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Automation and Machine Learning for Accelerated Polymer Characterization and Development: Past, Potential, and a Path Forward Macromolecules (IF 5.1) Pub Date : 2024-09-07 Peter A. Beaucage, Duncan R. Sutherland, Tyler B. Martin
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Multicomponent Polymerization of β-Propiolactone, Epoxides, Anhydrides, and CO2: Synthesizing Sustainable Materials with Widely Adjustable Properties Macromolecules (IF 5.1) Pub Date : 2024-09-06 Bai-Hao Ren, Jin-Ming Fu, Wen-Bing Li, Geoffrey W. Coates, Xiao-Bing Lu
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Investigating the Water-Induced Stiffening Mechanism in a Novel Polyurethane through Simulation and Experimental Analysis Macromolecules (IF 5.1) Pub Date : 2024-09-05 Ao Wang, Wenkai Liu, Xiaohan Jin, Hecheng Wu, Dongfei Zhang, Xianglong Han, Yang Liu, Zhen Li, Mingming Ding, Jiehua Li, Hong Tan
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Design of Robust and Recyclable Covalent Elastomeric Networks through Dynamic Enamine–Urea Bonds Macromolecules (IF 5.1) Pub Date : 2024-09-04 Silong Chen, Jian Ding, Youlong Zhao, Anqian Yuan, Yansheng Liao, Xingbao Chen, Yuan Lei, Liang Jiang, Jingxin Lei, Xiaowei Fu
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Phase Behavior and Self-Assembly of Semiflexible Polymers in Poor-Solvent Solutions† Macromolecules (IF 5.1) Pub Date : 2024-09-04 Tobia Arcangeli, Tatjana Škrbić, Somiealo Azote, Davide Marcato, Angelo Rosa, Jayanth R. Banavar, Roberto Piazza, Amos Maritan, Achille Giacometti
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Low Dielectric, Good Adhesive, and Flame-Retardant Aromatic Poly(ether)s with Phosphine Sulfide Groups Macromolecules (IF 5.1) Pub Date : 2024-09-03 Ryoyu Hifumi, Ikuyoshi Tomita
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Tuning Crystallinity of Poly(L-Lactic Acid) Microspheres through Emulsification Temperature Changes Macromolecules (IF 5.1) Pub Date : 2024-09-03 Giulia Tamburini, Giulia Tarricone, Sergio Piva, Adele Sassella, Stefano Bertagnoli, Roberto Lorenzi, Alberto Paleari
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Precise Controlling Microstructure of All-in-One Hybrid Membrane Achieved via Hansen Solubility Parameters after Introducing Nonsolvent Component toward Implantable Energy Storage Device Macromolecules (IF 5.1) Pub Date : 2024-09-02 Meimei Yu, Yuanyou Peng, Xiangya Wang, Lei Zhao, Suting Zhou, Yuxia Zhang, Dongli Guo, Fen Ran
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All-Hydrocarbon High-Refractive-Index Cyclic Olefin Copolymer Optical Materials Macromolecules (IF 5.1) Pub Date : 2024-09-03 Yihua Zhao, Lei Cui, Yixin Zhang, Zhongbao Jian
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Density of Physical Network Junctions in the Amorphous Phase of Polyethylene and Its Copolymers: The Effect of Crystallinity, Domain Sizes, and Molecular Weight Macromolecules (IF 5.1) Pub Date : 2024-09-02 Shiyan Li, Victor M. Litvinov, Yongfeng Men
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Multi-Pathway Chemical Recycling of Bio-Based Polycarbonates Containing Spirocyclic Acetal Structures Macromolecules (IF 5.1) Pub Date : 2024-09-02 Keita Saito, Fabian Eisenreich, Željko Tomović
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Impact of Hydrodynamic Interactions on the Collapse-Expansion Kinetics of Nanogels Macromolecules (IF 5.1) Pub Date : 2024-09-01 Jiaxing Yuan, Hajime Tanaka
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Enhanced Fatigue Resistance of Liquid Crystal Elastomers Enabled by Dynamic Sacrificial Bonds Macromolecules (IF 5.1) Pub Date : 2024-08-29 Yangyang Zhu, Meng Wang, Jiaxiang Huang, Hao Mi, Zhentian Xu, Feiyan Wu, Lie Chen, Hong Yang, Yiwang Chen
