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Dipolar and Contact Paramagnetic NMR Chemical Shifts in AnIV Complexes with Dipicolinic Acid Derivatives Inorg. Chem. (IF 5.165) Pub Date : 2022-06-24 Md. Ashraful Islam, Matthieu Autillo, Laetitia Guérin, Christelle Tamain, Philippe Moisy, Hélène Bolvin, Claude Berthon
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Understanding of the Mechanism and Kinetics of the Fast Solid-State Reaction between NaF and VPO4 to Form Na3V2(PO4)2F3 Inorg. Chem. (IF 5.165) Pub Date : 2022-06-24 Daria O. Semykina, Marat R. Sharafutdinov, Nina V. Kosova
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Synthesis of Water-Soluble Planar Cobalt(II), Nickel(II), and Copper(II) Hydroxo Clusters Using a (1,4,7-Triazacyclononane)cobalt(III) Complex as a Hydrolysis-Terminating Group Inorg. Chem. (IF 5.165) Pub Date : 2022-06-24 Sugiarto, Yuya Imai, Yoshihito Hayashi
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Heterometallic Polyoxotitanium Clusters as Bifunctional Electrocatalysts for Overall Water Splitting Inorg. Chem. (IF 5.165) Pub Date : 2022-06-24 Yi-Qi Tian, Er-Meng Han, Bo Wan, Wei-Dong Yu, Ming-Zhao Chen, Jun Yan, Xiao-Yi Yi, Chao Liu
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Exploring the Reduction Mechanism of 99Tc(VII) in NaClO4: A Spectro-Electrochemical Approach Inorg. Chem. (IF 5.165) Pub Date : 2022-06-24 Diana M. Rodríguez, Natalia Mayordomo, Andrés Parra-Puerto, Dieter Schild, Vinzenz Brendler, Thorsten Stumpf, Katharina Müller
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Oxidation of Hypophosphorous Acid by a Ruthenium(VI) Nitrido Complex in Aqueous Acidic Solution. Evidence for a Proton-Coupled N-Atom Transfer Mechanism Inorg. Chem. (IF 5.165) Pub Date : 2022-06-24 Ji-Rui Li, Li-Ping Xu, Hui-Mei Jiang, Feng-Qin Wang, Jianhui Xie, Wai-Lun Man, Qian Wang, Shuping Zhuo, Tai-Chu Lau
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Aromatic Amino Acid-Mediated Perovskite Nanocrystals: Fluorescence Tuning and Morphological Evolution Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Sukanya Ghosh, Prasenjit Kar
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Dinuclear Fluoride Single-Bridged Lanthanoid Complexes as Molecule Magnets: Unprecedented Coupling Constant in a Fluoride-Bridged Gadolinium Compound Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Julio Corredoira-Vázquez, Cristina González-Barreira, Matilde Fondo, Ana M. García-Deibe, Jesús Sanmartín-Matalobos, Silvia Gómez-Coca, Eliseo Ruiz, Enrique Colacio
A new synthetic method allows isolating fluoride-bridged complexes Bu4N{[M(3NO2,5Br-H3L1,1,4)]2(μ-F)} (M = Dy, 1; M = Ho, 2; M = Gd, 3) and Bu4N{[Dy(3Br,5Cl-H3L1,2,4)]2(μ-F)}·2H2O, 4·2H2O. The crystal structures of 1·5CH3C6H5,·2·2H2O·0.75THF, 3, and 4·2H2O·2THF show that all of them are dinuclear compounds with linear single fluoride bridges and octacoordinated metal centers. Magnetic susceptibility
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Ligand-Protecting Strategy for the Controlled Construction of Multinuclear Copper Cores within a Ring-Shaped Polyoxometalate Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Yoshihiro Koizumi, Kentaro Yonesato, Kazuya Yamaguchi, Kosuke Suzuki
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Aromaticity of Singlet and Triplet Boron Disk-like Clusters: A Test for Electron Counting Aromaticity Rules Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Slađana Đorđević, Miquel Solà, Slavko Radenković
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Neuro-Fuzzification Architecture for Modeling of Electrochemical Ion-Sensing Data of Imidazole-Dicarboxylate-Based Ru(II)–Bipyridine Complex Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Anik Sahoo, Toushique Ahmed, Sourav Deb, Sujoy Baitalik
