-
A mixed-valence CuI/CuII metal-organic framework for CO2 conversion Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-26 Yu-Mei Wang, Kai-Ming Mo, Dong Luo, Mei-Xia Tao, Xu Chen, Guo-Hong Ning, Dan Li
The development of noble-metal-free and efficient metal-organic frameworks (MOFs) as hetergenous catalysts for carbon dioxide (CO2) conversion is particular interest, but remains challenging. In this study, a CuⅠ/CuⅡ mixed-valent MOF (1) was synthesized, consisting of copper(I) cyclic trinuclear units (CuI-CTUs) and CuII-paddlewheel units. The MOF featured a (3,4,4-c) network topology, which is rarely
-
Pyramidal Inversion in the Solid State Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-26 Robin Turnbull, Javier Gonzalez-Platas, Alfonso Munoz, Josu Sanchez-Martin, M Jasmin, Gaston Garbarino, Daniel Errandonea, Akun Liang
Pyramidal inversion is a stereochemical phenomenon that describes the interconversion between two equivalent pyramidal configurations of the same chemical species. Using the IO3 molecule as a prototypical trigonal pyramidal unit, pyramidal inversion has been observed in the solid state by applying hydrostatic pressure to crystals of barium di-iodate monohydrate, Ba(IO3)2⋅H2O, without chemical reaction
-
Visible-Light-Active Benzothiadiazole-based MOFs as Efficient ROS Generator for the Synthesis of Benzimidazole and Benzothiazole Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-26 Hua Liu, Wenwen Yi, Quan-Quan Li, Shu-Ya Zhao
The utilization of reactive oxygen species (ROS) in photochemical synthesis has garnered significant attention owing to their exceptional oxidative capacity under mild conditions. Recently, metal-organic frameworks (MOFs) have been employed to transfer molecular oxygen (O2) to ROS for photocatalysis. However, visible-light-active MOFs for effective oxygen activation remains scarce. Herein, a simple
-
Electronic structures of two-dimensional covalent organic frameworks based on a series of period 4 transition metal phthalocyanines and ethynyl moieties Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-26 Xin Chen, Xianran Xing
-
Universal synthesis of coral-like Ternary MOF-Derived Sulfides as efficient OER electrocatalysts Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-26 Tianpeng Liu, Yangping Zhang, Jun Yu, Mengyun Hu, Zhengying Wu, Xiao Wei, Shudi Yu, Yukou Du
The strategy of synthesizing a high-efficiency oxygen evolution reaction (OER) catalysts by sacrificing metal-organic frameworks (MOF) templates is considered promising. However, few reports have focused on improving the intrinsic electrocatalytic activity of the MOF templates. Herein, we have developed an universal synthesis method to synthesize a series of ternary coral-like FeNiM (M = Zn, Co and
-
Synergy of experimental and computational chemistry: structure and biological activity of Zn(II) hydrazone complexes Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Milica Savić, Andrej Pevec, Nevena Stevanović, Irena Novaković, Ivana Z. Matić, Nina Petrović, Tatjana Stanojković, Karla Milčić, Matija Zlatar, Iztok Turel, Božidar Čobeljić, Miloš Milčić, Maja Gruden
-
Inorganic Chemistry Frontiers welcomes the inaugural Early Career Advisory Board Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-25
-
