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Efficacious and sustained release of an anticancer drug mitoxantrone from new covalent organic frameworks using protein corona Chem. Sci. (IF 9.825) Pub Date : 2022-06-18 Subhajit Bhunia, Pranay Saha, Parikshit Moitra, Matthew A. Addicoat, Santanu Bhattacharya
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Site specific NMR characterization of abeta-40 oligomers cross seeded by abeta-42 oligomers Chem. Sci. (IF 9.825) Pub Date : 2022-06-22 Han-Wen Chang, Ho-I. Ma, Yi-Shan Wu, Ming-Che Lee, Eric Chung-Yueh Yuan, Shing-Jong Huang, Yu-Sheng Cheng, Meng-Hsin Wu, Ling-Hsien Tu, Jerry Chun Chung Chan
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The underappreciated influence of ancillary halide on metal–ligand proton tautomerism Chem. Sci. (IF 9.825) Pub Date : 2022-06-20 Anant Kumar Jain, Michael R. Gau, Patrick J. Carroll, Karen I. Goldberg
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Intact living-cell electrolaunching ionization mass spectrometry for single-cell metabolomics Chem. Sci. (IF 9.825) Pub Date : 2022-06-17 Yunlong Shao, Yingyan Zhou, Yuanxing Liu, Wenmei Zhang, Guizhen Zhu, Yaoyao Zhao, Qi Zhang, Huan Yao, Hansen Zhao, Guangsheng Guo, Sichun Zhang, Xinrong Zhang, Xiayan Wang
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Supramolecular copolymerization through self-correction of non-polymerizable transient intermediates Chem. Sci. (IF 9.825) Pub Date : 2022-06-17 Ganyu Chen, Peichen Shi, Longhui Zeng, Liubin Feng, Xiuxiu Wang, Xujing Lin, Yibin Sun, Hongxun Fang, Xiaoyu Cao, Xinchang Wang, Liulin Yang, Zhongqun Tian
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Electron-beam lithography of cinnamate polythiophene films: conductive nanorods for electronic applications Chem. Sci. (IF 9.825) Pub Date : 2022-06-16 N. Maximilian Bojanowski, Christian Huck, Lisa Veith, Karl-Philipp Strunk, Rainer Bäuerle, Christian Melzer, Jan Freudenberg, Irene Wacker, Rasmus R. Schröder, Petra Tegeder, Uwe H. F. Bunz
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From computational high-throughput screenings to the lab: taking metal–organic frameworks out of the computer Chem. Sci. (IF 9.825) Pub Date : 2022-06-16 Aurelia Li, Rocio Bueno-Perez, David Madden, David Fairen-Jimenez
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Coacervation of poly-electrolytes in the presence of lipid bilayers: mutual alteration of structure and morphology Chem. Sci. (IF 9.825) Pub Date : 2022-06-16 Sayantan Mondal, Qiang Cui
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Acylhydrazone-based supramolecular assemblies undergoing a converse sol-to-gel transition on trans → cis photoisomerization Chem. Sci. (IF 9.825) Pub Date : 2022-06-16 Zhao Gao, Fei Yan, Lulu Shi, Yifei Han, Shuai Qiu, Juan Zhang, Feng Wang, Si Wu, Wei Tian
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Comparing interfacial cation hydration at catalytic active sites and spectator sites on gold electrodes: understanding structure sensitive CO2 reduction kinetics Chem. Sci. (IF 9.825) Pub Date : 2022-06-15 Jaclyn A. Rebstock, Quansong Zhu, L. Robert Baker
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Discrete palladium clusters that consist of two mutually bisecting perpendicular planes Chem. Sci. (IF 9.825) Pub Date : 2022-06-15 Naoya Kojima, Misaki Kato, Yusuke Sunada
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Machine learning and semi-empirical calculations: a synergistic approach to rapid, accurate, and mechanism-based reaction barrier prediction Chem. Sci. (IF 9.825) Pub Date : 2022-06-14 Elliot H. E. Farrar, Matthew N. Grayson
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Deep neural network based quantum simulations and quasichemical theory for accurate modeling of molten salt thermodynamics Chem. Sci. (IF 9.825) Pub Date : 2022-06-15 Yu Shi, Stephen T. Lam, Thomas L. Beck
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Ambient synthesis of an iminium-linked covalent organic framework for synergetic RNA interference and metabolic therapy of fibrosarcoma Chem. Sci. (IF 9.825) Pub Date : 2022-06-15 Le-Le Zhou, Qun Guan, Wei Zhou, Jing-Lan Kan, Yu-Bin Dong
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Cobalt-catalyzed chemoselective dehydrogenation through radical translocation under visible light Chem. Sci. (IF 9.825) Pub Date : 2022-06-15 Wan-Lei Yu, Zi-Gang Ren, Ke-Xing Ma, Hui-Qing Yang, Jun-Jie Yang, Haixue Zheng, Wangsuo Wu, Peng-Fei Xu