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Synthesis of a Triphenylphosphinimide-Substituted Silirane as a “Masked” Acyclic Silylene Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Andreas Saurwein, Matthias Nobis, Shigeyoshi Inoue, Bernhard Rieger
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Formation of Iridium(III) and Rhodium(III) Amine, Imine, and Amido Complexes Based on Pyridine–Amine Ligands: Structural Diversity Arising from Reaction Conditions, Substituent Variation, and Metal Centers Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Xueyan Hu, Lihua Guo, Mengqi Liu, Mengru Sun, Qiuya Zhang, Hongwei Peng, Fanjun Zhang, Zhe Liu
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Investigation of the Synthesis of Zeolitic Vanadotungstate and its Use in the Separation of Propylene/Propane at High Temperature and Humidity Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Shufan Yao, Qingqing Liu, Qianqian Zhu, Yanshuo Li, Wataru Ueda, Zhenxin Zhang
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Comparative Analysis of Mononuclear 1:1 and 2:1 Tetravalent Actinide (U, Th, Np) Complexes: Crystal Structure, Spectroscopy, and Electrochemistry Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Deepak Bansal, Peter Kaden, Michael Patzschke, Juliane März, Moritz Schmidt
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Covalent Metalloporphyrin Polymer Coated on Carbon Nanotubes as Bifunctional Electrocatalysts for Water Splitting Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Yujia Wang, Dengmeng Song, Jun Li, Qing Shi, Jiale Zhao, Yanping Hu, Fanlong Zeng, Ning Wang
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Two Mixed Alkali-Metal Borates Templated from Cations to Clusters Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Xu-Yan Li, Guo-Yu Yang
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Two Distinct Cu(II)–V(IV) Superexchange Interactions with Similar Bond Angles in a Triangular “CuV2” Fragment Inorg. Chem. (IF 5.165) Pub Date : 2022-06-23 Yiran Wang, Masayuki Fukuda, Sergey Nikolaev, Atsushi Miyake, Kent J. Griffith, Matthew L. Nisbet, Emily Hiralal, Romain Gautier, Brandon L. Fisher, Masashi Tokunaga, Masaki Azuma, Kenneth R. Poeppelmeier
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Dissociation of Pyridinethiolate Ligands during Hydrogen Evolution Reactions of Ni-Based Catalysts: Evidence from X-ray Absorption Spectroscopy Inorg. Chem. (IF 5.165) Pub Date : 2022-06-22 Kathryn Ledbetter, Christopher B. Larsen, Hyeongtaek Lim, Marija R. Zoric, Sergey Koroidov, C. Das Pemmaraju, Kelly J. Gaffney, Amy A. Cordones
The protonation of several Ni-centered pyridine-2-thiolate photocatalysts for hydrogen evolution is investigated using X-ray absorption spectroscopy (XAS). While protonation of the pyridinethiolate ligand was previously thought to result in partial dechelation from the metal at the pyridyl N site, we instead observe complete dissociation of the protonated ligand and replacement by solvent molecules
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From Small Metal Clusters to Molecular Nanoarchitectures with a Core–Shell Structure: The Synthesis, Redox Fingerprint, Theoretical Analysis, and Solid-State Structure of [Co38As12(CO)50]4– Inorg. Chem. (IF 5.165) Pub Date : 2022-06-22 Roberto Della Pergola, Luigi Garlaschelli, Piero Macchi, Irene Facchinetti, Riccardo Ruffo, Stefano Racioppi, Angelo Sironi
The cluster [Co38As12(CO)50]4– was obtained by pyrolysis of [Co6As(CO)16]−. The metal cage features a closed-packed core inside a Co/As shell that progressively deforms from a cubic face-centered symmetry. The redox and acid–base reactivities were determined by cyclic voltammetry and spectrophotometric titrations. The calculated electron density revealed the shell-constrained distribution of the atomic