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Electron-Transporting Polymer with Perfluoroalkyl Spacer Enables Efficient and Stable Non-Fullerene Organic Solar Cells Macromolecules (IF 5.1) Pub Date : 2024-08-29 Dongdong Xia, Jiali Wang, Xiang Chen, Chaowei Zhao, Jie Fang, Qian Xie, Yuefeng Zhang, Cheng Luo, Zhiyun Hu, Xudong Jiang, Rongrong Li, Shengyong You, Yu Xie, Lang Jiang, Weiwei Li
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Investigation of Crowding Effect on the Flow-Driven Compression-Induced Fractionation (CIF) of Polymer Chains through Nanochannels by Experimental Observation and Computational Simulation Macromolecules (IF 5.1) Pub Date : 2024-08-29 Jianing Zhou, Tao Zheng, Huanli Qi, Yiren Wang, Mingming Ding, Lianwei Li
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Tuning of Folding Height in Bilayer-Folded Lamellae by Bending Rigidity Control Macromolecules (IF 5.1) Pub Date : 2024-08-29 Minjoong Shin, Soon Mo Park, Jimin Yoo, Ahjin Lee, Hyungju Ahn, Dong Ki Yoon, Myungeun Seo
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2-(Benzylthio)ethyl Glycidyl Ether: A Gateway to Redox-Responsive Polyethers Macromolecules (IF 5.1) Pub Date : 2024-08-29 Ahyun Kim, Jinsu Baek, Byeong-Su Kim
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Effects of Composition and Cure Parameters on the Mechanical and Optical Properties of Silicone/Methacrylate Hybrid Elastomers Macromolecules (IF 5.1) Pub Date : 2024-08-28 Anthony J. Silvaroli, Victoria Chang, Tyler R. Heyl, Jeremy M. Beebe, Dongchan Ahn, Shane Mangold, Brian Clark, Muzhou Wang, Kenneth R. Shull
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Advantages of Pyrene Excimer Formation (PEF) over Fluorescence Resonance Energy Transfer (FRET) for Probing the Conformation of Macromolecules in Solution Macromolecules (IF 5.1) Pub Date : 2024-08-28 Sanjay Patel, Jean Duhamel
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Role of Solvophobic Sequences in Amphiphilic Hyperbranched Polymers during Self-Assembly and Photoresponsiveness Macromolecules (IF 5.1) Pub Date : 2024-08-28 Ankita Kumari, Raj Kumar Roy
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Role of Dynamical Asymmetry on the Orientation of Block Copolymers in Shear Flow: Computer Simulation and Experiment Macromolecules (IF 5.1) Pub Date : 2024-08-28 Niklas Blagojevic, Matthias Heck, Manfred Wilhelm, Marcus Müller
The ability of diblock copolymers to self-assemble into periodic microstructures with length scales in the nanometer range offers many opportunities for fundamental research and applications. For practical applications, it is often desirable that the microstructures have a high degree of order on macroscopic length scales and are oriented in a desired direction. This can be achieved in a large volume
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Comprehensive Characterization of Drying Oil Oxidation and Polymerization Using Time-Resolved Infrared Spectroscopy Macromolecules (IF 5.1) Pub Date : 2024-08-27 Gwen DePolo, Piet Iedema, Kenneth Shull, Joen Hermans
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Structural Insights into Low-Temperature Copolymerization of Thermodegradable Amino Acids Mediated by Pyroglutamic Acid Macromolecules (IF 5.1) Pub Date : 2024-08-27 Davide Carboni, Marta Cadeddu, Luigi Stagi, Roberto Anedda, Luigi Menduti, Luisa De Cola, Luca Malfatti, Plinio Innocenzi
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Deeper Spectroscopic Characterizations of Vinylidene Fluoride (VDF) Oligomers Prepared via Iodine Transfer Polymerization (ITP) Macromolecules (IF 5.1) Pub Date : 2024-08-27 Umut Ugur Ozkose, Pierre Pacholski, Olinda Gimello, Sebastien Schramm, Frédéric Aubriet, Frédéric Progent, Bruno Améduri
