-
Selective Extraction of Thorium(IV) from Uranium and Rare Earth Elements Using Tetraphenylethane-1,2-diylbis(phosphoramidate) Inorg. Chem. (IF 5.436) Pub Date : 2023-06-03 Abhijit Saha, Khushboo Kumari, Shikha Sharma, Ravi Kumar, Manjulata Sahu, Rama Mohana Rao Dumpala, M. Shafeeq PP, Sadhan Bijoy Deb, Manoj Kumar Saxena
-
Derivatization of the Peptidic Xxx-Zzz-His Motif toward a Ligand with Attomolar CuII Affinity under Maintaining High Selectivity and Fast Redox Silencing Inorg. Chem. (IF 5.436) Pub Date : 2023-06-03 Katharina Zimmeter, Bertrand Vileno, Carlos Platas-Iglesias, Bharath Vinjamuri, Angélique Sour, Peter Faller
-
Coordination-Induced Multivalent Self-Assembling Catalysts for Spectral Sensing Zn2+ with High Selectivity and Sensitivity Inorg. Chem. (IF 5.436) Pub Date : 2023-06-03 Shuai-Bing Li, Jiang-Shan Shen
-
Simultaneous Thermal Enhancement of Upconversion and Downshifting Luminescence by Negative Thermal Expansion in Nonhygroscopic ZrSc(WO4)2PO4:Yb/Er Phosphors Inorg. Chem. (IF 5.436) Pub Date : 2023-06-03 Jinsheng Liao, Zhuo Han, Fulin Lin, Biao Fu, Guoliang Gong, Haokun Yan, Haiping Huang, He-Rui Wen, Bao Qiu
-
Multimode Dynamic Photoluminescence of Bi3+-Activated ZnGa2O4 for Optical Information Encryption Inorg. Chem. (IF 5.436) Pub Date : 2023-06-03 Zishuo Yi, Peng Liu, Yan Xu
-
Electrochemical activation-induced Co-Ni-Mo-O nanosheets with low-crystalline and abundant active sites for the efficient and ultra-stable hydrogen generation Dalton Trans. (IF 4.569) Pub Date : 2023-06-03 Kailu Guo, Jinzhi Jia, Haixia Wu
Co/Ni/Mo-based oxides are promising candidates for hydrogen evolution reaction (HER). However, these electrocatalysts often exhibit unsatisfactory HER performance due to the lack of active sites. Herein, an in situ electrochemical activation strategy is proposed to modify the surface structure of a Co-Ni-Mo-O catalyst. During the HER in alkaline electrolyte, the Co-Ni-Mo-O nanosheets display an activation
-
Titanium(II) as a Fuel Atom in Energetic Materials Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Alexandra M. Bacon, Warren Tomlinson, Joseph P. Hooper, Michael J. Zdilla
-
Formation of the Sub-oxide Sc4Au2O1–x and the Drastically Negative 27Al NMR Shift in Sc2Al Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Elias C. J. Gießelmann, Mathis Radzieowski, Samir F. Matar, Oliver Janka
-
Naphthalene Diimide-Functionalized Half-Sandwich Ru(II) Complexes as Mitochondria-Targeted Anticancer and Antimetastatic Agents Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Yuliang Yang, Xiaofeng Zou, Yanyan Sun, Feihong Chen, Jian Zhao, Shaohua Gou
-
Three Semiconductive 1D Naphthalene Diimide/Iodoplumbate Perovskites with High Moisture Tolerance and Long-Lived Charge Separation States Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Hua Fang, Fu-Hai Chen, Shu-Quan Zhang, Mei-Jin Lin
-
Ultrafast Microwave Synthesis of Ru-Doped MoP with Abundant P Vacancies as the Electrocatalyst for Hydrogen Generation in a Wide pH Range Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Qichang Li, Xueying Luan, Zhenyu Xiao, Weiping Xiao, Guangrui Xu, Zhenjiang Li, Zexing Wu, Lei Wang
-
A broadband near-infrared Cr3+-doped phosphor applied to near-infrared light-emitting diodes: enhanced luminescence and thermal stability by annealing Dalton Trans. (IF 4.569) Pub Date : 2023-05-29 Tao Tan, Ran Pang, Shangwei Wang, Haiyan Wu, Jiutian Wang, Su Zhang, Chengyu Li, Hongjie Zhang
-