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Photoluminescence of Lanthanide–Titanium–Oxo Clusters Eu9Ti2 and Tb9Ti2 Based on a β-Diketone Ligand Inorg. Chem. (IF 5.165) Pub Date : 2022-06-22 Wei-Dong Liu, Guan-Jun Li, Han Xu, Ming-Hao Du, La-Sheng Long, Lan-Sun Zheng, Xiang-Jian Kong
A series of acetylacetone-protected lanthanide–titanium–oxo clusters (LTOCs), formulated as [La6Ti(μ3-OH)8(acac)12(CH3O)2(CH3OH)6] (La6Ti; Hacac = acetylacetone) and [Ln9Ti2(μ4-O)(μ3-OH)14(acac)17(CH3O)2(CH3OH)3] [Ln = Eu (Eu9Ti2) and Tb (Tb9Ti2)], were synthesized through the reactions of LnCl3·6H2O (Ln = La, Eu, and Tb), Hacac, Ti(OiPr)4, and triethylamine in methanol. Crystal structural analysis
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Synthesis and Structure of Pb[C2O5]: An Inorganic Pyrocarbonate Salt Inorg. Chem. (IF 5.165) Pub Date : 2022-06-22 Dominik Spahr, Jannes König, Lkhamsuren Bayarjargal, Rita Luchitskaia, Victor Milman, Alexander Perlov, Hanns-Peter Liermann, Björn Winkler
We have synthesized Pb[C2O5], an inorganic pyrocarbonate salt, in a laser-heated diamond anvil cell (LH-DAC) at 30 GPa by heating a Pb[CO3] + CO2 mixture to ≈2000(200) K. Inorganic pyrocarbonates contain isolated [C2O5]2– groups without functional groups attached. The [C2O5]2– groups consist of two oxygen-sharing [CO3]3– groups. Pb[C2O5] was characterized by synchrotron-based single-crystal structure
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Enhanced Electron–Phonon Coupling Effect in Rare-Earth Borate Crystals Containing a “Quasi-Free-Oxygen” Motif Inorg. Chem. (IF 5.165) Pub Date : 2022-06-22 Yanling Cheng, Jingcheng Feng, Fangyan Wang, Fei Liang, Guochun Zhang, Zhoubin Lin, Haohai Yu, Huaijin Zhang, Yicheng Wu
Revealing the interaction between electrons and phonons, e.g., electron–phonon coupling or decoupling, is a great challenge for physics and functional material communities. For rare-earth single crystals, the electron–phonon coupling and fluorescence behaviors strongly depend on the crystal structure and constituent motifs. Here, we proposed a universal “quasi-free O” as an effective structural motif
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IrIII/NiII-Metallaphotoredox-Catalyzed Enantioselective Decarboxylative Arylation of α-Amino Acids: Theoretical Insight of Enantio-Determining Outer-Sphere Reductive Elimination Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Yu-Jie Liang, Bo Zhu, Zhong-Min Su, Wei Guan
The IrIII/NiII-metallaphotoredox-catalyzed enantioselective decarboxylative arylation of α-amino acids has been systematically investigated using density functional theory calculations. The combination of oxidative quenching (IrIII–*IrIII–IrIV–IrIII) or reductive quenching (IrIII–*IrIII–IrII–IrIII) cycle with the nickel catalytic cycle (NiII–NiI–NiIII–NiII) is possible. The favorable reaction mechanism
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Substituent Dependence on Series of Cationic Gyroidal MOFs in utc-c Topology with High CO2 Affinity and Ultrahigh Anionic Dye Adsorption Capacity Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Wan-Cui Liu, Hua-Shu Wu, Zi-Ying Huang, Yue Qin, Ze-Xian Tao, Wei-Quan Lin, Zhi-Guang Xu, Jian-Zhong Wu, Yong-Cong Ou
A substituent decorating strategy for modification of the functional cavity is of great importance in the design of metal–organic frameworks (MOFs). Herein, three new isostructural cationic MOFs, [Cu3(Xpip)2]·NO3·nH2O (Xpip stands for X-substituted phenylimidazophenanthroline, where X = adm (SCNU-2), f (SCNU-3), and none for SCNU-4), have been successfully synthesized and shown gyroidal utc-c topology
