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Surface chemistry of gold nanoparticles for health-related applications Chem. Sci. (IF 9.556) Pub Date : 2020-01-15 Jiangjiang Zhang; Lei Mou; Xingyu Jiang
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Surface chemistry dictates stability and oxidation state of supported single metal catalyst atoms† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 Konstantinos Alexopoulos; Dionisios G. Vlachos
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Regio- and diastereoselective dearomatizations of N-alkyl activated azaarenes: the maximization of the reactive sites† Chem. Sci. (IF 9.556) Pub Date : 2019-12-17 Hong-Jie Miao; Le-Le Wang; Hua-Bin Han; Yong-De Zhao; Qi-Lin Wang; Zhan-Wei Bu
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A water-based and metal-free dye solar cell exceeding 7% efficiency using a cationic poly(3,4-ethylenedioxythiophene) derivative† Chem. Sci. (IF 9.556) Pub Date : 2020-01-14 Federico Bella; Luca Porcarelli; Daniele Mantione; Claudio Gerbaldi; Claudia Barolo; Michael Grätzel; David Mecerreyes
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Biomimetic O2 adsorption in an iron metal–organic framework for air separation† Chem. Sci. (IF 9.556) Pub Date : 2020-01-10 Douglas A. Reed; Dianne J. Xiao; Henry Z. H. Jiang; Khetpakorn Chakarawet; Julia Oktawiec; Jeffrey R. Long
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Metabolic inhibitors of bacterial glycan biosynthesis† Chem. Sci. (IF 9.556) Pub Date : 2020-01-08 Daniel A. Williams; Kabita Pradhan; Ankita Paul; Ilana R. Olin; Owen T. Tuck; Karen D. Moulton; Suvarn S. Kulkarni; Danielle H. Dube
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Tri-functional platform for construction of modular antibody fragments for in vivo18F-PET or NIRF molecular imaging† Chem. Sci. (IF 9.556) Pub Date : 2020-01-07 Raymond F. Gamache; Kirstin A. Zettlitz; Wen-Ting K. Tsai; Jeffrey Collins; Anna M. Wu; Jennifer M. Murphy
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Adsorption processes on a Pd monolayer-modified Pt(111) electrode† Chem. Sci. (IF 9.556) Pub Date : 2020-01-07 Xiaoting Chen; Laura P. Granda-Marulanda; Ian T. McCrum; Marc T. M. Koper
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Breaking scaling relations for efficient CO2 electrochemical reduction through dual-atom catalysts† Chem. Sci. (IF 9.556) Pub Date : 2020-01-06 Yixin Ouyang; Li Shi; Xiaowan Bai; Qiang Li; Jinlan Wang
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Tuning the stability of organic radicals: from covalent approaches to non-covalent approaches Chem. Sci. (IF 9.556) Pub Date : 2020-01-04 Bohan Tang; Jiantao Zhao; Jiang-Fei Xu; Xi Zhang
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Rotaxane PtII-complexes: mechanical bonding for chemically robust luminophores and stimuli responsive behaviour† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 Zhihui Zhang; Graham J. Tizzard; J. A. Gareth Williams; Stephen M. Goldup
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Supramolecular assembly of bent dinuclear amphiphilic alkynylplatinum(ii) terpyridine complexes: diverse nanostructures through subtle tuning of the mode of molecular stacking† Chem. Sci. (IF 9.556) Pub Date : 2019-11-27 Sam Ka-Ming Leung; Alan Kwun-Wa Chan; Sammual Yu-Lut Leung; Ming-Yi Leung; Vivian Wing-Wah Yam
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Diminished viability of human ovarian cancer cells by antigen-specific delivery of carbon monoxide with a family of photoactivatable antibody-photoCORM conjugates† Chem. Sci. (IF 9.556) Pub Date : 2019-11-20 Brian Kawahara; Lucy Gao; Whitaker Cohn; Julian P. Whitelegge; Suvajit Sen; Carla Janzen; Pradip K. Mascharak
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Regioselective electrosynthesis of tetra- and hexa-functionalized [60]fullerene derivatives with unprecedented addition patterns† Chem. Sci. (IF 9.556) Pub Date : 2019-11-20 Kai-Qing Liu; Jun-Jie Wang; Xing-Xing Yan; Chuang Niu; Guan-Wu Wang
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Exploiting the versatile alkyne-based chemistry for expanding the applications of a stable triphenylmethyl organic radical on surfaces† Chem. Sci. (IF 9.556) Pub Date : 2019-11-20 J. Alejandro de Sousa; Francesc Bejarano; Diego Gutiérrez; Yann R. Leroux; Ewa Malgorzata Nowik-Boltyk; Tobias Junghoefer; Erika Giangrisostomi; Ruslan Ovsyannikov; Maria Benedetta Casu; Jaume Veciana; Marta Mas-Torrent; Bruno Fabre; Concepció Rovira; Núria Crivillers
