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Rheo-NMR at the Phase Transition of Liquid Crystalline Poly-γ-benzyl-l-glutamate: Phase Kinetics and a Valuable Tool for the Measurement of Residual Dipolar Couplings Macromolecules (IF 5.5) Pub Date : 2023-09-29 Fabian Hoffmann, Karel Kouřil, Stefan T. Berger, Benno Meier, Burkhard Luy
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Multicolor Luminescence of a Polyurethane Derivative Driven by Heat/Light-Induced Aggregation Macromolecules (IF 5.5) Pub Date : 2023-09-29 Nan Jiang, Ke-Xin Li, Wei Xie, Shu-Ran Zhang, Xin Li, Yue Hu, Yan-Hong Xu, Xing-Man Liu, Martin R. Bryce
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Structure, Dynamics, and Rheology of Vitrimers Macromolecules (IF 5.5) Pub Date : 2023-09-29 Jianshe Xia, Julia Ann Kalow, Monica Olvera de la Cruz
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Modeling hard-soft block copolymers as a liquid crystalline polymer Polymer (IF 4.6) Pub Date : 2023-09-29 M. Manav, M. Ponga, M. Ortiz
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Immiscible thermoplastic polymer blends with alternative layered encapsulation structure: Modeling and processing Polymer (IF 4.6) Pub Date : 2023-09-29 Yue Wang, Li-Bo Chen, Kai Ke, Kai Zhang, Bo Yin, Ming-Bo Yang
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Thermoresponsive double-network hydrogel/elastomer hybrid bilayer laminates with high interfacial toughness and controllable shape deformations Polymer (IF 4.6) Pub Date : 2023-09-29 Xuefeng Li, Yuxin Zhao, Danni Xu, Dapeng Li, Wei Wang, Dezheng Hu, Yiwan Huang, Shijun Long
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Structure and properties of biaxial stretched submicron thin UHMWPE membranes Polymer (IF 4.6) Pub Date : 2023-09-29 Zirui Wang, He Zhang, Junkan Yue, Man Chen, Xinda You, Runlai Li, Qiang Fu
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Deformation kinetics of single-fiber polypropylene composites: Adhesion improvement at the expense of toughness Polymer (IF 4.6) Pub Date : 2023-09-28 Stan F.S.P. Looijmans, Hamid Ahmadi, Patrick D. Anderson, Lambèrt C.A. van Breemen
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Intraspherulitic mechanical heterogeneities and microstructure of i-PP highlighted by nanoindentation and atomic force microscopy Polymer (IF 4.6) Pub Date : 2023-09-27 Jérémy Grondin, Olga Smerdova, Sylvie Castagnet, Christophe Tromas
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Determining the influence of temperature and pressure on the structural stability in a polyurea elastomer Polymer (IF 4.6) Pub Date : 2023-09-27 T. Eastmond, J. Hu, V. Alizadeh, R. Hrubiak, J. Oswald, K. Kim, A. Amirkhizi, P. Peralta
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Influence of network structure determined by Time-domain 1H Double Quantum NMR on the creep properties of non-stoichiometric epoxy-amine resins aimed for chemical anchoring applications Polymer (IF 4.6) Pub Date : 2023-09-27 Martin Demleitner, Fabian Hübner, Andreas Mainz, Holger Ruckdäschel, Volker Altstädt, Laurent Michely, Agustín Rios de Anda
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Influence of chain entanglements and melt memory effect on the crystallization behavior of polyphenylene sulfide Polymer (IF 4.6) Pub Date : 2023-09-27 Sihao Hu, Feng Yang, Ya Cao, Yuanwei Yan, Tong Wu, Qiang Fu
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Determination of the Interfacial Energy between Graphene Nanoplatelets and Deuterated or Hydrogenated Polystyrene Macromolecules (IF 5.5) Pub Date : 2023-09-29 Yu-Chung Lin, Xiaoyang Liu, Gavin Onghai, Aniket Raut, Yiwei Fang, Yifan Yin, Shi Fu, Haoyan Fang, Kuan-Che Feng, Xuelong Wang, Ping Liu, Tai-De Li, Jonathan Sokolov, Miriam Rafailovich
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Adsorption of a Polyelectrolyte Chain at Dielectric Surfaces: Effects of Surface Charge Distribution and Relative Dielectric Permittivity Macromolecules (IF 5.5) Pub Date : 2023-09-27 Ruochao Wang, Valeriy V. Ginzburg, Jian Jiang, Zhen-Gang Wang
