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Bimetallic ZIF derived Co nanoparticle anchored N-doped porous carbons for an efficient oxygen reduction reaction† Inorg. Chem. Front. (IF 5.934) Pub Date : 2020-01-02 Kaili Li; Daohao Li; Liangkui Zhu; Zhuangzhuang Gao; Qianrong Fang; Ming Xue; Shilun Qiu; Xiangdong Yao
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Unsymmetric 2-phenylpyridine (ppy)-type cyclometalated Ir(iii) complexes bearing both 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene and phenylsulfonyl groups for tuning optoelectronic properties and electroluminescence abilities† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-13 Yindi Zhang; Xi Chen; Dongdong Song; Daokun Zhong; Xiaolong Yang; Yuanhui Sun; Boao Liu; Guijiang Zhou; Zhaoxin Wu
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A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane units† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-01 Diego Rota Martir; Lucie Delforce; David B. Cordes; Alexandra M. Z. Slawin; Stuart L. Warriner; Denis Jacquemin; Eli Zysman-Colman
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Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-30 Zi-Jian Li; Shangyao Guo; Huangjie Lu; Yongjia Xu; Zenghui Yue; Linhong Weng; Xiaofeng Guo; Jian Lin; Jian-Qiang Wang
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In situ transformation of a tridentate to a tetradentate unsymmetric Schiff base ligand via deaminative coupling in Ni(ii) complexes: crystal structures, magnetic properties and catecholase activity study† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-24 Monotosh Mondal; Soumavo Ghosh; Souvik Maity; Sanjib Giri; Ashutosh Ghosh
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Highly efficient oxidation of various thioethers catalyzed by organic ligand-modified polyoxomolybdates† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-17 Haiyan An; Yujiao Hou; Shenzhen Chang; Jie Zhang; Qingshan Zhu
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Polymorphs, phase transitions and stability in BaM2(PO4)2 M = Mn, Fe, Co systems† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-11 Bastien Leclercq; Houria Kabbour; Angel Arevalo-Lopez; Marielle Huvé; Sylvie Daviero-Minaud; Claire Minaud; Ignacio Blazquez Alcover; Olivier Mentré
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Pb3Ba3Zn6(BO3)8 and α-BaZn2(BO3)2: new members of the zincoborates containing two different dimensional Zn–O units† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-10 Xiaobo Pan; Hongping Wu; Shichao Cheng; Zhengping Wang
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Construction of a bifunctional Zn(ii)–organic framework containing a basic amine functionality for selective capture and room temperature fixation of CO2† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-09-20 Rajesh Das; Sandeep Singh Dhankhar; C. M. Nagaraja
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Optimization of Cu catalysts for nitrophenol reduction, click reaction and alkyne coupling† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-30 Yu Huang; Kaibo Zheng; Xiang Liu; Xu Meng; Didier Astruc
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Regulating the structural dimensionality and dynamic properties of a porous dysprosium coordination polymer through solvent molecules† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-26 Fang Ma; Rong Sun; Ai-Huan Sun; Jin Xiong; Hao-Ling Sun; Song Gao
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The substituent guest effect on four-step spin-crossover behavior† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-24 Cui-Juan Zhang; Kai-Ting Lian; Si-Guo Wu; Yang Liu; Guo-Zhang Huang; Zhao-Ping Ni; Ming-Liang Tong
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Enhanced hydrogen generation performance of CaMg2-based materials by ball milling† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-23 Miaolian Ma; Kang Chen; Jun Jiang; Xusheng Yang; Hui Wang; Huaiyu Shao; Jiangwen Liu; Liuzhang Ouyang
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Three stable dinuclear [M2(OH)0.5(NO3)0.5(RCOO)2(RN)4] (M = Cu, Ni) based metal–organic frameworks with high CO2 adsorption and selective separation for O2/N2 and C3H8/CH4† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-03 Liang Kan; Lan Li; Guanghua Li; Lirong Zhang; Yunling Liu
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A ferromagnetic Ni(ii)–Cr(iii) single-chain magnet based on pentagonal bipyramidal building units† Inorg. Chem. Front. (IF 5.934) Pub Date : 2020-01-06 Kateryna Bretosh; Virginie Béreau; Carine Duhayon; Céline Pichon; Jean-Pascal Sutter
