Ratios of (un)reactive iron species, authigenic molybdenum contents (Moauth), and molybdenum isotope compositions (δ98Moauth) in sedimentary rocks are geochemical proxies that are widely used to reconstruct past marine redox states, which have been calibrated in modern marine settings covering oxic to euxinic conditions. However, syn- and postdepositional processes can result in alterations and ambiguities

Bromine is a key halogen element in the quantification of volcanic volatiles, but analytical difficulties in measuring its very low abundances have prevented progress in understanding its behavior and its role in volcanic emissions. We present a new data set of bromine, chlorine, and fluorine concentrations in melt inclusions and matrix glasses for two rhyolitic super-eruptions from the Toledo and

Natural glass occurs on Earth in different geological contexts, mainly as volcanic glass, fulgurites, and impact glass. All these different types of glasses are predominantly composed of silica with variable amounts of impurities, especially the alkalis, and differ in their water content due to their mode of formation. Distinguishing between different types of glasses, on Earth and also on the Moon

Crustal roots are identified in collision chains worldwide. Frequently mirroring the summits of mountain systems, they elegantly encapsulate the concept of isostasy. The rugged topography of northern Iberia results from convergence with the European plate during the Alpine orogeny that formed the Pyrenean-Cantabrian mountain range. From east to west, the range comprises three distinct parts: the Pyrenees

Carbonate platforms are built mainly by corals living in shallow light-saturated tropical waters. The Saya de Malha Bank (Indian Ocean), one of the world's largest carbonate platforms, lies in the path of the South Equatorial Current. Its reefs do not reach sea level, and all carbonate production is mesophotic to oligophotic. New geological and oceanographic data unravel the evolution and environment

Continental collisions commonly involve highly curved passive plate margins, leading to diachronous continental subduction during trench rollback. Such systems may feature back-arc extension and ophiolite obduction postdating initial collision. Modern examples include the Alboran and Banda arcs. Ancient systems include the Newfoundland and Norwegian Caledonides. While external forces or preexisting

The mid-Atlantic coastal plain (eastern United States) preserves high-resolution records of the Paleocene-Eocene Thermal Maximum (PETM) and attendant carbon isotope excursion (CIE), though preservation is highly variable from site to site. Here, we use a dip transect of expanded (as much as 15 m thick) PETM sections from the New Jersey coastal plain to build a cross-shelf PETM depositional model that

In marine basins, gas hydrate systems are usually identified by a bottom simulating reflection (BSR) that parallels the seafloor and coincides with the base of the gas hydrate stability zone (GHSZ). We present a newly discovered gas hydrate system, Moby-Dick, located in the Ship Basin in the northern Gulf of Mexico. In the seismic data, we observe a channel-levee complex with a consistent phase reversal

Widespread oceanic anoxia, biological crises, and volcanic activity are associated with the onset of Early Aptian (ca. 120 Ma) Oceanic Anoxic Event 1a (OAE1a). Reconstructions of oceanic deoxygenation and its links to broadly contemporaneous volcanism, however, remain poorly resolved. We use geochemical data, including δ53Cr ratios and rare Earth element abundances, to define the timing and tempo of

We show that recalescence, or spontaneous reheating of a cooling material due to rapid release of latent heat, can occur during disequilibrium crystallization of depolymerized Mg-rich melts. This can only happen at fast cooling rates, where the melt becomes undercooled by tens to hundreds of degrees before crystallization begins. Using a forward-looking infrared (FLIR) camera, we documented recalescence

The Great Unconformity is an iconic geologic feature that coincides with an enigmatic period of Earth's history that spans the assembly and breakup of the supercontinent Rodinia and the Snowball Earth glaciations. We use zircon (U-Th)/He thermochronology (ZHe) to explore the erosion history below the Great Unconformity at its classic Grand Canyon locality in Arizona, United States. ZHe dates are as

Uranium-Th-Pb dating of phosphate minerals in very low-grade metasedimentary rocks from the Archean Pilbara Craton, Western Australia, has revealed a long history of deformation and fluid flow during the Paleoproterozoic. However, this technique has not detected evidence for fluid flow along craton margins during Phanerozoic rifting and breakup. We report the use of in situ Th-Pb geochronology of rhabdophane