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Hydrogen-Bonded Polymer Nanomedicine with AIE Characteristic for Intelligent Cancer Therapy ACS Macro Lett. (IF 5.8) Pub Date : 2023-09-28 Zeke Li, Senbin Chen, Wolfgang H. Binder, Jintao Zhu
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Stress-Stabilized Crystalline Phases of Ultrahigh Molecular Weight Polyethylene under Tensile Stress ACS Macro Lett. (IF 5.8) Pub Date : 2023-09-26 Hao Zhang, Lukun Feng, Yuhai Guo, Feng Tian, Yongna Qiao, Huichao Liu, Zheng Tang, Caizhen Zhu, Jian Xu
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Spatial Organization of Slit-Confined Melts of Ring Polymers with Nonconserved Topology: A Lattice Monte Carlo Study Macromolecules (IF 5.5) Pub Date : 2023-09-28 Mattia Alberto Ubertini, Angelo Rosa
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Lewis acids modulation in phosphorus phenol nickel catalyzed ethylene polymerization and copolymerization Polym. Chem. (IF 4.6) Pub Date : 2023-09-28 Wenbing Wang, Nan Nie, Menghe Xu, Chen Zou
Recently, the phosphorus phenol nickel catalysts have attracted widespread attention from the academic community due to their excellent copolymerization performance. Here, a series of phosphorus phenol nickel catalysts containing N atoms were designed and synthesized. We utilized the coordination of N atoms of ligands with metal salt Lewis acid to form steric hindrance, and studied the polymerization
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Stille Polycondensation: A Multifaceted Approach towards the Synthesis of Polymers with Semiconducting Properties Polym. Chem. (IF 4.6) Pub Date : 2023-09-28 Zhen Liang, Andriy Neshchadin, Zhen Zhang, Fugang Zhao, Xunshan Liu, Luping Yu
Recent years have witnessed the rapid development of numerous organic polymer-based semiconductors for applications in areas ranging from organic electronics to bioimaging and biosensing. In the synthesis of these polymer materials, Stille polycondensation has emerged as a highly versatile and effective tool owing to its mild reaction conditions, functional group tolerance, and versatility. This perspective
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Corner-opened cage-silsesquioxane as a directional template for tripodal poly(methyl methacrylate) Polym. Chem. (IF 4.6) Pub Date : 2023-09-27 Ryota Tanaka, Amato Igarashi, Taihei Hayashi, Hiroyasu Masunaga, Hideaki Takagi, Nobutaka Shimizu, Noriyuki Igarashi, Shinichi Sakurai, Hiroaki Imoto, Kensuke Naka
Branched polymers with directional polymer chains require scaffolds with multiple functional groups oriented in a single direction. Inorganic clusters are suitable for attaining unique three-dimensional structures. The incompletely condensed polyhedral oligomeric silsesquioxanes (IC-POSS) contain three silanol groups at the open corners of the cubic siloxane core. The three-directional silanol groups
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A General Synthetic Strategy for the Synthesis of Imine-Linked Covalent Organic Frameworks in Choline Chloride–Hexafluoroisopropanol-Based Deep Eutectic Solvents Macromolecules (IF 5.5) Pub Date : 2023-09-27 Linlin Deng, Luchun Wang, Shaochi Liu, Qiuyi Liu, Junji Wang, Yongqing Tao, Meng Tian, Yulian Yang, Yuemeng Zou, Hong Niu, Dandan Wang, Die Gao
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Radical Cyclocopolymerization of a Transformable Divinyl Monomer with a Monovinyl Monomer and Postpolymerization Modification for the Synthesis of AAB-Type Alternating Copolymers Composed of NIPAM and Vinyl Ether Macromolecules (IF 5.5) Pub Date : 2023-09-27 Xiaoyan Xu, Makoto Ouchi
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Design of Linear Block Copolymers and ABC Star Terpolymers That Produce Two Length Scales at Phase Separation Macromolecules (IF 5.5) Pub Date : 2023-09-26 Merin Joseph, Daniel J. Read, Alastair M. Rucklidge