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Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage Chem. Sci. (IF 9.825) Pub Date : 2022-06-14 Alexander Okorn, Arumugam Jayaraman, Lukas Englert, Merle Arrowsmith, Theresa Swoboda, Jeanette Weigelt, Carina Brunecker, Merlin Hess, Anna Lamprecht, Carsten Lenczyk, Maximilian Rang, Holger Braunschweig
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Nickel-catalysed diversification of phosphine ligands by formal substitution at phosphorus Chem. Sci. (IF 9.825) Pub Date : 2022-06-14 Sven Roediger, Sebastian U. Leutenegger, Bill Morandi
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Low-cost prediction of molecular and transition state partition functions via machine learning Chem. Sci. (IF 9.825) Pub Date : 2022-06-14 Evan Komp, Stéphanie Valleau
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Strong non-Arrhenius behavior at low temperatures in the OH + HCl → H2O + Cl reaction due to resonance induced quantum tunneling Chem. Sci. (IF 9.825) Pub Date : 2022-06-13 Xin Xu, Jun Chen, Xiaoxiao Lu, Wei Fang, Shu Liu, Dong H. Zhang
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Iron-catalysed hydroalumination of internal alkynes Chem. Sci. (IF 9.825) Pub Date : 2022-06-13 Wen-Tao Li, Meng-Yang Hu, Jun-Wen Xiong, Xin-Yu Zhang, Shou-Fei Zhu
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Bare and ligand protected planar hexacoordinate silicon in SiSb3M3+ (M = Ca, Sr, Ba) clusters Chem. Sci. (IF 9.825) Pub Date : 2022-06-13 Chen Chen, Meng-hui Wang, Lin-Yan Feng, Lian-Qing Zhao, Jin-Chang Guo, Hua-Jin Zhai, Zhong-hua Cui, Sudip Pan, Gabriel Merino
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A machine learning protocol for revealing ion transport mechanisms from dynamic NMR shifts in paramagnetic battery materials Chem. Sci. (IF 9.825) Pub Date : 2022-06-13 Min Lin, Jingfang Xiong, Mintao Su, Feng Wang, Xiangsi Liu, Yifan Hou, Riqiang Fu, Yong Yang, Jun Cheng
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Temperature-responsive Pickering high internal phase emulsions for recyclable efficient interfacial biocatalysis Chem. Sci. (IF 9.825) Pub Date : 2022-06-10 Chao Wang, Hui Chi, Fan Zhang, Xinyue Wang, Jiarui Wang, Hao Zhang, Ying Liu, Xiaona Huang, Yungang Bai, Kun Xu, Pixin Wang
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Preparation of trimetallic electrocatalysts by one-step co-electrodeposition and efficient CO2 reduction to ethylene Chem. Sci. (IF 9.825) Pub Date : 2022-06-10 Shuaiqiang Jia, Qinggong Zhu, Haihong Wu, Shitao Han, Mengen Chu, Jianxin Zhai, Xueqing Xing, Wei Xia, Mingyuan He, Buxing Han
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Copper-catalyzed radical cascade reaction of simple cyclobutanes: synthesis of highly functionalized cyclobutene derivatives Chem. Sci. (IF 9.825) Pub Date : 2022-06-10 Chunyang Liu, Xiaoyan Shangguan, Yan Li, Qian Zhang
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Catalytic defluorinative ketyl–olefin coupling by halogen-atom transfer Chem. Sci. (IF 9.825) Pub Date : 2022-06-10 Peter Bellotti, Huan-Ming Huang, Teresa Faber, Ranjini Laskar, Frank Glorius
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A DNAzyme-augmented bioorthogonal catalysis system for synergistic cancer therapy Chem. Sci. (IF 9.825) Pub Date : 2022-06-10 Yawen You, Hao Liu, Jiawei Zhu, Yibo Wang, Fang Pu, Jinsong Ren, Xiaogang Qu
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Between imide, imidyl and nitrene – an imido iron complex in two oxidation states Chem. Sci. (IF 9.825) Pub Date : 2022-06-09 Sascha Reith, Serhiy Demeshko, Beatrice Battistella, Alexander Reckziegel, Christian Schneider, Andreas Stoy, Crispin Lichtenberg, Franc Meyer, Dominik Munz, C. Gunnar Werncke
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Systematic synthesis of bisected N-glycans and unique recognitions by glycan-binding proteins Chem. Sci. (IF 9.825) Pub Date : 2022-06-09 Xuefeng Cao, Shuaishuai Wang, Madhusudhan Reddy Gadi, Ding Liu, Peng G. Wang, Xiu-Feng Wan, Jian Zhang, Xi Chen, Lauren E. Pepi, Parastoo Azadi, Lei Li
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Zintl cluster supported low coordinate Rh(I) centers for catalytic H/D exchange between H2 and D2 Chem. Sci. (IF 9.825) Pub Date : 2022-06-09 Oliver P. E. Townrow, Simon B. Duckett, Andrew S. Weller, Jose M. Goicoechea
