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Self-photocatalysis with multiple activities: divergent synthesis of benzo[b]fluorenones and benzo[b]fluorenols from enone-ynes Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-11 Jifu Shi, Qingyao Sun, YunLing Gao, Yongqin Hu, Weili Li, Binbin He, Shulin Gao, Shaoguang Sun, Deqiang Liang
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Polyfluorinated reagents for peptide stapling Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-11 Wanzhen Lin, Xin Ding, Jun-Wei Han, Li-Shuang Yu, Fa-Jie Chen
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Recent advances on electrocyclic reactions in complex natural product synthesis: an update Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-08 Ruyi Chen, Yanlin Liu, Hanfeng Ding
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Recent advances in hydrofunctionalisation of cyclopropenes via carbon–heteroatom bond formation Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-12 Jorge García-Lacuna, Gema Domínguez, Ángel Manu Martínez, Javier Pérez-Castells
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Photoredox catalytic phosphine-mediated deoxygenative alkynylation of carboxylic acids with alkynyl sulfones for alkynone synthesis Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-10 Wen-Huan Tang, Li-Yuan Wu, Quan-Quan Zhou, Jie-Ping Wan
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Solvation and temperature-modulated supramolecular assembly of amphiphilic water-soluble Schiff base-containing platinum(II) complexes Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-11 Huilan Zhang, Michael Ho-Yeung Chan, Jonathan Lam, Ming-Yi Leung, Lixin Wu, Vivian Wing-Wah Yam
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Enantioselective synthesis of isoxazolines bearing allenes by palladium-catalyzed carboetherification of β,γ-unsaturated ketoximes with propargylic acetates Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-11 Feifei Jin, Cangzhu Hu, Shuaijie Wu, Guodong Zhang, Ying Han, Chao-Guo Yan, Wenbo Li, Chaoshen Zhang, Lei Wang
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Visible-light induced direct C(sp3)–H bond disulfidation of saturated N-heterocycles through a hydrogen atom transfer (HAT) process Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-05 Junlei Wang, Guocheng Gao, Chengcheng Shi, Han Gao, Ji Luo, Guofen Wei, Daohai Zhang, Hongqing Li, Tonghao Yang, Binbin Huang
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Synthesis of carbazoles: light-promoted tandem coupling of nitroarenes with Grignard reagents Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-06 Chen Yang, Ya-Fei Wan, Tong Sun, Gang Li, Zhang-Jie Shi, Dong Xue
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Photocatalytic selective disulfuration of aryl aldehydes and alkenyl aldehydes with dithiosulfonate as a bifunctional disulfur reagent and hydrogen atom acceptor Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-01 Jingchao Jiao, Juan Xu, Jingru Li, Hongru He, Runliang Yang, Xiaorui Ren, Qianwen Gao, Xi Wang
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Water mediated synthesis of dialkylphosphine oxides from white phosphorus and N-(acyloxy)phthalimides Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-05 Guo Tang, Xuanlin Zhu, Jiali He, Yan Liu, Yufen Zhao
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A superior and accessible cavitand receptor for the binding of monoterpenes and sesquiterpenes in water Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-04 Hugo Marchi Luciano, Ricard López-Coll, Rubén Álvarez-Yebra, Agustí Lledó
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A transition-metal-free azide–alkyne cycloaddition/oxetane ring opening cascade reaction for the construction of hydroxymethyl decorated triazole-fused piperazin-2-ones and [1,4]diazepin-4-ones Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-04 Cong Fu, Mingjin Xu, Qicai Ma, Wenjing Wang, Shanyue Li, Qingjie Zhao, Wei Zhou
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Lewis acid-catalyzed divergent synthesis of polysubstituted furans and pyrroles Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-29 Chenguang Li, Tongxiang Cao, Shifa Zhu
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Organic reactions catalyzed by the Brønsted acid B(C6F5)3·H2O Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-01 Tianwei Liu