Copper dopants facilitated generation of high-valent cobalt sites for improved oxygen evolution Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-25 Jingrui Han, Jieshu Zhou, Hao Zhang, Haibin Wang, Kangning Liu, Xuhui Sun, Lihua Liu, Hongyan Liang
Developing a reliable strategy to adjust dynamic reconstruction and formation of active oxygen species on electrocatalyst surfaces is crucial for enhancing OER performance and still needs further elaborate elucidation. Here, we report a strategy for adjusting surface reconstruction of Co4N, in which inert Co3O4 on the reconstruction surface is activated via Cu introducing (Cu-Co4N), and facilitates
-
Effects of Fe-doping induced by valence modulation engineering on the nickel hydroxyfluoride cathode of hybrid supercapacitors Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-25 Yutong Zhao, Zeshuo Meng, Jian Xu, Zhengyan Du, Zeyu Hao, Shulong Wang, Hongwei Tian, Zhiqiang Niu, Dawei Su
-
Exposing coordination-unsaturated Co sites in Co-MOF for efficient photocatalytic water oxidation Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-22 Jie-Yi Zhou, Xin-Yu Guan, Hui-Ping Zhang, Dong Luo, Xusheng Wang, Xiao-Ping Zhou, Dan Li
-
Cancer Phototherapy by CO Releasing Terpyridine-Based Re(I) Tricarbonyl Complexes via ROS Generation and NADH Oxidation Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Rajesh Kushwaha, Aarti Upadhyay, Sukanta Saha, Ashish Kumar Yadav, Arpan Bera, Arnab Dutta, Samya Banerjee
Here, we have synthesized and characterized three visible light responsive terpyridine based-Re(I)-tricarbonyl complexes; [Re(CO)3(ph-tpy)Cl] (Retp1), [Re(CO)3(an-tpy)Cl] (Retp2), and [Re(CO)3(py-tpy)Cl] (Retp3) where ph-tpy = 4'-phenyl-2,2':6',2''-terpyridine; an-tpy = 4'-anthracenyl-2,2':6',2''-terpyridine, py-tpy = 4'-pyrenyl-2,2':6',2''-terpyridine. The structure of Retp1 and Retp2 were confirmed
-
Effect of the heteroatom on the magnetic and luminescent properties of hybrid lanthanide-substituted Keggin-type polyoxometalates Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Janire Bustamante-Fernández, Estibaliz Ruiz-Bilbao, Corina Rodríguez-Esteban, Mathieu Gonidec, Jose Angel Garcia, Luis Lezama, Juan Manuel Gutierrez-Zorrilla, Itziar Oyarzabal, Beñat Artetxe
Replacement of the heteroatom from Si to Ge has a strong influence on the luminescent properties of a series of hybrid, sandwich-type K5[Ln(α-GeW11O39)(C20H22Br2N2O4)]·14H2O (1Ge-Ln, Ln = Sm to Lu) anions. Interestingly, the Gd and Yb derivatives retain their ability to display slow relaxation of magnetisation.
-
Copper(I) Complexes Bearing the Pyrrole-Bridged S,N and N-Donor Ligands as Catalysts for the Tandem Hydroamination-Alkynylation: Effect of Anions on Product Formation Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Ganesan Mani, Munmun Mondal
The reaction between 2-(3,5-dimethylpyrazolylmethyl)-5-(dimethylaminomethyl)pyrrole and thiophenol under heating conditions afforded the new ligand 2-(3,5-dimethylpyrazolylmethyl)-5-(phenylthiomethyl)pyrrole 2. The reaction of 2 with meta-chloroperbenzoic acid gave the sulfoxide 3 and sulfone 4 groups containing ligands. The reaction of 2 with copper(I) halides gave the binuclear complexes: [Cu(-
-
Hydrothermal synthesis of (Zr,U)SiO4, an efficient pathway to incorporate uranium in zircon Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Paul Estevenon, Thomas Barral, Arthur Avallone, Mateo Jeffredo, Alexis De La Hos, Andrew Strzelecki, Xavier F Le Goff, Stéphanie Szenknect, Kristina O. Kvashnina, Philippe Moisy, Renaud Podor, Xiaofeng Guo, Nicolas Dacheux