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Importance of an Axial LnIII–F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Emma Regincós Martí, Angelos B. Canaj, Tanu Sharma, Anna Celmina, Claire Wilson, Gopalan Rajaraman, Mark Murrie
The recently reported compound [DyIIILF](CF3SO3)2·H2O (L = 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraaza-cyclododecane) displays a strong axial magnetic anisotropy, due to the short axial Dy–F bond, and single-molecule magnet (SMM) behavior. Following our earlier [DyIIILF]2+ work, herein we report the systematic structural and magnetic study of a family of [LnIIILF](CF3SO3)2·H2O compounds (Ln(III)
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Unsymmetrically β-Functionalized π-Extended Porphyrins: Synthesis, Spectral, Electrochemical Redox Properties, and Their Utilization as Efficient Two-Photon Absorbers Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Amir Sohel Bulbul, Nivedita Chaudhri, Mohd Shanu, Jitendra Nath Acharyya, G. Vijaya Prakash, Muniappan Sankar
Two new series of unsymmetrically β-functionalized porphyrins, MTPP(NO2)MA (1M), (MA = methyl acrylate) and MTPP(NO2)MB (2M) (MB = mono-benzo) (where M = 2H, Co(II), Ni(II), Cu(II) and Zn(II)), were synthesized and characterized by various spectroscopic techniques. The saddle shape conformation of ZnTPP(NO2)MAPy and ZnTPP(NO2)MB was confirmed by single-crystal X-ray analysis. Density functional theory
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Synthesis and Characterization of Magnetoelectric Ba7Mn4O15 Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Gabriel R. M. Clarke, Martin R. Lees, Clemens Ritter, Ivan da Silva, Mark S. Senn
We present the synthesis of a novel binary metal oxide material: Ba7Mn4O15. The crystal structure has been investigated by high-resolution powder synchrotron X-ray diffraction in the temperature range of 100–300 K as well as by powder neutron diffraction at 10 and 80 K. This material represents an isostructural barium-substituted analogue of the layered material Sr7Mn4O15 that forms its own structural
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Trapping an Oxidized and Protonated Intermediate of the [FeFe]-Hydrogenase Cofactor under Mildly Reducing Conditions Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Moritz Senger, Jifu Duan, Mariia V. Pavliuk, Ulf-Peter Apfel, Michael Haumann, Sven T. Stripp
The H-cluster is the catalytic cofactor of [FeFe]-hydrogenase, a metalloenzyme that catalyzes the formation of dihydrogen (H2). The catalytic diiron site of the H-cluster carries two cyanide and three carbon monoxide ligands, making it an excellent target for IR spectroscopy. In previous work, we identified an oxidized and protonated H-cluster species, whose IR signature differs from that of the oxidized
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Stimuli-Responsive Naphthalenediimide Cd-MOFs Tuned by Different Aliphatic Dicarboxylic Acids with Extended Spacers Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Chen Wang, Guang Zeng, Zi-Xin You, Yong-Heng Xing, Feng-Ying Bai, Li-Xian Sun
A series of novel Cd metal–organic frameworks (MOFs) (1–9) with different extended spacers with seven kinds of the aliphatic dicarboxylic acids as secondary building linkers based on N,N′-di(4-pyridylacylamino)-1,4,5,8-naphthalenediimide (NDI-A) have been designed and synthesized by changing the volume ratio of solvents under solvothermal conditions. In addition, the secondary building linkers of aliphatic
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Aurivillius Phase Bi4V3O12 with d1 Magnetic Cations, Anisotropic and Negative Thermal Expansion, Multiple Structural Transitions, and Low-Dimensional Magnetism Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Alexei A. Belik
