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Molybdenum Disorder in Hydrated Sedovite, Ideally U(MoO4)2·nH2O, a Microporous Nanocrystalline Mineral Characterized by Three-Dimensional Electron Diffraction, Density Functional Theory Computations, and Complexity Analysis Inorg. Chem. (IF 5.165) Pub Date : 2021-09-24 Gwladys Steciuk, Boris Kiefer, Wolfgang Hornfeck, Anatoly V. Kasatkin, Jakub Plášil
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Triangular Palladium Cluster from Activation of the Si–Si Bond in a Disilane with Phosphine Pendants Inorg. Chem. (IF 5.165) Pub Date : 2021-09-24 Ryosuke Usui, Yusuke Sunada
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Impact of Green Cosolvents on the Catalytic Dehydrogenation of Formic Acid: The Case of Iridium Catalysts Bearing NHC-phosphane Ligands Inorg. Chem. (IF 5.165) Pub Date : 2021-09-24 Ana Luque-Gómez, Susana García-Abellán, Julen Munarriz, Victor Polo, Vincenzo Passarelli, Manuel Iglesias
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Unusual Melting Trend in an Alkali Asymmetric Sulfonamide Salt Series: Single-Crystal Analysis and Modeling Inorg. Chem. (IF 5.165) Pub Date : 2021-09-23 Luke Schkeryantz, Phu Nguyen, William D. McCulloch, Curtis E. Moore, Kah Chun Lau, Yiying Wu
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Contrasting Bonding Extremes in Two [Ge6]n− Complexes: A Wadian Polyhedron (n = 2) versus a Hydrocarbon-like 2c–2e Polygermanide (n = 12) Inorg. Chem. (IF 5.165) Pub Date : 2021-09-23 Ai-Min Li, Yi Wang, Peter Y. Zavalij, Yu-Sheng Chen, Alvaro Muñoz-Castro, Bryan W. Eichhorn
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Aqueous Synthesis of Manganese Phosphate Hydrate Crystals for Creating Inorganic Pigment Materials Inorg. Chem. (IF 5.165) Pub Date : 2021-09-23 Hiroaki Uchiyama, Itta Okumura, Sho Inoue, Masanori Kato, Masashi Wakahara
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Trimodal Ratiometric Luminescent Thermometer Covering Three Near-Infrared Transparency Windows Inorg. Chem. (IF 5.165) Pub Date : 2021-09-23 Zhiying Wang, Mochen Jia, Mingxuan Zhang, Xiaoyang Jin, Hanyu Xu, Zuoling Fu
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Enhancing the Photoluminescence Property of Pr3+ Ions by Understanding the Polymorphous Influence of the K3Lu(PO4)2 Host Inorg. Chem. (IF 5.165) Pub Date : 2021-09-23 Xiangyu Han, Jiaming Wu, Changqing Hu, Qingchun Yang, Chengrui Xin, Shuxian Wang, Zhengmao Ye
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Reactions of Iso(thio)cyanates with Dialanes: Cycloaddition, Reductive Coupling, or Cleavage of the C═S or C═O Bond Inorg. Chem. (IF 5.165) Pub Date : 2021-09-22 Vladimir A. Dodonov, Weixing Chen, Li Liu, Vladimir G. Sokolov, Evgeny V. Baranov, Alexandra A. Skatova, Yanxia Zhao, Biao Wu, Xiao-Juan Yang, Igor L. Fedushkin
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Structure and Thermodynamics of Eu(III) and Cm(III) Complexes with Glucuronic Acid Inorg. Chem. (IF 5.165) Pub Date : 2021-09-22 Sebastian Reese, Peter Kaden, Corey J. Taylor, Roger Kloditz, Moritz Schmidt
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Assembly of Interlocked Superstructures with a Titanium Oxide Molecular Ring in Water Inorg. Chem. (IF 5.165) Pub Date : 2021-09-22 Caiyun Liu, Chang Gao, Amir Said, Huihui Niu, Dexin Wang, Chen-Ho Tung, Yifeng Wang
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Triggering Copper(II)-Mediated Base Pair Formation by Light Inorg. Chem. (IF 5.165) Pub Date : 2021-09-22 Shuvankar Naskar, Jens Müller
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Exploring the Geometric Space of Metal–Organic Polyhedrons (MOPs) of Metal-Oxo Clusters Inorg. Chem. (IF 5.165) Pub Date : 2021-09-22 Balamurugan Kandasamy, Edward Lee, De-Liang Long, Nicola Bell, Leroy Cronin
