-
Spectroscopy predicts catalyst functionality Nat. Catal. (IF 41.813) Pub Date : 2022-06-24 Janis Timoshenko
-
Ammonia to chiral α-amino acid Nat. Catal. (IF 41.813) Pub Date : 2022-06-24 Liangliang Yang, Jianwei Sun
-
Tuning at the subnanometre scale Nat. Catal. (IF 41.813) Pub Date : 2022-06-24 Sanjana Srinivas, Dionisios G. Vlachos
-
Mechanically interlocked pyrene-based photocatalysts Nat. Catal. (IF 41.813) Pub Date : 2022-06-24 Amine Garci, Jacob A. Weber, Ryan M. Young, Masoud Kazem-Rostami, Marco Ovalle, Yassine Beldjoudi, Ahmet Atilgan, Youn Jue Bae, Wenqi Liu, Leighton O. Jones, Charlotte L. Stern, George C. Schatz, Omar K. Farha, Michael R. Wasielewski, J. Fraser Stoddart
-
Oxygenate-based routes regulate syngas conversion over oxide–zeolite bifunctional catalysts Nat. Catal. (IF 41.813) Pub Date : 2022-06-23 Yi Ji, Pan Gao, Zhenchao Zhao, Dong Xiao, Qiao Han, Hongyu Chen, Ke Gong, Kuizhi Chen, Xiuwen Han, Xinhe Bao, Guangjin Hou
-
Long-chain hydrocarbons by CO2 electroreduction using polarized nickel catalysts Nat. Catal. (IF 41.813) Pub Date : 2022-06-20 Yansong Zhou, Antonio José Martín, Federico Dattila, Shibo Xi, Núria López, Javier Pérez-Ramírez, Boon Siang Yeo
-
Mechanism-guided tunnel engineering to increase the efficiency of a flavin-dependent halogenase Nat. Catal. (IF 41.813) Pub Date : 2022-06-16 Kridsadakorn Prakinee, Aisaraphon Phintha, Surawit Visitsatthawong, Narin Lawan, Jeerus Sucharitakul, Chadaporn Kantiwiriyawanitch, Jiri Damborsky, Penchit Chitnumsub, Karl-Heinz van Pée, Pimchai Chaiyen
-
Oxygen reduction reaction electrocatalysis in neutral media for bioelectrochemical systems Nat. Catal. (IF 41.813) Pub Date : 2022-06-16 Carlo Santoro, Paolo Bollella, Benjamin Erable, Plamen Atanassov, Deepak Pant
-
Cation-doped ZnS catalysts for polysulfide conversion in lithium–sulfur batteries Nat. Catal. (IF 41.813) Pub Date : 2022-06-16 Zihan Shen, Xin Jin, Jiaming Tian, Matthew Li, Yifei Yuan, Shuo Zhang, Susu Fang, Xing Fan, Weigao Xu, Hong Lu, Jun Lu, Huigang Zhang
-
Deep learning-based kcat prediction enables improved enzyme-constrained model reconstruction Nat. Catal. (IF 41.813) Pub Date : 2022-06-16 Feiran Li, Le Yuan, Hongzhong Lu, Gang Li, Yu Chen, Martin K. M. Engqvist, Eduard J. Kerkhoven, Jens Nielsen
-
Experimental Sabatier plot for predictive design of active and stable Pt-alloy oxygen reduction reaction catalysts Nat. Catal. (IF 41.813) Pub Date : 2022-06-09 Jin Huang, Luca Sementa, Zeyan Liu, Giovanni Barcaro, Miao Feng, Ershuai Liu, Li Jiao, Mingjie Xu, Denis Leshchev, Sung-Joon Lee, Mufan Li, Chengzhang Wan, Enbo Zhu, Yang Liu, Bosi Peng, Xiangfeng Duan, William A. Goddard, Alessandro Fortunelli, Qingying Jia, Yu Huang
-
High carbon utilization in CO2 reduction to multi-carbon products in acidic media Nat. Catal. (IF 41.813) Pub Date : 2022-06-09 Yi Xie, Pengfei Ou, Xue Wang, Zhanyou Xu, Yuguang C. Li, Ziyun Wang, Jianan Erick Huang, Joshua Wicks, Christopher McCallum, Ning Wang, Yuhang Wang, Tianxiang Chen, Benedict T. W. Lo, David Sinton, Jimmy C. Yu, Ying Wang, Edward H. Sargent
-
Atomically dispersed Pt and Fe sites and Pt–Fe nanoparticles for durable proton exchange membrane fuel cells Nat. Catal. (IF 41.813) Pub Date : 2022-06-02 Fei Xiao, Qi Wang, Gui-Liang Xu, Xueping Qin, Inhui Hwang, Cheng-Jun Sun, Min Liu, Wei Hua, Hsi-wen Wu, Shangqian Zhu, Jin-Cheng Li, Jian-Gan Wang, Yuanmin Zhu, Duojie Wu, Zidong Wei, Meng Gu, Khalil Amine, Minhua Shao
-
Iron-catalysed ring-opening metathesis polymerization of olefins and mechanistic studies Nat. Catal. (IF 41.813) Pub Date : 2022-06-02 Satoshi Takebayashi, Mark A. Iron, Moran Feller, Orestes Rivada-Wheelaghan, Gregory Leitus, Yael Diskin-Posner, Linda J. W. Shimon, Liat Avram, Raanan Carmieli, Sharon G. Wolf, Ilit Cohen-Ofri, Rajashekharayya A. Sanguramath, Roy Shenhar, Moris Eisen, David Milstein
-
Metal-like molecules Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 S. David Tilley
Molecular catalysts anchored on electrode surfaces are commonly assumed to behave similarly to their homogeneous counterparts. Under some conditions, however, they can behave like metallic electrodes. Now, the underlying phenomena behind this fresh paradigm in heterogeneous electrocatalysis are uncovered.
