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π–π stacked DNA G-wire nanostructures formed by a short G-rich oligonucleotide containing a 3′–3′ inversion of polarity site Org. Chem. Front. (IF 5.155) Pub Date : 2020-07-06 Maria Marzano; Andrea P. Falanga; Principia Dardano; Stefano D'Errico; Ilaria Rea; Monica Terracciano; Luca De Stefano; Gennaro Piccialli; Nicola Borbone; Giorgia Oliviero
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Synthesis of aziridines with multiple chiral substitutions by copper-catalyzed diastereoselective radical aminotrifluoromethylation of alkenes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-24 Shuanglin Qin; Linbin Yao; Yunhao Luo; Tongtong Liu; Jiayuan Xu; Yue Sun; Ning Wang; Jun Yan; Bencan Tang; Guang Yang; Cheng Yang
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Pd-Catalyzed one-pot synthesis of vinylsilanes via a three-component tandem reaction Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-29 Wenguang Li; Chao Zhang; Haiyan Lu; Yajun Wang; Guobo Deng; Yun Liang; Yuan Yang
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Dual N-heterocyclic carbene/photocatalysis: a new strategy for radical processes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-23 Qiang Liu; Xiang-Yu Chen
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Radical reactions promoted by trivalent tertiary phosphines Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-22 Dingwu Pan; Guihua Nie; Shichun Jiang; Tingting Li; Zhichao Jin
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Recent advances in photoelectrochemical cells (PECs) for organic synthesis Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-23 Yan-Chen Wu; Ren-Jie Song; Jin-Heng Li
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Silver(I)-catalyzed selective hydroalkoxylation of C2-alkynyl quinazolinones to synthesize quinazolinone-fused eight-membered N,O-heterocycles Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-18 Xiang-Fei Kong; Xiu-Yun Guo; Zi-Yu Gu; Lin-Su Wei; Lu-Lu Liu; Dong-Liang Mo; Cheng-Xue Pan; Gui-Fa Su
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The construction of three C–P bonds of P-stereogenic tertiary phosphines containing (L)-menthyl Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-28 Jing-Jing Ye; Bing-Xia Yan; Ji-Ping Wang; Jing-Hong Wen; Yu Zhang; Mao-Ran Qiu; Qiang Li; Chang-Qiu Zhao
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DFT study on the E-stereoselective reductive A3-coupling reaction of terminal alkynes with aldehydes and 3-pyrroline Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-23 Yuan Yao; Xue Zhang; Shengming Ma
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Recent advances in metal catalyzed or mediated cyclization/functionalization of alkynes to construct isoxazoles Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-22 Jianxiao Li; Zidong Lin; Wanqing Wu; Huanfeng Jiang
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Tuning the structure and the properties of dithiafulvene metalla-assembled tweezers Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-22 Maksym Dekhtiarenko; Serhii Krykun; Vincent Carré; Frédéric Aubriet; David Canevet; Magali Allain; Zoia Voitenko; Marc Sallé; Sébastien Goeb
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Silver-catalyzed cascade reactions of 3-cyanochromone with 1,1-enediamines: synthesis of highly functionalized 2-(pyridin-3-yl)-chromeno[2,3-d]pyrimidines Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-17 Qiang Xiao; Jin Liu; Jia-Hui Nie; Ling-Bin Kong; Jun Lin; Sheng-Jiao Yan
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Pleurocorols A and B: rearranged steroids from the fruiting bodies of Pleurotus cornucopiae Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-30 Takashi Kikuchi; Maki Mori; Yasuko In; Jie Zhang; Takeshi Yamada; Tomoya Hirano
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Copper-catalyzed regioselective sulfonylcyanations of vinylarenes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-22 Lei Liu; Mingran Si; Shengnan Han; Yan Zhang; Jie Li
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Palladium-catalyzed ortho-selective C–H hydroxylation of carboxybenzyl-protected benzylamines Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-02 Chenyang Dai; Yi Han; Lingling Liu; Zhi-Bin Huang; Da-Qing Shi; Yingsheng Zhao