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The influence of an acid additive on linear and branch selectivity in the C–H alkylation of N-pyridinecarbonyl-protected 2-methylbenzylamine with 1-heptene catalyzed by Rh2(OAc)4: a theoretical investigation Org. Chem. Front. (IF 4.6) Pub Date : 2025-02-01 Lingli Han, Fei Guan, Zifan Chen, Yaqian Xing, Zitong Meng, Kang Lv, Tao Liu
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Cooperative iridium and organocatalysis: a new frontier in asymmetric chemistry Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Divakar Chaudhary, Rakesh K. Saunthwal
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Ligand-modulated phosphine-free Ni(II) complexes for Z-selective semi-transfer hydrogenation of alkynes and dual transfer hydrogenation of α,β-unsaturated ketones using ammonia borane Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-31 Tanmoy Kumar Ghosh, Anirban Sau, Divya Mahapatra, Sabuj Kundu
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Direct C1 homologation of carboxylic acids: free radical approach enabled by acridine catalysis Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-30 Zakhar M. Rubanov, Vitalij V. Levin, Alexander D. Dilman
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Stereoselective construction of chiral flavanones via enzymatic intramolecular C(sp3)–H activation Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-30 Hanzi Gao, Edgar Africano Camargo, Jude N. Ubi, Xiuyuan Duan, Guojun Zheng, Shuaihua Gao, Qipeng Yuan
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Diastereoselective visible-light-induced radical cascade trifluoromethylation/sulfuration/cyclization of 1,6-enynes with S-aryl trifluoromethanesulfonothioate (TTSA) Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-30 Yuhao Jiang, Jiapeng Sun, Qi Hu, Jianmin Huang, Yingming Song, Hua Cao, Yue Yu
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Palladium-catalyzed Catellani-type selective C–H silylation of aryl-TT salts Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-30 Ziyao Tang, Mangang Guan, Tianqiang Wang, Guojun Yu, Jiaze Qin, Jingfeng Lan, Rulong Yan
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FeCl3 promoted cycloisomerization of 1,6-dienes Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-29 Zhongjian Du, Chenlei Ji, Xu Wang, Zhenyu Wang, Zhenguo Guo, Yang'en You
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Spiro-fused dibenzo[g,p]chrysene: annulative π-extension (APEX) synthesis and properties Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-29 Kanghui Song, Yuying Zhang, Shuai Wu, Sha Yang, Shengchen Wei, Songhua Chen, Hideto Ito, Kenichiro Itami, Yuanming Li
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Advances in synthetic strategies for two-dimensional conjugated polymers Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Ruyan Zhao, Guoqin Liu, Philomène Leonore Koko, Mingchao Wang, Xinliang Feng
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Recent progress in electrochemical rearrangement reactions Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Zhaojiang Shi, Chao-Yan Wen, Li-Xue Yang, Jianan Li, Xiaoxia Sun
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Understanding the influence of metal centers on the mechanism and chemoselectivity of transition-metal-catalyzed cyclizations of dienyl aldehydes Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Jian-Biao Liu, Yan Wang, Hai-Yan Wang, Xiao-Jun Liu
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Cyclopropanation vs. single-carbon insertion of pyrrole-2,3-diones with sulfonium ylides: synthesis of functionalized 2-azabicyclo[3.1.0]hexanes and pyridine-2,3-diones Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Maria M. Muranova, Andrey R. Galeev, Andrey N. Maslivets, Maksim V. Dmitriev
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From monomers to pentamers, diverse antimicrobial benzofuran polyketides from marine-derived Striaticonidium cinctum Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Chunmei Chen, Jian Cai, Chun Yang, Yi Chen, Manli Liu, Wei Fang, Bin Yang, Huaming Tao, Yonghong Liu, Xuefeng Zhou
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Divergent synthesis of functionalized indazole N-oxides with anticancer activity via the cascade reaction of N-nitrosoanilines with diazo compounds and HFIP Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-28 Yuqian Sun, Shengnan Yan, Kelin Wang, Bin Li, Chunhua Ma, Xinying Zhang, Xuesen Fan