The Pliocene-Pleistocene transition resulted in extensive global cooling and glaciation, but isolating this climate signal within erosion and exhumation responses in tectonically active regimes can be difficult. The Nenana Gravel is a foreland basin deposit in the northern foothills of the Alaska Range (USA) that has long been linked to unroofing of the Alaska Range starting ca. 6 Ma. Using 26Al/10Be

Global Neoproterozoic glaciations are related to extreme environmental changes and the reprise of iron formation in the rock record. However, the lack of narrow age constraints on Cryogenian successions bearing iron-formation deposits prevents correlation and understanding of these deposits on a global scale. Our new multiproxy data reveal a long Cryogenian record for the Jacadigo Group (Urucum District

The locations and orientations of more than 1000 late Quaternary subglacial and ice-marginal landforms, including streamlined sedimentary bed forms, glacitectonic hill-hole pairs, meltwater channels, and eskers, were mapped from blocks of multibeam data (area of 4861 km2) in the little-known Russian Barents Sea. Between Sentralbanken and Admiralty Bank, at ∼75°N, there is evidence for southward ice

To help resolve current controversies surrounding the fundamental question of synchrony between end-Permian mass extinction on land and in the sea, we examined the marine Permian–Triassic reference section at Meishan (southeastern China) for land-derived molecular degradation products of pentacyclic triterpenoids with oleanane carbon skeletons, diagnostic for the Permian plant genus Gigantopteris.

Tectonically controlled topography influences deep-water sedimentary systems. Using 3-D seismic reflection data from the Levant Basin, eastern Mediterranean Sea, we investigate the spatial and temporal evolution of bedforms on a deep-water fan cut by an active normal fault. In the footwall, the fan comprises cyclic steps and antidunes along its axial and external portions, respectively, which we interpret

Coastal erosion, including sea-cliff retreat, represents both an important component of some sediment budgets and a significant threat to coastal communities in the face of rising sea level. Despite the importance of predicting future rates of coastal erosion, few prehistoric constraints exist on the relative importance of sediment supplied by coastal erosion versus rivers with respect to past sea-level

River channels are among the most common landscape features on Earth. An essential characteristic of channels is sinuosity: their tendency to take a circuitous path, which is quantified as along-stream length divided by straight-line length. River sinuosity is interpreted as a characteristic that either forms randomly at channel inception or develops over time as meander bends migrate. Studies tend

The Laurentide Ice Sheet (LIS) was the largest ice sheet during the last glacial period. An accurate representation of its behavior during the last deglaciation is critical to understanding its influence on and response to a changing climate. We use 10Be dating and Bayesian modeling to track the recession of the southwest sector of the Labrador Dome of the LIS along an ∼500-km-long transect west of

Landforms produced beneath former ice sheets offer insights into inaccessible subglacial processes and present analogues for how current ice masses may evolve in a warming climate. Large subglacial channels cut by meltwater erosion (tunnel valleys [TVs]) have the potential to provide valuable empirical constraints for numerical ice-sheet models concerning realistic melt rates, water routing, and the

Fjords are glacially carved estuaries that profoundly influence ice-sheet stability by draining and ablating ice. Although abundant on modern high-latitude continental shelves, fjord-network morphologies have never been identified in Earth's pre-Cenozoic glacial epochs, hindering our ability to constrain ancient ice-sheet dynamics. We show that U-shaped valleys in northwestern Namibia cut during the

Wind-blown sand self-organizes into bedforms that have now been identified on six different planetary bodies. These bedforms, including ripples and dunes, exhibit patterns that are diagnostic of surface-atmosphere interactions and can be used to interpret winds and sediment supply from satellite images of planetary surfaces. Patterns in dune and ripple fields change when one or more bedforms interact

The 1.87–1.84 Ga Black Hills dike swarm of the Kalahari craton (South Africa) is coeval with several regional magmatic provinces used here to resolve the craton's position during Columbia assembly. We report a new 1850 ± 4 Ma (U-Pb isotope dilution–thermal ionization mass spectrometry [ID-TIMS] on baddeleyite) crystallization age for one dike and new paleomagnetic data for 34 dikes of which 8 have