Origin of Unexpected Ir3+ in a Superconducting Candidate Sr2IrO4 System Analyzed by Photoelectron Holography Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Rie Horie, Tomohiro Matsushita, Sota Kawamura, Tsubasa Hase, Kazumasa Horigane, Hiroki Momono, Soichiro Takeuchi, Masaki Tanaka, Hiroto Tomita, Yusuke Hashimoto, Kaya Kobayashi, Yuichi Haruyama, Hiroshi Daimon, Yoshitada Morikawa, Munetaka Taguchi, Jun Akimitsu
-
The Prolific Ternary System Pt/Sn/Nd: Insertion of Pt into the Structures of Sn/Nd Intermetallics Yields Structural Complexity and Wealth Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Chris Celania, Volodymyr Smetana, Gerd H. Meyer, Anja-Verena Mudring
-
A Near-Infrared Luminescent 11-Metal Cd(II)–Nd(III) Nanocluster for the Rapid Excitation Wavelength-Dependent Detection of Rutin Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Ying Liu, Jinni Zhao, Xiaoping Yang, Xilong Leng, Chengri Wang, Zhi Yang, Desmond Schipper
-
Hole and Electron Doping Outcomes in Bi2YO4Cl Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Jyoti Pandey, Neetu Yadav, Priyanka Yadav, Shivangi Rao, Kashmira Malla, Poojan Koirala, Madhav Prasad Ghimire, Rajamani Nagarajan
-
{Ti12} Cluster-Added Poly(polyoxometalate) Containing Mixed Trivacant Keggin and Dawson Fragments Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Hai-Lou Li, Chen Lian, Guo-Yu Yang
-
Cooperative Activation of Small Molecules by Base-Stabilized Borylenes Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Barsha Chakraborty, Flora Emilia Basumatary, Holger Braunschweig, Ashwini K. Phukan
-
XeF2 Coordination Complexes of the [BrO2]+ Cation, [O2Br(FXeF)n][AsF6] (n = 1, 2) and [O2Br(FXeF)2][SbF6]; Their Syntheses and Structural Characterizations Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Mark R. Bortolus, Griffin J. LaChapelle, Hélène P. A. Mercier, Jamie Haner, Gary J. Schrobilgen
-
Single-Source Precursors for the Controlled Aqueous Synthesis of Bismuth Oxyhalides Inorg. Chem. (IF 5.436) Pub Date : 2023-06-02 Matthew N. Gordon, Yanyao Liu, M. Kevin Brown, Sara E. Skrabalak
-
Water-Soluble Pd6L3 Molecular Bowl for Separation of Phenanthrene from a Mixture of Isomeric Aromatic Hydrocarbons Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Dharmraj Prajapati, Pallab Bhandari, Neal Hickey, Partha Sarathi Mukherjee
-
Halide perovskite photovoltaic-electrocatalysis for solar fuel generation Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-06-02 Jin Wook Yang, You Jin Ahn, Deok Ki Cho, Jin Young Kim, Ho Won Jang
Photovoltaic-electrochemical (PV-EC) fuel production is a promising technology that combines solar energy conversion and electrochemical catalysis to produce sustainable hydrogen and hydrocarbon from renewable sources. Halide perovskite solar cells with adjustable band gaps are attractive to PV-EC devices since their tailored photovoltages in tandem structures with other photovoltaic materials can
-
Crown ethers-like discrete clusters for sodium binding and gas adsorptions Dalton Trans. (IF 4.569) Pub Date : 2023-06-02 Lan Deng, Denghui Ma, Zhenlang Xie, Rong-Yan Lin, Zhao-Hui Zhou
Hexanuclear polyoxomolybdenum-based discrete supermolecules Nax[MoV6O6(μ2-O)9(Htrz)6-x(trz)x]·nH2O (x = 0, n = 15, 1; x = 1, n = 12, 2; x = 2, n = 10, 3; x = 2, n = 49, 4; Htrz = 1H-1,2,3-triazole) have been precipitated and fully characterized with different amounts of sodium cations inside and outside the intrinsic holes. Structural analyses demonstrate that they all exist a triangular channel constructed
-
Synthesis, Post-Functionalization, and Photoluminescence of Contorted Diazaphosphepine-Based Polycyclic Aromatic Heterocycles Dalton Trans. (IF 4.569) Pub Date : 2023-06-02 Can Li, Kai Yang, Xinyu Li, Shuya Wen, Na Yu, Yi Ren