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Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-02 Jingqi Han; Kin-Man Tang; Shun-Cheung Cheng; Chi-On Ng; Yuen-Kiu Chun; Shing-Lun Chan; Shek-Man Yiu; Man-Kit Tse; Vellaisamy A. L. Roy; Chi-Chiu Ko
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Superlithiophilic graphene-silver enabling ultra-stable hosts for lithium metal anodes† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-19 Huifeng Zhuang; Ping Zhao; Yue Xu
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Coordinative helix–helix association of heteroleptic metallosupramolecular helicates† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-19 Philjae Kang; Hyojong Yoo
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A rate equation model for the energy transfer mechanism of a novel multi-color-emissive phosphor, Ca1.624Sr0.376Si5O3N6:Eu2+† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-02 Jin Hee Lee; Satendra Pal Singh; Minseuk Kim; Myoungho Pyo; Woon Bae Park; Kee-Sun Sohn
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Insights into the complexity of the excited states of Eu-doped luminescent materials† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-17 Jonas J. Joos; Philippe F. Smet; Luis Seijo; Zoila Barandiarán
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Combined NMR, DFT and X-ray studies highlight structural and hydration changes of [Ln(AAZTA)]− complexes across the series† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-13 Zsolt Baranyai; Daniela Delli Castelli; Carlos Platas-Iglesias; David Esteban-Gomez; Attila Bényei; Lorenzo Tei; Mauro Botta
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Strain-engineering enables reversible semiconductor–metal transition of skutterudite IrAs3† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-09 Yan Liu; Da Li; Fubo Tian; Defang Duan; Bingbing Liu; Tian Cui
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Eight Cd(ii) coordination polymers with persistent room-temperature phosphorescence: intriguing dual emission and time-resolved afterglow modulation† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-06 Yajie Li; Tianyu Gai; Yuejin Lin; Wenjing Zhang; Kai Li; Yan Liu; Yanquan Duan; Baojun Li; Jie Ding; Jinpeng Li
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Effective removal of uranium from aqueous solution by using novel sustainable porous Al2O3 materials derived from different precursors of aluminum† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-11 Jun Liao; Yong Zhang
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Optical properties of undoped, Eu3+ doped and Li+ co-doped Y2Hf2O7 nanoparticles and polymer nanocomposite films† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-08 Santosh K. Gupta; Jose P. Zuniga; Maya Abdou; P. S. Ghosh; Yuanbing Mao
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Interaction of U(vi) with α-MnO2@layered double hydroxides by combined batch experiments and spectroscopy studies† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-07 Junping Ma; Chen Wang; Qiuyu Zhao; Jianlin Ren; Zhe Chen; Jianjun Wang
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High energy-storage performance of PLZS antiferroelectric multilayer ceramic capacitors† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-09 Xiaohui Liu; Yong Li; Ningning Sun; Xihong Hao
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Plasma treated Bi2WO6 ultrathin nanosheets with oxygen vacancies for improved photocatalytic CO2 reduction† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-02 Qidi Li; Xingwang Zhu; Jinman Yang; Qing Yu; Xianglin Zhu; Jinyu Chu; Yansheng Du; Chongtai Wang; Yingjie Hua; Huaming Li; Hui Xu
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Electron-withdrawing anion intercalation and surface sulfurization of NiFe-layered double hydroxide nanoflowers enabling superior oxygen evolution performance† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-18 Yan-Yan Dong; Dong-Dong Ma; Xin-Tao Wu; Qi-Long Zhu
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Solvatochromic dual luminescence of Eu–Au dyads decorated with chromophore phosphines† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-01 Andrey Belyaev; Sofia O. Slavova; Igor V. Solovyev; Vladimir V. Sizov; Janne Jänis; Elena V. Grachova; Igor O. Koshevoy
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Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-01 Maria Drosou; Fotios Kamatsos; Christiana A. Mitsopoulou