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2D van der Waals Layered [C(NH2)3]2SO3S Exhibits Desirable UV Nonlinear-Optical Trade-Off Inorg. Chem. (IF 5.165) Pub Date : 2021-09-22 Youchao Liu, Xiaomeng Liu, Zheyao Xiong, Binwen Liu, Jinlong Xu, Lina Li, Sangen Zhao, Zheshuai Lin, Maochun Hong, Junhua Luo
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The Role of Fluorine-Substituted Positions on the Phase Transition in Organic–Inorganic Hybrid Perovskite Compounds Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Wenjun Rao, Mingli Li, Xiuli You, Zhenhong Wei, Mengxia Zhang, Lingyu Wang, Hu Cai
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Water’s Role in Polymorphic Platinum(II) Complexes Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Nathaniel M. Barker, Stephen D. Taylor, Ethan Ferguson, Jeanette A. Krause, Allen G. Oliver, William B. Connick, Peng Zhang
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Dual-Emissive Tris-Heteroleptic Ruthenium Complexes: Tuning the DNA-Triggered Ratiometric Emission Response by Ancillary Ligands Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Si-Hai Wu, Rong Yang, Bin Sun, Jian-Hong Tang, Zhong-Liang Gong, Junjie Ma, Lianhui Wang, Jieqing Liu, Dian-Xue Ma, Jiang-Yang Shao, Yu-Wu Zhong
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Self-Assembly and Multifaceted Bioactivity of a Silver(I) Quinolinate Coordination Polymer Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Sabina W. Jaros, Agnieszka Krogul-Sobczak, Barbara Bażanów, Magdalena Florek, Dominik Poradowski, Dmytro S. Nesterov, Urszula Śliwińska-Hill, Alexander M. Kirillov, Piotr Smoleński
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Structures and Spin States of Iron(II) Complexes of Isomeric 2,6-Di(1,2,3-triazolyl)pyridine Ligands Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Izar Capel Berdiell, Daniel J. Davies, Jack Woodworth, Rafal Kulmaczewski, Oscar Cespedes, Malcolm A. Halcrow
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Way to Enforce Selectivity via Steric Hindrance: Improvement of Am(III)/Eu(III) Solvent Extraction by Loaded Diphosphonic Acid Esters Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Petr I. Matveev, Pin-Wen Huang, Anna A. Kirsanova, Ivan V. Ananyev, Tsagana B. Sumyanova, Anastasia V. Kharcheva, Evgenii Yu. Khvorostinin, Vladimir G. Petrov, Wei-Qun Shi, Stepan N. Kalmykov, Nataliya E. Borisova
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Distorted Copper(II) Complex with Unusually Short CF···Cu Distances Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Claire C. Cody, H. Ray Kelly, Brandon Q. Mercado, Victor S. Batista, Robert H. Crabtree, Gary W. Brudvig
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Stepwise Assembly of a Multicomponent Heterometallic Metal–Organic Framework via Th6-Based Metalloligands Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Xianghe Kong, Kongqiu Hu, Zhiwei Huang, Qunyan Wu, Jipan Yu, Lei Mei, Zhifang Chai, Changming Nie, Weiqun Shi
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Single-Crystal-to-Single-Crystal Cluster Transformation in a Microporous Molybdoarsenate(V)-Metalorganic Framework Inorg. Chem. (IF 5.165) Pub Date : 2021-09-21 Nour Dissem, Beñat Artetxe, Leire San Felices, Garikoitz Beobide, Oscar Castillo, Estibaliz Ruiz-Bilbao, Luis Lezama, María dM. Vivanco, Amor Haddad, Juan M. Gutiérrez-Zorrilla
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Synthesis and Reactivity of Cationic Gallium(I) [12]Crown-4 Complexes Inorg. Chem. (IF 5.165) Pub Date : 2021-09-20 Jeremy L. Bourque, Robert A. Nanni, Mark C. Biesinger, Kim M. Baines
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Structural and Interfacial Engineering of Ni2P/Fe3O4 Porous Nanosheet Arrays for Efficient Oxygen Evolution Reaction Inorg. Chem. (IF 5.165) Pub Date : 2021-09-20 Wenli Tian, Dengchao Zheng, Xun Sun, Xin Guan, Hao Feng, Chengyi Li, Minglei Yan, Yadong Yao
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Application in Anticounterfeiting for Multistimuli Smart Luminescent Materials Based on MOF-on-MOF Inorg. Chem. (IF 5.165) Pub Date : 2021-09-20 Yanan Wang, Huijun Li, Xinglei He, Zhouqing Xu
