Tertiary Fluoride Stereocenters by Organocatalytic Fluorocyclization J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-16 Qiang Wang; Marvin Lübcke; Maria Biosca; Martin Hedberg; Lars Eriksson; Fahmi Himo; Kálmán J. Szabó
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Crescent-Shaped Supramolecular Tetrapeptide Nanostructures J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-13 Yin Wang; Zhao Li; Yulia Shmidov; Ryan J. Carrazzone; Ronit Bitton; John B. Matson
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Photostimulated Spiropyran for Instantaneous Visualization of Thermal Field Distribution and Flow Pattern J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-10-30 Yahui Chen; Yefei Liu; Sheng Lu; Shuang Ye; Hao Gu; Jian Qiang; Yourong Li; Xiaoqiang Chen
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Molecular Interaction Regulates the Performance and Longevity of Defect Passivation for Metal Halide Perovskite Solar Cells J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-16 Yepin Zhao; Pengchen Zhu; Shu Huang; Shaun Tan; Minhuan Wang; Rui Wang; Jingjing Xue; Tae-Hee Han; Sung-Joon Lee; Anni Zhang; Tianyi Huang; Pei Cheng; Dong Meng; Jin-Wook Lee; Jaime Marian; Jia Zhu; Yang Yang
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Universal Single-Residue Terminal Labels for Fluorescent Live Cell Imaging of Microproteins J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Lorenzo Lafranchi; Dörte Schlesinger; Kyle J. Kimler; Simon J. Elsässer
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Crystallizing Atomic Xenon in a Flexible MOF to Probe and Understand Its Temperature-Dependent Breathing Behavior and Unusual Gas Adsorption Phenomenon J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-10 Hao Wang; Mark Warren; Jacek Jagiello; Stephanie Jensen; Sanjit K. Ghose; Kui Tan; Liang Yu; Thomas J. Emge; Timo Thonhauser; Jing Li
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Copper(I)-Catalyzed Asymmetric 1,4-Conjugate Hydrophosphination of α,β-Unsaturated Amides J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Yan-Bo Li; Hu Tian; Liang Yin
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Strongly Reducing (Diarylamino)benzene-Based Covalent Organic Framework for Metal-Free Visible Light Photocatalytic H2O2 Generation J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-13 Chidharth Krishnaraj; Himanshu Sekhar Jena; Laurens Bourda; Andreas Laemont; Pradip Pachfule; Jérôme Roeser; C. Vinod Chandran; Sander Borgmans; Sven M. J. Rogge; Karen Leus; Christian V. Stevens; Johan A. Martens; Veronique Van Speybroeck; Eric Breynaert; Arne Thomas; Pascal Van Der Voort
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Single-Crystal-to-Single-Crystal [2 + 2] Photocycloaddition Reaction in a Photosalient One-Dimensional Coordination Polymer of Pb(II) J. Am. Chem. Soc. (IF 14.612) Pub Date : 2020-11-11 Bibhuti Bhusan Rath; Jagadese J. Vittal
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