-
Microporous Na–Nd Heterometallic Organic Frameworks for C2H2/CO2 and C3H4/C3H6 Separation Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Nana Li, Rui Qian, Tingting Ma, Xin Huang, Jing-Xin Ma
-
Stereoselective Synthesis of High Trans-1,4-Regularity Polyisoprene via Controlled Polymerization with Amidinate Rare-Earth Metal Catalysts Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Yun Li, Jue Chen, Wei Xu, Hongzhen Xie, Yunjie Luo
-
Photoluminescence in Square-Planar Ni(II) Complexes: A Study of Electronic Structure and Quantum Dynamics Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Kishan Kumar Dakua, Rituparna Sinha, Sabyashachi Mishra
-
Artificial Acoustic Shock Wave-Induced Kinetic Disordering-Assisted Switchable Ordered-to-Disordered Phase Transition on a Natural Barite (BaSO4) Single Crystal toward the Implications on Natural Shock Sensors Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Sivakumar Aswathappa, Lidong Dai, Sahaya Jude Dhas Sathiyadhas, Raju Suresh Kumar
-
Ligand and Stoichiometry Engineering Unlock Narrowband Red Emission in Colloidal PEA2SnI4 Nanoplatelets Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Yuchao Huang, Di Li, Jie Guo, Zeyu Miao, Shuo Li, Ziqi Song, Wenxu Yin, Xiaoyu Zhang
-
Europium(II) Activated Blue–Cyan Aluminosilicate Phosphors with Zero Thermal Quenching Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Xinzhe Zhou, Mingyu Yao, Zixuan Li, Mengjiao Li, Panlai Li, Wei Zhang, Huanrong Li
The ″cyan gap″ is the bottleneck of full-visible-spectrum white light-emitting diodes (WLEDs), and the development of high thermal stability blue–cyan phosphors plays a decisive role in compensating for the cyan gap. Herein, we report a blue–cyan-emitting celsian phosphor prepared using Ba2+-doped LTA/FAUX zeolite. Excited by UV light, celsian phosphors show a super broad emission at the blue–cyan
-
Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids Inorg. Chem. (IF 4.7) Pub Date : 2025-06-23 Qian Wu, Tianyu Wang, Jingfang Zhou, Pifu Gong, Haochen Li, Haotian Tian, Mingjun Xia
-
Circularly Polarized Luminescence in Chiral Antimony(III) Chloride [Sb2Cl10]4– Dimers Induced by Asymmetric Hydrogen Bonding Inorg. Chem. (IF 4.7) Pub Date : 2025-06-22 Qiulian Luo, Jing Li, Jianwu Wei, Binbin Luo, Liya Zhou, Peican Chen, Jie Tian, Jiahong Pan, Alexei V. Emeline, Qi Pang
Metal halide species with multimeric anionic frameworks exhibit outstanding coordination chiralities and intriguing photophysical properties, making them highly promising for emerging photonic applications. However, their chiroptical activities remain largely unexplored to date. Herein, lead-free chiral hybrid 0D materials composed of edge-sharing [Sb2Cl10]4– dimers were synthesized via a natural cooling
-
Unveiling the Transformation Pathway from ε-Al13 to δ-Al13 Inorg. Chem. (IF 4.7) Pub Date : 2025-06-22 Qi Zhao, Minjuan Zhao, Yufei Sun, Xiuling Jiao, Yuguo Xia, Dairong Chen
-