-
Spatial decoupling boosts CO2 electro-biofixation Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 Hongyuan Sheng, Chong Liu
Bioelectrochemical CO2 fixation often suffers from a mismatch between the electrochemical and biological components. Now, a spatial decoupling strategy, where CO2 electrolysis produces electrolyte-free acetic acid as the feed for engineered yeast fermentation, enables highly productive synthesis of glucose or fatty acids.
-
Nitrogenase loosens its belt to fix dinitrogen Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 Ross D. Milton
Nitrogenase reduces dinitrogen at one of its iron–sulfur cores to produce ammonia by a convoluted mechanism. Now, research highlights the importance of sulfur mobility on one of nitrogenase’s metallocofactors for nitrogen fixation.
-
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 Jiajia Ma, Shuming Chen, Peter Bellotti, Tobias Wagener, Constantin Daniliuc, Kendall N. Houk, Frank Glorius
-
Adsorbed cobalt porphyrins act like metal surfaces in electrocatalysis Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 Corey J. Kaminsky, Sophia Weng, Joshua Wright, Yogesh Surendranath
-
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 Hao Yang, Fusheng Li, Shaoqi Zhan, Yawen Liu, Wenlong Li, Qijun Meng, Alexander Kravchenko, Tianqi Liu, Yi Yang, Yuan Fang, Linqin Wang, Jiaqi Guan, István Furó, Mårten S. G. Ahlquist, Licheng Sun
-
Enhancing the connection between computation and experiments in electrocatalysis Nat. Catal. (IF 41.813) Pub Date : 2022-05-25 Joaquin Resasco, Frank Abild-Pedersen, Christopher Hahn, Zhenan Bao, Marc T. M. Koper, Thomas F. Jaramillo
-
Capabilities and limitations of rotating disk electrodes versus membrane electrode assemblies in the investigation of electrocatalysts Nat. Catal. (IF 41.813) Pub Date : 2022-05-23 Timon Lazaridis, Björn M. Stühmeier, Hubert A. Gasteiger, Hany A. El-Sayed
-
Mo3+ hydride as the common origin of H2 evolution and selective NADH regeneration in molybdenum sulfide electrocatalysts Nat. Catal. (IF 41.813) Pub Date : 2022-05-19 Jeremy A. Bau, Abdul-Hamid Emwas, Pavlo Nikolaienko, Areej A. Aljarb, Vincent Tung, Magnus Rueping
-
Enantioselective synthesis of amino acids from ammonia Nat. Catal. (IF 41.813) Pub Date : 2022-05-16 Mao-Lin Li, Jia-Bin Pan, Qi-Lin Zhou
-
Evidence of substrate binding and product release via belt-sulfur mobilization of the nitrogenase cofactor Nat. Catal. (IF 41.813) Pub Date : 2022-05-16 Chi Chung Lee, Wonchull Kang, Andrew J. Jasniewski, Martin T. Stiebritz, Kazuki Tanifuji, Markus W. Ribbe, Yilin Hu
-
Standardized protocols for evaluating platinum group metal-free oxygen reduction reaction electrocatalysts in polymer electrolyte fuel cells Nat. Catal. (IF 41.813) Pub Date : 2022-05-09 Hanguang Zhang, Luigi Osmieri, Jae Hyung Park, Hoon Taek Chung, David A. Cullen, Kenneth C. Neyerlin, Deborah J. Myers, Piotr Zelenay
-
Photoinduced chemomimetic biocatalysis for enantioselective intermolecular radical conjugate addition Nat. Catal. (IF 41.813) Pub Date : 2022-05-02 Xiaoqiang Huang, Jianqiang Feng, Jiawen Cui, Guangde Jiang, Wesley Harrison, Xin Zang, Jiahai Zhou, Binju Wang, Huimin Zhao
-
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering Nat. Catal. (IF 41.813) Pub Date : 2022-04-28 Tingting Zheng, Menglu Zhang, Lianghuan Wu, Shuyuan Guo, Xiangjian Liu, Jiankang Zhao, Weiqing Xue, Jiawei Li, Chunxiao Liu, Xu Li, Qiu Jiang, Jun Bao, Jie Zeng, Tao Yu, Chuan Xia
-
A happy couple makes acetate from CO Nat. Catal. (IF 41.813) Pub Date : 2022-04-26 Lei Wang
