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Monitoring the Formation of Nickel-Poor and Nickel-Rich Oxide Cathode Materials for Lithium-Ion Batteries with Synchrotron Radiation Chem. Mater. (IF 10.508) Pub Date : 2023-01-31 Bixian Ying, Jack R. Fitzpatrick, Zhenjie Teng, Tianxiang Chen, Tsz Woon Benedict Lo, Vassilios Siozios, Claire A. Murray, Helen E. A. Brand, Sarah Day, Chiu C. Tang, Robert S. Weatherup, Michael Merz, Peter Nagel, Stefan Schuppler, Martin Winter, Karin Kleiner
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Catalytic Cleavage of the Dative Bond of Ammonia Borane by Polymeric Carbonyl Groups for Enhanced Energy Generation Chem. Mater. (IF 10.508) Pub Date : 2023-01-31 Prithwish Biswas, Yujie Wang, Steven Herrera, Pankaj Ghildiyal, Michael R. Zachariah
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Cation Exchange during the Synthesis of Colloidal Type-II ZnSe-Dot/CdS-Rod Nanocrystals Chem. Mater. (IF 10.508) Pub Date : 2023-01-31 Jannik Rebmann, Hans Werners, Florian Johst, Marcel Dohrmann, Yannic U. Staechelin, Christian Strelow, Alf Mews, Tobias Kipp
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Perspective on Ferroelectric Devices: Lessons from Interfacial Chemistry† Chem. Mater. (IF 10.508) Pub Date : 2023-01-31 Kun Yang, Se Hyun Kim, Hyun Woo Jeong, Dong Hyun Lee, Geun Hyeong Park, Younghwan Lee, Min Hyuk Park
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Flexing of a Metal–Organic Framework upon Hydrocarbon Adsorption: Atomic Level Insights from Neutron Scattering Chem. Mater. (IF 10.508) Pub Date : 2023-01-31 Benjamin A. Trump, Omid T. Qazvini, Seok J. Lee, Elnaz Jangodaz, Wei Zhou, Craig M. Brown, Shane G. Telfer
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Self-Templated Synthesis of Triphenylene-Based Uniform Hollow Spherical Two-Dimensional Covalent Organic Frameworks for Drug Delivery Chem. Mater. (IF 10.508) Pub Date : 2023-01-31 Changsheng Du, Wenjing Na, Mingchao Shao, Shengcong Shang, Yunqi Liu, Jianyi Chen
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Inhibitor-Free Area-Selective Atomic Layer Deposition with Feature Size Down to Nearly 10 nm Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Chun-Yi Chou, Chi-Lin Mo, Chih-Piao Chuu, Ting-Yun Wang, Chin-Chao Huang, Cheng-Hung Hou, Chun-Ho Chuang, Yu-Sen Jiang, Jing-Jong Shyue, Miin-Jang Chen
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Adhesive Composite Hydrogel Patch for Sustained Transdermal Drug Delivery To Treat Atopic Dermatitis Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Ye Eun Kim, Hoo Yeon Jung, Nuri Park, Jaeyun Kim
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Molecular Electronic Coupling-Induced Photoacoustics for NIR-I/II Duplex in Vivo Imaging Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Zong Chang, Liangjian Liu, Jingying Zhai, Chenchen Liu, Xiao Wang, Chengbo Liu, Xiaojiang Xie, Qinchao Sun
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Revealing Hidden Patterns through Chemical Intuition and Interpretable Machine Learning: A Case Study of Binary Rare-Earth Intermetallics RX Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Volodymyr Gvozdetskyi, Balaranjan Selvaratnam, Anton O. Oliynyk, Arthur Mar
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Anisotropic Hydrogels Constructed via a Novel Bilayer-Co-Gradient Structure Strategy toward Programmable Shape Deformation Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Shan Ye, Wenjing Ma, Guodong Fu
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Supercritical CO2 Synthesis of Porous Metalloporphyrin Frameworks: Application in Photodynamic Therapy Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Márta Kubovics, Oriol Careta, Oriol Vallcorba, Guillermo Romo-Islas, Laura Rodríguez, Jose A. Ayllón, Concepción Domingo, Carme Nogués, Ana M. López-Periago
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Rewritable Pressure-Driven n–p Conduction Switching in Marcasite-Type CrSb2 Chem. Mater. (IF 10.508) Pub Date : 2023-01-30 Chen Li, Ke Liu, Shang Peng, Qi Feng, Dequan Jiang, Ting Wen, Hong Xiao, Binbin Yue, Yonggang Wang
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Operando Characterization and Theoretical Modeling of Metal|Electrolyte Interphase Growth Kinetics in Solid-State Batteries. Part II: Modeling Chem. Mater. (IF 10.508) Pub Date : 2023-01-28 Nicholas J. Williams, Edouard Quérel, Ieuan D. Seymour, Stephen J. Skinner, Ainara Aguadero
