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New frontiers in the transition-metal-free synthesis of heterocycles from alkynoates: an overview and current status Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-22 Imtiaz Khan; Sumera Zaib; Aliya Ibrar
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The continuous-flow electrosynthesis of 4-(sulfonylmethyl)isoquinoline-1,3(2H,4H)-diones from N-alkyl-N-methacryloyl benzamides under metal-free and oxidant-free conditions Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-10 Jia Xu; Zhao Yang; Jiawei Hua; Yang Lin; Mixue Bian; Yuguang Li; Chengkou Liu; Wei He; Zheng Fang; Kai Guo
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Angular ladder-type meta-phenylenes: synthesis and electronic structural analysis Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-16 Anitha Boddeda; Mohammad Mosharraf Hossain; M. Saeed Mirzaei; Sergey V. Lindeman; Saber Mirzaei; Rajendra Rathore
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Photoredox-catalyzed halotrifluoromethylations of alkynes with triethylammonium halides: synthesis of tetrasubstituted alkenes containing CF3 and halogens Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-14 Woori Lee; Yeonhee Lee; Minjin Yoo; Soo Bong Han; Hyun Jin Kim
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Mapping the resources and approaches facilitating computer-aided synthesis planning Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-28 Zheng Wang; Wei Zhao; Gefei Hao; Baoan Song
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Correction: Hydride transfer enabled switchable dearomatization of indoles in the carbocyclic ring and the pyrrole ring Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-16 Kang Duan; Hongjin Shi; Lin-Xuan Wang; Shuai-Shuai Li; Lubin Xu; Jian Xiao
Correction for ‘Hydride transfer enabled switchable dearomatization of indoles in the carbocyclic ring and the pyrrole ring’ by Kang Duan et al., Org. Chem. Front., 2020, 7, 2511–2517, DOI: 10.1039/D0QO00658K.
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Diastereoselective synthesis of dispiro[indoline-3,3′-furan-2′,3′′-pyrrolidine] via [3 + 2]cycloaddition reaction of MBH maleimides of isatins and 1,3-dicarbonyl compounds Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-08 Liu-Na Pan; Jing Sun; Rong-Guo Shi; Chao-Guo Yan
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A removable directing group-assisted Rh(III)-catalyzed direct C–H bond activation/annulation cascade to synthesize highly fused isoquinolines Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-27 Yilang Cheng; Xu Han; Junyou Li; Yu Zhou; Hong Liu
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Identification, cloning, expression and functional interrogation of the biosynthetic pathway of the polychlorinated triphenyls ambigol A–C from Fischerella ambigua 108b Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-20 Elke R. Duell; Tobias M. Milzarek; Mustafa El Omari; Luis J. Linares-Otoya; Till F. Schäberle; Gabrielle M. König; Tobias A. M. Gulder
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Copper-catalyzed 1,1-alkynylalkylation of alkynes: access toward conjugated enynes Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-24 Y. Lv; Y. Wang; W. Pu; X. Zhu; N. Wu; Y. Zhao
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Metal-free reductive coupling of aliphatic aldehydes/ketones with 4-cyanopyridines: expanded scope and mechanistic studies Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-24 Liuzhou Gao; Guoqiang Wang; Hui Chen; Jia Cao; Xiaoshi Su; Xueting Liu; Mo Yang; Xu Cheng; Shuhua Li
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Transition metal-free synthesis of 3-trifluoromethyl chromones via tandem C–H trifluoromethylation and chromone annulation of enaminones Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-24 Qing Yu; Yunyun Liu; Jie-Ping Wan
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Palladium-catalyzed double-carbonylative cyclization of propargyl alcohols and aryl triflates to expedite construction of 4-aroyl-furan-2(5H)-ones Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-24 Jun Ying; Zhengjie Le; Xiao-Feng Wu
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Amplisins A–E, chromone methide polymers with hypoglycemic activity from a new fungicolous fungus Amplistroma fungicola Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-20 Baosong Chen; Junjie Han; Mengmeng Wang; Huanqin Dai; Jinjin Zhang; Lei Cai; Shenglong Wei; Xue Zhang; Hongwei Liu
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NBS-activated cross-dehydrogenative esterification of carboxylic acids with DMSO Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-20 Ya Wu; Mengsha Zhang; Yanli Zhang; Mingyang Li; Weisheng Feng; Xiaoke Zheng; Lin Tang