Enhancing Photocatalytic Hydrogen Production Performance of Zr-Tetracarboxylate Frameworks through Topology/Substituent Tunings Inorg. Chem. (IF 4.7) Pub Date : 2025-06-22 Dan Liu, Bin He, Hao Zhang, Feifan Lang, Shuwen Gong
-
Catalytic Effect of Pd0 NPs Encapsulated in UiO-66(Zr) under Microenvironment Modulation for the Degradation of Trimethoprim in Fenton-like Reaction Inorg. Chem. (IF 4.7) Pub Date : 2025-06-22 Ying Gao, Ruibin Yang, Qinqin Chen, Xinhao Shen, Dapeng Li, Juanhong Li, Feng Liu, Jianhua Wu, Sanjian Ma, Guoliang Dai, Dongmei Wang, Lei Xie, Zixia Lin, Xin Liu
-
Ligand tuned catalytic activity of Ruthenium-imidazolylamine complexes for reversible formic acid dehydrogenation and CO2 hydrogenation to formic acid Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-23 Khanindra Kalita, Sanjeev Kushwaha, Sanjay Kumar Singh
Formic acid (FA) dehydrogenation was investigated over several arene-ruthenium catalysts with various imidazolyl-, thiophenyl- and furyl-based ligands. The catalyst with the N-((1H-imidazol-2-yl)methyl)propan-2-amine ligand (Ru/L7) outperformed the other catalysts for FA dehydrogenation at 90 °C in water. Furthermore, the developed process was scaled up by a factor of 10 without any loss in activity
-
Zn(II)/Ag(I) bi-heterometallic based assemblies with unexpected highly catalytic activity for the hydrolysis of phosphodiester Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-23 Shuai-Bing Li, Ning Liu, Yan-Zhen Zheng, Jiang-Shan Shen
Almost all reported artificial phosphodiesterases with high catalytic efficiency are based on binuclear homometallic models, typically involving two Zn²⁺ ions or two adjacent Zn²⁺ centers forming a catalytic pocket within multivalent assemblies (e.g., Au nanoparticles). However, bi-heterometallic artificial phosphodiesterases remain largely unexplored, representing significant research potential in
-
High-Stability Electrocatalytic CO2 Reduction in Seawater Over Heterostructure Cu-Bi Nanosheets with H-Spillover Effect Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-23 Bangli Feng, Yixin Ouyang, Peng Liu, Shanshan Zheng, Liwen Wang, Yifan Yang, Zisen Wang, Zhifeng Xin, Xiuyun Zhang, Yifa Chen
Direct electrocatalytic CO2 reduction in seawater to produce valuable products offers significant advantages for CO2 mitigation and minimizes the use of freshwater resources or electrolytes. Nevertheless, the complexity and high concentration of ions in seawater can lead to the corrosion of catalysts, posing challenges to their activity and stability. This study presents a kind of ultrathin heterostructure
-
Investigating the Impact of Counter Anions on Electrocatalytic Alcohol Oxidation Reaction over MOF-derived Catalysts Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-23 Yining Li, Abhishek Dutta Chowdhury
The electrocatalytic oxidation of alcohols (AOR) using low-cost metal-organic framework (MOF)-derived electrocatalysts is a promising renewable energy technology. This study explores the impact of the counter anion in MOFs and its relevance to catalytic efficiency to improve understanding of structure-reactivity relationships.