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s-Block metal ions induce structural transformations between figure-eight and double trefoil knots†‡ Chem. Sci. (IF 9.556) Pub Date : 2020-01-07 Li-Long Dang; Xiang Gao; Yue-Jian Lin; Guo-Xin Jin
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Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex† Chem. Sci. (IF 9.556) Pub Date : 2020-01-06 Katherine J. Fisher; Margalit L. Feuer; Hannah M. C. Lant; Brandon Q. Mercado; Robert H. Crabtree; Gary W. Brudvig
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Nanocluster growth via “graft-onto”: effects on geometric structures and optical properties† Chem. Sci. (IF 9.556) Pub Date : 2019-12-27 Xi Kang; Shan Jin; Lin Xiong; Xiao Wei; Manman Zhou; Chenwanli Qin; Yong Pei; Shuxin Wang; Manzhou Zhu
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Selenophosphoramide-catalyzed diamination and oxyamination of alkenes† Chem. Sci. (IF 9.556) Pub Date : 2019-12-26 John R. Tabor; Derek C. Obenschain; Forrest E. Michael
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Correction: Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles Chem. Sci. (IF 9.556) Pub Date : 2020-01-10 Jichao Chen; Shang Gao; Ming Chen
Correction for ‘Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles’ by Jichao Chen et al., Chem. Sci., 2019, 10, 10601–10606.
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Direct cyclopropanation of activated N-heteroarenes via site- and stereoselective dearomative reactions† Chem. Sci. (IF 9.556) Pub Date : 2020-01-10 Jiyoun Lee; Donguk Ko; Hyunju Park; Eun Jeong Yoo
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An intelligent ZIF-8-gated polydopamine nanoplatform for in vivo cooperatively enhanced combination phototherapy† Chem. Sci. (IF 9.556) Pub Date : 2020-01-10 Jie Feng; Wenqian Yu; Zhen Xu; Fuan Wang
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Programmable adenine deamination in bacteria using a Cas9–adenine-deaminase fusion† Chem. Sci. (IF 9.556) Pub Date : 2020-01-06 Ya Zhang; Hongyuan Zhang; Zhipeng Wang; Zhaowei Wu; Yu Wang; Na Tang; Xuexia Xu; Suwen Zhao; Weizhong Chen; Quanjiang Ji
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A localized molecular automaton for in situ visualization of proteins with specific chemical modifications† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 Lu Liu; Siqiao Li; Anwen Mao; Guyu Wang; Yiran Liu; Huangxian Ju; Lin Ding
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Correction: Laser cleavable probes for in situ multiplexed glycan detection by single cell mass spectrometry† Chem. Sci. (IF 9.556) Pub Date : 2020-01-09 Jing Han; Xi Huang; Huihui Liu; Jiyun Wang; Caiqiao Xiong; Zongxiu Nie
Correction for ‘Laser cleavable probes for in situ multiplexed glycan detection by single cell mass spectrometry’ by Jing Han et al., Chem. Sci., 2019, 10, 10958–10962.
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Seed-mediated evolution of hierarchical metal–organic framework quaternary superstructures† Chem. Sci. (IF 9.556) Pub Date : 2020-01-03 Liang Feng; Kun-Yu Wang; Tian-Hao Yan; Hong-Cai Zhou
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Readily accessible sp3-rich cyclic hydrazine frameworks exploiting nitrogen fluxionality† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 Conor Dean; Sundaram Rajkumar; Stefan Roesner; Nessa Carson; Guy J. Clarkson; Martin Wills; Matthew Jones; Michael Shipman
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Development of copper-catalyzed enantioselective decarboxylative aldolization for the preparation of perfluorinated 1,3,5-triols featuring supramolecular recognition properties† Chem. Sci. (IF 9.556) Pub Date : 2019-12-27 Céline Sperandio; Jean Rodriguez; Adrien Quintard
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Programmable dynamic covalent nanoparticle building blocks with complementary reactivity† Chem. Sci. (IF 9.556) Pub Date : 2019-11-14 Nicolas Marro; Flavio della Sala; Euan R. Kay
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Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED† Chem. Sci. (IF 9.556) Pub Date : 2019-11-13 Alexander S. Romanov; Saul T. E. Jones; Qinying Gu; Patrick J. Conaghan; Bluebell H. Drummond; Jiale Feng; Florian Chotard; Leonardo Buizza; Morgan Foley; Mikko Linnolahti; Dan Credgington; Manfred Bochmann
