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Structural Stability and Photoluminescence Property of Cs2UCl6 Single Crystal Derived from Spent Nuclear Fuel Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Yibo Wang, Kun Yang, Feida Chen, Xianlin Qu, Yanmei He, Daniu Han, Xiaobin Tang
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Solid-State Synthesis Enables Enhanced Crystallinity and Tunable Optical Properties in Lanthanum Oxytelluride Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Melissa S. Orr, Hoa H. Nguyen, Thomas S. Ie, Muhammad N. Huda, Mercouri G. Kanatzidis, Michael Bozlar, Robin T. Macaluso
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Sustainable Synthesis of MCM-22 Zeolite as a Catalytic Platform for Propane Dehydrogenation Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Xiaotao Yu, Yuxuan Chen, Min Guo, Song Lu, Jiadi Ying, Tiancun Liu, Qi Shen, Yeqing Wang, Zhixin Yu
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Synthesis and Characterization of Solvated and Base-Free Cerium(III) Mixed-Sandwich Complexes Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Pragati Pandey, Aleksandr Zaichenko, Patrick W. Smith, Dominic R. Russo, Michael R. Gau, Patrick J. Carroll, Taylor M. Keller, Alexandra M. Bacon, Stefan G. Minasian, Jochen Autschbach, Eric J. Schelter
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Impact of Metal Species on Chain Transfer Mode in Bis(imino)pyridyl Complexes Catalyzed Ethylene Polymerization Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Yuan Yuan, Zhengpeng Yan, Shengyu Dai
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Synthesis of YFeO3–Y3Fe5O12 Heterogeneous Structure Magnetic Nanomaterials and Preparation of Nanofibers by Coprecipitation Method Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Jia-Li Wang, Xue Xi, Ke-Di Cai, Zhi-Han Chang, Jian-Fang Chi, Xiao-Shi Lang
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One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy Inorg. Chem. (IF 4.3) Pub Date : 2025-02-12 Huige Chen, Deshuai Xiao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Lei Kang
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Elucidation of the Activity and pH Stability Limits of Polyoxometalate-Intercalated Layered Double Hydroxide Nanocomposites toward Water Oxidation Catalysis Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Joaquín Soriano-López, Javier Quirós-Huerta, Álvaro Seijas-Da Silva, Ramón Torres-Cavanillas, Eduardo Andres-Garcia, Gonzalo Abellán, Eugenio Coronado
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Gold(I) Complexes with Bulky Phosphanes: A Dual Approach to Triplet Harvesting and Hydroamination Catalysis Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Araceli de Aquino, Nazaret Santamaría, Artur J. Moro, David Aguilà, Auxiliadora Prieto, M. Carmen Nicasio, João Carlos Lima, Laura Rodríguez
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Modulating Defect Concentration of Boron Nitride Flowers for CO2 Photoreduction Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Zhehao Liu, Baker Rhimi, Zheyang Liu, Liang Mao, Min Zhou, Zhaochen Jiang, Zhifeng Jiang
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Fabricating MOF–GO Composites by Modulating Graphene Oxide Content to Achieve Superprotonic Conductivity Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Parvathy M. Unnikrishnan, Gopika Premanand, Samar K. Das
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Highly Sensitive and Selective Detection of Uranyl Ions Based on a Tb3+-Functionalized MOF via Competitive Host–Guest Coordination Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Jian Xie, Jinpeng Liang, Ji Lei, Yiheng Xiao, Feng Luo, Baowei Hu
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Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-12 Ping Feng, Shenghua Zhou, Mao-Yin Ran, Bing-Xuan Li, Xintao Wu, Hua Lin, Qi-Long Zhu
The development of Eu-based chalcogenides with exceptional nonlinear optical (NLO) performance in the infrared (IR) region has garnered increasing attention. However, the design and synthesis of such compounds with non-centrosymmetric (NCS) structures remain a significant challenge. In this study, we report the successful synthesis of a novel quaternary Eu-based chalcogenide, β-EuZnGeS₄, achieved through