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In Appreciation of Reviewers Inorg. Chem. (IF 5.165) Pub Date : 2021-09-20 William B. Tolman
Authors are of course primarily responsible for the quality of the articles published in Inorganic Chemistry. However, they cannot do it alone. Reviewers play a critical role, providing useful oversight and helpful ideas that lead to significant improvements. It is selfless work, done in the service of the journal and our community of inorganic chemists. On behalf of the entire team of editors, we
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Nanostructural Perspective for Destabilization of Mg Hydride Using the Immiscible Transition Metal Mn Inorg. Chem. (IF 5.165) Pub Date : 2021-09-20 Yanshan Lu, Kohta Asano, Herman Schreuders, Hyunjeong Kim, Kouji Sakaki, Akihiko Machida, Tetsu Watanuki, Bernard Dam
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Diversity in Small-Molecule Activation: The Adventure Continues Inorg. Chem. (IF 5.165) Pub Date : 2021-09-20 Peter W. Roesky, Alison R. Fout
This article is part of the Advances in Small-Molecule Activation special issue. The sustainable transformation of small molecules such as CO2, N2, O2, and CH4 into other products has always been central to endeavors in chemical science. Indeed, from an inorganic chemistry perspective, the catalytic activation of typically inert small molecules has had an evergreen presence in the research community
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C–H Bond Cleavage by Bioinspired Nonheme Metal Complexes Inorg. Chem. (IF 5.165) Pub Date : 2021-09-07 Justin L. Lee, Dolores L. Ross, Suman K. Barman, Joseph W. Ziller, A. S. Borovik
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Energy Decomposition Analysis of Lewis Acid/Base Adducts and Frustrated Lewis Pairs: The Use of EOrb/ESteric Ratios as a Reaction Parameter Inorg. Chem. (IF 5.165) Pub Date : 2021-07-30 Elon A. Ison, Joshua L. Tubb
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pH Changes That Induce an Axial Ligand Effect on Nonheme Iron(IV) Oxo Complexes with an Appended Aminopropyl Functionality Inorg. Chem. (IF 5.165) Pub Date : 2021-07-22 Reza Latifi, Taryn D. Palluccio, Wanhua Ye, Jennifer L. Minnick, Kwame S. Glinton, Elena V. Rybak-Akimova, Sam P. de Visser, Laleh Tahsini
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Reversible Electron Transfer and Substrate Binding Support [NiFe3S4] Ferredoxin as a Protein-Based Model for [NiFe] Carbon Monoxide Dehydrogenase Inorg. Chem. (IF 5.165) Pub Date : 2021-09-07 Luke C. Lewis, Hannah S. Shafaat
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H2 Evolution from Electrocatalysts with Redox-Active Ligands: Mechanistic Insights from Theory and Experiment vis-à-vis Co-Mabiq Inorg. Chem. (IF 5.165) Pub Date : 2021-07-23 G. Ceren Tok, Sebastian Reiter, Anna T. S. Freiberg, Leonhard Reinschlüssel, Hubert A. Gasteiger, Regina de Vivie-Riedle, Corinna R. Hess
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Trans Element-Hydrogen Bonds: A Distinctive Difference Between Transition Metals and Main Group Elements Inorg. Chem. (IF 5.165) Pub Date : 2021-07-22 Brian T. H. Tsui, Robert H. Morris
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Synthesis, Structure, and Ammonia Oxidation Catalytic Activity of Ru-NH3 Complexes Containing Multidentate Polypyridyl Ligands Inorg. Chem. (IF 5.165) Pub Date : 2021-09-07 Jan Holub, Nataliia Vereshchuk, Francisco-Javier Sánchez-Baygual, Marcos Gil-Sepulcre, Jordi Benet-Buchholz, Antoni Llobet
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Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides Inorg. Chem. (IF 5.165) Pub Date : 2021-09-02 Kelsie E. Wentz, Andrew Molino, Lucas A. Freeman, Diane A. Dickie, David J. D. Wilson, Robert J. Gilliard, Jr.