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Unique aqueous self-assembly behavior of a thermoresponsive diblock copolymer† Chem. Sci. (IF 9.556) Pub Date : 2019-11-12 Sarah J. Byard; Cate T. O'Brien; Matthew J. Derry; Mark Williams; Oleksandr O. Mykhaylyk; Adam Blanazs; Steven P. Armes
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Copper-catalyzed enantioselective arylalkynylation of alkenes† Chem. Sci. (IF 9.556) Pub Date : 2020-01-08 Guangyue Lei; Hanwen Zhang; Bin Chen; Meichen Xu; Guozhu Zhang
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Targeted cell imaging properties of a deep red luminescent iridium(iii) complex conjugated with a c-Myc signal peptide† Chem. Sci. (IF 9.556) Pub Date : 2020-01-08 Adam H. Day; Martin H. Übler; Hannah L. Best; Emyr Lloyd-Evans; Robert J. Mart; Ian A. Fallis; Rudolf K. Allemann; Eman A. H. Al-Wattar; Nathaniel I. Keymer; Niklaas J. Buurma; Simon J. A. Pope
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The hunt for reactive alkynes in bio-orthogonal click reactions: insights from mechanochemical and conceptual DFT calculations† Chem. Sci. (IF 9.556) Pub Date : 2019-12-23 Tom Bettens; Mercedes Alonso; Paul Geerlings; Frank De Proft
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Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex† Chem. Sci. (IF 9.556) Pub Date : 2019-12-19 Amélie Nicolay; Micah S. Ziegler; David W. Small; Rebecca Grünbauer; Manfred Scheer; T. Don Tilley
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A near-infrared fluorescent probe reveals decreased mitochondrial polarity during mitophagy† Chem. Sci. (IF 9.556) Pub Date : 2019-12-18 Xiaoyi Li; Xiaohua Li; Huimin Ma
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Design of high-temperature f-block molecular nanomagnets through the control of vibration-induced spin relaxation† Chem. Sci. (IF 9.556) Pub Date : 2019-12-02 Luis Escalera-Moreno; José J. Baldoví; Alejandro Gaita-Ariño; Eugenio Coronado
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Nitric oxide imaging in cancer enabled by steric relaxation of a photoacoustic probe platform† Chem. Sci. (IF 9.556) Pub Date : 2020-01-07 Christopher J. Reinhardt; Ruiwen Xu; Jefferson Chan
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DNA nanotweezers for stabilizing and dynamically lighting up a lipid raft on living cell membranes and the activation of T cells† Chem. Sci. (IF 9.556) Pub Date : 2020-01-07 Lele Sun; Yingying Su; Jun-Gang Wang; Fei Xia; Ying Xu; Di Li
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“Disrupt and induce” intermolecular interactions to rationally design organic semiconductor crystals: from herringbone to rubrene-like pitched π-stacking† Chem. Sci. (IF 9.556) Pub Date : 2020-01-07 Chengyuan Wang; Daisuke Hashizume; Masahiro Nakano; Takuya Ogaki; Hiroyuki Takenaka; Kohsuke Kawabata; Kazuo Takimiya
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Independent control over size, valence, and elemental composition in the synthesis of DNA–nanoparticle conjugates† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 Yugang Bai; Hang Xing; Yunhao Bai; Li Huey Tan; Kevin Hwang; Ji Li; Yi Lu; Steven C. Zimmerman
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Protocells programmed through artificial reaction networks Chem. Sci. (IF 9.556) Pub Date : 2019-12-19 Yifan Lyu; Ruizi Peng; Hui Liu; Hailan Kuai; Liuting Mo; Da Han; Juan Li; Weihong Tan
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Rational synthesis of interpenetrated 3D covalent organic frameworks for asymmetric photocatalysis† Chem. Sci. (IF 9.556) Pub Date : 2019-12-19 Xing Kang; Xiaowei Wu; Xing Han; Chen Yuan; Yan Liu; Yong Cui
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Correction: O2-3-Aminopropyl diazeniumdiolates suppress the progression of highly metastatic triple-negative breast cancer by inhibition of microvesicle formation via nitric oxide-based epigenetic regulation Chem. Sci. (IF 9.556) Pub Date : 2020-01-06 Fenghua Kang; Jiayi Zhu; Jianbing Wu; Tian Lv; Hua Xiang; Jide Tian; Yihua Zhang; Zhangjian Huang
Correction for ‘O2-3-Aminopropyl diazeniumdiolates suppress the progression of highly metastatic triple-negative breast cancer by inhibition of microvesicle formation via nitric oxide-based epigenetic regulation’ by Fenghua Kang et al., Chem. Sci., 2018, 9, 6893–6898.