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Heavier alkaline earth and heterobimetallic s-block “ate” complexes of a di(amido)siloxane ligand: solid-state structure and dynamic solution-phase behaviour Dalton Trans. (IF 3.5) Pub Date : 2025-02-12 Matthew D. Haynes, Andrea O'Reilly, Alice J. M. Poole, Aisling F. Roper, Stefan Thum, Louis J. Morris, Martyn P. Coles, J. Robin Fulton, Sjoerd Harder, Zoë R. Turner, Dermot O'Hare
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Shining light on the ferrous analogue: excited state dynamics of an Fe(II) hexa-carbene scorpionate complex Dalton Trans. (IF 3.5) Pub Date : 2025-02-12 Catherine E. Johnson, Mawuli Deegbey, Aleksandra Ilic, Nidhi Kaul, Om Prakash, Kenneth Wärnmark, Elena Jakubikova, Reiner Lomoth
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Three-dimensional perchlorate-based alkali metal hybrid perovskite molecular ferroelastic crystals Dalton Trans. (IF 3.5) Pub Date : 2025-02-12 yusi liu, Zhe-Kun Xu, Jia-Mei Zhang, Xiao-Gang Chen, Yan Qin, Zhong-Xia Wang
Hybrid perovskites possessing structural diversity and solution processability have been extensively studied in numerous application scenarios and either aroused significant interest in the design of high-performance molecular ferroelectric and ferroelastic materials. However, reports on the construction of three-dimensional (3D) perchlorate-based alkali metal hybrid perovskite molecular ferroelastics
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Single-ion magnet behaviour in highly axial lanthanide mononitrides encapsulated in boron nitride nanotubes: a quantum chemical investigation Dalton Trans. (IF 3.5) Pub Date : 2025-02-12 Kusum Kumari, Shruti Moorthy, Saurabh Kumar Singh
Lanthanide-based single-ion magnets (Ln-SIMs) have garnered significant interest for their potential application in designing molecular-level information storage devices. Among various strategies to enhance magnetization blocking barriers in SIMs, synthesizing highly axially symmetric compounds is the most promising approach. In the present work, using state-of-the-art computational tools, we have
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Transition of the Coordination Modes in Sodiated Uridine Radicals Revealed by Infrared Multiphoton Dissociation Spectroscopy and Theoretical Calculations Dalton Trans. (IF 3.5) Pub Date : 2025-02-12 Kairui Yang, Zicheng Zhao, Jinyang Li, Xianglei Kong, Min Kou
The stable generation and structural characterization of sodium cationized nucleic acid radicals at the molecular level have always been a difficult problem to solve. Herein, we produced the radical cation of [Urd+Na-H]•+ through ultraviolet photodissociation (UVPD) of the precursor ion of [I-Urd+Na]+ in the gas phase and further studied its infrared multiphoton dissociation (IRMPD) spectrum in the
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Size-dependent catalytic reactivity of NO Reduction by CO mediated by the RhnV2O3– clusters (n = 2–5) Dalton Trans. (IF 3.5) Pub Date : 2025-02-12 Jin-You Chen, Hai Zhu, Tongmei Ma, Xiaona Li
A fundamental understanding on the precise structural characteristic of interface active sites confined in heterogeneous catalysts is pivotal to construct vigorous metal–support boundary. Herein, a series of RhnV2O3–5– (n = 2–5) clusters were theoretically designed and we demonstrated that RhnV2O3–5– can catalytically reduce NO into N2 selectively by CO. We identified that the structure of RhnV2O3−
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Acceptorless oxidant-free dehydrogenation of amines catalyzed by Ru–hydride complexes of amide-acid/ester ligands Dalton Trans. (IF 3.5) Pub Date : 2025-02-11 Samanta Yadav, Rajeev Gupta
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Absence of Long-Range Magnetic Ordering in a Trirutile High-Entropy Oxide (Mn0.2Fe0.2Co0.2Ni0.2Cu0.2)Ta1.92O6−δ Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Gina Angelo, Liana Klivansky, Jeremy G. Philbrick, Tai Kong, Jian Zhang, Xin Gui