The preparation of synthetic (Zr,U)SiO4 solid solution is a challenging operation, as the conventional high temperature solid state method limits the solubility of uranium (4 ± 1 mol.%). in the orthosilicate phase due to is thermodynamic instability. However, these compounds are of great interest as (Zr,U)SiO4 solid solutions with uranium contents exceeding this concentration, were observed in corium
-
Facile synthesis of five-membered cyclic RE2P–H iron(0) complexes Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Philipp C. Brehm, Gregor Schnakenburg, Rainer Streubel
-
Er3+/Tm3+ co-doped Zr0.85Y0.15O1.925:Yb3+ phosphors: Dual-mode ratiometric thermometry based on near infrared up-conversion/down-shifting photoluminescence Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Takuya Hasegawa, Yuki Takahashi, Tomoyo Goto, Yasushi Sato, Ayahisa Okawa, Shu Yin
Ratiometric thermometry is among the emerging applications in phosphor materials. Particularly, the technique of ultrafine-space thermometry has garnered significant attention in bio-imaging. Near-infrared (NIR) light, with its high tissue permeability, serves not only as an excitation source for up-conversion photoluminescence (UCPL) but also induces down-shifting photoluminescence (DSPL) at longer
-
Phenalenyl-ruthenium synergism for effectual catalytic transformations of primary amines to amides Dalton Trans. (IF 3.5) Pub Date : 2024-07-25 Nilaj Bandopadhyay, Krishnendu Paramanik, Gayetri Sarkar, Suvojit Roy, Subhra Jyoti Panda, Chandra Shekhar Purohit, Bhaskar Biswas, Hari Sankar Das
Synthesis of amides holds great promise for their impeccable contributions as the building blocks for highly-valued functional derivatives. Herein, we disclose the design, synthesis and crystal structure of a mixed-ligands ruthenium(II) complex, [Ru(6-Cym)(O,O-PLY)Cl], (1) where Cym = 1-isopropyl-4-methyl-benzene and O,O-PLY = deprotonated form of 9-hydroxy phenalenone (HO,O-PLY). The complex catalyzes
-
Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Fang-Che Hsueh, Luciano Barluzzi, Thayalan Rajeshkumar, Rosario Scopelliti, Ivica Zivkovic, Laurent Maron, Marinella Mazzanti
-
Aza-metallacycles with a heptavalent Re (d0) center Dalton Trans. (IF 3.5) Pub Date : 2024-07-22 Qianhang Wang, Yarong Wang, Yue Zhao, Yang Li, Wenfeng Jiang, Wei Bai
-
Unravelling the Mechanism of Apoptosis Induced by Copper(II) Complexes of NN2-Pincer Ligands in Lung Cancer Cells Dalton Trans. (IF 3.5) Pub Date : 2024-07-24 Athulya Das, Muniyandi Sankaralingam
The invention of efficient chemotherapeutic drugs is essential for human health and development. Keeping this in mind, a series of copper(II) pincer complexes, 1–4 of ligands L1(H) = 2-morpholino-N-(quinolin-8-yl)acetamide, L2(H) = 2-di-n-propylamino-N-(quinolin-8-yl)acetamide, and L3(H) = 2-di-n-butylamino-N-(quinolin-8-yl)acetamide and L4(H) = 2-di-n-benzylamino-N-(quinolin-8-yl)acetamide have been
-
Amine-directed synthesis, valence state control, and optical properties of two new organic–inorganic tin chlorides Dalton Trans. (IF 3.5) Pub Date : 2024-07-20 Xuemei Wen, Gangji Yi, Zhizhuan Zhang, Caihong Guo, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin
-
Multifunctional Near-Infrared Phosphors Cr3+/Ni2+ Codoped Mg3Ga2GeO8 Based on Energy Transfer from Cr3+ to Ni2+ Inorg. Chem. (IF 4.3) Pub Date : 2024-07-24 Chengqian Wang, Yaping Niu, Yun Wang, Fugen Wu, Qi Zhang, Yun Teng, Huafeng Dong, Zhongfei Mu