Heteratom-doped organic π-conjugated molecules (OCMs) have become one type of emerging optoelectronic materials with intriguing functionalities. Phosphorus (P)-doped OCMs are a special member of the heteratom-doped OCMs where rich P-chemistry is able to fine-tune optoelectronic properties. Herein, we report a new series of nonplanar diazaphosphepine-based polycyclic aromatic hydrocarbons (DPP-PAHs)
-
Second Harmonic Generation from Symmetry Breaking Stimulated by Organic Cations Mixing in Zero-Dimensional Hybrid Metal Halides Dalton Trans. (IF 4.569) Pub Date : 2023-06-02 Jing Zhao, Jindong Cao, Kunjie Liu, mingzhen quan, an hou, Xing-Xing Jiang, Zheshuai Lin, Quanlin Liu
Mixing cations with different chemical properties to induce the generation of asymmetric structures is a new approach for tuning the optical properties of hybrid organic-inorganic metal halide (HOIMH). In this study, zero-dimensional (C9N3H15)(C9H13SO)MBr6 (M = Bi/Sb, [C9N3H15]2+ = [(C4N2H10)(C5NH5)]2+ and [C9H14SO]+ = [CH3(C6H4)OS(CH3)2]+) are synthesized. Two different cations cause both compounds
-
PtII(C^N)(N-donor ligand)Cl-type complexes showing highly sensitive aggregation-induced phosphorescent emission (AIPE) behavior fulfilled by long-size ligands and distorted molecular configuration Dalton Trans. (IF 4.569) Pub Date : 2023-06-02 Xinyue Lu, Siqi Liu, Xi Chen, Zhao Feng, Daokun Zhong, Xiaolong Yang, Yuanhui Sun, Bochao Su, Guijiang Zhou, Bo Jiao, Zhaoxin Wu
A series of four-coordinated PtII(C^N)(N-donor ligand)Cl-type complexes have been synthesized through combination between long-size C^N-type and N-donor ligands. In addition, by variating the coordinating site in the N-donor ligand, distorted molecular configuration has been constructed in these complexes. Photophysical features, aggregation-induced phosphorescent emission (AIPE) behaviors, electrochemical
-
Controlled preparation of CoNi2S4 nanorods derived from MOF-74 nanoarrays involving exchange reaction for high energy density supercapacitors Dalton Trans. (IF 4.569) Pub Date : 2023-06-02 Qihang Chen, Wenna Zhao, Zihao Huang, Guochang Li, Kai Tao, Lei Han
Binary transition metal sulfides are considered to be a promising material for supercapacitors, possessing a richer electrochemical active site and superior electrochemical performance. Metal-organic frameworks (MOFs) are often used as self-sacrificing templates for the preparation of metal sulfides. Usually, direct sulfidation of MOFs tends to cause collapse of the morphological structure and blockage
-
Approaching high-performance lithium storage materials of CoNiO2 microspheres wrapped coal tar pitch-derived porous carbon Dalton Trans. (IF 4.569) Pub Date : 2023-06-02 Nan Zhang, Si-Yu Qi, Ya-Fei Guo, Peng-Fei Wang, Ning Ren, Ting-Feng Yi
Ternary transition metal oxides (TMOs) are deemed as the hopeful anode materials of Li-ion batteries (LIBs) because of the large theoretical capacity, and rich redox reaction. Nevertheless, inherent semiconductor characteristic, and enormous volume variation of TMOs during cycling bring about sluggish reaction kinetics, fast capacity fading and poor rate capability. Herein, a three-dimension (3D) porous
-
Conformational dynamicity in a copper(II) coordination complex Dalton Trans. (IF 4.569) Pub Date : 2023-05-29 Paul J. Griffin, Matthew J. Dake, Alesandro D. Remolina, Lisa Olshansky
-
Circularly Polarized Luminescence from New Heteroleptic Eu(III) and Tb(III) Complexes Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Silvia Ruggieri, Silvia Mizzoni, Chiara Nardon, Enrico Cavalli, Cristina Sissa, Michele Anselmi, Pier Giorgio Cozzi, Andrea Gualandi, Martina Sanadar, Andrea Melchior, Francesco Zinna, Oliver G. Willis, Lorenzo Di Bari, Fabio Piccinelli
-