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Exploring Bonding Properties and Photophysical Behavior of Naphthoquinone-Based Rhenium(I) Tricarbonyl Complexes: A Combined Experimental and Theoretical Approach Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Tamara Maldonado, Belén Gómez-Arteaga, Lucas Lodeiro, Alberto Aravena, Geraldine Jara, Andrés Vega, Guillermo Ferraudi, Alejandra Gómez, Sebastián Gallardo-Fuentes
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Structural Reconstruction via Carbon Nanotube Spatially Confined Metal Catalysis: A Morphology-Controlled Approach to Convert Polycyclic Aromatic Hydrocarbon into Carbon Nanofibers for Highly Active Anodes in Li-Ion Batteries Inorg. Chem. (IF 4.3) Pub Date : 2025-02-11 Ming Chen, Ming-Yang Zhao, Ke Liu, Feng-Ming Liu, Zhong-Yong Yuan, Xing Qian, Rong Wan, Chun-Sheng Li, Ai-Xiang Ding
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Studies on a Urea-Complexed Iron(III) Dichromate, a Precursor of Chromium-Rich Nanospinel Catalysts Prepared for the Reductive Transformation of Carbon Dioxide Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Kende Attila Béres, Zoltán Homonnay, Laura Bereczki, Vladimir M. Petruševski, Attila Farkas, Zsuzsanna Czégény, Péter Németh, Péter Pekker, Fanni Béres-Szilágyi, Tomáš Stryšovský, Libor Kvitek, Ágnes Gömöry, László Kótai
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Charge Transfer Between Ce and Fe During Cooling of an Aluminosilicate Melt: An In Situ XANES Investigation Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Adrien Donatini, Peggy Georges, Tiphaine Fevre, Laurent Cormier, Daniel R. Neuville
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A Porphyrin-Based Metal–Organic Framework Nanozyme with Superior Peroxidase-like Activity for Combating Antibacterial Infections and Promoting Wound Healing Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Han-Xiao Feng, Zijie Zhou, Jilin Jiang, Yi-Fei Hui, Bing-Xin Li, Shulin Li, Huiling Guo, Fa-Qiang Tang, Zu-Jin Lin, Lai-Peng Yan
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Reductive Coupling of Ketones: Contrasting the Reactivity of an Aluminyl and a Gallyl Anion Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Andrea O’Reilly, Rebecca A. Robson, Matthew J. Evans, J. Robin Fulton, Martyn P. Coles
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Determining the Zero-Field Cooling/ Field Cooling Blocking Temperature from AC-Susceptibility data for Single-Molecule Magnets Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-11 Yolimar Gil, María Mar Quesada-Moreno, Maria A. Palacios, Silvia Gómez-Coca, Enrique Colacio, Eliseo Ruiz, Daniel Aravena
We present a general relation between the magnetisation blocking temperature (TB) measured using the zero-field cooling/field cooling technique (ZFC/FC) and their temperature-dependent spin relaxation time obtained from ac-susceptibility and magnetisation decay measurements. The presented mathematical approach provides ZFC/FC blocking temperatures at any heating rate (RH), providing comparable values
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A high phase transition temperature organic-inorganic Sn(IV)-based metal halide designed by amino position isomerism of cation Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-11 Zhang-Tian Xia, Hui-Ping Chen, Jun-Chao Qi, Hang Peng, Xin Shen, Yong-Ju Bai, Zhen-Yu Wang, Tian-En Yang, Wei-Qiang Liao
Organic-inorganic metal halides (OIMHs) have recently received extensive interest from researchers because of their diverse functionalities, such as phase transition. A high phase transition temperature (Tc) is highly desirable for the practical applications of OIMH phase transition materials. Here, by applying cation amino positional isomerism to the lead-free Sn(IV)-based OIMH [n-butylammonium]2SnCl6
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Ultrathin two-dimensional mesoporous holmium oxide nanosheet stabilized copper nanoparticle for stable and efficiency electrocatalytic semi-hydrogenation of acetylene Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-11 Huawei Li, Miao He, Senyao Meng, Ping Wang, Cheng Yang, Jiasai Yao, Zikang Hu, Zhenxing Li