-
Cathodic NiOOH emerging during hydrogen release toward the strong coupling catalyst for durable ampere-level H2 generation Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-23 Wendi Zhang, Xuan Yang, Hongyu Ma, Hongguang Zhang, Xuqiang Ji
The elaborate interface engineering based on in-situ surface reconstruction during catalysis, especially on the cathode, is effective in promoting hydrogen evolution reaction (HER) but plagued by uncontrollably reconstruction extent and structure collapse. In view of the reasonable reaction-intermediates adsorption and accelerating kinetics of hydroxy oxides (MOOH), we focused on the HER-electrode
-
Enhancing Electrocatalytic Activities of High-Entropy Borides (HEBs) for C–N Coupling in Induced Cation and pH-Dependent Microenvironments via Multiscale Modeling Strategy Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-23 Yan Feng, Yingchun Ding, Li Liu, Yi Xiao
Currently, the renewable energy–driven carbon dioxide reduction reaction (CO2RR) has been identified as a promising carbon neutralization option capable of generating a variety of high-value hydrocarbon products. Importantly, high-entropy borides (HEBs), which are similar to high-entropy carbides, have attracted extensive attention because of their outstanding chemical and physical properties, which
-
Electric dipole resonance driven terahertz broadband absorber with wide-angle and dynamic tunability Dalton Trans. (IF 3.3) Pub Date : 2025-06-23 gengliang zou, Tao Liu, Chunlan Wang, Chi Luo, Zihan Qin, Zao Yi, jiaying ji
To address the challenges of limited bandwidth and structural complexity in terahertz absorbers, this study proposes a vanadium dioxide (VO₂)-based broadband terahertz (THz) absorber driven by electric dipole resonance. The device achieves broadband absorption exceeding 90% within 3.55-9.95 THz, Absorption bandwidth of 6.4 THz and a relative bandwidth reaching 94.81%. Through comprehensive analyses
-
Reactivity of titanium pyrazolates towards CO2, CS2 and N2O Dalton Trans. (IF 3.3) Pub Date : 2025-06-23 Felix Kracht, Sophie Mayer, Caecilia Maichle-Moessmer, Reiner Anwander
The tetravalent titanium pyrazolate Ti(pzMe2)4 inserts two molecules of carbon dioxide instantly at ambient temperature and 1 bar heteroallene, forming the complex Ti(CO2∙pzMe2)2(pzMe2)2 (pzMe2 = 3,5‐dimethylpyrazolato). CO2 insertion is reversible as proven by thermogravimetric analysis (TGA). Solid Ti(CO2∙pzMe2)2(pzMe2)2 exhibits an exceptionally high stability at ambient atmosphere but converts
-
Dose-dependent gamma irradiation effects on Ni nanoparticle size in rGO–Ni nanocomposites for enhanced electrochemical performance Dalton Trans. (IF 3.3) Pub Date : 2025-06-23 Raynara M. S. Jacovone, Miguel Duarte, Jaqueline J. S. Soares, Rubens N. Faria, Rafael H. L. Garcia, Lucio Angnes, Solange K. Sakata
-
Tailoring hydron-halogen bond networks in heptazine architectures for controlled fabrication of high-performance C-doped porous carbon nitride photocatalyst Dalton Trans. (IF 3.3) Pub Date : 2025-06-23 Jiawei Xia, Yuming He, Yongke Hu, Ting Hu, Yuxuan Tong, Xingyue Qian, Xue Chen, Guangyu He, Haiqun Chen
The fast massive sublimation of small N-rich monomers due to poor thermal stability for carbon nitride (CN) material synthesis based on supramolecular assembly technique usually causes defects and insufficient integrity that inhibit charge migration for a better photoactivity. Herein, we introduced a highly thermal stable supramolecular assembly of C-doped melem with HCl for the controllable synthesis
-