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Structural, electrochemical and photophysical behavior of Ru(ii) complexes with large bite angle sulfur-bridged terpyridyl ligands† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-31 Christopher M. Brown; Nicole E. Arsenault; Trevor N. K. Cross; Duane Hean; Zhen Xu; Michael O. Wolf
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Alterations to secondary building units of metal–organic frameworks for the development of new functions Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-28 Junsu Ha; Jae Hwa Lee; Hoi Ri Moon
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Enhanced thermoelectric properties of Sb2Te3/CH3NH3I hybrid thin films by post-annealing Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-28 Shuo Chen; Fu Li; Yuexing Chen; Jingting Luo; Guangxing Liang; Xianghua Zhang; Zhuanghao Zheng; Ping Fan
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A novel core–double shell heterostructure derived from a metal–organic framework for efficient HER, OER and ORR electrocatalysis† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-25 Jing Li; Guangshe Li; Jianghao Wang; Chenglin Xue; Xiangshuai Li; Shuo Wang; Bingqi Han; Min Yang; Liping Li
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Understanding the roles of amorphous domains and oxygen-containing groups of nitrogen-doped carbon in oxygen reduction catalysis: toward superior activity† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-25 Jasper Biemolt; Gadi Rothenberg; Ning Yan
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Recent progress in pyrolyzed carbon materials as electrocatalysts for the oxygen reduction reaction Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-25 Chen Ouyang; Xun Wang
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Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-24 Seong Won Hong; Ju Won Paik; Dongju Seo; Jae-Min Oh; Young Kyu Jeong; Jin Kuen Park
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Solid-state-stabilization of molecular vanadium oxides for reversible electrochemical charge storage† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-24 Simon Greiner; Montaha H. Anjass; Maximilian Fichtner; Carsten Streb
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A reverse slipping strategy for bulk-reduced TiO2−x preparation from Magnéli phase Ti4O7† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-22 Jiantao Huang; Xiangli Che; Jijian Xu; Wei Zhao; Fangfang Xu; Fuqiang Huang
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Theoretical insights into the effect of pristine, doped and hole graphene on the overall performance of dye-sensitized solar cells† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-21 Yuanchao Li; Xin Li; Yanling Xu
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Metal–organic ferroelectric complexes: enantiomer directional induction achieved above-room-temperature homochiral molecular ferroelectrics† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-21 Yu-Ling Liu; Jia-Zhen Ge; Zhong-Xia Wang; Ren-Gen Xiong
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A facile fabrication of 1D/2D nanohybrids composed of NiCo-hydroxide nanowires and reduced graphene oxide for high-performance asymmetric supercapacitors† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-21 Xu Zhang; Qiuyu Fan; Siyu Liu; Ning Qu; He Yang; Man Wang; Juan Yang
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Magnetite-like mixed-valence iron ferrimagnetic homohelical chains exhibiting spin canting, spin-flop and field induced SCM like behaviours† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-17 Lin-Lin Lv; Ying-Xi Sun; Cui-Xian Ji; Shuai Ma; Jian-Wei Ren; Wei-Wei Wang; Jiong-Peng Zhao; Zhong-Yi Liu; Qing Lin; Kaimin Su; Yun He; Fu-Chen Liu
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Controlled synthesis of flower-like cobalt phosphate microsheet arrays supported on Ni foam as a highly efficient 3D integrated anode for non-enzymatic glucose sensing† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-15 Xue Wang; Mingzhu Wang; Shiya Feng; Daiping He; Ping Jiang
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Lysosome-targeted iridium(iii) compounds with pyridine-triphenylamine Schiff base ligands: syntheses, antitumor applications and mechanisms† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-15 Shujiao Chen; Xicheng Liu; Xingxing Ge; Qinghui Wang; Yaoqi Xie; Yingying Hao; Ying Zhang; Lei Zhang; Wenjing Shang; Zhe Liu