Selective electroreduction of CO2-derived CO presents an opportunity to produce sustainable fuels and chemicals; however, its performance has been below practical levels. Now, an ordered Cu–Pd bimetallic catalyst has been developed for selective electroreduction of CO to acetate at an industrially relevant activity.
-
Don’t cross the streams Nat. Catal. (IF 41.813) Pub Date : 2022-04-26 Sarah Lamaison, David Wakerley
Low-temperature CO2 electrolysis is increasingly attractive for the production of sustainable electrofuels and electrochemicals as intensified research keeps pushing performance higher. Recent efforts on system engineering now offer solutions to downstream purification challenges, taking this technology one step closer to maturity.
-
Non-innocent electrophiles unlock exogenous base-free coupling reactions Nat. Catal. (IF 41.813) Pub Date : 2022-04-26 Georgios Toupalas, Bill Morandi
-
Efficient exploration of terpenoid biosynthetic gene clusters in filamentous fungi Nat. Catal. (IF 41.813) Pub Date : 2022-04-26 Yujie Yuan, Shu Cheng, Guangkai Bian, Pan Yan, Zhengning Ma, Wen Dai, Rong Chen, Shuai Fu, Huiwen Huang, Haoming Chi, Yousheng Cai, Zixin Deng, Tiangang Liu
-
High loading of single atomic iron sites in Fe–NC oxygen reduction catalysts for proton exchange membrane fuel cells Nat. Catal. (IF 41.813) Pub Date : 2022-04-25 Asad Mehmood, Mengjun Gong, Frédéric Jaouen, Aaron Roy, Andrea Zitolo, Anastassiya Khan, Moulay-Tahar Sougrati, Mathias Primbs, Alex Martinez Bonastre, Dash Fongalland, Goran Drazic, Peter Strasser, Anthony Kucernak
-
Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses Nat. Catal. (IF 41.813) Pub Date : 2022-04-21 Janis Timoshenko, Arno Bergmann, Clara Rettenmaier, Antonia Herzog, Rosa M. Arán-Ais, Hyo Sang Jeon, Felix T. Haase, Uta Hejral, Philipp Grosse, Stefanie Kühl, Earl M. Davis, Jing Tian, Olaf Magnussen, Beatriz Roldan Cuenya
-
Fully exposed palladium cluster catalysts enable hydrogen production from nitrogen heterocycles Nat. Catal. (IF 41.813) Pub Date : 2022-04-21 Chunyang Dong, Zirui Gao, Yinlong Li, Mi Peng, Meng Wang, Yao Xu, Chengyu Li, Ming Xu, Yuchen Deng, Xuetao Qin, Fei Huang, Xuyan Wei, Yang-Gang Wang, Hongyang Liu, Wu Zhou, Ding Ma
-
Ground-state destabilization by electrostatic repulsion is not a driving force in orotidine-5′-monophosphate decarboxylase catalysis Nat. Catal. (IF 41.813) Pub Date : 2022-04-21 Sören Rindfleisch, Matthias Krull, Jon Uranga, Tobias Schmidt, Fabian Rabe von Pappenheim, Laura Liliana Kirck, Angeliki Balouri, Thomas Schneider, Ashwin Chari, Ronald Kluger, Gleb Bourenkov, Ulf Diederichsen, Ricardo A. Mata, Kai Tittmann
-
Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes Nat. Catal. (IF 41.813) Pub Date : 2022-04-21 Zechao Zhuang, Yihang Li, Ruohan Yu, Lixue Xia, Jiarui Yang, Zhiquan Lang, Jiexin Zhu, Jiazhao Huang, Jiaou Wang, Yu Wang, Liangdong Fan, Jinsong Wu, Yan Zhao, Dingsheng Wang, Yadong Li
-
Recovering carbon losses in CO2 electrolysis using a solid electrolyte reactor Nat. Catal. (IF 41.813) Pub Date : 2022-04-18 Jung Yoon ‘Timothy’ Kim, Peng Zhu, Feng-Yang Chen, Zhen-Yu Wu, David A. Cullen, Haotian Wang
-
Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium Nat. Catal. (IF 41.813) Pub Date : 2022-04-14 Jun Gu, Shuo Liu, Weiyan Ni, Wenhao Ren, Sophia Haussener, Xile Hu
-
Author Correction: Design and evolution of chimeric streptavidin for protein-enabled dual gold catalysis Nat. Catal. (IF 41.813) Pub Date : 2022-04-01 Fadri Christoffel,Nico V. Igareta,Michela M. Pellizzoni,Laura Tiessler-Sala,Boris Lozhkin,Daniel C. Spiess,Agustí Lledós,Jean-Didier Maréchal,Ryan L. Peterson,Thomas R. Ward