Semirigid Highly Conjugated Zirconium–Organic Framework for the Capture of Micropollutants and Solar-Light Photodegradation Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Yongchun Wang, Xiang Li, Xusheng Zhou, Panqi Song, Muling Zeng, Wenhui Shang, Yan-Qing Xu, Zhiyu Jia, Guo-Yu Yang
-
Control of Hole Density in Russellite Bi2WO6 via Intentional Chemical Doping Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Makoto Minohara, Yuka Dobashi, Naoto Kikuchi, Seiya Suzuki, Akane Samizo, Takashi Honda, Keishi Nishio, Yoshihiro Aiura
-
Nanoscale Saturn Systems Based on C60/70 Bucky Ball and a Newly Designed [4]Cyclopara-1,2-diphenylethylene Hoop: A Strategy for Fullerene Encapsulation Release and Selective Recognition for C70 Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Yanzhi Liu, Kun Yuan, Mengyang Li, Pei Zhao, Yaoxiao Zhao, Xiang Zhao
-
Structural Transformation and Photoluminescent Property of Manganese-Doped Bismuth-Based Perovskites Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Jing Liu, Qichuan Hu, Hailong Yu, Hanqi Xu, Jinyang Yu, Qiuju Han, Wenzhi Wu
-
Application of Metal–Organic Frameworks with Sulfonic Acid Tags in the Synthesis of Pyrazolo[3,4-b]pyridines via a Cooperative Vinylogous Anomeric-Based Oxidation Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Hassan Sepehrmansourie, Milad Mohammadi Rasooll, Mahmoud Zarei, Mohammad Ali Zolfigol, Yanlong Gu
-
Synthesis, Kinetic Studies, and Atom Transfer Reactivity of [2Fe-2E] Model Compounds Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-06-01 Erwin Weerawardhana, Matthias Zeller, Wei-Tsung Lee
The synthesis of [2Fe-2E] (E = S and Se) complexes supported by an N-alkyl,N'-aryl-β-diketiminate ligand is described. The [2Fe-2S] model compound has an unusually long Fe···Fe distance, but the equivalent distance in the [2Fe-2Se] compound is comparable to those reported in the literature. These model compounds display varying electron transfer capabilities, which were elucidated through electronic
-
Solution Combustion Synthesis and Characterization of Magnesium Copper Vanadates Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Abhishek Rawat, Laura Clark, Chuzhong Zhang, John Cavin, Vinod K. Sangwan, Peter S. Toth, Csaba Janáky, Riddhi Ananth, Elise Goldfine, Michael J. Bedzyk, Emily A. Weiss, James M. Rondinelli, Mark C. Hersam, Efstathios I. Meletis, Krishnan Rajeshwar
-
Modeling Uranyl Adsorption on MoS2/Mo2CTx Heterostructures Using DFT and BOMD Methods Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Cheng Meng, Weihui Shu, Kun Zhao, Chunpei Yan, Zuojia Li, Qianglin Wei, Minjia Wang, Yunhai Liu, Zhibin Zhang
-
Intermetallic Pd–Sn Nanoparticles on Supports with High Metal Loading Facilitated by the Metal–Metal Bond for High-Performance Cooperative Catalysis Inorg. Chem. (IF 5.436) Pub Date : 2023-06-01 Amishwar Raysing Shelte, Sanjay Pratihar
-
A dual protection strategy for stable lithium metal anode by Ag nanoseeds decorated F-doped porous graphene current collector Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-06-01 Yang Yan, Jing Sun, Ying Zhang, Wen Liu, Yu-jie Wang, Hui-qin Yang, Chengjie Li, Juan Zhang
Lithium metal batteries have been regarded as typical representative of high-energy storage systems. However, the lithium dendrite growth and fragile solid electrolyte interface (SEI) leads to safety issues and unsatisfactory performances. We tackle the above issues by a dual protection strategy via designing silver (Ag) decorated F-doped graphene (Ag@FG) matrix. The Ag@FG was synthesized by a one-step
-