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Scaling Relation and Rheological Behaviors of Polymerized Ionic Liquids in Ionic Liquid/Dimethylformamide Solutions Macromolecules (IF 5.1) Pub Date : 2024-08-27 Gang Liu, Huan Luo, Yongjie Dan, Yanhua Niu, Guangxian Li
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Intercalation Characteristics of Montmorillonite Modified with Poly(2-n-alkyl-2-oxazoline)s Macromolecules (IF 5.1) Pub Date : 2024-08-26 Marek Pribus, Luboš Jankovič, Valériá Bizovská Kureková, Martin Barlog, Jana Madejová
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Enhancing Mechanical Properties of Sustainable Thermoplastic Elastomers through Incorporating Ionic Interactions Macromolecules (IF 5.1) Pub Date : 2024-08-26 Wenyue Ding, Josiah Hanson, Yi Shi, Yan Yao, Megan L. Robertson
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Sulfonated Aromatic Polypentenamers: Scope of the Acetyl Sulfate Reaction Macromolecules (IF 5.1) Pub Date : 2024-08-24 Courtney M. Leo, Skylar N. Alonzo, Emily Grumbles, Justin G. Kennemur
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In Situ Adhesive and Crack Detectable Polyurea Adhesive at Extremely Low Temperatures Macromolecules (IF 5.1) Pub Date : 2024-08-24 Lijing Han, Jiacheng Xu, Lixia Li, Jiajia Lin, Kailu Ren, Kai Yang, Aiguo Wu, Ruoyu Zhang
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Photoinduced Ultrafast Shape-Changing Self-Assembled Arylazopyrazole-Based Polymeric Micelles Macromolecules (IF 5.1) Pub Date : 2024-08-24 Kalipada Manna, Anirban Dolai, Sanjib Ghosh, Subha Samanta, Shaon Dey, Sagar Pal
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Living Anionic Polymerization of 5-Substituted 2-Vinylthiophenes Macromolecules (IF 5.1) Pub Date : 2024-08-23 Yuki Kurishiba, Ayaka Oguri, Daisuke Yamamoto, Chihiro Homma, Raita Goseki, Takashi Ishizone
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Critical Role of Free Amine Groups in the Imine Bonds Exchange in Dynamic Covalent Networks Macromolecules (IF 5.1) Pub Date : 2024-08-23 Gregory P. Carden, Murillo L. Martins, Gaukhar Toleutay, Sirui Ge, Bingrui Li, Sheng Zhao, Alexei P. Sokolov
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Cross-Linking Vitrimers after Melt Processing Using Supramolecularly Masked Dynamic Cross-Linkers Macromolecules (IF 5.1) Pub Date : 2024-08-23 Georges J. M. Formon, Jonathan Jayaratnam, Clément Guibert, Nathan J. Van Zee, Renaud Nicolaÿ
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Confined Segmental Diffusion in Nanophase Separated Janus Polynorbornenes as Investigated by Quasielastic Neutron Scattering Macromolecules (IF 5.1) Pub Date : 2024-08-22 Paulina Szymoniak, Mohamed A. Kolmangadi, Martin Böhning, Bernhard Frick, Markus Appel, Richard A. Mole, Nicolas R. De Souza, Reiner Zorn, Andreas Schönhals
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Chain Shuttle between Dual Sites of a Monomolecular Organocatalyst Enables Controlled Ring-Opening Copolymerization Macromolecules (IF 5.1) Pub Date : 2024-08-22 Ximin Feng, Xiaowei Geng, Chengjian Zhang, Xinghong Zhang
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Dynamic Covalent Polymer–Nanoparticle Networks as High-Performance Green Lubricants: Synergetic Effect in Load-Bearing Capacity Macromolecules (IF 5.1) Pub Date : 2024-08-21 Hua Xue, Changhao Wang, Fengchun Liang, Jiapeng He, Qun He, Meirong Cai, Qiang Tian, Guanjun Chang, Qing Huang, Muhammad Siddiq, Feng Zhou, Weifeng Bu
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Dielectric Relaxations of Polymer and Primary and Slow Water in Water Mixtures of Poly(vinyl methyl ether) as a Polymer with Low Glass Transition Temperature Macromolecules (IF 5.1) Pub Date : 2024-08-21 Masanobu Takatsuka, Yuka Arai, Kaito Sasaki, Rio Kita, Shin Yagihara, Naoki Shinyashiki