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Photoinduced Low-Spin → High-Spin Mechanism of an Octahedral Fe(II) Complex Revealed by Synergistic Spin-Vibronic Dynamics Inorg. Chem. (IF 5.165) Pub Date : 2021-09-09 Mátyás Pápai
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Two Isostructural Titanium Metal–Organic Frameworks for Light Hydrocarbon Separation Inorg. Chem. (IF 5.165) Pub Date : 2021-09-09 Yayong Sun, Mei-Yan Gao, Yuexin Sun, Dong-Fei Lu, Fei Wang, Jian Zhang
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Synthesis and a Catalytic Study of Diastereomeric Cationic Chiral-at-Cobalt Complexes Based on (R,R)-1,2-Diphenylethylenediamine Inorg. Chem. (IF 5.165) Pub Date : 2021-08-27 Mikhail A. Emelyanov, Nadezhda V. Stoletova, Alexander F. Smol’yakov, Mikhail M. Il’in, Victor I. Maleev, Vladimir A. Larionov
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Synthesis, Short-Range Order Structure, and Thermal Properties of Mixed Oxy-sulfide Nitride (MOSN) Glasses Inorg. Chem. (IF 5.165) Pub Date : 2021-08-31 Steven Kmiec, Steve W. Martin
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Enhancing Steric Hindrance via Ligand Design in Dysprosium Complexes: From Induced Slow Relaxation to Zero-Field Single-Molecule Magnet Properties Inorg. Chem. (IF 5.165) Pub Date : 2021-08-27 Christina M. Legendre, Regine Herbst-Irmer, Dietmar Stalke
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Influence of Polymorphism on the Magnetic Properties of Co5TeO8 Spinel Inorg. Chem. (IF 5.165) Pub Date : 2021-09-08 Stanislav Podchezertsev, Nicolas Barrier, Alain Pautrat, Emmanuelle Suard, María Retuerto, Jose Antonio Alonso, María Teresa Fernández-Díaz, Juan Rodríguez-Carvajal
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Prolonged Luminescence Lifetime of a Dual Emissive Ruthenium Dipyridophenazine-Type Complex in Aprotic and Protic Solvents Inorg. Chem. (IF 5.165) Pub Date : 2021-09-08 Dajana Isakov, Marie-Ann Schmid, Djawed Nauroozi, Sven Rau, Stefanie Tschierlei
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Toward Electrochromic Metallopolymers: Synthesis and Properties of Polyazomethines Based on Complexes of Transition-Metal Ions Inorg. Chem. (IF 5.165) Pub Date : 2021-08-16 Sergiusz Napierała, Maciej Kubicki, Monika Wałęsa-Chorab
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Cobalt–Nitrogen Compounds at High Pressure Inorg. Chem. (IF 5.165) Pub Date : 2021-08-30 Shuang Liu, Ran Liu, Haiyan Li, Zhen Yao, Xuhan Shi, Peng Wang, Bingbing Liu
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3d/4f Sandwich Complex Based on Metallacrowns Inorg. Chem. (IF 5.165) Pub Date : 2021-08-31 Andreas Rauguth, Alexander Kredel, Luca M. Carrella, Eva Rentschler
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Synthesis of Cationic Silaamidinate Germylenes and Stannylenes and the Catalytic Application for Hydroboration of Pyridines Inorg. Chem. (IF 5.165) Pub Date : 2021-09-10 Chaopeng Hu, Jianying Zhang, Hao Yang, Lulu Guo, Chunming Cui
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Incorporation of [Cp*Rh] and [Cp*Ir] Species into Heterobimetallic Complexes via Protonolysis Reactivity and Dioximato Chelation Inorg. Chem. (IF 5.165) Pub Date : 2021-08-29 Amit Kumar, Chelsea G. Comadoll, Daniel S. King, Allen G. Oliver, Victor W. Day, James D. Blakemore
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Variational Energy Decomposition Analysis of Charge-Transfer Interactions between Metals and Ligands in Carbonyl Complexes Inorg. Chem. (IF 5.165) Pub Date : 2021-08-30 Jingting Han, Adam Grofe, Jiali Gao