-
Early-stage evaluation of catalyst manufacturing cost and environmental impact using CatCost Nat. Catal. (IF 41.813) Pub Date : 2022-03-31 Kurt M. Van Allsburg, Eric C. D. Tan, John D. Super, Joshua A. Schaidle, Frederick G. Baddour
-
Distinguishing thermal from non-thermal contributions to plasmonic hydrodefluorination Nat. Catal. (IF 41.813) Pub Date : 2022-03-28 Yonatan Dubi,Ieng Wai Un,Joshua H. Baraban,Yonatan Sivan
-
Reply to: Distinguishing thermal from non-thermal contributions to plasmonic hydrodefluorination Nat. Catal. (IF 41.813) Pub Date : 2022-03-28 Hossein Robatjazi,Andrea Schirato,Alessandro Alabastri,Phillip Christopher,Emily A. Carter,Peter Nordlander,Naomi J. Halas
-
Selective CO-to-acetate electroreduction via intermediate adsorption tuning on ordered Cu–Pd sites Nat. Catal. (IF 41.813) Pub Date : 2022-03-28 Yali Ji, Zheng Chen, Ruilin Wei, Chao Yang, Yuhang Wang, Jie Xu, Hao Zhang, Anxiang Guan, Jiatang Chen, Tsun-Kong Sham, Jun Luo, Yaoyue Yang, Xin Xu, Gengfeng Zheng
-
Kinetics of redox-mediated catalysis in batteries Nat. Catal. (IF 41.813) Pub Date : 2022-03-25 Haoshen Zhou
Studying the kinetics of high-energy and high-power batteries is a formidable challenge. Now, it has been shown that redox-mediated (RM) catalysis in Li–O2 and Li–S batteries can be controlled by tuning parameters such as Li-ion concentration or electrolyte solvent, revealing threshold potentials in which rate constants increase several-fold.
-
A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation Nat. Catal. (IF 41.813) Pub Date : 2022-03-25 Agus R. Poerwoprajitno, Lucy Gloag, John Watt, Soshan Cheong, Xin Tan, Han Lei, Hassan A. Tahini, Aaron Henson, Bijil Subhash, Nicholas M. Bedford, Benjamin K. Miller, Peter B. O’Mara, Tania M. Benedetti, Dale L. Huber, Wenhua Zhang, Sean C. Smith, J. Justin Gooding, Wolfgang Schuhmann, Richard D. Tilley
-
Interpretable machine learning for knowledge generation in heterogeneous catalysis Nat. Catal. (IF 41.813) Pub Date : 2022-03-17 Jacques A. Esterhuizen, Bryan R. Goldsmith, Suljo Linic
-
Potassium hydride-intercalated graphite as an efficient heterogeneous catalyst for ammonia synthesis Nat. Catal. (IF 41.813) Pub Date : 2022-03-17 Fei Chang, Ilker Tezsevin, Jan Willem de Rijk, Johannes D. Meeldijk, Jan P. Hofmann, Süleyman Er, Peter Ngene, Petra E. de Jongh
-
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production Nat. Catal. (IF 41.813) Pub Date : 2022-03-10 Yongmin He, Liren Liu, Chao Zhu, Shasha Guo, Prafful Golani, Bonhyeong Koo, Pengyi Tang, Zhiqiang Zhao, Mangzhang Xu, Chao Zhu, Peng Yu, Xin Zhou, Caitian Gao, Xuewen Wang, Zude Shi, Lu Zheng, Jiefu Yang, Byungha Shin, Jordi Arbiol, Huigao Duan, Yonghua Du, Marc Heggen, Rafal E. Dunin-Borkowski, Wanlin Guo, Qi Jie Wang, Zhuhua Zhang, Zheng Liu
-
Highly selective and productive reduction of carbon dioxide to multicarbon products via in situ CO management using segmented tandem electrodes Nat. Catal. (IF 41.813) Pub Date : 2022-03-03 Tianyu Zhang, Justin C. Bui, Zhengyuan Li, Alexis T. Bell, Adam Z. Weber, Jingjie Wu
-
Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries Nat. Catal. (IF 41.813) Pub Date : 2022-03-03 Deqing Cao, Xiaoxiao Shen, Aiping Wang, Fengjiao Yu, Yuping Wu, Siqi Shi, Stefan A. Freunberger, Yuhui Chen
-
Activating catalysts by adsorbate-induced reconstructions Nat. Catal. (IF 41.813) Pub Date : 2022-02-25 Albert Bruix
Solid catalysts often exhibit a dynamic behaviour when exposed to reactive environments. Now, a study showcases how such behaviour can be exploited to maximize activity.