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Metastability and Photoelectrochemical Properties of Cu2SnO3 and Cu2–xLixTiO3: Two Cu(I)-Based Oxides with Delafossite Structures Chem. Mater. (IF 10.508) Pub Date : 2023-01-27 Shaun O’Donnell, Reinhard K. Kremer, Paul A. Maggard
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Regulating Eu2+ Multisite Occupation through Structural Disorder toward Broadband Near-Infrared Emission Chem. Mater. (IF 10.508) Pub Date : 2023-01-27 Yingze Zhu, Xuesong Wang, Jianwei Qiao, Maxim S. Molokeev, Hendrik C. Swart, Lixin Ning, Zhiguo Xia
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Antibody Functionalization of Ultrasmall Fluorescent Core–Shell Aluminosilicate Nanoparticle Probes for Advanced Intracellular Labeling and Optical Super Resolution Microscopy Chem. Mater. (IF 10.508) Pub Date : 2023-01-27 Jacob A. Erstling, Nada Naguib, Joshua A. Hinckley, Rachel Lee, Grant B. Feuer, James F. Tallman, Lieihn Tsaur, Danni Tang, Ulrich B. Wiesner
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Interpretable Machine Learning Enabled Inorganic Reaction Classification and Synthesis Condition Prediction Chem. Mater. (IF 10.508) Pub Date : 2023-01-27 Christopher Karpovich, Elton Pan, Zach Jensen, Elsa Olivetti
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Supported Metal Nanohydrides for Hydrogen Storage Chem. Mater. (IF 10.508) Pub Date : 2023-01-27 Estefania German, Johanna Sandoval, Adrián Recio, Abdolvahab Seif, Julio A. Alonso, María J. López
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Methylamine Magnesium Borohydrides as Electrolytes for All-Solid-State Magnesium Batteries Chem. Mater. (IF 10.508) Pub Date : 2023-01-27 Mads B. Amdisen, Jakob B. Grinderslev, Lasse N. Skov, Torben R. Jensen
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Synthesis of Edge-Shared Octahedral MAPbBr3 via Pressure- and Temperature-Induced Multiple-Stage Processes Chem. Mater. (IF 10.508) Pub Date : 2023-01-26 Mei Li, Kejun Bu, Junlong Li, Hao Wang, Yixuan Xu, Songhao Guo, Hui Luo, Bingyan Liu, Dongliang Yang, Yu Gong, Yonggang Wang, Yufeng Liu, Xujie Lü, Chuanlong Lin
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Influence of Ion Exchange on Photoresponsive Properties of Potassium Poly(heptazine imide) Chem. Mater. (IF 10.508) Pub Date : 2023-01-26 Mai Hattori, Miyu Nakamichi, Aika Yamaguchi, Chihiro Miyazaki, Goichiro Seo, Ryosuke Ohnuki, Shinya Yoshioka, Kaname Kanai
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Phase Transformation of Colloidal Cs3Cu2Cl5 Nanocrystals to CsMCl (M = Zn, Bi, Cd) by Cation Exchange and Their Thermodynamic Study by Density Functional Theory Calculations Chem. Mater. (IF 10.508) Pub Date : 2023-01-25 Hyo-Geun Kwon, Seung Min Lee, Jehyeon Ryu, Ju Hyun Park, Sang Kyu Kwak, Sang-Wook Kim
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Weak Correlation between the Polyanion Environment and Ionic Conductivity in Amorphous Li–P–S Superionic Conductors Chem. Mater. (IF 10.508) Pub Date : 2023-01-25 Byungju Lee, KyuJung Jun, Bin Ouyang, Gerbrand Ceder
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Is Cu3–xP a Semiconductor, a Metal, or a Semimetal? Chem. Mater. (IF 10.508) Pub Date : 2023-01-25 Andrea Crovetto, Thomas Unold, Andriy Zakutayev
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Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results Chem. Mater. (IF 10.508) Pub Date : 2023-01-24 Wen-Dong Yao, Xiyue Cheng, Sheng-Ping Guo, Myung-Hwan Whangbo, Bohan Ding, Shuiquan Deng
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The Autonomous Formulation Laboratory: An Open Liquid Handling Platform for Formulation Discovery Using X-ray and Neutron Scattering Chem. Mater. (IF 10.508) Pub Date : 2023-01-24 Peter A. Beaucage, Tyler B. Martin
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Connecting Vibrational Spectroscopy to Atomic Structure via Supervised Manifold Learning: Beyond Peak Analysis Chem. Mater. (IF 10.508) Pub Date : 2023-01-24 Daniel Vizoso, Ghatu Subhash, Krishna Rajan, Rémi Dingreville