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Indazole enhances Ru-catalyzed hydrogenation of unsaturated bonds Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-27 Wenjun Jiang, Xiulin Li, Yaru Liu, Chunyan Zhang, Guoying Zhang, Ali Morsali
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Photoredox-catalyzed selective head-to-head reductive coupling of activated alkenes Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-25 Shenhao Chen, Zongchang Han, Han-Shi Hu, Jun Li, Chanjuan Xi
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Ligand-enabled enantio- and site-selective remote C–H arylation of 2-(2-phenpropyl)pyridine derivatives Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-24 Dai-Yu Li, Jin-Ping Li, Shunsuke Yabu, Li-Sheng Wang, Hirofumi Sato, Masahiro Higashi, Yoichiro Kuninobu, Hong-Liang Li
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Modular supramolecular capsules based on α,γ-cyclic peptide dimers for the development of confined catalysis Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-24 Ezequiel Troncoso Mondragón, Alberto Fuertes, Martín Calvelo, Ángel L. Fuentes de Arriba, Manuel Amorín, Juan R. Granja
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Visible-light-mediated C–S bond activation in cysteine derivatives with quinoxalinones for the synthesis of heteroaryl amino acids Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-24 Shuqi Ling, Jingjie Hai, Xinyao Li
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Access to chiral 3-benzylchromanones and 2,6-disubstituted cyclohexanones via Rh-catalyzed chemo- and enantioselective hydrogenation of arylidene chromanones/cyclohexanones Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-24 Qianling Guo, Chaochao Xie, Guofu Zi, Yuping Huang, Guohua Hou
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Selective functionalization of Trp residues via copper-catalyzed Ullmann coupling Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-24 Xinru Liang, Junjie Shi, Qiuju Zhong, Lai Li, Yutao Liu, Tong Sun, Junxi Liang, Xianying Shi, Gaoqiang Li, Mingyu Yang
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Total synthesis of cyclopropane-containing natural products: recent progress (2016–2024) Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-24 Neng Wang, Jin-Xin Zhao, Jian-Min Yue
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Combination of the structural components of amino acids with fatty acids: access to an unknown class of “fatty” α-amino acids by palladium-catalyzed amidocarbonylation Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-23 Mohammad Asadpour, Edson Leonardo Scarpa de Souza, Anke Spannenberg, Carlos Roque Duarte Correia, Helfried Neumann, Matthias Beller
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Mastering palladium-catalyzed cross-coupling reactions: the critical role of in situ pre-catalyst reduction design Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-22 Tommaso Fantoni, Chiara Palladino, Riccardo Grigolato, Beatrice Muzzi, Lucia Ferrazzano, Alessandra Tolomelli, Walter Cabri
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Enantioselective synthesis of vicinal diamines and β-amino amides by NiH-catalyzed hydroamidation of alkenyl amides Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-22 Xun Tian, Shengzu Duan, Yuan Ma, Ailin Pan, Yamiao Meng, Guogang Deng, Hongbin Zhang, Xiaodong Yang
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Atom-controlled divergent synthesis of spiro and fused rings via base-catalyzed chemoselective annulation Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-22 Gang Chen, Guangjie Nie, Linxuan Li, Jie Fu, Hui Yao, Nianyu Huang, Nengzhong Wang
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Synthesis and chiral self-sorting of spirobifluorene-containing boronate ester cages Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-22 Natalie Schäfer, Lukas Glanz, Arne Lützen, Florian Beuerle
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Iron(III)-catalyzed mono-, di- and tricyanomethylation of primary amines with diazoacetonitrile: construction of α-amino acetonitriles and asymmetric α-amino succinonitriles Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-22 Gang Wang, Yu-Heng Zeng, Qian-Yu Jiang, Jia-Yi Chen, Rong Zhou, Huai-Bo Zou
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Copper-catalyzed Buchner reaction and phenyl cyclopropanation through diyne cyclization Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-22 Tong Li, Jia-Juan He, Kai-Yu Fan, Long-Wu Ye, Bo Zhou, Xin-Qi Zhu