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Spiromyrrhenes A–D: unprecedented diterpene–sesquiterpene heterodimers as intermolecular [4 + 2] cycloaddition products from Resina Commiphora that inhibit tumor stemness in esophageal cancer Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-19 Bin-Yuan Hu; Shao-Xiang Wang; Yong-Ming Yan; Jia-Wang Liu; Da-Peng Qin; Yong-Xian Cheng
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Palladium-catalyzed domino Heck cyclization/ring opening of sulfolenes/desulfitative coupling: regio- and stereoselective synthesis of alkylated conjugated dienes Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-19 Xin-Xing Wu; Hao Ye; Hong Dai; Bing Yang; Yang Wang; Shufeng Chen; Lanping Hu
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Transamidation via C–N bond cleavage of amides and tertiary amines Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-18 Muhammad Aliyu Idris; Sunwoo Lee
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Indium-mediated difunctionalization of iodoalkyl-tethered unactivated alkenes via an intramolecular cyclization and an ensuing palladium-catalyzed cross-coupling reaction with aryl halides Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-17 Xuan-Di Song; Xiang-Rui Li; Ya-Wen Wang; Xue-Qiang Chu; Weidong Rao; Haiyan Xu; Guo-Zhi Han; Zhi-Liang Shen
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Transition-metal-free highly regioselective C–H acetoxylation of pyrrolo[2,3-d]pyrimidine derivatives Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-12 Zhengtong Mao; Min Liu; Gaoyang Zhu; Jing Zhou; Xingxian Zhang
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A thermal decarboxylative Cloke–Wilson rearrangement of dispirocyclopropanes derived from para-quinone methides and bromo-Meldrum's acids: an approach to synthesize spirobutyrolactone para-dienones Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-11 Tong Li; Dandan Yan; Chaoxing Cui; Xixi Song; Junbiao Chang
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Synthesis of 2,3-disubstituted indoles via a tandem reaction Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-11 Shiqiang Ma; Dan Long; Peiqi Chen; Hongliang Shi; Huilin Li; Ran Fang; Xiaolei Wang; Xingang Xie; Xuegong She
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NIS-promoted intermolecular bis-sulfenylation of allenamides via a two-step radical process: synthesis of 1,3-dithioethers Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-10 Xiao Yuan; Xiaoju Tan; Na Ding; Yongchun Liu; Xiaoxiao Li; Zhigang Zhao
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A concise and unexpected one-pot methodology for the synthesis of pyrazinone-fused pyridones Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-06 Jie Lei; Jia Xu; Dian-Yong Tang; Jing-Wei Shao; Hong-yu Li; Zhong-Zhu Chen; Zhi-Gang Xu
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Brønsted-acid-catalyzed one-pot tandem annulation/[5 + 2]-cycloaddition of o-propargyl alcohol benzaldehydes with alkynes: regioselective and stereoselective synthesis of dibenzo[a,f]azulen-12-ones Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-06 Ni-Ni Zhou; Si-Si Ning; Lin-Qiang Li; Jie-Yun Zhang; Ming-Jin Fan; De-Suo Yang; Hai-Tao Zhu
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Enzymatic and non-enzymatic crosslinks found in collagen and elastin and their chemical synthesis Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-04 Jakob Gaar; Rafea Naffa; Margaret Brimble
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Organic micro/nanoscale materials for photonic barcodes Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-04 Yue Hou; Zhenhua Gao; Yong Sheng Zhao; Yongli Yan
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A bench-stable low-molecular-weight vinyl azide surrogate for a cascade reaction: facile access to novel N-vinyl-1,2,3-triazoles Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-04 Zhenhua Liu; Lianxiao Wang; Tian Yu; Yanan Sun; Huimin Chen; Wen Gao; Bo Tang
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Phosphine-catalyzed conjugate cyanation of β-trifluoromethyl enones: access to α-trifluoromethyl γ-carbonyl nitriles Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-04 Tao Zhou; Xin Ji; Junliang Zhang; Lu Liu
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Emissive tetraphenylethylene (TPE) derivatives in a dissolved state tightly fastened by a short oligo(ethylene glycol) chain Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-31 Yuma Tanaka; Takashi Machida; Toshiaki Noumi; Kazuki Sada; Kenta Kokado
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Dimerization–cyclization reactions of isocyanoaryl-tethered alkylidenecyclobutanes via a triplet biradical mediated process Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-31 Le-Yi Tao; Yin Wei; Min Shi