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Copper-catalyzed mild desulfonylation of vinyl sulfonyl molecules Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-02 Ying Jiang; Wan-Yin Fang; K. P. Rakesh; Hua-Li Qin
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Recent applications of biphotonic processes in organic synthesis Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-02 Jorge Castellanos-Soriano; Jorge C. Herrera-Luna; David Díaz Díaz; M. Consuelo Jiménez; Raúl Pérez-Ruiz
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Organocatalytic asymmetric Friedel–Crafts alkylation/hemiketalization/lactonization cascade reactions: highly enantioselective synthesis of furo[2,3-b]benzofuranones Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-29 Kunhua Xu; Wenming Chen; Xu Chen; Biao Wang; Jun Huang; Xu Tian
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Recent developments in 1,6-addition reactions of para-quinone methides (p-QMs) Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-28 Jia-Yin Wang; Wen-Juan Hao; Shu-Jiang Tu; Bo Jiang
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Regio- and stereoselective halothiolation of alkynes using lithium halides and N-thiosuccinimides Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-28 Shiwen Liu; Xiaojun Zeng; Bo Xu
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Aerobic C(sp3)–H oxidation and oxygenation of quaternarized quinolines and pyridines by visible-light-induced photocatalysis Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-28 Tonghao Han; Yunqi Jiang; Xiaochen Ji; Guo-Jun Deng; Huawen Huang
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Copper(I)-catalyzed highly enantioselective [3 + 3]-cycloaddition of γ-alkyl enoldiazoacetates with nitrones Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-27 Kuiyong Dong; Xinfang Xu; Michael P. Doyle
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Mechanism and origins of gold-catalyzed domino cyclization to spiroindolines: the role of periplanar cooperation and hydrogen bonding interactions Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-27 Yunhe Li; Xiang Zhao
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Iodine-promoted synthesis of pyrazoles from 1,3-dicarbonyl compounds and oxamic acid thiohydrazides Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-27 Anna S. Komendantova; Konstantin A. Lyssenko; Igor V. Zavarzin; Yulia A. Volkova
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Total synthesis of antiallergic bicyclic peptide seongsanamide A Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-26 Feipeng Han; Yian Guo; Tao Ye
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TFA/TBHP-promoted oxidative cyclisation for the construction of tetracyclic quinazolinones and rutaecarpine Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-26 Feng-Cheng Jia; Tian-Zhi Chen; Xiao-Qiang Hu
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Asymmetric N-alkylation of indoles with isatins catalyzed by N-heterocyclic carbene: efficient synthesis of functionalized cyclic N,O-aminal indole derivatives Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-26 Chengyuan Wang; Zhuopeng Li; Jiong Zhang; Xin-Ping Hui
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Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-26 Irene Bosque; Rafael Chinchilla; Jose C. Gonzalez-Gomez; David Guijarro; Francisco Alonso
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Radical addition-polar termination cascade: efficient strategy for photoredox-neutral-catalysed cyclopropanation and Giese-type reactions of alkenyl N-methyliminodiacetyl boronates Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-26 Yongjun Liu; Wenping Luo; Jiali Wu; Yewen Fang; Yan Li; Xiaoping Jin; Li Zhang; Zongyong Zhang; Fenfen Xu; Chan Du
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Photocatalyzed formal carbooxygenation of terminal alkynes Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-21 Fengjuan Chen; Can Yang; Xinwei Hu; Xiaoqi Zhang; Haisheng Xie; Huanfeng Jiang; Fubin Jiang; Wei Zeng
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Selective functionalisation of aromatic alcohols with supramolecularly regulated gold(I) catalysts Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-20 Lucas Carreras; Antonio Franconetti; Arnald Grabulosa; Antonio Frontera; Anton Vidal-Ferran