Aurivillius phases are an important class of inorganic compounds as they often show ferroelectric properties, and some members of this family are used in nonvolatile ferroelectric memories. The majority of Aurivillius phases have nonmagnetic d0 cations in the perovskite block. Bi4Ti3O12 is the best-known and extensively studied compound within this family. Here, using a high-pressure, high-temperature
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Unveiling the Synergistic Effects of Monodisperse Sea Urchin-like PdPb Alloy Nanodendrites as Stable Electrocatalysts for Ethylene Glycol and Glycerol Oxidation Reactions Inorg. Chem. (IF 5.165) Pub Date : 2022-06-21 Tong Sun, Jianyu Chen, Xianzhuo Lao, Xingxue Zhang, Aiping Fu, Wei Wang, Peizhi Guo
In recent times, the fabrication of noble metal-based catalysts with controllable morphologies has become a research hotspot. Electrocatalytic devices with excellent catalytic performance and enhanced durability for the ethylene glycol oxidation reaction (EGOR) and the glycerol oxidation reaction (GOR) are significant for commercial direct fuel cells. Herein, a series of PdPb sea urchin-like nanodendrite
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Theoretical Insight into the Phosphate-Targeted Silver’s Antibacterial Action: Differentiation between Gram (+) and Gram (−) Bacteria Inorg. Chem. (IF 5.165) Pub Date : 2022-06-20 Nikoleta Kircheva, Stefan Dobrev, Valya Nikolova, Silvia Angelova, Todor Dudev
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Bismuth Coordinates with Iodine Atoms to Form Chemical Bonds for Existing Stabilization in Boron Glass Inorg. Chem. (IF 5.165) Pub Date : 2022-06-20 Qian Wen, Wencai Cheng, Meng Yan, Yi Liu, Zhentao Zhang, Yi Xie, Dadong Shao, Xirui Lu
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Synthesis of N-Methyl-o-phenylenediamine-Bridged Bis(phenolato) Lanthanide Alkoxides and Their Catalytic Performance for the (Co)Polymerization of rac-Butyrolactone and l-Lactide Inorg. Chem. (IF 5.165) Pub Date : 2022-06-18 Tian Tian, Chunping Feng, Yaorong Wang, Xuehua Zhu, Dan Yuan, Yingming Yao
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Effects of Subsurface Oxide on Cu1/CeO2 Single-Atom Catalysts for CO Oxidation: A Theoretical Investigation Inorg. Chem. (IF 5.165) Pub Date : 2022-06-18 Weihua Ji, Na Wang, Xin Chen, Qiang Li, Kun Lin, Jinxia Deng, Jun Chen, Xianran Xing
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NiCoPd Inlaid NiCo-Bimetallene for Efficient Electrocatalytic Methanol Oxidation Inorg. Chem. (IF 5.165) Pub Date : 2022-06-18 Long Zhao, Ming Wen, Hao Fang, Kexin Meng, Xiaoyu Qiu, Qingsheng Wu, Yongqing Fu
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Combination of High pH and an Antioxidant Improves Chemical Stability of Two-Dimensional Transition-Metal Carbides and Carbonitrides (MXenes) in Aqueous Colloidal Solutions Inorg. Chem. (IF 5.165) Pub Date : 2022-06-17 Shuohan Huang, Vadym N. Mochalin
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Microscopic Studies and Application of a Stabilized Ceric Ammonium Nitrate Oxidizer in Environmentally Friendly Pyrotechnic Strobes Inorg. Chem. (IF 5.165) Pub Date : 2022-06-17 Hannes Dettlaff, Alicia M. W. Dufter-Münster, Konstantin Karaghiosoff, Thomas M. Klapötke, Hans-Christian Müller, Jesse J. Sabatini
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Recyclable Luminescent Sensor for Detecting Creatinine Based on a Lanthanide–Organic Framework Inorg. Chem. (IF 5.165) Pub Date : 2022-06-17 Li Luo, Yao Xie, Sheng-Li Hou, Yue Ma, Bin Zhao