Visible-light-driven photocatalytic CO2 reduction using ruthenium complexes having a CNC-type pincer ligand: comparison of substituent effect on a CNC ligand Dalton Trans. (IF 3.3) Pub Date : 2025-06-18 Yasuhiro Arikawa, Momo Morinaga, Miyu Kubota, Kenichiro Omoto, Eri Sakuda, Keisuke Umakoshi
-
A series of pinwheel-shaped Ln21-oxo-cluster-embedded polyoxometalates as single-crystal proton-conductive and tunable photoluminescent materials Inorg. Chem. Front. (IF 6.4) Pub Date : 2025-06-22 Yun-Fei Cao, Xinrong Jin, Wen-Jun Xia, Yan-Qiong Sun, Xin-Xiong Li, Shou-Tian Zheng
The integration of high-nuclearity lanthanide-oxo (Ln-O) clusters into polyoxotungstates (POTs) represents a formidable synthetic challenge due to intricate assembly mechanisms and the labile nature of lanthanide coordination. Herein, we present an innovative alkaline-mediated templating strategy for constructing unprecedented Ln-oxo-cluster-encapsulated POTs through synergistic assembly of lacunary
-
Anticancer Iron–Iridium Organometallic Conjugates Inorg. Chem. (IF 4.3) Pub Date : 2025-06-21 Chiara Zappelli, Zhimei Xiao, Silvia Schoch, Viviana Barberio, Marco Bortoluzzi, Gilles Gasser, Fabio Marchetti
The diiron vinyliminium complexes [Fe2Cp2(CO)(μ-CO){μ-η1:η3-C(3-C5H4N)CHCN(R)(Me)}]CF3SO3 (Cp = η5-C5H5; R = 2,6-C6H3Me2 = Xyl, 2a, R = Me, 2b) reacted with [IrCp*(Phpy)Cl] (IrCl; Cp* = η5-C5Me5, Phpy = κN,κC-2-phenylpyridine) and AgCF3SO3 to afford the bis-cationic iron–iridium conjugates [Fe2Cp2(CO)(μ-CO){μ-η1:η3-C(3-C5H4NIrCp*Phpy)CHCN(Me)(R)}][CF3SO3]2 (4a–b), in nearly quantitative yields. Similarly
-
Stable astatine-metal bond in gold-based carriers for targeted alpha-particle therapy: role of charge-shift bonding Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-21 Samuel D Mador, Franck Fuster, François Guérard, Julien PILME, Nicolas Galland
211At is a highly attractive radionuclide for alpha-particle therapy of cancers, provided it is firmly bounded to a suitable targeting agent. In recent years, various radiolabeled gold nano-objects have been evaluated in vitro and in vivo, drawing on the formation of a covalent bond between astatine and gold atoms. While stability was found for 211At-labeling of Au(I)-NHC (NHC = N-heterocyclic carbene)
-
A Hybrid Bronze Age: Progress and Potential in Mixed-Valence Organic–Inorganic Metal Oxides Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 W. Lakna N. Dayaratne, Raúl Torres-Cadena, Anton F. Walte, Suchen Wan, Joshua Morales Campos, Adam Jaffe
-
Cation–Cation Interactions in Neptunium(V,VI)-diglycolamide System Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Christelle Tamain, Matthieu Autillo, Dominique Guillaumont, Luca Briscese, Claude Berthon
-
Experimental Evaluation of the Hydricity of Hydrosilanes Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Laurent Sévery, Emmanuel Nicolas, Alexis Mifleur, Thibault Cantat
-
Sequential Separation of Metal Cations Using Nor-seco-cucurbit[10]uril as a Supramolecular Material Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Ran Cen, Li-Xia Chen, Shang-Wei Yuan, Cheng-Hui Wang, Qing-Hong Bai, Li Zeng, An-Ting Zhao, Hou-Jing Liu, Xin Xiao
-
High-Entropy Germanide (RuRhPdPt)1–xIrxGe: Synthesis, Phase Stability, and Transport Properties Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Yuto Muramatsu, Kengo Miyata, Daigorou Hirai, Koshi Takenaka
-
The Variable Di(mesityl)boroxide Coordination Chemistry of the Lanthanide Metals Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Kito Gilbert-Bass, Domonic Caruth, Tyler Kerr, Joseph W. Ziller, William J. Evans
-