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Macromolecular Architectures of Corannulene: Synthesis, Properties, and Applications of Polymers Containing a Molecular Bowl of Carbon† Chem. Mater. (IF 10.508) Pub Date : 2023-01-24 Mihaiela C. Stuparu
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The Future of Drug Delivery Chem. Mater. (IF 10.508) Pub Date : 2023-01-24 Jingjing Gao, Jeffrey M Karp, Robert Langer, Nitin Joshi
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Understanding the Electrochemical Performances of Si Anodes Incorporating Mechanically Interlocked Binders Prepared from α-Cyclodextrin-Based Polyrotaxanes Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Fanny Bétermier, Nour Daher, Laura Albero Blanquer, Julie Brun, Alba Marcellan, Nathalie Jarroux, Jean-Marie Tarascon
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Correction to Single-Layer Electroluminescent Devices and Photoinduced Hydrogen Production from an Ionic Iridium(III) Complex Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Michael S. Lowry, Jonas I. Goldsmith, Jason D. Slinker, Robert A. Pascal, Jr., George G. Malliaras, Stefan Bernhard
There was an arithmetical error when the excited-state redox potentials for the last entry in Table 3 were computed. (1) This is the corrected version of this table: Affiliation for this author at the time of original publication. This article references 1 other publications. This article has not yet been cited by other publications. This article references 1 other publications.
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The Future of Healthcare Materials Chem. Mater. (IF 10.508) Pub Date : 2023-01-24 Niveen M. Khashab, Frank Caruso
In recent years, applying nanotechnology in the medical field has been under heavy scrutiny, largely due to challenges in the effective translation of designed materials from the bench to the clinic. However, the mRNA vaccines that were successfully used during the current COVID-19 pandemic have underpinned renewed interest in nanotechnology-enabled materials for healthcare nanoparticle drug delivery
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Monitoring Amine Intercalation in H3Sb3P2O14 Thin Films Based on Real-Time X-ray Diffraction Data Analysis Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Marie Däntl, Johannes Maschita, Peter Wochner, Alberto Jiménez-Solano, Hugo A. Vignolo-González, Daniel Putzky, Robert E. Dinnebier, Sebastian Bette, Bettina V. Lotsch
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Defect-Stabilized Tin-Based Perovskite Solar Cells Enabled by Multifunctional Molecular Additives Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Jinhyeok Choi, Seok Joo Yang, Se Gyo Han, Woong Sung, Dongho Yoo, Kilwon Cho
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Second Harmonic Generation in the Polar A′SmNb2O7 (A′ = Rb, Cs) Dion–Jacobson Layered Perovskites Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Sachin Pal, Rajamani Nagarajan, Sitharaman Uma
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Self-Healing Multimodal Flexible Optoelectronic Fiber Sensors Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Xiaochun Wang, Guangxue Chen, Kaili Zhang, Ren’ai Li, Zihan Jiang, Hongyou Zhou, Jiulin Gan, Minghui He
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Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation Chem. Mater. (IF 10.508) Pub Date : 2023-01-23 Anna A. Berseneva, Lakshani W. Masachchi, Luiz G. Jacobsohn, Hans-Conrad zur Loye
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Inverse Design of Tetracene Polymorphs with Enhanced Singlet Fission Performance by Property-Based Genetic Algorithm Optimization Chem. Mater. (IF 10.508) Pub Date : 2023-01-21 Rithwik Tom, Siyu Gao, Yi Yang, Kaiji Zhao, Imanuel Bier, Eric A. Buchanan, Alexandr Zaykov, Zdeněk Havlas, Josef Michl, Noa Marom
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ARC–MOF: A Diverse Database of Metal-Organic Frameworks with DFT-Derived Partial Atomic Charges and Descriptors for Machine Learning Chem. Mater. (IF 10.508) Pub Date : 2023-01-20 Jake Burner, Jun Luo, Andrew White, Adam Mirmiran, Ohmin Kwon, Peter G. Boyd, Stephen Maley, Marco Gibaldi, Scott Simrod, Victoria Ogden, Tom K. Woo