-
Thorium Cluster Synthesized by a Solvent-Free Flux Approach: The Richest Coordination Diversity and Application Exploration Inorg. Chem. (IF 4.3) Pub Date : 2024-07-24 Dan Zhou, Yang Yang, Zhehui Weng, Jueqiong Wang, Yizhou Yan, Liwei Cheng, Yingtong Fan, Lixi Chen, Hailong Zhang, Long Chen, Yanlong Wang, Shuao Wang
-
Synthesis and Luminescence Studies of a Tethered, Trigonal, Silver(I) Tris(alkyne) Complex Inorg. Chem. (IF 4.3) Pub Date : 2024-07-24 Maxwell H. Furigay, Brett D. Vincenzini, Jun Gu, Michael R. Gau, Eric J. Schelter
-
Thiol–Amino Bifunctional Metal–Organic-Framework-Based Membrane Regulating Hydrophobic Sites for Selective Separation of Artesunate Inorg. Chem. (IF 4.3) Pub Date : 2024-07-24 Chuanxun Zhang, Bo Hu, Jiajia Ren, Wanqi Du, Minjia Meng
-
Electron Tandem Transport Channel in a Cu3P/Sv-ZnIn2S4 p–n Heterojunction for Photothermal-Photocatalytic Benzyl Alcohol Oxidation and H2 Production Inorg. Chem. (IF 4.3) Pub Date : 2024-07-24 Haopeng Jiang, Jinghang Xu, Lijuan Sun, Jinhe Li, Lele Wang, Weikang Wang, Qinqin Liu, Juan Yang
-
DMNP as an Effective Cage for Ln3+: A Spectroscopic and Thermodynamic Study Inorg. Chem. (IF 4.3) Pub Date : 2024-07-23 Walter G. Gonzalez, Setareh Sakhdari, Md Shofiul Alam, Gangadhar Dhulipala, Konstantinos Kavallieratos, Jaroslava Miksovska
-
Comparative Study on the Proton Conduction Behaviors of Two Acidic Amphiphilic and Hydrophilic Coordination Compounds in Nafion Composite Membranes Inorg. Chem. (IF 4.3) Pub Date : 2024-07-23 Huiqi Zou, Zhipeng Huan, Na Wang, Jing Lu, Houting Liu, Suna Wang, Yunwu Li
-
Aggregation-Induced Emission Phosphorescence Featured Au–Ag Coordination Polymer with a Diphosphine N-Heterocyclic Carbene Ligand for Highly Sensitive Detection of Cr(VI) Inorg. Chem. (IF 4.3) Pub Date : 2024-07-23 Sisi Yan, Yuanyuan Hu, Lin Cui, Mengyao Feng, David James Young, Hong-Xi Li, Xuewen He, Chengrong Lu, Zhi-Gang Ren
-
Minimal Functionalization of Ruthenium Compounds with Enhanced Photoreactivity against Hard-to-Treat Cancer Cells and Resistant Bacteria Inorg. Chem. (IF 4.3) Pub Date : 2024-07-23 Geângela de Fátima Sousa Oliveira, Florencio Sousa Gouveia, Jr., Alexandre Lopes Andrade, Mayron Alves de Vasconcelos, Edson Holanda Teixeira, Marcos V. Palmeira-Mello, Alzir A. Batista, Luiz Gonzaga de França Lopes, Idalina Maria Moreira de Carvalho, Eduardo Henrique Silva Sousa
-
Utilizing Domain Engineering to Achieve High-Polarization Relaxor Ferroelectrics for Low-Consumption Ceramic Capacitors Inorg. Chem. (IF 4.3) Pub Date : 2024-07-23 Zixiong Sun, Liming Diwu, Yongming Hu, Shibo Zhao, Jingru Xu, Ting Wang, Yongping Pu, Zhuo Wang
-
A Palladium-Containing Polyoxotungstate with Anisotropic Proton Conductivity Inorg. Chem. (IF 4.3) Pub Date : 2024-07-23 Lei Jia, Yi-Xin Liu, Xin-Xiong Li, Cai Sun, Shou-Tian Zheng
-
Achieving Cr6+-free Cr3+-activated spinel phosphor by one-step solid-state reaction Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-24 Yiqing Zhou, Quantian Cao, Yue Han, Zhongxian Qiu, Jilin Zhang, Wenli Zhou, Shixun Lian
Cr3+-doped oxide phosphors attract increasing attention due to their tunable photoluminescence and versatile applications. Meanwhile, a hidden danger of toxic Cr6+-formation during the synthesis of Cr3+ phosphors should also be emphasized. Herein, a co-doping strategy of Bi3+ to spinel-typed ZnAl2O4:Cr3+ phosphor is performed and thoroughly suppresses the formation of Cr(Ⅵ). As a result, an environmentally