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Enantiopure piperidines via stereoselective Ireland–Claisen rearrangement: entry into corynanthe alkaloids Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-21 Niklāvs Ūdris, Rebeka Ločmele, Juris Pelšs, Anastasija Ture, Guna Sakaine, Artis Kinēns, Gints Smits
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HFIP-promoted formal [2π + 2σ] cycloaddition of para-quinone methides with bicyclo[1.1.0]butanes: an approach towards spiro-bicyclo[2.1.1]hexanes Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-21 Haijian Wu, Manman Sun, Jing Zhang, Zhiming Wang, Jianguo Yang, Gangguo Zhu
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Spiroamentotaxols A–D: unprecedented 6/6/6/5/6/6/6/6 spiro-octacyclic bis-diterpene heterodimers from the endangered conifer Amentotaxus yunnanensis and their bioactivities Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-20 Peng-Jun Zhou, Ze-Yu Zhao, Sha Chen, Gong-Pu Luo, Jin-Xin Zhu, Xu-Wen Li, Yeun-Mun Choo, Mark T. Hamann, Juan Xiong, Jin-Feng Hu
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Visible-light-mediated cobaloxime-catalyzed isomerization and hydroalkenylation of bicyclo[1.1.0]butanes Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-20 Ben Mao, Sheng-Hao Jiang, Zheng Xiong, Yin Wei, Min Shi
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Redox reaction between N-heterocyclic carbenes and sulfonates: insights into unproductive catalytic paths Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-17 Jia Song, Wei Wang, Guanjie Wang, Wen-Xin Lv
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Divergent application of 5-amino-isoxazoles for the construction of nitrogen heterocycles via the hydride transfer strategy Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-17 Mengzhe Pan, Feng-Wei Guo, Xinjie Sun, Jie Zhang, Wei Lu, Lubin Xu, Fangzhi Hu, Shuai-Shuai Li
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Influencing optical and charge transport properties by controlling the molecular interactions of merocyanine thin films Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-14 Lukas Böhner, Philipp Weitkamp, Thorsten Limböck, Nora Gildemeister, Daniele Fazzi, Manuela Schiek, Ruth Bruker, Dirk Hertel, Roland Schäfer, Klas Lindfors, Klaus Meerholz
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Recent advances in enantioselective construction of C–N bonds involving radical intermediates Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-14 Jiaqiong Sun, Guangfan Zheng, Ge Zhang, Yan Li, Qian Zhang
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Visible-light-driven anion relay chemistry (ARC): construction of fully substituted pyrazoles Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-13 Guodan Lu, Tao Zhang, Xionglve Cheng, Kehan Qian, Yong Wang, Xiaobing Wan
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Diverse C(sp3)–H functionalizations through electrochemical benzylic oxygenation Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-16 Yan He, Tian-Sheng Chen, Xuesen Fan, Hai-Chao Xu
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Synthesis of antimicrobial active 9,10-phenanthrenequinones by carbene organocatalytic tandem reactions Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-15 Yaoluo Hu, Ya Hong, Yuting Zheng, Yi Huang, Jixiang Chen, Xingxing Wu
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Computational study on Pd-catalyzed ipso,meta-dimethylation of ortho-substituted iodoarenes: mechanisms and the role of the base Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-09 Kang Lv, Yihang Zhou, Zitong Meng, Jing Zhang, Tao Liu
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Recent advances in catalytic asymmetric reactions of Morita–Baylis–Hillman adducts Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-14 Xu-Hong Duan, Hui-Rui Du, Yong-Xing Song
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Highly selective visible-light-induced cascade cyclization of vinyl sulfoxonium ylides with azides: a novel synthetic approach towards trisubstituted furans Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-14 Jia-Huan Cui, Mei Tan, Jun Zhang, Yan He, Xingguang Li, Pei-Nian Liu
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Constructing less-conjugated olefins via unusual regioselective hydrogen atom transfer from acetals Org. Chem. Front. (IF 4.6) Pub Date : 2025-01-14 Zhaoshan Wang, Huiying Liu, Tiantian Liu, Qixiang Wang, Youhao Wei, Xiaoguang Bao, Xinxin Wu
更新日期：2025-02-04
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