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Investigation of the remote acyl group participation in glycosylation from conformational perspectives by using trichloroacetimidate as the acetyl surrogate Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-20 Ke Xu; Qingmin Man; Yang Zhang; Jia Guo; Yichu Liu; Zunyun Fu; Yueyue Zhu; Yingxia Li; Mingyue Zheng; Ning Ding
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Chemodivergent synthesis of functionalized methanodibenzo[b,f][1,5]diazocin-13-ylmethanones and tetrahydroquinolines via solvent-dependent AB2 and A2B2 multicomponent annulation reactions Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-19 Isravel Muthukrishnan; Muthu Karuppasamy; B. S. Vachan; Diksha Rajput; Nagarajan Subbiah; C. Uma Maheswari; Vellaisamy Sridharan
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Total synthesis study of rauvomines A and B: construction of the pentacyclic core structure Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-18 Binglu Wu; Zhi-Jiang Jiang; Jianbo Tang; Zhanghua Gao; Hongze Liang; Bencan Tang; Jia Chen; Kewei Lei
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NHC-catalyzed β-specific addition of N-based nucleophiles to allenoates Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-11 Wenchao Wu; Shuangli Xu; Yan Zhang; Xiu Wang; Ruotong Li; Fang Sun; Chenxia Yu; Tuanjie Li; Donghui Wei; Changsheng Yao
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Palladium-catalyzed domino Heck-disilylation and -borylation of alkene-tethered 2-(2-halophenyl)-1H-indoles: access to diverse disilylated and borylated indolo[2,1-a]isoquinolines Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-22 Haiyan Lu; Xiumei Yang; Liwei Zhou; Wenguang Li; Guobo Deng; Yuan Yang; Yun Liang
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Semiconducting and electropolymerizable liquid crystalline carbazole-containing porphyrin-core dendrimers Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-24 Alberto Concellón; Roberto Termine; Attilio Golemme; Pilar Romero; Mercedes Marcos; José Luis Serrano
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Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-17 Xianli Shu; Ruting Xu; Qiang Ma; Saihu Liao
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BODIPY-amino acid conjugates – tuning the optical response with a meso-heteroatom Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-15 Marco Farinone; Joanna Cybińska; Miłosz Pawlicki
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Light-mediated olefin coordination polymerization and photoswitches Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-15 Mingyuan Li; Ruibin Wang; Moris S. Eisen; Sehoon Park
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One-electron oxidative dehydrogenative annulation and cyclization reactions Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-15 Xiazhen Bao; Wei Jiang; Jia Liang; Congde Huo
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Graphene oxide: a green oxidant-acid bifunctional carbon material for the synthesis of functionalized isoindolin-1-ones via formal amide insertion and substitution Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-15 Xiangjun Peng; Dan Hu; Panpan Huang; Huiwu Liao; Yong Zeng; Qian Liu; Liangxian Liu
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Oxidative cascade cyclization of 2-cyano-3-arylaniline derived acrylamides with toluenes, ethers, aliphatic alcohols or simple alkanes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-16 Wen-Jin Xia; Yangchun Xin; Zhi-Wei Zhao; Xin Chen; Xiang-Xiang Wang; Yi Li; Guanlin Wang; Ya-Min Li
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Rapid construction of the ABD tricyclic skeleton in meliacarpinin B from carvone enabled by an INOC strategy Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-17 Changming Dong; Tianjiao Qiao; Yi Xie; Xiao Zhang; Junli Ao; Guangxin Liang
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A metal-free visible-light-promoted phosphorylation/cyclization reaction in water towards 3-phosphorylated benzothiophenes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-17 Xiao-Ya Yuan; Fan-Lin Zeng; Hu-Lin Zhu; Yan Liu; Qi-Yan Lv; Xiao-Lan Chen; Lifen Peng; Bing Yu