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Bimodal Rates for Cavitation-Induced Chain Exchange Between Micelles Macromolecules (IF 5.5) Pub Date : 2023-09-26 Taylor Larison, Eric Williams, Coby S. Collins, Sai Venkatesh Pingali, Morgan Stefik
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High-Molecular-Weight Poly(aromatic amide) Foldamers via Living Polymerization Macromolecules (IF 5.5) Pub Date : 2023-09-25 Subhajit Pal, Linda Hong, Rafael V. M. Freire, Saquib Farooq, Stefan Salentinig, Andreas F. M. Kilbinger
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Naphthalene-based semiconducting microporous polyimides for high-efficiency photo-catalytic dye degradation Polym. Chem. (IF 4.6) Pub Date : 2023-09-28 Yujie Lei, Bo Lin, Jieyao Wang, Wangzhi Chen, Xiao xuan Dai, Xingyu Ma, Lei Li
Microporous polyimides (MPIs) with extended π-conjugated structure have attracted interests thanks to the synergetic effects between large surface areas and semiconducting characteristics plus their anticipated photo-catalysis applications. In this study, three naphthalene-based semiconducting MPIs with a maximum surface area of 1909 m2 g−1 have been prepared within 30 min via solvothermal method,
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Thermal Controlling of Multi-Block Sequence Using Anion-Migrated Ring-Opening Polymerization Polym. Chem. (IF 4.6) Pub Date : 2023-09-28 Hongyuan Bai, Li Han, Xuefei Wang, Hong Yan, Siwei Chen, Haitao Leng, Zijing Yao, Hongwei Ma
The construction of well-defined multiblock copolymers in a facile manner is a meaningful but challenging task in polymer synthesis. Herein, we disclose that the sequence distribution of 1-cyclopropylvinylbenzene (CPVB) and p-tert-butylstyrene (t-St) units along the chain exhibits great discrepancies at different reaction temperatures during living anionic polymerization when the feeding raio of CPVB
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Living/Controlled Polymerization of Renewable Lignin-Based Monomers by Lewis Pairs Macromolecules (IF 5.5) Pub Date : 2023-09-27 Yi Wan, Wuchao Zhao, He Zhao, Mengqian Zhou, Jianghua He, Yuetao Zhang
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Introducing Molecular Asymmetry in Copolymer Structures to Favor Herringbone-Like Aggregation and Tune the Chiral Expression Macromolecules (IF 5.5) Pub Date : 2023-09-26 Annelien Van Oosten, Cynthia Verduyckt, Guy Koeckelberghs
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Salt-Dependent Phase Re-entry of Weak Polyelectrolyte Complexes: from Associative to Segregative Liquid–Liquid Phase Separation Macromolecules (IF 5.5) Pub Date : 2023-09-26 Huiling Li, Ying Liu, Fujie Lan, Mohsen Ghasemi, Ronald G. Larson
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Stereocomplex-Driven Morphological Transition of Coil–Rod–Coil Poly(lactic acid)-Based Cylindrical Nanoparticles Macromolecules (IF 5.5) Pub Date : 2023-09-25 Yujie Xie, Wei Yu, Tianlai Xia, Rachel K. O’Reilly, Andrew P. Dove
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Synthesis of Oxazoline/Methacrylate-Based Graft-Copolymers via Grafting-Through Method and Evaluation of Their Self-Assembly in Water and Dodecane Macromolecules (IF 5.5) Pub Date : 2023-09-25 Matilde Concilio, Nga Nguyen, Stephen C. L. Hall, Steven Huband, C. Remzi Becer
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Fast thermally-responsive azatriphenylene ionic discotic liquid crystalline polymers with shape-memory properties Polym. Chem. (IF 4.6) Pub Date : 2023-09-21 Xiao-Ping Xiong, Qian Yang, Ruo-Jun Wang, Ling-Yi Zeng, Wen-Hao Yu, Hong-Mei Chen, Hai-Liang Ni, Chun Feng, Ke-Qing Zhao, Ping Hu
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Catalytic Living ROMP: Synthesis of Degradable Star Polymers ACS Macro Lett. (IF 5.8) Pub Date : 2023-09-25 Ankita Mandal, Andreas F. M. Kilbinger
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Amphiphilic oligo(2-ethyl-2-oxazoline)s via straightforward synthesis and their self-assembly behaviour Polym. Chem. (IF 4.6) Pub Date : 2023-09-25 James Lefley, Zivani Varanaraja, Ben A Drain, Steven Huband, James Beament, C. Remzi Becer