Delta/Lambda Chirality: From Enantiomers to Diastereomers in Heterometallic Complexes with Chelating Ligands Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Yuxuan Zhang, Haixiang Han, Zheng Wei, Muhammad Zulqarnain, Tieyan Chang, Yu-Sheng Chen, Evgeny V. Dikarev
-
Werner Complexes Can Still Surprise: The Chelated O2BOH2– Ligand Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Jinming Yang, Erin M. Leitao, Mitchell A. Nascimento, Timothy D. Christopher, Tilo Söhnel, Tony Chen, Lawrence R. Gahan, Allan G. Blackman
-
Cation Exchange as a Route to Introduce Magnetism to Hybrid-Improper Polar Phases Inorg. Chem. (IF 4.3) Pub Date : 2025-06-20 Rachel Conway, Fabio Orlandi, Pascal Manuel, Yujie Zhang, P. Shiv Halasyamani, Michael A. Hayward
-
Fluctuating Behavior and Ligand-Dependent Reactivity of Isocyanates with Bis(pentafulvene)titanium Complexes Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Marcel Eilers, Tobias Bötel, Kevin Schwitalla, Marc Schmidtmann, Rüdiger Beckhaus
-
Effect of Nanocrystal Shape on Charge Injection and Transport in CdSe Nanocrystalline Films Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Mrinmoy Roy, Ehsan Rezaie Ahari, Štefan Nagy, Milan Sýkora
-
Polar Lithium l-Aspartate Monohydrate: A Semiorganic Ultraviolet Transparent Nonlinear Optical Crystal Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Yong Wang, Zhiyong Bai, Shanshan Chen, Xu Chen, Liangmeng Zhu, Tao Ouyang, Yanqiang Li, Weiqi Huang, Yipeng Song, Sangen Zhao, Junhua Luo
-
1,4-Phosphagermines: An Anionic 6π-heteroaromatic Biradicaloid and a Persistent π-Delocalized Radical Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Surendar Karwasara, Philipp C. Brehm, Tatjana Terschüren, Mridhul Ramachandran, Rosa M. Gomila, Gregor Schnakenburg, Takahiro Sasamori, Olav Schiemann, René T. Boeré, Antonio Frontera, Rainer Streubel
-
Magnesium-Catalyzed Primary, Secondary, and Tertiary Amide Hydroboration Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Biplab Mahata, V. Devaraj, Soumya Ranjan Dash, Rajesh G. Gonnade, Kumar Vanka, Sakya S. Sen
-
Charge Transfer Stimulated Visible-Light Photochromism of Naphthalenediimide-Based Zinc Halide Coordination Polymers for Detecting/Filtrating Harmful Blue Rays Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-20 Xiaojuan Zhang, Ming Kang, Shimin Zhang, Jingfang Wang, Yifang Zhang, Pengfei Hao, Junju Shen, Yunlong Fu
Due to high penetration, low photo-toxicity, and low background signal of red-shifted visible light, the development of visible-light photochromic materials is of great importance but still a challenging task. In this study, four one-dimensional (1D) naphthalenediimide (NDI) photochromic coordination polymers (CPs), namely {[ZnCl2(4-PMNDI)]·H2O}n (1), {[ZnBr2(4-PMNDI)]·2H2O}n (2), {[ZnCl2(3-PMNDI)]}n
-
Active CuxCo1−xAl2O4 spinel catalysts with potent SO2 tolerance for toluene combustion: Measuring Cu substitution capacity in spinel lattice with XRD extrapolation Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-20 Junhua Cao, Haojun Liu, Zhang Shijing, Teng Liu, Yu Lv, Zhiqiang Wu, Xianglan Xu, Junwei Xu, Xiuzhong Fang, Xiang Wang
To obtain more applicable catalysts with sulphur and water vapor tolerance for toluene combustion, CuxCo1−xAl2O4 compounds by substituting Co−site of CoAl2O4 spinel with different amount of Cu have been purposely designed. For the first time, the XRD extrapolation method has been adopted to measure the substitution capacity of Cu2+ in the spinel matrix, which is with an x = 0.53. Below the capacity
-
Coinage metal(I) clusters based on a flexible P,P′(N,N′)2-ligand: colorful phosphorescence, abnormal thermal quenching behavior and anticounterfeiting application Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-16 Andrey Yu. Baranov, Evgeniya P. Doronina, Mariana I. Rakhmanova, Irina Yu. Bagryanskaya, Konstantin A. Brylev, Taisiya S. Sukhikh, Alexander V. Artem'ev