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Mixed Valence of Bismuth in Hexagonal Chalcohalide Nanocrystals Chem. Mater. (IF 10.508) Pub Date : 2023-01-20 Danila Quarta, Stefano Toso, Gabriele Saleh, Rocco Caliandro, Anna Moliterni, Andrea Griesi, Giorgio Divitini, Ivan Infante, Giuseppe Gigli, Cinzia Giannini, Liberato Manna, Carlo Giansante
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Surface Chemistry of InP Quantum Dots, Amine–Halide Co-Passivation, and Binding of Z-Type Ligands Chem. Mater. (IF 10.508) Pub Date : 2023-01-20 Kim Corinna Dümbgen, Jari Leemans, Vic De Roo, Matthias Minjauw, Christophe Detavernier, Zeger Hens
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Operando Characterization and Theoretical Modeling of Metal|Electrolyte Interphase Growth Kinetics in Solid-State Batteries. Part I: Experiments Chem. Mater. (IF 10.508) Pub Date : 2023-01-20 Edouard Quérel, Nicholas J. Williams, Ieuan D. Seymour, Stephen J. Skinner, Ainara Aguadero
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Thermodynamic and Kinetic Barriers Limiting Solid-State Reactions Resolved through In Situ Synchrotron Studies of Lithium Halide Salts Chem. Mater. (IF 10.508) Pub Date : 2023-01-20 Monty R. Cosby, Christopher J. Bartel, Adam A. Corrao, Andrey A. Yakovenko, Leighanne C. Gallington, Gerbrand Ceder, Peter G. Khalifah
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Organic–Inorganic Hybrid Alkali Copper Iodides for Bright Emission across the Visible Spectrum Chem. Mater. (IF 10.508) Pub Date : 2023-01-20 Yanyan Li, Zhicong Zhou, Fu Kit Sheong, Zengshan Xing, Kam Sing Wong, Herman H. Y. Sung, Ian D. Williams, Jonathan E. Halpert
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Facile High-Yield Synthesis of Ag–In–Ga–S Quaternary Quantum Dots and Coating with Gallium Sulfide Shells for Narrow Band-Edge Emission Chem. Mater. (IF 10.508) Pub Date : 2023-01-19 Taro Uematsu, Manunya Tepakidareekul, Tatsuya Hirano, Tsukasa Torimoto, Susumu Kuwabata
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Anthracene-Bridged Photosensitizers for Effective and Safe Photodynamic Therapy Chem. Mater. (IF 10.508) Pub Date : 2023-01-19 Jucai Gao, Hui Yang, Yaru Lu, Qiankun Shi, Shidang Xu, Wenbo Wu, Fang Hu, Bin Liu
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Half-Metallicity and Magnetic Anisotropy in Double-Perovskite GdBaCo2O6 Films Prepared via Topotactic Oxidation Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Tsukasa Katayama, Shishin Mo, Akira Chikamatsu, Yuji Kurauchi, Hiroshi Kumigashira, Tetsuya Hasegawa
Double-perovskite GdBaCo2Ox is a promising material owing to its fascinating electronic and magnetic features, such as spin crossover, charge and spin-state ordering, magnetic-field or photo-induced antiferromagnetic-to-ferromagnetic phase transition, and large magnetoresistance (MR). These properties can be controlled by changing the oxygen content (x), and an increase of x is effective for stabilizing
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Nanoconfinement-Dependent Chain Orientation of Polymorphs in Poly(3-dodecylthiophene)s Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Hyewon Park, Hyeonjung Park, Hyungju Ahn, Wooseop Lee, Jinseok Park, Bumjoon J. Kim, Dong Ki Yoon
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Nonclassical Nucleation and Growth of Pd Nanocrystals from Aqueous Solution Studied by In Situ Liquid Transmission Electron Microscopy Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Walid Dachraoui, Rolf Erni
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Polar–Nonpolar Transition-Type Negative Thermal Expansion with 11.1% Volume Shrinkage by Design Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Takumi Nishikubo, Takashi Imai, Yuki Sakai, Masaichiro Mizumaki, Shogo Kawaguchi, Norihiro Oshime, Ayumu Shimada, Kento Sugawara, Kenji Ohwada, Akihiko Machida, Tetsu Watanuki, Kosuke Kurushima, Shigeo Mori, Takashi Mizokawa, Masaki Azuma
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Two Types of Negative Thermal Expansion Observed in PbCr1–xTixO3 Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Yuki Sakai, Kana Matsuno, Takumi Nishikubo, Masayuki Fukuda, Shogo Wakazaki, Masahito Ikeda, Kazuki Takahashi, Zhao Pan, Lei Hu, Masaki Azuma