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Modulating the Contact Angle between Nonpolar Polymers and SiO2 Nanoparticles Macromolecules (IF 5.1) Pub Date : 2024-08-20 Anirban Majumder, Anne N. Radzanowski, Ching-Yu Wang, Yijiang Mu, E. Bryan Coughlin, Raymond J. Gorte, John M. Vohs, Daeyeon Lee
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Poly-3-hydroxybutyrate, a Crystal-Mobile Biodegradable Polyester Macromolecules (IF 5.1) Pub Date : 2024-08-20 Afiq Anuar, Qiang Yu, Katalee Jariyavidyanont, Albrecht Petzold, René Androsch, Thomas Thurn-Albrecht, Kay Saalwächter
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Thiazolyl-Substituted Isomeric Benzodithiophenes Boost the Photovoltaic Performance of Polymer Donors Macromolecules (IF 5.1) Pub Date : 2024-08-20 Kangqiao Ma, Huazhe Liang, Yuxin Wang, Xinyuan Jia, Wendi Shi, Zhaoyang Yao, Xiangjian Wan, Chenxi Li, Yongsheng Chen
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Impact of Chain Orientation on the Melting of the α-Form of Isotactic Polypropylene Macromolecules (IF 5.1) Pub Date : 2024-08-19 Damilola Ojedeji, Manolis Doxastakis
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General Condition for Polymer Cononsolvency in Binary Mixed Solvents Macromolecules (IF 5.1) Pub Date : 2024-08-20 Xiangyu Zhang, Jing Zong, Dong Meng
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Crystal Structure and Phase Transition Behavior of Poly(1,2-difluoroethylene) Macromolecules (IF 5.1) Pub Date : 2024-08-20 Ryouichi Yano, Kohji Tashiro, Hiroyasu Masunaga, Sono Sasaki
For several decades, poly(1,2-difluoroethylene) [PVLF, −(CHFCHF)n−] had been believed to be atactic and amorphous. However, our recent study has revealed that PVLF is an atactic but partially crystalline polymer. In the present report, the crystal structure of PVLF, as the most important basic structural information, was determined by the quantitative analysis of 2D wide-angle X-ray diffraction (WAXD)
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Fragmentation Kinetics of Block Copolymer Micelles: Effect of Core and Corona Block Lengths Macromolecules (IF 5.1) Pub Date : 2024-08-20 Sanghee Yang, Ali Sattari, Dongwoo Han, Timothy P. Lodge
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Unveiling the Pressure-Induced Dynamics on the Glass Transition Temperature of Hydrogenated Nitrile Rubber Macromolecules (IF 5.1) Pub Date : 2024-08-20 Le Cai, Xuming Chen, Anil K. Bhowmick, Ramanan Krishnamoorti
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Molecular Interactions Underlying Dissolution Trends in Cannabidiol-Polymer Amorphous Solid Dispersions Macromolecules (IF 5.1) Pub Date : 2024-08-20 Baris E. Ugur, Nicholas J. Caggiano, Stephanie Monson, Alexander G. Bechtold, Yejoon Seo, Robert K. Prud’homme, Rodney D. Priestley, Michael A. Webb
Cannabidiol (CBD) is viewed as a promising therapeutic agent against a variety of health ailments; however, its efficacy is limited by poor aqueous solubility. Amorphous solid dispersions (ASDs) can enhance the solubility of therapeutics by distributing them throughout a polymer matrix. In consideration of ASD formulations with CBD, we investigate the interactions of CBD with various polymers: poly(vinylpyrrolidone)
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Effect of Grafting Density on the Crystallization Behavior of Molecular Bottlebrushes Macromolecules (IF 5.1) Pub Date : 2024-08-19 Jeffrey T. Wilk, Carl T. Furner, Ethan W. Kent, Michael T. Kelly, Bin Zhao, Christopher Y. Li
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Correction to “Surface Segregation in Athermal Polymer Blends Due to Conformational Asymmetry” Macromolecules (IF 5.1) Pub Date : 2024-08-19 Russell K. W. Spencer, Mark W. Matsen