-
Fluoride-free synthesis of high-silica RHO zeolite for the highly selective synthesis of methylamine Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-22 Yufei Wang, Jinfeng Han, Keyan Jin, Shuang Liu, Qiang Li, Pan Hou, Shiping Liu, Qi Song, Zhendong Wang, Peng Tian, Wenfu Yan
-
Enhancing Catalytic Properties of Silicalite-1 through Ammonium Fluoride Modification for Waste Glycerol Acetalization Dalton Trans. (IF 3.5) Pub Date : 2024-07-24 Jolanta Kowalska-Kuś, Ewa Janiszewska, Kinga Góra-Marek, Aldona Jankowska, Agnieszka Held
Silicalite-1 is a silica with a zeolitic MFI (Mobil Five) structure devoid of noticeable catalytically active (e.g. acid) sites. In this study, we present its modification with NH4F solutions of varying concentrations (0.5-3 M), which generates efficient and selective acid sites for the acetalization of glycerol with acetone towards solketal (2,2-dimethyl-1,3-dioxolane-4-methanol). The creation of
-
Ni(II) and Pd(II) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(II)-assisted intraligand cyclization forms phenoxazinyl ring Dalton Trans. (IF 3.5) Pub Date : 2024-07-24 Saumitra Bhowmik, Arunava Sengupta, Rabindranath Mukherjee
Square planar complexes of Ni(II) and Pd(II) of a new redox-active pentadentate azo-appended 2-aminophenol ligand (H4L = N,N'-bis(2-hydroxy-3,5-di-tert-butylphenyl)-2,2'-diamino-ortho-azobenzene) in three accessible redox levels [amidophenolate(2−), semiquinonate(1−) π radical and quinone (0)] have been synthesized. The coordinated HL(3−) ligand provides effectively four donor sites [two N(iminophenolates)
-
Theoretical Exploration of Single-Molecule Magnetic and Single-Molecule Toroic Behavior in Peroxide-Bridged Double-triangular {MII3LnIII3} (M = Ni, Cu and Zn; Ln = Gd, Tb and Dy) Complexes Dalton Trans. (IF 3.5) Pub Date : 2024-07-24 Amit Gharu, Kuduva R. Vignesh
Detailed state-of-the-art ab initio and Density functional theory (DFT) calculations have been undertaken to understand both Single-Molecule Magnetic (SMM) and Single-Molecule Toroic (SMT) behavior of fascinating 3d-4f;{M3Ln3} triangular complexes having a molecular formula [MII3LnIII3(O2)L3(PyCO2)3](OH)2(ClO4)2·8H2O (when M = Zn; Ln = Dy (1), Tb (2) & Gd (3) and M = Cu; Ln = Dy (4), Tb (5) & Gd (6))
-
Decrypting the hydrogen evolution in alkaline water with newfangled magnetoactive cobalt(II) complexes-driven cobalt oxide electrocatalysts Dalton Trans. (IF 3.5) Pub Date : 2024-07-24 Subhajit Saha, Nilankar Diyali, Sangharaj Diyali, Subhra Jyoti Panda, Mainak Das, Sobhna Acharya, Prafullya Kumar Mudi, Monika Singh, Partha Ray, Chandra Shekhar Purohit, Bhaskar Biswas
Under the gravity of future socio-economic development, the viability of water electrolysis still hinges on the accessibility of stable earth-abundant electrocatalysts and net energy efficiency. This work emphasizes the design and synthesis of two newly developed cobalt(II) complexes, [Co(HL)2(NCS)2] (Comono) and [Co2(L)3(CH3OH)]ClO4 (Codi) with a (N,O)-donor ligand, HL (2-methoxy-6-(((2-methoxyph
-
Gastric stability of bare & chitosan-fabricated ferritin and its bio-mineral: Implication towards potential dietary iron supplement Dalton Trans. (IF 3.5) Pub Date : 2024-07-24 Rohit Kumar Raut, Gargee Bhattacharyya, Rabindra K Behera