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Intermetallic Ni2Si/SiCN as a highly efficient catalyst for the one-pot tandem synthesis of imines and secondary amines† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-15 Xiao Chen; Shuhua Han; Dongdong Yin; Changhai Liang
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RbNa(HC3N3O3)·2H2O exhibiting a strong second harmonic generation response and large birefringence as a new potential UV nonlinear optical material† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-14 Yunxia Song; Donghong Lin; Min Luo; Chensheng Lin; Qiaoling Chen; Ning Ye
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The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-04 Mi Zhou; El-Sayed M. El-Sayed; Zhanfeng Ju; Wenjing Wang; Daqiang Yuan
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Novel cage-like MOF for gas separation, CO2 conversion and selective adsorption of an organic dye† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-13 Yong-Zhi Li; Gang-Ding Wang; Hong-Yun Yang; Lei Hou; Yao-Yu Wang; Zhonghua Zhu
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Recent advances in the synthesis and application of Yb-based fluoride upconversion nanoparticles Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-06 Bing Chen; Feng Wang
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A one-step synthesis of hierarchical porous CoFe-layered double hydroxide nanosheets with optimized composition for enhanced oxygen evolution electrocatalysis† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-25 Jun Zhao; Xiao-ru Wang; Feng-wei Chen; Chao He; Xiao-jing Wang; Yu-pei Li; Rui-hong Liu; Xue-min Chen; Ying-juan Hao; Min Yang; Fa-tang Li
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Anchoring nanosized Pd on three-dimensional boron- and nitrogen-codoped graphene aerogels as a highly active multifunctional electrocatalyst for formic acid and methanol oxidation reactions† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-04 Ying Yang, Huajie Huang, Binfeng Shen, Ling Jin, Quanguo Jiang, Lu Yang, Haiyan He
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An amine-functionalized mesoporous silica-supported PdIr catalyst: boosting room-temperature hydrogen generation from formic acid† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-28 Wendan Nie, Yixing Luo, Qifeng Yang, Gang Feng, Qilu Yao, Zhang-Hui Lu
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A polythreaded MnII-MOF and its super-performances for dye adsorption and supercapacitors† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-26 Jiadi Liu, Zikai Wang, Rong Bi, Feifei Mao, Kuaibing Wang, Hua Wu, Xin Wang
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Anticancer activity of ruthenium and osmium cyclometalated compounds: identification of ABCB1 and EGFR as resistance mechanisms† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-09 Cynthia Licona, Jean-Baptiste Delhorme, Gilles Riegel, Vania Vidimar, Ricardo Cerón-Camacho, Bastien Boff, Aina Venkatasamy, Catherine Tomasetto, Priscila da Silva Figueiredo Celestino Gomes, Didier Rognan, Jean-Noel Freund, Ronan Le Lagadec, Michel Pfeffer, Isabelle Gross, Georg Mellitzer, Christian Gaiddon
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The effect of the electronic structure and flexibility of the counteranions on magnetization relaxation in [Dy(L)2(H2O)5]3+ (L = phosphine oxide derivative) pentagonal bipyramidal SIMs† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-12-02 Ismael F. Díaz-Ortega, Juan Manuel Herrera, Sourav Dey, Hiroyuki Nojiri, Gopalan Rajaraman, Enrique Colacio
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Recent progress on metal–organic framework-derived materials for sodium-ion battery anodes Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-26 Taiqiang Chen, Xinjuan Liu, Lengyuan Niu, Yinyan Gong, Can Li, Shiqing Xu, Likun Pan
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Design, synthesis, crystal structure and luminescent properties of a new tantalum-phosphate K3BiTaP3O13 with negligible concentration quenching and good thermostability† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-11-25 Dan Zhao, Yali Xue, Ruijuan Zhang, Baozhong Liu, Yanping Fan, Shaojie Dai, Shirui Zhang, Zhao Ma
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Narrow-band green emission of Eu2+ in a rigid tunnel structure: site occupations, barycenter energy calculations and luminescence properties† Inorg. Chem. Front. (IF 5.934) Pub Date : 2019-10-25 Lili Wang, Xiaoying Kong, Peng Li, Weiguang Ran, Xuefang Lan, Qian Chen, Jinsheng Shi
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