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Efficient trinuclear Ru(ii)–Re(i) supramolecular photocatalysts for CO2 reduction based on a new tris-chelating bridging ligand built around a central aromatic ring† Chem. Sci. (IF 9.556) Pub Date : 2019-12-14 Ambra M. Cancelliere; Fausto Puntoriero; Scolastica Serroni; Sebastiano Campagna; Yusuke Tamaki; Daiki Saito; Osamu Ishitani
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Uncommon structural and bonding properties in Ag16B4O10† Chem. Sci. (IF 9.556) Pub Date : 2019-12-09 Anton Kovalevskiy; Congling Yin; Jürgen Nuss; Ulrich Wedig; Martin Jansen
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Site-selective redox isomerizations of furanosides using a combined arylboronic acid/photoredox catalyst system† Chem. Sci. (IF 9.556) Pub Date : 2020-01-03 Victoria Dimakos; Daniel Gorelik; Hsin Y. Su; Graham E. Garrett; Gregory Hughes; Hiromitsu Shibayama; Mark S. Taylor
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Silica-supported, narrowly distributed, subnanometric Pt–Zn particles from single sites with high propane dehydrogenation performance† Chem. Sci. (IF 9.556) Pub Date : 2019-12-23 Lukas Rochlitz; Keith Searles; Jan Alfke; Dmitry Zemlyanov; Olga V. Safonova; Christophe Copéret
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Pot and time economies in the total synthesis of Corey lactone† Chem. Sci. (IF 9.556) Pub Date : 2019-12-23 Nariyoshi Umekubo; Yurina Suga; Yujiro Hayashi
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Phase segregated Cu2−xSe/Ni3Se4 bimetallic selenide nanocrystals formed through the cation exchange reaction for active water oxidation precatalysts† Chem. Sci. (IF 9.556) Pub Date : 2019-12-19 Sungwon Kim; Hiroki Mizuno; Masaki Saruyama; Masanori Sakamoto; Mitsutaka Haruta; Hiroki Kurata; Taro Yamada; Kazunari Domen; Toshiharu Teranishi
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Borane-induced ring closure reaction of oligomethylene-linked bis-allenes† Chem. Sci. (IF 9.556) Pub Date : 2019-12-18 Xin Tao; Karel Škoch; Constantin G. Daniliuc; Gerald Kehr; Gerhard Erker
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The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks† Chem. Sci. (IF 9.556) Pub Date : 2019-12-16 Tomoya Itakura; Hiroshi Matsui; Tomofumi Tada; Susumu Kitagawa; Aude Demessence; Satoshi Horike
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Automated linkage of proteins and payloads producing monodisperse conjugates† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 Igor Dovgan; Alexandre Hentz; Oleksandr Koniev; Anthony Ehkirch; Steve Hessmann; Sylvain Ursuegui; Sébastien Delacroix; Margaux Riomet; Frédéric Taran; Sarah Cianférani; Sergii Kolodych; Alain Wagner
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2-Amino-3′-dialkylaminobiphenyl-based fluorescent intracellular probes for nitric oxide surrogate N2O3† Chem. Sci. (IF 9.556) Pub Date : 2020-01-02 P. Rogelio Escamilla; Yanming Shen; Quanjuan Zhang; Derek S. Hernandez; Cecil J. Howard; Xuhong Qian; Daria Y. Filonov; Alexander V. Kinev; Jason B. Shear; Eric V. Anslyn; Youjun Yang
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Trisulfur radical anion-triggered stitching thienannulation: rapid access to largely π-extended thienoacenes† Chem. Sci. (IF 9.556) Pub Date : 2019-12-20 Feng Su; Shuqi Chen; Xiaogang Mo; Kongchuan Wu; Jiajun Wu; Weidong Lin; Zhiwei Lin; Jianbin Lin; Hui-Jun Zhang; Ting-Bin Wen
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Al(ORF)3 (RF = C(CF3)3) activated silica: a well-defined weakly coordinating surface anion† Chem. Sci. (IF 9.556) Pub Date : 2019-12-19 Damien B. Culver; Amrit Venkatesh; Winn Huynh; Aaron J. Rossini; Matthew P. Conley
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Serine is the molecular source of the NH(CH2)2 bridgehead moiety of the in vitro assembled [FeFe] hydrogenase H-cluster† Chem. Sci. (IF 9.556) Pub Date : 2019-12-18 Guodong Rao; Lizhi Tao; R. David Britt
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ATP-fuelled self-assembly to regulate chemical reactivity in the time domain† Chem. Sci. (IF 9.556) Pub Date : 2019-12-18 Maria A. Cardona; Leonard J. Prins
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Proton-conduction photomodulation in spiropyran-functionalized MOFs with large on–off ratio† Chem. Sci. (IF 9.556) Pub Date : 2019-12-18 Anemar Bruno Kanj; Abhinav Chandresh; Aaron Gerwien; Sylvain Grosjean; Stefan Bräse; Yuemin Wang; Henry Dube; Lars Heinke
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A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes† Chem. Sci. (IF 9.556) Pub Date : 2019-12-17 Wai Chung Fu; Fuk Yee Kwong
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