-
Addressing misconceptions in dithiocarbamate chemistry Dalton Trans. (IF 3.5) Pub Date : 2025-06-20 David Pugh, Graeme Hogarth
Dithiocarbamates are monoanionic chelating ligands, easily prepared from CS2 and secondary or primary amines, that find widespread use in agriculture, medicine, materials science and coordination chemistry. This is (in part) due to their ability to stabilise metals in a wide range of oxidation states, a result of soft (dithiocarbamate) and hard (thioureide) resonance forms. However, in the many thousands
-
Stability and relaxometric characterization of a manganase(II) based macrocyclic complex containing malonate pendant Dalton Trans. (IF 3.5) Pub Date : 2025-06-20 Abraham Debretsion, Szilvia Bunda, Norbert Lihi, Zoltán Garda, Sabine Van Doorslaer, Emese Kun, Tibor Csupász, Gyula Tircsó, Eva J Toth, Ferenc Krisztián Kálmán
In this study, we report the thermodynamic, kinetic, relaxation and structural features of the Mn(II) complex formed with a newly synthetized O-pyclen ligand bearing a malonate pendant. The thermodynamic stability of [Mn(OPMMA)] is lower (pMn = 6.27) than that reported for the Mn(II) chelates of OPC2A (pMn = 8.69) and 3,9-PC2A ligands (pMn = 8.64), and it dissociates faster than those at physiological
-
2D Borophene: An Emerging Material for Supercapacitor Applications Dalton Trans. (IF 3.5) Pub Date : 2025-06-20 Gopinath Sahoo, Sang Mun Jeong, Chandra Sekhar Rout
The progress of high-performance supercapacitor electrode based on emerging 2D materials have received tremendous attention due to their high power density (> 10 kW kg-1) and long charge-discharge cycle life (>105 cycles). Having discovered in 2015, 2D borophene has emerged as a unique material among Xenes due to its excellent electron mobility, metallic behaviour, thermal conductivity, Dirac nature
-
Design of new thorium nuclear clock materials based on polyatomic ions Dalton Trans. (IF 3.3) Pub Date : 2025-06-17 Harry W. T. Morgan, Hoang Bao Tran Tan, Andrei Derevianko, Ricky Elwell, James E. S. Terhune, Eric R. Hudson, Anastassia N. Alexandrova
-
Preyssler-Type POM-Based CPs Incorporating V-Type N-Heterocyclic Ligands as Proton Conductors Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Jun-Jie Cai, Jin Han, Yu Nie, Kun Gao, Wei Li, Jing-Qi Zhang, Hui-Jie Lun, Ya-Min Li
-
Understanding Reactive Sulfur Species Storage from Hybrid S/N Crosstalk Species: Perthionitrite (SSNO–) and Thionitrite (SNO–) Activation by a Mononuclear Nonheme FeII Complex Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Keyan Li, Juan F. Hernandez, George W. Piepgras, Lev N. Zakharov, Michael D. Pluth
-
Modification of Hydrophobic and Hydrophilic Features in Isostructural 3D Pillar-Layered Coordination Polymers for Adsorption Studies Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Jitti Suebphanpho, Sujitra Tunsrichon, Xin Zheng, Yun Chen, Shin-ichiro Noro, Jaursup Boonmak
-
Degradation of Organophosphorus Pollutants into Inorganic Phosphates by Co(II)/NaBO3 System and Its Phosphorus Recycling Inorg. Chem. (IF 4.3) Pub Date : 2025-06-19 Huan Luo, Xiaohong Liu, Huibin Niu, Yingping Huang, Lei Jin, Zhongxu Dai, Jun Jin, Junjie Wang, Di Huang, Xiang Liu
-
Investigating the Mechanism of Selective Adsorption of Nucleoside Compounds by Hydrophilic Flower-Like Zr-MOF Nanosheets Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Tao Cheng, Lu Liu, Jia Hui Chen, Pan Wang, Jian Ming Pan
-