Two negative thermal expansions (NTEs) with different mechanisms were observed in solid solutions of perovskite-type oxides PbCrO3 and PbTiO3. PbCr1–xTixO3 was found to adopt a cubic structure the same as that of PbCrO3 for x ≤ 0.6 and a PbTiO3-type tetragonal structure for x ≥ 0.7. The NTE observed at x ≤ 0.6 was accompanied by a cubic-to-cubic phase transition originating from the rearrangement of
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First-Principles Calculation Guided High-Purity Layer Control of 4 in. MoS2 by Plasma RIE Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Changmin Kim, Muyoung Kim, Donghyun Cho, Chaitanya Kaluram Kanade, Hyunho Seok, Moon Soo Bak, Daewoong Kim, Woo Seok Kang, Taesung Kim, Hyeong-U Kim
Two-dimensional molybdenum disulfide (MoS2) is one of the most promising candidates for next-generation semiconductors. Among the advantages offered by MoS2, a tunable bandgap that depends on the thickness is essential for the on-demand manufacturing of nanoelectronics. For this reason, elaborate layer control of MoS2 has been a long-standing research objective. However, prior efforts had several critical
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Engineering Solution-Processed Non-Crystalline Solid Electrolytes for Li Metal Batteries Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Pooja Vadhva, Thomas E. Gill, Joshua H. Cruddos, Samia Said, Marco Siniscalchi, Sudarshan Narayanan, Mauro Pasta, Thomas S. Miller, Alexander J. E. Rettie
Non-crystalline Li-ion solid electrolytes (SEs), such as lithium phosphorus oxynitride, can uniquely enable high-rate solid-state battery operation over thousands of cycles in thin film form. However, they are typically produced by expensive and low throughput vacuum deposition, limiting their wide application and study. Here, we report non-crystalline SEs of composition Li–Al–P–O (LAPO) with ionic
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Oxide Ion Mobility in V- and P-doped Bi2O3-Based Solid Electrolytes: Combining Quasielastic Neutron Scattering with Ab Initio Molecular Dynamics Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Bettina Schwaighofer, Miguel Angel Gonzalez, Markus Appel, Michael Marek Koza, Ivana Radosavljevic Evans
We report the direct observation of oxide ion dynamics on both nano- and picosecond timescales in the isostructural Bi2O3-derived solid electrolytes Bi0.852V0.148O1.648 and Bi0.852P0.148O1.648 using quasielastic neutron scattering. Comprehensive ab initio molecular dynamics simulations allowed us to reproduce the experimental picosecond timescale data by directly simulating the scattering function
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Terminal Groups of Nonfullerene Acceptors: Design and Application† Chem. Mater. (IF 10.508) Pub Date : 2023-01-18 Huifeng Yao, Jingwen Wang, Ye Xu, Jianhui Hou
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Enhanced Blue Emission in Rb2HfCl6 Double Perovskite via Bi3+ Doping and Cs+ Alloying Chem. Mater. (IF 10.508) Pub Date : 2023-01-17 Haoyue Wan, Fengyan Jia, Filip Dinic, Muhammad Imran, Benjamin Rehl, Yanjiang Liu, Watcharaphol Paritmongkol, Pan Xia, Ya-Kun Do Wang, Yuan Liu, Sasa Wang, Quan Lyu, Giovanni Francesco Cotella, Peter Chun, Oleksandr Voznyy, Sjoerd Hoogland, Edward H. Sargent
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Spectroelectrochemical Network Measurements for Redox Bioelectronics Chem. Mater. (IF 10.508) Pub Date : 2023-01-17 Zhiling Zhao, Eunkyoung Kim, Dana Motabar, William E. Bentley, Gregory F. Payne
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Synthesis, Surface Chemistry, and Fluorescent Properties of InP Quantum Dots Chem. Mater. (IF 10.508) Pub Date : 2023-01-17 Sophia M. Click, Sandra J. Rosenthal
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Circularly Polarized Fluorescence Energy Transfer for Constructing Multicolor Circularly Polarized Luminescence Films with Controllable Handedness Chem. Mater. (IF 10.508) Pub Date : 2023-01-15 Kai Yang, Shuo Ma, Youping Wu, Biao Zhao, Jianping Deng
Utilizing achiral fluorophores to fabricate circularly polarized luminescence (CPL) materials is of significant importance in both fundamental research and practical applications; chirality transfer has become an indispensable process in routine efforts reported so far. However, this may restrict or even become a bottleneck in further advancing CPL materials starting from achiral fluorophores. Inspired