The removal of acetylene (C2H2) from ethylene (C2H4) is a critical step in the production of high-purity C2H4. Due to the low reaction temperature and energy consumption and high selectivity of C2H4, the electrocatalytic semi-hydrogenation of C2H2 is the ideal method for removing C2H2. Herein, the ultrathin two-dimensional (2D) mesoporous holmium oxide nanosheet stabilized copper nanoparticle (Cu/Ho2O3)
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β-LaTeBO5 and RETeBO5 (RE = Y, Gd, Tb): Explorations of New Optical Materials in the RE(III)-Te(IV)-B-O System Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-11 Peng-Fei Chen, Chun-Li Hu, Ming-Zhi Zhang, Jiang-Gao Mao
Exploring new materials and enhancing their optical properties is an endeavor of great significance. Combining different types of optical functional groups such as borate and tellurite anions into a same compound can produce new material with novel structure and enhanced optical performance. In the RE(III)-Te(IV)-B-O system, a borate tellurite, namely, β-LaTeBO5 (β-LTBO) and a series of lanthanide
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A comprehensive survey of cytotoxic active half-sandwich Ir(III) complexes: structural perspective, and mechanism of action Dalton Trans. (IF 3.5) Pub Date : 2025-02-11 Ahmed M. Mansour, Mohamed M. Arafa, Yara S. Hegazy, Muhammed S. Sadek, Hadeer H. Ibrahim, Yomna S. Abdullah, Ola R. Shehab
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Substituent effect on the ligand-centred electrocatalytic hydrogen evolution of antimony(III) corroles Dalton Trans. (IF 3.5) Pub Date : 2025-02-11 Qing-Hua Yu, Yu-Fei Li, Xu-You Cao, Liang-Hong Liu, Junying Chen, Li-Ping Si, Hai-Yang Liu
A series of antimony(III) triaryl corroles bearing different numbers of meso-pentafluorophenyl substituents were synthesized and evaluated as catalysts for electrocatalytic hydrogen evolution. The introduction of electron-withdrawing pentafluorophenyl to the corrole macrocycle led to a significant boost in electro-catalytic hydrogen evolution reaction (HER) activity both in organic and aqueous media
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Indium(III)-terpyridine complexes: synthesis, structures and remarkable antifungal and anticancer activities Dalton Trans. (IF 3.5) Pub Date : 2025-02-11 Guoqi Zhang, Michelle C. Neary, Qinguo Zhang, Xiao Chen, Hyunjeong Kim, Ashley Kaswer, Maisha Ahmed, Shu-Yuan Cheng, Jason M. Rauceo
Complexes of non-radioactive indium(III) with 2,2´;6´,2´´-terpyridine (tpy) ligands are rarely explored despite the popularity of tpy as a strong chelating ligand backbone. Herein, three mononuclear indium(III) complexes (In-1, In-2 and In-3) of tpy and its 4´-Cl and 4´-pyridyl derivatives have been synthesized and structurally characterized. While the crystal structure of In-1 has been previously
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The Role of Ancillary Ligands on Benzodipyridophenazine Based Ru(II)/Ir(III) Complexes for Dark and Light Toxicity against TNBC Cells¥ Dalton Trans. (IF 3.5) Pub Date : 2025-02-11 T. Nivedya, Rishav Das, Selva Kumar Ramasamy, shanooja shanavas, R. Bhaskar, Mujthaba Aatif A, Chandrapaul Mukherjee, Riona Roy, Jhimli Sengupta, Bipasha Bose, Ashok S.K. Kumar, Priyankar Paira
The study investigated the impact of benzodipyridophenazine-based Ru(II) and Ir(III) complexes (Ru1, Ru2, Ir1, and Ir2) on their anticancer activity. Metal complexes displayed three significant absorption bands because of intra-ligand charge transfer (ILCT), ligand-to-ligand charge transfer (LLCT), and metal-to-ligand charge transfer (MLCT). Binding studies with biomolecules has been performed with
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Synthesis of 2,3-dihydroquinazolinimines and 1,3-diimino isoindolines catalyzed by rare earth metal alkyl complexes through tandem addition/cyclization of nitriles with amines Dalton Trans. (IF 3.5) Pub Date : 2025-02-11 Dianjun Guo, Jinqiang He, Qingbing Yuan, Shuangliu Zhou, Xiancui Zhu