Iron deficiency anaemia (IDA), the most widespread nutritional disorder, is a persistent global health issue affecting millions, especially in resource-limited geographies. Oral iron supplementation is usually the first choice for exogenous iron administration due to its convenience, effectiveness and low cost. However, commercially available iron supplementations are often associated with oxidative
-
Colloidal synthesis of two-dimensional nanocrystals by the polyol route Dalton Trans. (IF 3.5) Pub Date : 2024-07-19 Tanner Q. Kimberly, Michelle H. Frasch, Susan M. Kauzlarich
-
A green approach to encapsulate proteins and enzymes within crystalline lanthanide-based Tb and Gd MOFs Dalton Trans. (IF 3.5) Pub Date : 2024-07-19 Davide Tocco, Madhura Joshi, Rosangela Mastrangelo, Emiliano Fratini, Andrea Salis, Martin Hartmann
-
Dinuclear enantiopure Ln3+ complexes with (S-) and (R-) 2-Phenylbutirate Ligands. Luminescence, CPL and magnetic properties. Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Ànnia Tubau, Francesco Zinna, Lorenzo Di Bari, Merce Font-Bardia, Ramon Vicente
The reaction of Ln(NO3)2·6H2O (Ln = Nd, Sm, Eu, Tb, Dy, Tm and Yb) with the respective enantiopure (R)-(-)-2-Phenylbutyric or (S)-(+)-2-Phenylbutyric acid (R/S-2-HPhBut) and 4,7-Diphenyl-1,10-phenanthroline (Bphen) allows the isolation of chiral dinuclear compounds of formula [Ln2(-R/S-2-PhBut)4(R/S-2PhBut)2(Bphen)2] were Ln = Nd3+ (R/S-Nd-a), Sm3+ (R/S-Sm-a), Eu3+ (R/S-Eu-a), Tb3+ (R/S-Tb-a and R/S-Tb-b)
-
Tuning the Spin-Crossover properties of [Fe2] Metal-Organic Cages Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Laia Navarro, Arnau Garcia-Duran, Jordi Cirera
A computational study of the interplay between ligand functionalization and guest effect over the transition temperature (T1/2) in the [Fe2(L1R)3]@X (L1 = 1,3-bis-(3-(pyridin-2-yl)-1H-pyrazol-5-yl)benzene, X = H-, F-, Cl-, Br-, I- and [BF4]-, R = H, F, or CH3) family of metal-organic cages (MOCs) is presented. Our results indicate that ligand functionalization with electron-donor or electron-withdrawing
-
Aerial carbon dioxide conversion to carbonate mediated by the lead(II) complex with tridentate bipyridine containing hydrazide ligand under electrochemical conditions yielding single-component white light-emitting phosphors Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-23 Ghodrat Mahmoudi, Isabel Garcia-Santos, MARIA ELENA LABISBAL-VIQUEIRA, Alfonso Castineiras, Vali Alizadeh, Rosa Maria Gomila, Antonio Frontera, Damir Safin
Novel tetranuclear complex [Pb4L4(CO3)2]∙4H2O (1∙4H2O) is reported, which was obtained by electrochemical oxidation of a lead anode under the ambient atmosphere in a CH3CN:MeOH solution of N'-isonicotinoylpicolinohydrazonamide (HL). The CO32– anions were formed from conversion of the aerial CO2 by the Pb2+–L complex system under electrochemical conditions. In the structure of 1, both the ligands L
-
Correction: Mechanical force-driven multi-state memory in WO3−δ thin films Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-23 Mingdi Yang, Zonglin Lv, Shan Li, Jiaqi Li, Jinpeng Cao, Junjie Chen, Yilin Wang, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
Correction for ‘Mechanical force-driven multi-state memory in WO3−δ thin films’ by Mingdi Yang et al., Inorg. Chem. Front., 2024, 11, 3919–3926, https://doi.org/10.1039/D4QI00789A.