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Enantioselective iodolactonization to prepare ε-lactone rings using hypervalent iodine Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Jenna L. Payne, Zihang Deng, Andrew L. Flach, Jeffrey N. Johnston
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Polymerization-induced self-assembly and disassembly during the synthesis of thermoresponsive ABC triblock copolymer nano-objects in aqueous solution Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Spyridon Varlas, Thomas J. Neal, Steven P. Armes
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Valence-controlled protein conjugation on nanoparticles via re-arrangeable multivalent interactions of tandem repeat protein chains Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Hyeongjoo Choi, Yongwon Jung
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Unveiling the interplay between homogeneous and heterogeneous catalytic mechanisms in copper–iron nanoparticles working under chemically relevant tumour conditions Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Javier Bonet-Aleta, Miguel Encinas-Gimenez, Esteban Urriolabeitia, Pilar Martin-Duque, Jose L. Hueso, Jesus Santamaria
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Carbazole-2-carbonitrile as an acceptor in deep-blue thermally activated delayed fluorescence emitters for narrowing charge-transfer emissions Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Chin-Yiu Chan, Yi-Ting Lee, Masashi Mamada, Kenichi Goushi, Youichi Tsuchiya, Hajime Nakanotani, Chihaya Adachi
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Origin of low melting point of ionic liquids: dominant role of entropy Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Takatsugu Endo, Kouki Sunada, Hiroki Sumida, Yoshifumi Kimura
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Cu-catalyzed carboboration of acetylene with Michael acceptors Chem. Sci. (IF 9.825) Pub Date : 2022-06-08 Tairan Cheng, Boxiang Liu, Rui Wu, Shifa Zhu
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The oxygen-resistant [FeFe]-hydrogenase CbA5H harbors an unknown radical signal Chem. Sci. (IF 9.825) Pub Date : 2022-06-07 Melanie Heghmanns, Andreas Rutz, Yury Kutin, Vera Engelbrecht, Martin Winkler, Thomas Happe, Müge Kasanmascheff
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Electronic structure of strongly correlated systems: recent developments in multiconfiguration pair-density functional theory and multiconfiguration nonclassical-energy functional theory Chem. Sci. (IF 9.825) Pub Date : 2022-06-07 Chen Zhou, Matthew R. Hermes, Dihua Wu, Jie J. Bao, Riddhish Pandharkar, Daniel S. King, Dayou Zhang, Thais R. Scott, Aleksandr O. Lykhin, Laura Gagliardi, Donald G. Truhlar
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Switchable photocatalysis for the chemodivergent benzylation of 4-cyanopyridines Chem. Sci. (IF 9.825) Pub Date : 2022-06-07 Eleni Georgiou, Davide Spinnato, Kang Chen, Paolo Melchiorre, Kilian Muñiz
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NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions Chem. Sci. (IF 9.825) Pub Date : 2022-06-07 Laura Kuehn, Ludwig Zapf, Luis Werner, Martin Stang, Sabrina Würtemberger-Pietsch, Ivo Krummenacher, Holger Braunschweig, Emmanuel Lacôte, Todd B. Marder, Udo Radius
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Combating small molecule environmental contaminants: detection and sequestration using functional nucleic acids Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Aimee A. Sanford, Brea A. Manuel, Misael A. Romero-Reyes, Jennifer M. Heemstra
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Construction of a quaternary stereogenic center by asymmetric hydroformylation: a straightforward method to prepare chiral α-quaternary amino acids Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Dequan Zhang, Jialin Wen, Xumu Zhang
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Highly stereoselective and enantiodivergent synthesis of cyclopropylphosphonates with engineered carbene transferases Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Xinkun Ren, Ajay L. Chandgude, Daniela M. Carminati, Zhuofan Shen, Sagar D. Khare, Rudi Fasan
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Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Pablo Ríos, Amor Rodríguez, Salvador Conejero