Ternary Antimony Selenide Semiconductors: Synthesis, Crystal Structure, Electronic Structure, and Optical Properties Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 James Pirez, Subhendu Jana, Eric Gabilondo, Scott McGuigan, P. Shiv Halasyamani, Paul A. Maggard
-
Enhanced Photostability in Aqueous-Prepared MAPbBr3@polymer Films through Ligand-Regulated Exciton Binding Energy and Radiative Recombination Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Jinliang Jiang, Chaoyi Chen, Hao Zhang, Hui Xie, Kai Li, Weiyou Yang, Jinju Zheng, Hui Fu
-
Mechanistic Investigations of Selective Alkoxysilane Substitutions by Primary Lithium Amides: From Mono- to Di- and Trisubstituted Si–N-Functionalized Silanes Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Jan-Lukas Kirchhoff, Tristan Mairath, Mara Schöler, Robin Risken, Carsten Strohmann
-
Engineering Pore Chemistry and Environment in Robust Metal–Organic Frameworks for One-Step C2H4 Purification from Ternary Mixtures Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Xue Wang, Jiacheng Li, Tao Zhao, Aziz Bakhtiyarovich Ibragimov, Junkuo Gao
-
In-situ sulfidation induced Bi2S3 heterogeneous phase on CuBi2O4 for boosting photoelectrochemical ammonia production Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-19 Xiaohong Wang, Pengpeng Yang, Zhonghua You, Longbao Yu, Chen Hao, Xiaoqi Fu, Hongye Bai, Guohai Xu, Weiqiang Fan
Photoelectrochemical nitrate reduction reaction (PEC-NIRR) provides a sustainable solution for addressing nitrogen-containing wastewater pollution and green ammonia synthesis. However, the reported catalysts are still limited by issues such as low carrier separation efficiency and competition from the hydrogen evolution reaction (HER). A surface sulfidation strategy was employed to epitaxially grow
-
Ligand-to-ligand charge transfer in anthracene-based cyclic trinuclear complexes enhanced photocatalytic deprotection of Weinreb amides Inorg. Chem. Front. (IF 6.1) Pub Date : 2025-06-19 Yun-Zhou Guo, Hui-Zhi Wei, Xu-Hang Zhong, Cui-Zhou Luan, Rui Zhou, Bingzhe Wang, Ji Zheng, Shang-Fu Yuan, Tao Wu, Dan Li
The development of efficient, visible-light-responsive photocatalysts remains critical for advancing sustainable chemical synthesis. Herein, we report a photosensitive cyclic trinuclear complex (CTC), An-Au3, featuring an anthracene (donor) and trifluoromethyl (acceptor) modified pyrazole ligand (donor–π–acceptor type ligand engineering), where the anthracene chromophore and weak metallophilic interactions
-
Assessing structure and dynamics of iron complexes supported by tris(amidate)amine ligands Dalton Trans. (IF 3.5) Pub Date : 2025-06-19 Lucy Huffman, Anjana Seshadri, Christopher D. Hastings, William W. Brennessel, Ignacio Franco, Brandon R. Barnett
Chelating ligand platforms derived from tris(2-aminoethyl)amine (TREN) can facilitate low coordination numbers and provide opportunities to tune the steric and electronic profile of the secondary coordination sphere. Herein, we examine the ability of two related tris(amidate)amine ligands to stabilize low-coordinate complexes of trivalent iron, and further use molecular dynamics (MD) simulations to
-
Bifunctional MOFs possessing both proton conductivity and fluorescence detection capabilities Dalton Trans. (IF 3.5) Pub Date : 2025-06-16 Yining Zhang, Xuebin Shang, Zhiyang Qi, Penglin Zhang, Chenxi Zhang, Qinglun Wang
-
Targeting One Precise Aggregation-Induced Emission (AIE) Mechanism to Design Indolocarbazole-Based AIE-Active Phosphorescent Pt(II) Complex and Its Anion Sensing Property Inorg. Chem. (IF 4.3) Pub Date : 2025-06-18 Qingqing Feng, Chunliang Yang, Chenghui Wang, Qingmei Ge, Jiang Zhao