-
Superhydrophobic fluorinated metal–organic framework (MOF) devices for high-efficiency oil–water separation Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-07-18 Jiaqi Ma, Mingshi Zhang, Rui Feng, Lu Dong, Wei Sun, Yanyuan Jia
-
Eco-friendly Porous Composite of Octaphenyl Polyhedral Oligomeric Silsesquioxane and HKUST-1 with Hydrophobic-Oleophilic Properties towards Sorption of Oils and Organic Solvents Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Kanakarasu Dharmaraj, Mohandas Sanjay Kumar, Nallasamy Palanisami, Muthuramalingam Prakash, Pushparaj Loganathan, Swaminathan Shanmugan
The degradation of water bodies caused by organic pollutants from industrial wastewater discharge has made it necessary to develop new functional materials like hydrophobic-oleophilic materials that can efficiently remediate water. It is factual that many of the synthetic methods for creating hydrophobic-oleophilic materials involve the use of toxic or harmful reactants, such as fluorine or sulfur
-
EPR spectroscopic characterisation of native CuII-binding sites in human serum albumin Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Katrin Ackermann, Dongmei Wu, Alan J. Stewart, Bela E Bode
Human serum albumin (HSA) is the most abundant plasma protein, which functions to transport a large range of ligands within the circulation. These interactions have important implications for human health and disease. The primary binding site for CuII ions on HSA is known to be the so-called amino-terminal CuII and NiII binding (ATCUN) motif. However, the number and identity of secondary binding sites
-
Analysis of Antiproliferative activity of New Half-sandwich Arene Ru(II) thiophene based aroylhydrazone complexes Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Ramya Prabaharan, Abirami Arunachalam, Ramesh Rengan
Efforts in researching the efficient anti-tumor properties of three novel arene ruthenium(II) complexes incorporating thiophene-based aroylhydrazone ligands have been undertaken. The complexes' elemental composition was [(η6-p-cymene)Ru(L)Cl]. They were comprehensively characterized through elemental and spectroscopic analyses (FT-IR, UV-vis, NMR, and HR-MS). Single crystal X-ray diffraction studies
-
Dual role of arsenite in hydrolysis and post-hydrolysis fluorescence sensing of selective pH-dependent probe† Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Pushpendra Singh, Kalyan K. Sadhu
In comparison to sensing activities, reactivity studies of arsenite (AsO_2^-) is less explored. Herein, we have focused on AsO_2^- reactivity studies based on its pKa and compared the study with other common anions. All the three pKa values of arsenite are >9.0 and these afford a flexible pH working range to design the probe for reactivity studies. We have designed and synthesized six pH dependent
-
Step-scheme photocatalyst of CsPbBr3/BiOBr with oxygen vacancy for efficient CO2 photoreduction Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Wanjun Sun, Jifei Liu, Feitian Ran, Na Li, Zengpeng Li, Yuanyuan Li, Kai Wang