Anchoring Atomic Antimony in an Intercalative MoS Framework via Soft Covalent Bonding for Fast-charging and Longevous Sodium Ion Battery Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-06-01 Baixin Peng, Zhuoran Lv, Yuqiang Fang, Tianxun Cai, Zhiyuan Shi, Ce Zhou, Yusha Gao, Fu Qiang Huang
Large volume change and grain pulverization are two major challenges of alloy-type anode materials for sodium ion batteries. Herein, we proposed a soft covalent bonding confinement strategy to dispersing high capacity Sb into robust and conductive MoS framework. The high capacity and high rate sodium storage are integrated into single phase Mo2SbS2 anode, in which atomic Sb is confined in a zig-zag
-
Synthesis, characterization, photophysical, electrochemical properties and biomolecular interaction of 2,2′-biquinoline based phototoxic Ru(II)/Ir(II) complexes Dalton Trans. (IF 4.569) Pub Date : 2023-06-01 Utpal Das, Priyankar Paira
Phototoxic nature of the drugs has been seen to convey an immense importance in photo activated chemotherapy (PACT) for selective treatment of the disease. Rationally, in order to eradicate the vehemence of cancer in living body, the design of phototoxic molecules has now been the growing interest of the research to establish a selective strategy of cancer therapy. Therefore, the present work portrays
-
Catalytic oxidation properties of an acid-resistant cross-bridged cyclen Fe(II) complex. Influence of the rigid donor backbone and protonation on the reactivity. Dalton Trans. (IF 4.569) Pub Date : 2023-06-01 Jean-Noël Rebilly, Christian Herrero, Katell Sénéchal-David, Régis Guillot, Frédéric Banse
The catalytic properties of an iron complex bearing a pentadentate cross-bridged ligand backbone are reported. With H2O2 as an oxidant, it displays moderate conversions in epoxidation and alkane hydroxylation, and satisfactory ones in aromatic hydroxylation. Upon addition of acid in the reaction medium, a significant enhancement in aromatic and alkene oxidation is observed. Spectroscopic analyses show
-
Additive-free selective oxidation of aromatic alcohols with molecular oxygen catalyzed by a mixed-valence polyoxovanadate-based metal–organic framework Dalton Trans. (IF 4.569) Pub Date : 2023-06-01 Hongrui Tian, Runhan Li, Jun Miao, Shuxia Liu, Fengfeng Wang, Zhiping Zheng
Selective oxidation of alcohols to aldehydes is an industrially significant chemical transformation. Herein, we report a mixed-valence polyoxovanadate-based metal–organic framework (MOF), (H2bix)5{[Cd(bix)2][VIV8VV7O36Cl]2}·3H2O (V-Cd-MOF), for catalyzing additive-free oxidation of a series of aromatic alcohols with high selectivity and in nearly quantitative yield to corresponding aldehydes with O2
-
Oligozwitterions in coordination polymers and frameworks – a structural view Dalton Trans. (IF 4.569) Pub Date : 2023-05-30 Lassaad Baklouti, Jack Harrowfield
-
Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to [(Me3P)xM(2-C6F4PPh2)2] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Robert Gericke, Martin A. Bennett, Steven H. Privér, Suresh K. Bhargava
-
Near-Ultraviolet Light-Driven Photocathodic Activity for (001)-Oriented BiOCl Thin Films Synthesized by Mist Chemical Vapor Deposition Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Zaichun Sun, Shaoyong Qin, Daichi Oka, Huijuan Zhang, Tomoteru Fukumura, Yuji Matsumoto, Bingchu Mei
-
Structure and Bonding of Halonium Compounds Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Juan D. Velasquez, Jorge Echeverría, Santiago Alvarez
-
Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Maureen Gumbo, Banothile C. E. Makhubela, Francoise M. Amombo Noa, Lars Öhrström, Bassem Al-Maythalony, Gift Mehlana
-
Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Jinxuan Ren, Yuqi Chen, Liying Ren, Yuqiao Zhou, Xuehua Dong, Daojiang Gao, Ling Huang, Liling Cao, Ning Ye
-
High-Temperature Metal-Free Molecular Ferroelectrics with Large Spontaneous Polarization Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Yan-Xin Zhao, Kai-Ge Gao, Zi-Shuo Yao, Jun Tao
-
High-Pressure-Stabilized Post-Spinel Phase of CdFe2O4 with Distinct Magnetism from Its Ambient-Pressure Spinel Phase Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Beihong Li, Xubin Ye, Xiao Wang, Jie Zhang, Dabiao Lu, Haoting Zhao, Maocai Pi, Zhiwei Hu, Hong-Ji Lin, Chien-Te Chen, Zhao Pan, Xiaomei Qin, Youwen Long
-
Target-Oriented Synthesis of Borate Derivatives Featuring Isolated [B3O3] Six-Membered Rings as Structural Features Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Meng Cheng, Congcong Jin, Wenqi Jin, Xueling Hou
-
Selenite-Decorated Polycrystalline NiO Nanosheets Generated from Cathodic Reconstruction for Electrocatalytic Hydrogen Production Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Kailu Guo, Xiaoyan Lu, Jinzhi Jia, Zhan Zhou, Junfeng Huang, Shuang Wang, Shihui Li, Haixia Wu, Cailing Xu
-
Constructing Type-II and S-Scheme Heterojunctions of Cu2O@Cu4(SO4)(OH)6·H2O Polyhedra by In Situ Etching Cu2O with Different Exposed Facets for Enhanced Photocatalytic Sterilization and Degradation Performance Inorg. Chem. (IF 5.436) Pub Date : 2023-05-31 Jin Du, Yongjian Hu, Xia Wan, Shaolong Tie, Sheng Lan, Xingsen Gao
-
First principles prediction of two-dimensional Janus STiXY2 (X = Si, Ge; Y = N, P, As) materials Dalton Trans. (IF 4.569) Pub Date : 2023-05-31 Zhen Gao, Xin He, Wenzhong Li, Yao He, Kai Xiong
-
Correction: A hollow urchin-like metal–organic framework with Ni–O-cluster SBUs as a promising electrode for an alkaline battery–supercapacitor device Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-05-31 Tianqi Chen, Sujuan Bian, Xutian Yang, Wenjie Lu, Kuaibing Wang, Yuxuan Guo, Cheng Zhang, Qichun Zhang
Correction for ‘A hollow urchin-like metal–organic framework with Ni–O-cluster SBUs as a promising electrode for an alkaline battery–supercapacitor device’ by Tianqi Chen et al., Inorg. Chem. Front., 2023, 10, 2380–2386, https://doi.org/10.1039/D3QI00123G.
-
From unprecedented 2,2′-bisimidazole-bridged rare earth organometallics to magnetic hysteresis in the dysprosium congener Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-05-31 Florian Benner, Selvan Demir
-
Fluoride Counterion Boosts Gold(I) Catalysis: Case Studies for Hydrodefluorination and CO2 Hydrosilylation Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-05-31 Yuhang Yao, Jiyun Hu, Guiyu Liu, Yin-Shan Meng, Song Gao, Jun-Long Zhang
We reported herein a novel gold(I) bifluoride complex, LAuHF2, supported by a sterically bulky ligand (L, tBuXantphos), displays exceptional reactivity toward hydrodefluorination (HDF) and hydrosilylation of CO2 in the presence of hydrosilanes. Compared to the LAuCl counterpart, the LAuHF2 complex exhibited an over 27-fold increase in turnover frequency in HDF and 16-time turnover numbers in the hydrosilylation
-
N-Heterocyclic Carbene-Ligated Metal Complexes and Clusters for Photocatalytic CO2 Reduction Inorg. Chem. Front. (IF 7.779) Pub Date : 2023-05-31 Yilin Jiang, Honghan Fei
Photocatalytic reduction of CO2 to high valued-added production is a green and sustainable approach to reducing excessive CO2 emissions. N-heterocyclic carbenes (NHCs) are an emerging class of versatile ligands due to their strong σ-donor properties, forming covalent bonds with many metal centers and activate CO2 molecules. The resulting NHC-ligated metal centers and clusters have high stability, tunable