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Deciphering electrochemical methanol production Nat. Catal. (IF 42.8) Pub Date : 2024-09-24 Stefan Ringe
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Carbon conversion on biophotonic leaf Nat. Catal. (IF 42.8) Pub Date : 2024-09-24 Jinhyeong Jang, Elena A. Rozhkova
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Solid electrolyte reactor for nitrate-to-ammonia Nat. Catal. (IF 42.8) Pub Date : 2024-09-24 Yuting Wang, Bin Zhang
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Unlocking C–C cleavage in the electrochemical toolbox Nat. Catal. (IF 42.8) Pub Date : 2024-09-24 Nikolay Kornienko
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Metallaphotoredox catalysis for sp3 C–H functionalizations through single-electron transfer Nat. Catal. (IF 42.8) Pub Date : 2024-09-24 Jingchang Zhang, Magnus Rueping
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Cation effect on the elementary steps of the electrochemical CO reduction reaction on Cu Nat. Catal. (IF 42.8) Pub Date : 2024-09-23 Yifei Xu, Zhaoming Xia, Wenqiang Gao, Hai Xiao, Bingjun Xu
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Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli Nat. Catal. (IF 42.8) Pub Date : 2024-09-19 Joseph B. Solomon, Chi Chung Lee, Yiling A. Liu, Calder Duffin, Markus W. Ribbe, Yilin Hu
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Unveiling metal mobility in a liquid Cu–Ga catalyst for ammonia synthesis Nat. Catal. (IF 42.8) Pub Date : 2024-09-19 Karma Zuraiqi, Yichao Jin, Caiden J. Parker, Jaydon Meilak, Nastaran Meftahi, Andrew J. Christofferson, Salvy P. Russo, Michelle J. S. Spencer, Huai Yong Zhu, Lizhuo Wang, Jun Huang, Rosalie K. Hocking, Ken Chiang, Sarina Sarina, Torben Daeneke
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Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol Nat. Catal. (IF 42.8) Pub Date : 2024-09-13 Maryam Abdinejad, Amirhossein Farzi, Robin Möller-Gulland, Fokko Mulder, Chengyu Liu, Junming Shao, Jasper Biemolt, Marc Robert, Ali Seifitokaldani, Thomas Burdyny
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Enantioselective Chan–Lam S-arylation of sulfenamides Nat. Catal. (IF 42.8) Pub Date : 2024-09-09 Qingjin Liang, Xinping Zhang, Madeline E. Rotella, Zeyu Xu, Marisa C. Kozlowski, Tiezheng Jia
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The structural basis of pyridoxal-5′-phosphate-dependent β-NAD-alkylating enzymes Nat. Catal. (IF 42.8) Pub Date : 2024-09-02 Takayoshi Awakawa, Takahiro Mori, Lena Barra, Yusef Ahmed, Richiro Ushimaru, Yaojie Gao, Naruhiko Adachi, Toshiya Senda, Tohru Terada, Dean J. Tantillo, Ikuro Abe
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Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states Nat. Catal. (IF 42.8) Pub Date : 2024-08-30 Subham Choudhury, Bharath Narayanan, Michael Moret, Vassily Hatzimanikatis, Ljubisa Miskovic
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Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions Nat. Catal. (IF 42.8) Pub Date : 2024-08-29 Christine Lucky, Shengli Jiang, Chien-Rung Shih, Victor M. Zavala, Marcel Schreier
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Reshaping catalysis beyond the conventional Nat. Catal. (IF 42.8) Pub Date : 2024-08-27 Amani M. Ebrahim
The catalysis Gordon Research Conference is a much-anticipated biennial gathering of the community to discuss the frontiers in design and development of catalytic materials and processes. Amani Ebrahim briefly touches upon this year’s themes centred on enabling technologies for sustainable societies.