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Straight access to highly fluorescent angular indolocarbazoles via merging Au- and Mo-catalysis Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-10 Fernando Martínez-Lara; Anisley Suárez; Samuel Suárez-Pantiga; M. José Tapia; Roberto Sanz
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The protecting group enabled para-selective C–H benzylation of anilides via iron(II) catalysis: a convenient approach for the synthesis of triarylmethanes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-10 Yi Han; Guobao Li; Lingling Liu; Chenyang Dai; Da-Qing Shi; Yingsheng Zhao
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Facile synthesis of the daphnane and tigliane framework by semi-flow tube-based-bubbling photooxidation and diastereoselective conjugate addition Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-09 Zhengwei Ding; Zhi Liu; Guanghu Tong; Linlin Hu; Yangqing He; Yueyun Bao; Zhouhang Lei; Hailong Zhang; Pengfei Li
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Fluorescence visualization of cucurbit[8]uril-triggered dynamic host–guest assemblies Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-09 Xiaodong Zhang; Tao Sun; Xin-Long Ni
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Synthesis of polysubstituted 5-trifluoromethyl isoxazoles via denitrogenative cyclization of vinyl azides with trifluoroacetic anhydride Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-08 Wei Wu; Qiaoling Chen; Yishi Tian; Yihui Xu; Yangjie Huang; Yi You; Zhiqiang Weng
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Recent advances in cyclization reactions of unsaturated oxime esters (ethers): synthesis of versatile functionalized nitrogen-containing scaffolds Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-05 Chen Chen; Jinghui Zhao; Xiaonan Shi; Liying Liu; Yan-Ping Zhu; Wan Sun; Bolin Zhu
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A semipinacol rearrangement of vinylogous α-ketol cocatalyzed by a cinchona-based primary amine and N-Boc-phenylglycines: mechanisms, roles of catalysts and the origin of enantioselectivity Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-05 Chao-Xian Yan; Fang-Ling Yang; Ka Lu; Xing Yang; Pan-Pan Zhou; Xiangfeng Shao
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Metal-free chemoselective hydrogenation of unsaturated carbon–carbon bonds via cathodic reduction Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-04 Yongwei Qin; Jingjun Lu; Zirong Zou; Huanliang Hong; Yamei Li; Yibiao Li; Lu Chen; Jinhui Hu; Yubing Huang
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Insights into Lewis base-catalyzed chemoselective [3 + 2] and [3 + 4] annulation reactions of MBH carbonates Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-04 Qianqian Deng; Shi-Jun Li; Donghui Wei; Yu Lan
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Computational study of catalyst-controlled regiodivergent pathways in hydroboration of 1,3-dienes: mechanism and origin of regioselectivity Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-04 Zhongxin Fu; Xianming Guo; Yupan Li; Juan Li
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Outstanding Reviewers for Organic Chemistry Frontiers in 2019 Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-03
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Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-02 Yuanjin Chen; Yangyang Ma; Liangkui Li; Mingshuo Cui; Zhiping Li
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Aromatization-driven deconstruction/refunctionalization of unstrained rings Org. Chem. Front. (IF 5.155) Pub Date : 2020-06-01 Fangzhi Hu; Liang Wang; Lubin Xu; Shuai-Shuai Li
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Combined KH/alkaline-earth metal amide catalysts for hydrogenation of alkenes Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-29 Xiang-Yu Zhang; Hui-Zhen Du; Dan-Dan Zhai; Bing-Tao Guan
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Ligand-controlled palladium catalysis enables switch between mono- and di-arylation of primary aromatic amines with 2-halobenzothiazoles Org. Chem. Front. (IF 5.155) Pub Date : 2020-05-28 Yan-Qiu Zhu; Rui Zhang; Wei Sang; Hua-Jing Wang; Yuan Wu; Bao-Yi Yu; Jun-Chao Zhang; Hua Cheng; Cheng Chen
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