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Elucidation of Structure–Activity Relationships in Indolobenzazepine-Derived Ligands and Their Copper(II) Complexes: the Role of Key Structural Components and Insight into the Mechanism of Action Inorg. Chem. (IF 5.165) Pub Date : 2022-06-17 Irina Kuznetcova, Felix Bacher, Samah Mutasim Alfadul, Max Jing Rui Tham, Wee Han Ang, Maria V. Babak, Peter Rapta, Vladimir B. Arion
Indolo[3,2-d][1]benzazepines (paullones), indolo[3,2-d][2]benzazepines, and indolo[2,3-d][2]benzazepines (latonduines) are isomeric scaffolds of current medicinal interest. Herein, we prepared a small library of novel indolo[3,2-d][2]benzazepine-derived ligands HL1–HL4 and copper(II) complexes 1–4. All compounds were characterized by spectroscopic methods (1H and 13C NMR, UV–vis, IR) and electrospray
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Controlled Assembly of Ru-Containing Polyoxometalates for Photocatalytic Activity of the Primary Amine Coupling Reaction Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Huafeng Li, Wenjing Chen, Zelong Yuan, Yuzhen Jin, Yujie Zhao, Pengtao Ma, Jingyang Niu, Jingping Wang
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Metal–Metal-Bonded Fe4 Clusters with Slow Magnetic Relaxation Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Phoebe R. Hertler, Linus Kautzsch, Alexander J. Touchton, Guang Wu, Trevor W. Hayton
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Structural Diversity in Oxoiridates with 1D IrnO3(n+1) Chain Fragments and Flat Bands Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Shu Guo, Hillary E. Mitchell Warden, R. J. Cava
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Giant Crown-Shaped Dy34 Nanocluster with High Acid–Base Stability Assembled by an out-to-in Growth Mechanism Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Yun-Lan Li, Hai-Ling Wang, Zhong-Hong Zhu, Fu-Pei Liang, Hua-Hong Zou
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Reactivity of FeMoO4 in CsCl Fluxes and Formation of the Salt-Inclusion Type of Compounds Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Anna K. Weber, Martin Panthöfer, Angela Möller
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In Situ X-ray Diffraction Studies on the Production Process of Molybdenum Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Simon Keilholz, Holger Kohlmann, Henning Uhlenhut, Andrea Gabke, Marleny García-Schollenbruch
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Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds Inorg. Chem. (IF 5.165) Pub Date : 2022-06-16 Shu-Fang Li, Liang Hu, Yao Ma, Fei-Fei Mao, Jie Zheng, Xiu-Du Zhang, Dong Yan
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Two Ligands of Interest in Recovering Uranium from the Oceans: The Correct Formation Constants of the Uranyl(VI) Cation with 2,2′-Bipyridyl-6,6′-dicarboxylic Acid and 1,10-Phenanthroline-2,9-dicarboxylic Acid Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Erica L. Fultz, S. Bart Jones, Alexander S. Ivanov, Vyacheslav S. Bryantsev, Sheng Dai, Robert D. Hancock
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Lithium, Magnesium, and Zinc Centers N,N′-Chelated by an Amine–Amide Hybrid Ligand Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Tomáš Chlupatý, Zdeňka Růžičková, Hana Kampová, Jan Merna, Aleš Růžička
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Evaluation of the Effect of Macrocyclic Ring Size on [203Pb]Pb(II) Complex Stability in Pyridyl-Containing Chelators Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Brooke L. McNeil, Karthika J. Kadassery, Anthony W. McDonagh, Wen Zhou, Paul Schaffer, Justin J. Wilson, Caterina F. Ramogida