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Harnessing electron-rich arenes in nickel photoredox catalysis Nat. Catal. (IF 42.8) Pub Date : 2024-08-27 Sneha Nayak, Laura K. G. Ackerman-Biegasiewicz
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Radical control for enantioselective Csp3–Csp3 cross-coupling Nat. Catal. (IF 42.8) Pub Date : 2024-08-27 Ju Byeong Chae, Annika R. Holm, Liviu M. Mirica
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A structured catalyst for anion exchange membrane water electrolysis Nat. Catal. (IF 42.8) Pub Date : 2024-08-27
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Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis Nat. Catal. (IF 42.8) Pub Date : 2024-08-27
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Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates Nat. Catal. (IF 42.8) Pub Date : 2024-08-19 Ibrahim Khalil, Marco Giulio Rigamonti, Kwinten Janssens, Aram Bugaev, Daniel Arenas Esteban, Sven Robijns, Thibaut Donckels, Mostafa Torka Beydokhti, Sara Bals, Dirk De Vos, Michiel Dusselier
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Overcoming limitations in non-activated alkene cross-coupling with nickel catalysis and anionic ligands Nat. Catal. (IF 42.8) Pub Date : 2024-08-15 Dong Wu, Weiyu Kong, Yang Bao, Chengmi Huang, Wei Liu, Yuqiang Li, Guoyin Yin
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Radical strain-release photocatalysis for the synthesis of azetidines Nat. Catal. (IF 42.8) Pub Date : 2024-08-14 Ricardo I. Rodríguez, Vasco Corti, Lorenzo Rizzo, Stefano Visentini, Marco Bortolus, Agnese Amati, Mirco Natali, Giorgio Pelosi, Paolo Costa, Luca Dell’Amico
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Seed-assisted formation of NiFe anode catalysts for anion exchange membrane water electrolysis at industrial-scale current density Nat. Catal. (IF 42.8) Pub Date : 2024-08-13 Zhiheng Li, Gaoxin Lin, Linqin Wang, Husileng Lee, Jian Du, Tang Tang, Guoheng Ding, Rong Ren, Wenlong Li, Xing Cao, Shiwen Ding, Wentao Ye, Wenxing Yang, Licheng Sun
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Electrochemical nitrate reduction to ammonia with cation shuttling in a solid electrolyte reactor Nat. Catal. (IF 42.8) Pub Date : 2024-08-12 Feng-Yang Chen, Ahmad Elgazzar, Stephanie Pecaut, Chang Qiu, Yuge Feng, Sushanth Ashokkumar, Zhou Yu, Chase Sellers, Shaoyun Hao, Peng Zhu, Haotian Wang
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Iridium nitrenoid-enabled arene C−H functionalization Nat. Catal. (IF 42.8) Pub Date : 2024-08-12 Liang-Wen Qi, Torben Rogge, K. N. Houk, Yixin Lu
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Carbon monoxide enabling synergistic carbonylation and (hetero)aryl migration Nat. Catal. (IF 42.8) Pub Date : 2024-08-06 Yuanrui Wang, Hefei Yang, Yan Zheng, Mingxia Hu, Jintao Zhu, Zhi-Peng Bao, Yanying Zhao, Xiao-Feng Wu
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Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes Nat. Catal. (IF 42.8) Pub Date : 2024-08-05 Zechao Zhuang, Yihang Li, Ruohan Yu, Lixue Xia, Jiarui Yang, Zhiquan Lang, Jiexin Zhu, Jiazhao Huang, Jiaou Wang, Yu Wang, Liangdong Fan, Jinsong Wu, Yan Zhao, Dingsheng Wang, Yadong Li
Correction to: Nature Catalysis https://doi.org/10.1038/s41929-022-00764-9, published online 21 April 2022.
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A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization Nat. Catal. (IF 42.8) Pub Date : 2024-07-30 Jimin Kim, Jia-An Lin, Jinhyun Kim, Inwhan Roh, Soohyung Lee, Peidong Yang
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Repurposing organic pollutants Nat. Catal. (IF 42.8) Pub Date : 2024-07-26 Francesco Zamberlan
They first established that, in dimethyl sulfoxide (DMSO), the alkyl bromide can act as a catalyst in the transfer of a chlorine atom from an alkyl chloride to the α-carbon of a carbonyl compound. This was further confirmed by mechanistic investigations, which enabled the team to propose a sequence of events where the halogenated compound reacts with DMSO at high temperature to yield an alkoxysulfonium
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Frustration-driven efficiency Nat. Catal. (IF 42.8) Pub Date : 2024-07-26 Chenyu Wang
Surface-frustrated Lewis pairs are unique catalytic sites formed by the combination of Lewis acid and Lewis base sites locked in close proximity on the material's surface. These pairs are particularly effective in accelerating catalytic conversions due to their collective ability to simultaneously accept and donate electrons, thereby facilitating bond breaking and formation. The team synthesized a
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Catalysing rate and capacity Nat. Catal. (IF 42.8) Pub Date : 2024-07-26 Soumyadip Mondal, Stefan A. Freunberger
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Identifying the activity of nanocatalyst sites Nat. Catal. (IF 42.8) Pub Date : 2024-07-26 Woong Hee Lee