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Reaction dynamics studied via femtosecond X-ray liquidography at X-ray free-electron lasers Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Eun Hyuk Choi, Yunbeom Lee, Jun Heo, Hyotcherl Ihee
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Albumin-mediated “Unlocking” of supramolecular prodrug-like nanozymes toward selective imaging-guided phototherapy Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Jingjing Han, Haidong Li, Luyang Zhao, Gyoungmi Kim, Yahui Chen, Xuehai Yan, Juyoung Yoon
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Rapid synthesis of layered KxMnO2 cathodes from metal–organic frameworks for potassium-ion batteries Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Ang Li, Changfeng Li, Peixun Xiong, Jinfeng Zhang, Dongling Geng, Yunhua Xu
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Highly selective addition of cyclosilanes to alkynes enabling new conjugated materials Chem. Sci. (IF 9.825) Pub Date : 2022-06-06 Qifeng Jiang, Alexandra F. Gittens, Sydnee Wong, Maxime A. Siegler, Rebekka S. Klausen
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Practical asymmetric amine nucleophilic approach for the modular construction of protected α-quaternary amino acids Chem. Sci. (IF 9.825) Pub Date : 2022-06-05 Teng Liu, Shaofei Ni, Wusheng Guo
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Highly selective acid-catalyzed olefin isomerization of limonene to terpinolene by kinetic suppression of overreactions in a confined space of porous metal–macrocycle frameworks Chem. Sci. (IF 9.825) Pub Date : 2022-06-03 Wei He, Shohei Tashiro, Mitsuhiko Shionoya
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Gramicidin A accumulates in mitochondria, reduces ATP levels, induces mitophagy, and inhibits cancer cell growth Chem. Sci. (IF 9.825) Pub Date : 2022-06-03 Yun-Wei Xue, Hiroaki Itoh, Shingo Dan, Masayuki Inoue
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Graph-based molecular Pareto optimisation Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Jonas Verhellen
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Efficient visible/NIR light-driven uncaging of hydroxylated thiazole orange-based caged compounds in aqueous media Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Ryu Hashimoto, Masafumi Minoshima, Souhei Sakata, Fumihito Ono, Hirokazu Ishii, Yuki Watakabe, Tomomi Nemoto, Saeko Yanaka, Koichi Kato, Kazuya Kikuchi
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Separation of pyrrolidine from tetrahydrofuran by using pillar[6]arene-based nonporous adaptive crystals Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Jiajun Cao, Yitao Wu, Qi Li, Weijie Zhu, Zeju Wang, Yang Liu, Kecheng Jie, Huangtianzhi Zhu, Feihe Huang
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Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Tobias Bischof, Xueying Guo, Ivo Krummenacher, Lukas Beßler, Zhenyang Lin, Maik Finze, Holger Braunschweig
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Light-driven molecular motors embedded in covalent organic frameworks Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Cosima Stähler, Lars Grunenberg, Maxwell W. Terban, Wesley R. Browne, Daniel Doellerer, Michael Kathan, Martin Etter, Bettina V. Lotsch, Ben L. Feringa, Simon Krause
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[Cu18H3(S-Adm)12(PPh3)4Cl2]: fusion of Platonic and Johnson solids through a Cu(0) center and its photophysical properties Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Anish Kumar Das, Sourav Biswas, Vaibhav S. Wani, Akhil S. Nair, Biswarup Pathak, Sukhendu Mandal
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Zn(II)-Coordination-driven self-assembled nanoagents for multimodal imaging-guided photothermal/gene synergistic therapy Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Hui Hu, Nan Yang, Jiahui Sun, Fu Zhou, Rui Gu, Yuan Liu, Li Wang, Xuejiao Song, Ruirui Yun, Xiaochen Dong, Guangfeng Wang
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Cytosine methylation regulates DNA bendability depending on the curvature Chem. Sci. (IF 9.825) Pub Date : 2022-06-02 Sanghun Yeou, Jihee Hwang, Jaehun Yi, Cheolhee Kim, Seong Keun Kim, Nam Ki Lee
更新日期：2022-06-17
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