Mononuclear rare-earth metal alkyl complexes with an anilido-imino ligand were synthesized and characterized, and their catalytic ability for the formation of dihydroquinazolines and isoindolines from nitriles and amines was investigated. Reactions of rare-earth-metal trialkyl complexes RE(CH2SiMe3)3(THF)2 with the proligand HL (L= (o-(NHDipp)C6H4CH=N(CH2)2NC4H8, Dipp = 2,6-iPr2C6H3) in toluene afforded
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Triple-chromic (photo-, thermo-, and mechano-chromic) metal complexes containing N-salicylideneaminopyridine ligands Dalton Trans. (IF 3.5) Pub Date : 2025-02-07 Haruki Sugiyama, Atsuko Arita, Akiko Sekine, Hidehiro Uekusa
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Unravelling Optical Properties and Self-Assembly Behavior of Ciprofloxacin in Ionic Liquid Environments: Probing the Role of Cationic Residues and Counter Anions Dalton Trans. (IF 3.5) Pub Date : 2025-02-10 Swapan Patra, Nilanjan Dey
This study investigates the interaction of ciprofloxacin (CIP) with three different ionic liquids (ILs) with distinct cationic residues (pyrrolidinium, IL1 vs imidazolium, IL2, with bis (trifluoromethylsulfonyl)imide as counter anion and counter anions (bis (trifluoromethylsulfonyl)imide, IL2 vs hexafluorophosphate, IL3 with imidazolium as cationic residue) in the aqueous environment. A series of spectroscopic
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Synergistic Teamwork of Non-Noble Metals: The Design of Active and Robust Intermetallic Compounds for Hydrogen Evolution Reaction in Industrial Alkaline Water Electrolysis Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Kai Wei, Li-Wen Cao, Ziqing Li, Yuan Yuan Sun, Nian-Tzu Suen
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Zn(II)/La(III) Coordination Polymers Based on New Schiff Base Ligands for Highly Selective and Sensitive Detection of 2,4,6-Trinitrophenol Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Ruonan Xuan, Du Ran, Chao Yang, Yuanying Lin, Weisheng Liu
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Water-Mediated Chiral Resolution of Ag–NHC(Nucleobase) Complexes Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Alvaro Polo, Ricardo Rodríguez, Ramón Macías, Daniel Cobo Paz, Pablo J. Sanz Miguel
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Generalized Synthetic Strategies toward Oxygen Vacancy-Enriched ZnO–ZnS Hollow Porous Spheres with Enhanced Photocatalytic Hydrogen Evolution Inorg. Chem. (IF 4.3) Pub Date : 2025-02-10 Yong Xie, Tingwei Wang, Huiquan Li, Chaozhong Sun, Jie Hu, Shunsheng Cao
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Zeolite Imidazole Framework-Derived Hollow Nickel–Cobalt Layered Double Hydroxide Intercalated with Metalloporphyrin for Enhanced Oxygen Evolution Reaction Inorg. Chem. (IF 4.3) Pub Date : 2025-02-09 Yajun Fu, Zhengkun Ji, Xinhao Li, Abing Guo, Zichao Gao, Weijun Yang
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Spatially Confining Atomically Precise Metal Nanoclusters Steers Photoredox Organic Transformation Inorg. Chem. (IF 4.3) Pub Date : 2025-02-09 Xian Yan, Bing-Xiong Zheng, Jun-Rong Zhu, Yu-Bing Li, Fang-Xing Xiao
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Synthesis, structure and magnetic properties of ACo5(SeO3)4(OH)2F (A = Rb, Cs): the first compounds with a distorted 2-uniform lattice (T29) Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-10 Wenhao Zhang, Meiyan Cui, Zhiying Zhao, Tianyu Zhu, Zhangzhen He
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Design, analysis, and application of metal–organic framework derived carbons Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-06 Joshua A. Powell, Yihao Yang, Hong-Cai Zhou
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Stepwise carbon coated submicron silicon dioxide anode for long life lithium ion batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-05 Mengqi Man, Yong Guo, Tianran Hu, Ying Sun, Aikai Yang, Xiqing Chen, Xingchao Wang