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CO2-to-methanol electroconversion on a molecular cobalt catalyst facilitated by acidic cations Nat. Catal. (IF 42.8) Pub Date : 2024-07-22 Sunmoon Yu, Hiroki Yamauchi, Shuo Wang, Abhishek Aggarwal, Junghwa Kim, Kiarash Gordiz, Botao Huang, Hongbin Xu, Daniel J. Zheng, Xiao Wang, Haldrian Iriawan, Davide Menga, Yang Shao-Horn
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Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts Nat. Catal. (IF 42.8) Pub Date : 2024-07-19 Ming Zhao, Wenjie Li, Muwen Yang, Zhiheng Zhao, Rong Ye, Xianwen Mao, Paul Padgett, Peng Chen
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Electrocatalytic cyclic deracemization enabled by a chemically modified electrode Nat. Catal. (IF 42.8) Pub Date : 2024-07-11 Cheng-Jie Zhu, Xiuying Yang, Jianchun Wang
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Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis Nat. Catal. (IF 42.8) Pub Date : 2024-07-11 Qing-Zhu Li, Wen-Lin Zou, Zhao-Yuan Yu, Xin-Xin Kou, Yan-Qing Liu, Xiang Zhang, Yu He, Jun-Long Li
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Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation Nat. Catal. (IF 42.8) Pub Date : 2024-07-10 Bingzhang Lu, Carolin Wahl, Roberto dos Reis, Jane Edgington, Xiao Kun Lu, Ruihan Li, Matthew E. Sweers, Brianna Ruggiero, G. T. Kasun Kalhara Gunasooriya, Vinayak Dravid, Linsey C. Seitz
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Atomic-scale identification of active sites of oxygen reduction nanocatalysts Nat. Catal. (IF 42.8) Pub Date : 2024-07-08 Yao Yang, Jihan Zhou, Zipeng Zhao, Geng Sun, Saman Moniri, Colin Ophus, Yongsoo Yang, Ziyang Wei, Yakun Yuan, Cheng Zhu, Yang Liu, Qiang Sun, Qingying Jia, Hendrik Heinz, Jim Ciston, Peter Ercius, Philippe Sautet, Yu Huang, Jianwei Miao
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The solvation environment of molecularly dispersed cobalt phthalocyanine determines methanol selectivity during electrocatalytic CO2 reduction Nat. Catal. (IF 42.8) Pub Date : 2024-07-08 Quansong Zhu, Conor L. Rooney, Hadar Shema, Christina Zeng, Julien A. Panetier, Elad Gross, Hailiang Wang, L. Robert Baker
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Enantioselective alkylation of α-amino C(sp3)−H bonds via photoredox and nickel catalysis Nat. Catal. (IF 42.8) Pub Date : 2024-07-04 Jian Li, Buqing Cheng, Xiaomin Shu, Zhen Xu, Chengyang Li, Haohua Huo
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Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3 Nat. Catal. (IF 42.8) Pub Date : 2024-07-02 Donato Decarolis, Monik Panchal, Matthew Quesne, Khaled Mohammed, Shaojun Xu, Mark Isaacs, Adam H. Clark, Luke L. Keenan, Takuo Wakisaka, Kohei Kusada, Hiroshi Kitagawa, C. Richard A. Catlow, Emma K. Gibson, Alexandre Goguet, Peter P. Wells
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Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization Nat. Catal. (IF 42.8) Pub Date : 2024-07-01 Jun-Jie Wang, He Huang, Han-Li Sun, Fan Yang, Jun Wen, Rong Zhu
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Embedded oxide clusters stabilize sub-2 nm Pt nanoparticles for highly durable fuel cells Nat. Catal. (IF 42.8) Pub Date : 2024-07-01 Bosi Peng, Zeyan Liu, Luca Sementa, Qingying Jia, Qiang Sun, Carlo U. Segre, Ershuai Liu, Mingjie Xu, Yu-Han (Joseph) Tsai, Xingxu Yan, Zipeng Zhao, Jin Huang, Xiaoqing Pan, Xiangfeng Duan, Alessandro Fortunelli, Yu Huang
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Gilding σ-type cyclopropenium cations Nat. Catal. (IF 42.8) Pub Date : 2024-06-26 Jan-Stefan Völler
Now, Jérôme Waser and colleagues report cyclopropenyl benziodoxoles as stable precursors of σ-type cyclopropenium cations and their subsequent application in catalytic transformations. The cyclopropenyl benziodoxoles were synthesized by deprotonation of cyclopropenes with n-butyllithium followed by addition of hypervalent iodine precursors. Then, σ-type CPC transfer to terminal alkynes and vinylboronic
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Oxygen evolving atoms Nat. Catal. (IF 42.8) Pub Date : 2024-06-26 Benjamin Martindale
Pt SA and Pt nanoparticles (NP) were separately deposited onto a TiO2 photoanode using established methods. While the Pt nanoparticles consisted of Pt in its metallic Pt(0) state, XPS data indicated that Pt SA contained Pt in a slightly oxidized form (Ptδ+) due to donation of electron density to the TiO2 support. Consistent with this, the charge transfer kinetics in TiO2 were altered in the presence
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The unbearable lightness of hyperbolic language Nat. Catal. (IF 42.8) Pub Date : 2024-06-26
This Editorial deals with scientific language in research papers, considering the causes — as well as the problems — associated with the use of hyperbolic statements.