-
Molecular water oxidation catalysts based on first-row transition metal complexes Nat. Catal. (IF 41.813) Pub Date : 2022-02-25 Marcos Gil-Sepulcre, Antoni Llobet
The discovery of robust and efficient water oxidation catalysts based on first-row transition metal complexes is still a challenge. Here, we describe the underlying chemistry related to the deactivation pathways of first-row transition metal complexes and put forward a series of principles and basic checks to enable the development of robust catalysts.
-
Critical enzyme reactions in aromatic catabolism for microbial lignin conversion Nat. Catal. (IF 41.813) Pub Date : 2022-02-25 Erika Erickson, Alissa Bleem, Eugene Kuatsjah, Allison Z. Werner, Jennifer L. DuBois, John E. McGeehan, Lindsay D. Eltis, Gregg T. Beckham
-
Redox-mediated electrosynthesis of ethylene oxide from CO2 and water Nat. Catal. (IF 41.813) Pub Date : 2022-02-24 Yuhang Li, Adnan Ozden, Wan Ru Leow, Pengfei Ou, Jianan Erick Huang, Yuhang Wang, Koen Bertens, Yi Xu, Yuan Liu, Claudie Roy, Hao Jiang, David Sinton, Chunzhong Li, Edward H. Sargent
-
Quantifying the electrochemical active site density of precious metal-free catalysts in situ in fuel cells Nat. Catal. (IF 41.813) Pub Date : 2022-02-24 Rifael Z. Snitkoff-Sol, Ariel Friedman, Hilah C. Honig, Yan Yurko, Alisa Kozhushner, Michael J. Zachman, Piotr Zelenay, Alan M. Bond, Lior Elbaz
-
Reaction product-driven restructuring and assisted stabilization of a highly dispersed Rh-on-ceria catalyst Nat. Catal. (IF 41.813) Pub Date : 2022-02-24 George Yan, Yu Tang, Yuting Li, Yixiao Li, Luan Nguyen, Tomohiro Sakata, Kotaro Higashi, Franklin Feng Tao, Philippe Sautet
-
A cell-free self-replenishing CO2-fixing system Nat. Catal. (IF 41.813) Pub Date : 2022-02-24 Shanshan Luo, Paul P. Lin, Liang-Yu Nieh, Guan-Bo Liao, Po-Wen Tang, Chi Chen, James C. Liao
-
Modulating the dynamics of Brønsted acid sites on PtWOx inverse catalyst Nat. Catal. (IF 41.813) Pub Date : 2022-02-21 Jiayi Fu, Shizhong Liu, Weiqing Zheng, Renjing Huang, Cong Wang, Ajibola Lawal, Konstantinos Alexopoulos, Sibao Liu, Yunzhu Wang, Kewei Yu, J. Anibal Boscoboinik, Yuefeng Liu, Xi Liu, Anatoly I. Frenkel, Omar A. Abdelrahman, Raymond J. Gorte, Stavros Caratzoulas, Dionisios G. Vlachos
-
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction Nat. Catal. (IF 41.813) Pub Date : 2022-02-21 Jonathan M. Ellis, Meghan E. Campbell, Prasanth Kumar, Eric P. Geunes, Craig A. Bingman, Andrew R. Buller