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Structural disproportionation of Ag20Cu10 highlights the impact of cluster structure on electrocatalytic properties for CO2 reduction Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-05 Yujiao Wang, Lin Xiong, Qian Cheng, Daqiao Hu, Shan Jin, Manzhou Zhu
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The synergic effect of neutral organophosphorus ligands combined with acidic β-diketones for the extraction and separation of trivalent actinides Dalton Trans. (IF 3.5) Pub Date : 2025-02-10 Connor K. Holiski, Tara Mastren, Jennifer A. Shusterman
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Immobilization of palladium(II) acetate on a polymer-anchored Schiff base as a new heterogeneous catalyst for three-component one-Pot Mizoroki–Heck coupling via an in situ witting reaction Dalton Trans. (IF 3.5) Pub Date : 2025-02-10 Akash V. Gujarati, Divyesh K. Patel
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How plutonium “brown” peroxo complex emerges from electrolysis experiments Dalton Trans. (IF 3.5) Pub Date : 2025-02-10 Richard Husar, Quentin Hervy, Thomas Dumas, Philippe Guilbaud, Matthieu Virot, Philippe Moisy
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In situ Raman investigation of Dy complexation in Cl-bearing aqueous solutions at 20–300 °C Dalton Trans. (IF 3.5) Pub Date : 2025-02-10 Sarah E. Smith-Schmitz, Nicole C. Hurtig, Alexander P. Gysi
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Exploring N2 activation using novel Lewis acid/base pairs: computational insight into frustrated Lewis pair reactivity Dalton Trans. (IF 3.5) Pub Date : 2025-02-07 Xuban Gastearena, Jon M. Matxain, Fernando Ruipérez
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Single Molecule Junction of Polynuclear Alkynylplatinum-Based Organometallic Molecular Wires: A Theoretical Study of the Long-Range Transport Effect of Linkage to Gold Surfaces Inorg. Chem. (IF 4.3) Pub Date : 2025-02-08 Imen Benkouider, Hiba Sahnoune, Aziz Elkechai, Nadjib Baadji, John A. Gladysz, Jean-François Halet
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Synergism of Hydrogen-Induced Interstitial Effect and Gold-Induced Alloying Effect in PdAuH Metallene for Urea Electrosynthesis from Nitrate and Carbon Dioxide Inorg. Chem. (IF 4.3) Pub Date : 2025-02-08 You Xu, Junjie Wang, Youwei Sheng, Yueji Wu, Qiqi Mao, Kai Deng, Hongjie Yu, Liang Wang, Hongjing Wang
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Epoxyethane Methoxycarbonylation over a Heterogeneous Catalyst Based on Functionalized Cobalt Carbonyl Inorg. Chem. (IF 4.3) Pub Date : 2025-02-08 Haoyi Tong, Jiankai Cheng, Yuntao He, Jiyang Wei, Zhangfeng Zhou, Xinyi Cao, Luyang Qiao, Yong Gao, Yuangen Yao
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Uranium(III) and Uranium(IV) meta-Terphenylthiolate Complexes Inorg. Chem. (IF 4.3) Pub Date : 2025-02-07 Benjamin L. L. Réant, John A. Seed, George F. S. Whitehead, Conrad A. P. Goodwin
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Enhancing CO2 Capture Via Fast Microwave-Assisted Synthesis of the CALF-20 Metal–Organic Framework Inorg. Chem. (IF 4.3) Pub Date : 2025-02-07 Daniel Pereira, Mariana Sardo, Ricardo Vieira, Ildefonso Marín-Montesinos, Luís Mafra
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Covalently Coupling Carbon Quantum Dots for Photoluminescence Red Shift Response to pH Inorg. Chem. (IF 4.3) Pub Date : 2025-02-07 Jun-Ru Tian, Jie-Yao Song, Zhongchang Wang
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Mn doping promotes deep surface reconstruction of CoP nanosheet arrays to drive efficient water splitting Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-02-08 Xiaoyan Liu, Tingting Huang, Hui Ding, Juan Xiao, Xiaolan Fan, Zhiwei Yu, Guan-Cheng Xu, Li Zhang
Among the non-precious metal electrocatalysts, transition metal phosphides (TMPs) show the greatest promise, but their activity and stability still fall short of expectations. Therefore, in order to improve the catalytic activity of TMPs, doping of heteroatoms with different electronegativity becomes one of the best methods. In this paper, the Mn10 doped CoP (the molar amount of Mn accounts for 10%