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Flux Growth, Crystal Structures, and Electronic Properties of the Ternary Intermetallic Compounds Ca3Pd4Bi8 and Ca3Pt4Bi8 Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Alexander Ovchinnikov, Anja-Verena Mudring
Reaction of the elements yielded Ca3Pt4Bi8 and CaPtBi, which are, to the best of our knowledge, the first reported ternary Ca–Pt–Bi compounds. The compounds crystallize isostructural to the Pd analogs Ca3Pd4Bi8 (own structure type) and CaPdBi (TiNiSi structure type), respectively. Employing a multistep temperature treatment allows for the growth of mm-sized single crystals of Ca3Pd4Bi8 and Ca3Pt4Bi8
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Valence Localization in Alkyne and Alkene Adducts of Synthetic [Fe4S4]+ Clusters Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Alexandra C. Brown, Daniel L. M. Suess
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Lone-Pair-Induced Intra- and Interlayer Polarizations in Sillén-Aurivillius Layered Perovskite Bi4NbO8Br Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Chengchao Zhong, Yui Ishii, Cédric Tassel, Tong Zhu, Daichi Kato, Kosuke Kurushima, Yukihiro Fujibayashi, Takashi Saito, Takafumi Ogawa, Akihide Kuwabara, Shigeo Mori, Hiroshi Kageyama
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Reactivity of Unsupported Transition Metal-Aluminyl Complexes: A Nucleophilic TM-Al Bond Inorg. Chem. (IF 5.165) Pub Date : 2022-06-15 Xueying Guo, Tilong Yang, Yichi Zhang, Fu Kit Sheong, Zhenyang Lin
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Non-Calcined Layer-Pillared Mn0.5Zn0.5 Bimetallic–Organic Framework as a Promising Electrocatalyst for Oxygen Evolution Reaction Inorg. Chem. (IF 5.165) Pub Date : 2022-06-14 Reza Abazari, Ali Reza Amani-Ghadim, Alexandra M. Z. Slawin, Cameron L. Carpenter-Warren, Alexander M. Kirillov
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Chemical Affinity of Ag-Exchanged Zeolites for Efficient Hydrogen Isotope Separation Inorg. Chem. (IF 5.165) Pub Date : 2022-06-14 Linda Zhang, Toshiki Wulf, Florian Baum, Wolfgang Schmidt, Thomas Heine, Michael Hirscher
We report an ion-exchanged zeolite as an excellent candidate for large-scale application in hydrogen isotope separation. Ag(I)-exchanged zeolite Y has been synthesized through a standard ion-exchange procedure. The D2/H2 separation performance has been systematically investigated via thermal desorption spectroscopy (TDS). Undercoordinated Ag+ in zeolite AgY acts as a strong adsorption site and adorbs
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Polyoxometalate-Incorporated Metal-Organic Network as a Heterogeneous Catalyst for Selective Oxidation of Aryl Alkenes Inorg. Chem. (IF 5.165) Pub Date : 2022-06-14 Wen-Jing Cui, Si-Meng Zhang, Yuan-Yuan Ma, Yue Wang, Ruo-Xuan Miao, Zhan-Gang Han
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Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture Inorg. Chem. (IF 5.165) Pub Date : 2022-06-14 Ashley M. Hastings, Debmalya Ray, Sylvia L. Hanna, WooSeok Jeong, Zhijie Chen, Allen G. Oliver, Laura Gagliardi, Omar K. Farha, Amy E. Hixon
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Exploring the Reactivity of Unsymmetrical Diphosphanes toward Heterocumulenes: Access to Phosphanyl and Phosphoryl Derivatives of Amides, Imines, and Iminoamides Inorg. Chem. (IF 5.165) Pub Date : 2022-06-14 Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
We present a comprehensive study on the diphosphanation of iso(thio)cyanates by unsymmetrical diphosphanes. The reactions involving unsymmetrical diphosphanes and phenyl isocyanate or phenyl thioisocyanate gave rise to phosphanyl, phosphoryl, and thiophosphoryl derivatives of amides, imines, and iminoamides. The structures of the diphosphanation products were confirmed through NMR spectroscopy, IR