Metal halide perovskite with a suitable energy band structure and excellent visible-light response have emerged as promising photocatalysts for CO2 reduction to valuable chemicals and fuels. However, the efficiency of CO2 photocatalytic reduction is often suffered from inefficient separation and sluggish transfer. Herein, a step-scheme (S-scheme) photocatalyst of CsPbBr3/BiOBr with oxygen vacancy possessing
-
Synthesis and evaluation of bifunctional DFO2K: a modular chelator with ideal properties for zirconium-89 chelation Dalton Trans. (IF 3.5) Pub Date : 2024-07-23 Akam K. Salih, Elaheh Khozeimeh Sarbisheh, Shvan J. Raheem, Moralba Dominguez-Garcia, Hillary H. Mehlhorn, Eric W. Price
-
Group 11 complexes of a bulky triazene ligand Dalton Trans. (IF 3.5) Pub Date : 2024-07-18 Tanner George, Tamika Grant, Isadora Schumann Munhoz, Thai Do, Jason D. Masuda
-
A bimetallic NiFe MOF with ultra-thin two-dimensional nanosheet structure effectively accelerates oxygen evolution reaction Dalton Trans. (IF 3.5) Pub Date : 2024-07-18 Jiaqi He, Xin Deng, Wenting Sun, Wenjing Shang, Yongbing Lou, Jinxi Chen
-
Fabrication of bimetallic MOF-74 derived materials for high-efficient adsorption of iodine Dalton Trans. (IF 3.5) Pub Date : 2024-07-22 Wenze Li, Fu-Yu Guo, Jing Li, Xiao-Sa Zhang, Yu Liu, Jian Luan
Owing to their high porosity, open metal sites, and huge surface area, metal-organic framework (MOF) materials were commonly employed in iodine adsorption processes. Bimetallic MOFs had drawn a lot of attention since mono-metal MOFs were unable to keep up with the demand. Bimetallic MOFs materials still had drawbacks, including limited adsorption capacity, extended adsorption time, poor stability,
-
Slow Magnetic Relaxation in a Heteroleptic Anilate-based DyIII Metal-Organic Framework Dalton Trans. (IF 3.5) Pub Date : 2024-07-22 Mariangela Oggianu, Federica Bertolotti, Fabio Manna, Francesco Congiu, CLAUDIO MELIS, Antonio Cappai, Giorgio Concas, Narcis Avarvari, Maria Laura Mercuri, Norberto Masciocchi
Novel heteroleptic anilate-based lanthanide MOFs (LnIII= Tb, Dy, Ho) have been obtained under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally isomorphous species contain octacoordinated LnIII ions with coordination polyhedra approaching an ideal D2d symmetry, best described by a distorted biaugmented trigonal prismatic C2v geometry. In the whole series, only Dy-MOF
-
Topochemical Modulations from 1D Iron Fluoride Precursor to 3D Frameworks Inorg. Chem. (IF 4.3) Pub Date : 2024-07-22 Arindam Ghosh, Dereje Bekele Tekliye, Emily E. Foley, Varimalla Raghavendra Reddy, Raphaële J. Clément, Gopalakrishnan Sai Gautam, Premkumar Senguttuvan
-
A Porphyrin-Faced Zn8L6 Cage for Selective Oxidation of C(sp3)–H Bonds and Sulfides Inorg. Chem. (IF 4.3) Pub Date : 2024-07-22 Haoyu Zhai, Zhong Wei, Xu Jing, Chunying Duan
-
Low-Coordinate Iron Hydride Chemistry at an N,N,C-Heteroscorpionate Platform Inorg. Chem. (IF 4.3) Pub Date : 2024-07-22 Addison Fraker, Brittany N. Linn, Alex McSkimming
-
Phosphine versus Carbene Metal Interactions: Bond Energies Inorg. Chem. (IF 4.3) Pub Date : 2024-07-22 Damian P. Duda, Kyle C. Edwards, David A. Dixon