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Connecting Features of Ionomer Scattering Profiles to the Real-Space Structural Features of Ionomer Domains Macromolecules (IF 5.1) Pub Date : 2024-08-19 Jason J. Madinya, Stephen Kronenberger, Benjamin Gould, Colin Peterson, Arthi Jayaraman
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Radical Copolymerization of Thionoglycolide and Derivatives for Preparation of Degradable Vinyl Polymers Macromolecules (IF 5.1) Pub Date : 2024-08-19 Oleksandr Ivanchenko, Stéphane Mazières, Sonia Mallet-Ladeira, Simon Harrisson, Mathias Destarac
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Active Diffusion of Self-Propelled Particles in Semiflexible Polymer Networks Macromolecules (IF 5.1) Pub Date : 2024-08-18 Yeongjin Kim, Won Kyu Kim, Jae-Hyung Jeon
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Exploring the Potential of Triphenylmethane-Based Polymers Prepared via Facile Friedel–Craft (F–C) Hydroxyalkylation Polymerization as Gas Separation Membranes: Effect of Substituent Group Macromolecules (IF 5.1) Pub Date : 2024-08-17 Mengdi Liu, Andrew Trowbridge, Alexander Hymes, Haifeng Gao, Ruilan Guo
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Grafting Kinetics and Compatibility Simulation in Surface Modification of Cellulose Nanocrystals with Poly(lactic acid) for Composites Macromolecules (IF 5.1) Pub Date : 2024-08-17 Yue Zhang, Ping Lan, Zechuan Yu, Tao Xia, Ning Lin
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The Role of Thermal History, Density, and Pressure Changes in the Nonequilibrium Glass Transition Dynamics of Low-Molecular-Weight Poly(phenylmethyl siloxane) (PMPS) under Nanopore Confinement Macromolecules (IF 5.1) Pub Date : 2024-08-17 Katarzyna Chat, Karolina Adrjanowicz, Ewa Juszyńska-Gałązka
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Improvement of Polymer Mechanical Behaviors by Introducing [2]Rotaxane Units with Intra- and Intermolecular Hydrogen Bonds Macromolecules (IF 5.1) Pub Date : 2024-08-16 Lang He, Jialin Wei, Zibin Zhang, Ning Shentu, Jiao Wang, Jiaxi Yu, Zhiqiang Ren, Jiyong Liu, Guangfeng Li, Feihe Huang, Shijun Li
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Oscillatory Interactions between Colloidal Particles in Polyelectrolyte Solutions: Linear Response Theory Macromolecules (IF 5.1) Pub Date : 2024-08-16 C. M. Martens, R. Tuinier, M. Vis
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Methyl Matters: Molecular Regulation of the Soft-to-Rigid Transition of Shape Memory Hydrogels for Programmable Deformation Macromolecules (IF 5.1) Pub Date : 2024-08-15 Zhiye Yuan, Yijie Jin, Yu Wu, Xinjun Wu, Nan Hai, Jianlei Lu, Chuanzhuang Zhao, Jiawei Zhang
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Coupling and Decoupling between Stickers and Backbones in Associating Polymers with Terminally Functionalized Side Chains Macromolecules (IF 5.1) Pub Date : 2024-08-15 Chien-Hua Tu, Eli J. Fastow, Roshni John Chethalen, George V. Papamokos, E. Bryan Coughlin, Karen I. Winey
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Shuttle Balance between Lithiophilic Functionalities Substituted on Conjugated Polymers to Improve Lithium-Ion Diffusion and Cycling Stability of Batteries Macromolecules (IF 5.1) Pub Date : 2024-08-15 Radhakisan Kargude, Bharathkumar H. Javaregowda, Sathishkumar Palani, Anup K. Singh, Kothandam Krishnamoorthy
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Light-Controlled Interfacial Self-Assembly of Bottlebrush Amphiphiles toward Highly Tunable Photonic Materials Macromolecules (IF 5.1) Pub Date : 2024-08-15 Xingzhou Li, Bingyuan Xia, Yuhang Song, Mohan Zheng, Caili Huang, Yuesheng Li, Dong-Po Song