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Enantioselective copper-catalysed defluorosilylation of trifluoro-methylated alkenes with silylboronates Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-29 Pan Gao; Liuzhou Gao; Longlong Xi; Zedong Zhang; Shuhua Li; Zhuangzhi Shi
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Organoselenium chemistry-based polymer synthesis Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-20 Qilong Li; Yuanyuan Zhang; Zijun Chen; Xiangqiang Pan; Zhengbiao Zhang; Jian Zhu; Xiulin Zhu
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Cavity-based applications of metallo-supramolecular coordination cages (MSCCs) Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-20 Sarita Yadav; Palanisamy Kannan; Guanyinsheng Qiu
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Recent advances in nitro-involved radical reactions Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-17 Jiapian Huang; Feng Ding; Pornchai Rojsitthisak; Fu-Sheng He; Jie Wu
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Palladium-catalyzed selective defluorinative sulfenylation for the synthesis of fluorovinylthioethers Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-09 Shi-Yu He; Xing-Guo Zhang
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Pd/NBE-catalyzed sequential carbamoylation/olefination of aryl iodides Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-07 Chen Chen; Liying Liu; Wan Sun; Jie Ding; Yan-Ping Zhu; Bolin Zhu
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Origin and stabilization of axial chirality in the construction of naphthyl-C2-indoles: a DFT study Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-01 Qianqian Deng; Yang Wang; Shi-Jun Li; Ling-Bo Qu; Yu Lan; Donghui Wei
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Asymmetric catalytic construction of fully substituted carbon stereocenters using acyclic α-branched β-ketocarbonyls: the “Methyl Rule” widely exists Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-20 Deqian Sun; Shuang Yang; Xinqiang Fang
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Stay positive: catalysis with 1,3,2-diazaphospholenes Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-03 John H. Reed; Johannes Klett; Craig Steven; Nicolai Cramer
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Recent advances in transition metal migration involving reactions Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-29 Xu Dong; Hui Wang; Hui Liu; Fagang Wang
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Rapid synthesis of hexahydropyrrolo[3,4-b]pyrrole-fused quinolines via a consecutive [3 + 2] cycloaddition and reduction/intramolecular lactamization cascade Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-10 Yan-Liang Lin; Yun-Ta Lee; Indrajeet J. Barve; Yi-Ting Huang; Chung-Ming Sun
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Copper-catalyzed carbonylative synthesis of pyrrolidine-containing amides from γ,δ-unsaturated aromatic oxime esters Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-04 Youcan Zhang; Han-Jun Ai; Xiao-Feng Wu
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A diversity of recently reported methodology for asymmetric imine reduction Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-03 Jonathan Barrios-Rivera; Yingjian Xu; Martin Wills; Vijyesh K. Vyas
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Remote C(sp3)–H vinylation via radical-mediated consecutive fission of C–H and C–C bonds Org. Chem. Front. (IF 5.155) Pub Date : 2020-09-02 Tao Niu; Shan Yang; Xinxin Wu; Chen Zhu
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Direct remote δ-C(sp2)–H olefination of β-aryl-substituted aliphatic aldehydes via palladium/enamine co-catalysis Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-31 Richa; Rajesh Kumar; Xiaofeng Zhang; Weiping Su
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Photoinduced double [2 + 2] cycloaddition relay of yne–allenones for highly diastereoselective synthesis of hexacyclic 1-naphthols Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-28 Shan-Shan Zhu; Jiang-Nan Zhou; Quan-Long Wu; Wen-Juan Hao; Shu-Jiang Tu; Bo Jiang
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Ruthenium(II)-catalyzed acyloxylation of the ortho-C–H bond in 2-aroyl-imidazoles with carboxylic acids Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-31 Chen-an Wang; Naoto Chatani
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An improved synthesis of the [5.6.7]-tricyclic core of cyrneine B and glaucopine C Org. Chem. Front. (IF 5.155) Pub Date : 2020-08-25 Guo-Jie Wu; Xiu Han
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