The synthesis of poly(2-oxazoline)s offers an unparalleled degree of functionalization when fabricating smart, functional polymers for biomedical uses. The termination of 2-oxazoline polymerisations by direct endcapping can be exploited to introduce a wide variety of end groups and could potentially offer an easier synthetic route to amphiphilic polymers that usually block copolymer synthesis. Herein
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Catalytic enrichment of oligothioalkynes: expanding horizons for functionalized oligotriazole synthesis through IrAAC-mediated post-modification Polym. Chem. (IF 4.6) Pub Date : 2023-09-25 Xueyan Zhang, Yunxin Sun, Kaifeng Sun, Fuqi Gou, Shengtao Ding
Discrete oligomers play an important role in both advanced material development and fundamental research. Nonetheless, practical applications have been somewhat hindered by the challenges associated with their facile and diverse preparation. In this study, we introduce a rapid approach to construct a range of functionalized 1,2,3-triazole-based oligomers. This approach involves facile assembly of internal
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Synthesis and degradation study of graft copolymers of poly(limonene carbonate) Polym. Chem. (IF 4.6) Pub Date : 2023-09-22 Dipannita Ghosh, Seema Agarwal
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Accelerated nitroxide-mediated polymerization of styrene and butyl acrylate initiated by BlocBuilder MA using flow reactors Polym. Chem. (IF 4.6) Pub Date : 2023-09-21 Ryo Takabayashi, Stephan Feser, Hiroshi Yonehara, Ilhyong Ryu, Takahide Fukuyama
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Tunable thermal property of poly(styrene-alt-phenylmaleimide)-based alternating copolymers through mediated hydrogen bonding strength Polymer (IF 4.6) Pub Date : 2023-09-25 Wei-Ting Du, Shiao-Wei Kuo
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Double-layered low-smoke and durable flame-retardant coating for cotton fabrics Polymer (IF 4.6) Pub Date : 2023-09-25 Qirui Guo, Yue Xie, Liju Xu, Dong Qiu
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Self-healing and malleable waterborne polyurethane bearing aliphatic disulfide linkages with hydrophobic branching chains Polymer (IF 4.6) Pub Date : 2023-09-25 Bailin Shan, Yan Wu, Xuejuan Cao, Boming Tang, Kuiling Wei
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Nitro and 4,4′-flourobenzhydryl functionalized bis(imino)pyridine-cobalt complexes for high molecular weight linear polyethylenes Polymer (IF 4.6) Pub Date : 2023-09-25 Desalegn Demise Sage, Qiuyue Zhang, Qaiser Mahmood, Yanping Ma, Ming Liu, Xiang Hao, Wen-Hua Sun
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Novel polyimides with improved adhesion to smooth copper and low coefficient of thermal expansion Polymer (IF 4.6) Pub Date : 2023-09-25 Zimeng He, Shan Huang, Xialei Lv, Jinhui Li, Guoping Zhang, Rong Sun
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Controlled formation of the β-phase in poly(9,9-dioctylfluorene) by blending with low-molecular-weight polystyrene Polymer (IF 4.6) Pub Date : 2023-09-21 Tomoya Sato, Tomohiro Kobayashi, Kohei Chichibu, Kaname Kanai
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Reduction of interfacial polycondensation self-limitation through solvent swelling to dynamically modulate shell thickness and structure of microcapsules Polymer (IF 4.6) Pub Date : 2023-09-20 Tianheng Wang, XueBao Liu, Jing Luo, Guanqing Sun, Ren Liu
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Metallic Lustrous Porphyrin Foil with an Exceptional Refractive Index Macromolecules (IF 5.5) Pub Date : 2023-09-22 Mitsuhiko Morisue, Miho Kawanishi, Yusuke Miyake, Kenji Kanaori, Kyoka Tachibana, Mizuki Ohke, Michinari Kohri, Jun Matsui, Taiki Hoshino, Sono Sasaki
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Itaconate-Based Clickable Surface-Anchored Cross-Linked Polymeric Coatings Macromolecules (IF 5.5) Pub Date : 2023-09-22 Vidyalakshmi Damodara, S. Ramakrishnan