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Cu/Ag Complex Modified Keggin-Type Coordination Polymers for Improved Electrochemical Capacitance, Dual-Function Electrocatalysis, and Sensing Performance Inorg. Chem. (IF 5.165) Pub Date : 2021-08-29 Xingzhi Liu, Liping Cui, Kai Yu, Jinghua Lv, Yuhang Liu, Yajie Ma, Baibin Zhou
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Polymorph of LiAlP2O7: Combined Computational, Synthetic, Crystallographic, and Ionic Conductivity Study Inorg. Chem. (IF 5.165) Pub Date : 2021-08-31 Elvis Shoko, Yun Dang, Guopeng Han, Benjamin B. Duff, Matthew S. Dyer, Luke M. Daniels, Ruiyong Chen, Frédéric Blanc, John B. Claridge, Matthew J. Rosseinsky
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Spectroscopic Analysis of Vibronic Relaxation Pathways in Molecular Spin Qubit [Ho(W5O18)2]9–: Sparse Spectra Are Key Inorg. Chem. (IF 5.165) Pub Date : 2021-08-20 Avery L. Blockmon, Aman Ullah, Kendall D. Hughey, Yan Duan, Kenneth R. O’Neal, Mykhaylo Ozerov, José J. Baldoví, Juan Aragó, Alejandro Gaita-Ariño, Eugenio Coronado, Janice L. Musfeldt
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Symmetry and the Role of the Anion Sublattice in Aurivillius Oxyfluoride Bi2TiO4F2 Inorg. Chem. (IF 5.165) Pub Date : 2021-09-01 Andrew T. Giddings, Euan A. S. Scott, Martin C. Stennett, David C. Apperley, Colin Greaves, Neil C. Hyatt, Emma E. McCabe
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Synthesis and Characterization of Bis[(R or S)-N-1-(X-C6H4)ethyl-2-oxo-1-naphthaldiminato-κ2N,O]-Λ/Δ-cobalt(II) (X = H, p-CH3O, p-Br) with Symmetry- and Distance-Dependent Vibrational Circular Dichroism Enhancement and Sign Inversion Inorg. Chem. (IF 5.165) Pub Date : 2021-09-03 Marcin Górecki, Mohammed Enamullah, Mohammad Ariful Islam, Mohammad Khairul Islam, Simon-Patrick Höfert, Dennis Woschko, Christoph Janiak, Gennaro Pescitelli
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Unraveling the Mechanism of Aerobic Alcohol Oxidation by a Cu/pytl-β-Cyclodextrin/TEMPO Catalytic System under Air in Neat Water Inorg. Chem. (IF 5.165) Pub Date : 2021-08-28 Chunmei Feng, Lin Cheng, Huiyan Ma, Lisha Ma, Qi Wu, Jucai Yang
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Optical and Structural Property Tuning in Physical Vapor Deposited Bismuth Halides Cs3Bi2(I1–xBrx)9 (0 ≤ x ≤ 1) Inorg. Chem. (IF 5.165) Pub Date : 2021-09-02 Sara Bonomi, Pietro Galinetto, Maddalena Patrini, Lidia Romani, Lorenzo Malavasi
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Secondary Coordination Effect on Monobipyridyl Ru(II) Catalysts in Photochemical CO2 Reduction: Effective Proton Shuttle of Pendant Brønsted Acid/Base Sites (OH and N(CH3)2) and Its Mechanistic Investigation Inorg. Chem. (IF 5.165) Pub Date : 2021-09-02 Changhyun Back, Yunjeong Seo, Sunghan Choi, Min Su Choe, Daehan Lee, Jin-Ook Baeg, Ho-Jin Son, Sang Ook Kang
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Ternary Ag2Se1–xTex: A Near-Room-Temperature Thermoelectric Material with a Potentially High Figure of Merit Inorg. Chem. (IF 5.165) Pub Date : 2021-09-02 Jie Chen, Hualei Yuan, Yu-Ke Zhu, Kun Zheng, Zhen-Hua Ge, Jun Tang, Dali Zhou, Lei Yang, Zhi-Gang Chen
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Ruthenium(II) Diphosphine Complexes with Mercapto Ligands That Inhibit Topoisomerase IB and Suppress Tumor Growth In Vivo Inorg. Chem. (IF 5.165) Pub Date : 2021-09-03 Monize M. da Silva, Gabriel H. Ribeiro, Mariana S. de Camargo, Antônio G. Ferreira, Leandro Ribeiro, Marília I. F. Barbosa, Victor M. Deflon, Silvia Castelli, Alessandro Desideri, Rodrigo S. Corrêa, Arthur B. Ribeiro, Heloiza D. Nicolella, Saulo D. Ozelin, Denise C. Tavares, Alzir A. Batista
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