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A radical strategy towards ortho-amination reactions Nat. Catal. (IF 42.8) Pub Date : 2024-06-26 Quoc Hoang Pham, Rene M. Koenigs
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Monitoring catalytic nanosites in action Nat. Catal. (IF 42.8) Pub Date : 2024-06-26 Katrin F. Domke
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Parallel experiments in electrochemical CO2 reduction enabled by standardized analytics Nat. Catal. (IF 42.8) Pub Date : 2024-06-26 Alessandro Senocrate, Francesco Bernasconi, Peter Kraus, Nukorn Plainpan, Jens Trafkowski, Fabian Tolle, Thomas Weber, Ulrich Sauter, Corsin Battaglia
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Absolute band-edge energies are over-emphasized in the design of photoelectrochemical materials Nat. Catal. (IF 42.8) Pub Date : 2024-06-26 Aaron J. Kaufman, Adam C. Nielander, Gerald J. Meyer, Stephen Maldonado, Shane Ardo, Shannon W. Boettcher
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Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media Nat. Catal. (IF 42.8) Pub Date : 2024-06-24 Zhi-Ming Zhang, Tao Wang, Yu-Chen Cai, Xiao-Yu Li, Jin-Yu Ye, Yao Zhou, Na Tian, Zhi-You Zhou, Shi-Gang Sun
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Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts Nat. Catal. (IF 42.8) Pub Date : 2024-06-18 Jiashun Liang, Shenzhou Li, Xuan Liu, Yangyang Wan, Yu Xia, Hao Shi, Siyang Zhang, Hsing-Lin Wang, Gang Lu, Gang Wu, Yunhui Huang, Qing Li
Correction to: Nature Catalysis https://doi.org/10.1038/s41929-024-01167-8, published online 3 June 2024
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Exploring mesoscopic mass transport effects on electrocatalytic selectivity Nat. Catal. (IF 42.8) Pub Date : 2024-06-14 Hendrik H. Heenen, Hemanth S. Pillai, Karsten Reuter, Vanessa J. Bukas
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Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries Nat. Catal. (IF 42.8) Pub Date : 2024-06-14 Yuhang Dai, Ruihu Lu, Chengyi Zhang, Jiantao Li, Yifei Yuan, Yu Mao, Chumei Ye, Zhijun Cai, Jiexin Zhu, Jinghao Li, Ruohan Yu, Lianmeng Cui, Siyu Zhao, Qinyou An, Guanjie He, Geoffrey I. N. Waterhouse, Paul R. Shearing, Yang Ren, Jun Lu, Khalil Amine, Ziyun Wang, Liqiang Mai
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Unravelling the effects of active site density and energetics on the water oxidation activity of iridium oxides Nat. Catal. (IF 42.8) Pub Date : 2024-06-07 Caiwu Liang, Reshma R. Rao, Katrine L. Svane, Joseph H. L. Hadden, Benjamin Moss, Soren B. Scott, Michael Sachs, James Murawski, Adrian Malthe Frandsen, D. Jason Riley, Mary P. Ryan, Jan Rossmeisl, James R. Durrant, Ifan E. L. Stephens
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Urea synthesis via electrocatalytic oxidative coupling of CO with NH3 on Pt Nat. Catal. (IF 42.8) Pub Date : 2024-06-05 Haocheng Xiong, Peiping Yu, Kedang Chen, Shike Lu, Qikun Hu, Tao Cheng, Bingjun Xu, Qi Lu
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Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts Nat. Catal. (IF 42.8) Pub Date : 2024-06-03 Jiashun Liang, Shenzhou Li, Xuan Liu, Yangyang Wan, Yu Xia, Hao Shi, Siyang Zhang, Hsing-Lin Wang, Gang Lu, Gang Wu, Yunhui Huang, Qing Li
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A boronic enzyme Nat. Catal. (IF 42.8) Pub Date : 2024-05-29 Francesco Zamberlan
The researchers initially incorporated pBoF at distinct positions in the hydrophobic cavity of the dimeric Lactococcal multidrug resistance regulatory protein, to provide distinct chemical environments where the boronic acid could accelerate the condensation reaction between racemic benzoin and hydroxylamine to the corresponding oxime. Insertion of pBoF at position 89 catalysed the reaction and discriminated