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Rheology of Smectic Liquid Crystalline Elastomers with Dynamic Covalent Bonds Macromolecules (IF 5.5) Pub Date : 2023-09-20 Huagao Fang, Fan Zhang, Yongpu Zhao, Xingchen Gao, Wenjuan Zhou, Guobin Qi, Yunsheng Ding, H. Henning Winter
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Reinforcement of Poly(vinyl alcohol) using hydrogen bonding of carboxylic acid-functionalized graphitic nanoplatelets Polymer (IF 4.6) Pub Date : 2023-09-22 Seo Jeong Yoon, In-Yup Jeon
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Aqueous buffer solution-induced crystallization competes with enzymatic depolymerization of pre-treated post-consumer poly (ethylene terephthalate) waste Polymer (IF 4.6) Pub Date : 2023-09-19 Akanksha Patel, Allen C. Chang, Abigail Mastromonaco, Mauricio Acosta Diaz, Sarah Perry, Olivia Ferki, Christian Ayafor, Umer Abid, Hsi-Wu Wong, Dongming Xie, Margaret J. Sobkowicz
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Role of Polymer–Particle Adhesion in the Reinforcement of Hybrid Hydrogels Macromolecules (IF 5.5) Pub Date : 2023-09-22 Anne-Charlotte Le Gulluche, Nadège Pantoustier, Annie Brûlet, Olivier Sanseau, Paul Sotta, Alba Marcellan
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Shear Thickening Behavior in Injectable Tetra-PEG Hydrogels Cross-Linked via Dynamic Thia-Michael Addition Bonds Macromolecules (IF 5.5) Pub Date : 2023-09-22 Anne D. Crowell, Thomas M. FitzSimons, Eric V. Anslyn, Kelly M. Schultz, Adrianne M. Rosales
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Entropic Penalty Switches Li+ Solvation Site Formation and Transport Mechanisms in Mixed Polarity Copolymer Electrolytes Macromolecules (IF 5.5) Pub Date : 2023-09-22 Chuting Deng, Peter Bennington, Regina J. Sánchez-Leija, Shrayesh N. Patel, Paul F. Nealey, Juan J. de Pablo
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Use of Hydrolysis-Robust Cyclic Vinyl Acetals in Radical Ring-Opening Emulsion Copolymerization Macromolecules (IF 5.5) Pub Date : 2023-09-22 Benjamin R. Kordes, Seema Agarwal
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MALDI-2 Mass Spectrometry for Synthetic Polymer Analysis Macromolecules (IF 5.5) Pub Date : 2023-09-22 Lidia Molina-Millán, Aljoscha Körber, Bryn Flinders, Berta Cillero-Pastor, Eva Cuypers, Ron M. A. Heeren
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Exploiting NIR Light-Mediated Surface-Initiated PhotoRAFT Polymerization for Orthogonal Control Polymer Brushes and Facile Postmodification of Complex Architecture through Opaque Barriers Macromolecules (IF 5.5) Pub Date : 2023-09-22 Gervase Ng, Zilong Wu, Tong Zhang, Anh Phong Dang, Yin Yao, Andrew R. J. Nelson, Stuart W. Prescott, Almar Postma, Graeme Moad, Craig J. Hawker, Cyrille Boyer
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Miktoarm PEG–PCL Star Copolymer (AB6) Blend Composite Solid Electrolyte for All-Solid-State Lithium Metal Battery Macromolecules (IF 5.5) Pub Date : 2023-09-22 Yuhan Li, Kaizheng Zhu, Huaitian Bu, Zhenyu Fu, Anna-Lena Kjøniksen, Bo Nyström, Shujiang Ding
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Chain-Folding of Alternating Copolymers to Achieve Main-Chain Alkyl Chain Crystallization with Minimum Six Carbon Atoms Macromolecules (IF 5.5) Pub Date : 2023-09-21 Changxu Zhang, Hui Pan, Yongfeng Zhou
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Controlling Mechanical Properties of Poly(methacrylic acid) Multilayer Hydrogels via Hydrogel Internal Architecture Macromolecules (IF 5.5) Pub Date : 2023-09-21 Maksim Dolmat, Veronika Kozlovskaya, John F. Ankner, Eugenia Kharlampieva
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Disappearance of Melt Memory Effect with Comonomer Incorporation in Isodimorphic Random Copolyesters Macromolecules (IF 5.5) Pub Date : 2023-09-21 Leire Sangroniz, Maryam Safari, Antxon Martínez de Ilarduya, Haritz Sardon, Dario Cavallo, Alejandro J. Müller