In the paleogeographic configuration of the Neoproterozoic supercontinent of Rodinia, the Tarim craton (northwestern China), traditionally seen as a single block, is placed either on the periphery near northern Australia or India or in a central position between Australia and Laurentia. To distinguish between these possibilities, we present here new primary paleomagnetic results from ca. 900 Ma volcanics

Variations in East Asian summer monsoon (EASM) precipitation impact agriculture, water resources, electricity generation, and economic development in the densely populated region of central eastern China. However, uncertainties remain in the history and driving mechanisms of precipitation changes in this region over the past two millennia. We present an 1800 yr multiproxy reconstruction of monsoon

Following rapid decompression in the conduit of a volcano, magma breaks into ash- to block-sized fragments, powering explosive sub-Plinian and Plinian eruptions that may generate destructive pyroclastic falls and flows. It is thus crucial to assess how magma breaks up into fragments. This task is difficult, however, because of the subterranean nature of the entire process and because the original size

Water can be stored in nominally anhydrous minerals as substitutional hydroxyl, generating vast but commonly unrecognized H2O reservoirs in ostensibly dry regimes. Researchers have long known that hematite (α-Fe2O3) can accommodate small concentrations of hydroxyl through the substitution of Fe3+ by 3H+. Our study of natural hematite has demonstrated the occurrence of “hydrohematite” phases that are

The origins of many supergiant ore deposits remain unresolved because the factors responsible for such extreme metal enrichments are not understood. One factor of critical importance is the timing of mineralization. However, timing information is commonly confounded by the difficulty of dating ore minerals. The world's largest uranium resource at Olympic Dam, South Australia, is exceptional because

Earthquake doublets have been described in fault systems around the world but have not yet been confidently resolved in paleoseismic records. Our current knowledge is limited to historical occurrences, preventing researchers from uncovering potential patterns or recognizing common fault behavior. Identification of prehistoric doublets is thus of crucial importance for adequate seismic hazard assessment

Much of our current understanding of continental topographic evolution is rooted in measuring and predicting the rates at which rivers erode the landscape. Flume tank and field observations indicate that stochasticity and local conditions play important roles in determining rates at small scales (e.g., <10 km, thousands of years). Obversely, preserved river profiles and common shapes of rivers atop

The tectonic history of the Philippine Sea plate is an essential piece in understanding the tectonic evolution of Southeast Asia, but it is still unclear and controversial. We present the first geochemical data obtained from lavas from the Gagua Ridge (GR) within the Philippine Sea. The GR lavas exhibit geochemical signatures typical of subduction-related arc magmatism. Plagioclase Ar-Ar ages of ca

Documenting the structural evolution of the Himalayan orogen is fundamental for understanding the dynamics of collisional orogenesis. We argue that the importance of deformation in the frontal, Lesser Himalayan–Subhimalayan (LH-SH) portion of the Himalayan thrust belt for driving crustal thickening over the past ~15–13 m.y. has long been overlooked. To quantify its contribution to thickening, we measured

Oxygen isotope ratios of garnet provide well-established means to investigate crustal fluid histories. Traditionally, δ18O values from skarn garnets have been used to track the hydrothermal evolution of an individual skarn body through time. We, however, use garnet from 14 skarns from the Jurassic (ca. 175 to ca. 148 Ma) Cordilleran margin arc (southwestern United States) to provide regional tectonic

Delicate impressions in lacustrine strata of the lower Permian (lower Cisuralian) Usclas Formation record ephemeral freezing in equatorial Pangea. These sediments accumulated in the paleoequatorial and intramontane Lodève Basin (southern Massif Central, France) during peak icehouse conditions of the Late Paleozoic Ice Age. Experimental replication of these features supports the interpretation that

The magma plumbing systems of volcanoes in subduction and divergent tectonic settings are relatively well known, whereas those of intraplate volcanoes remain elusive; robust geophysical information on the magma pathways and storage zones is lacking. We inverted magnetotelluric data to image the magma plumbing system of an intraplate monogenetic volcanic field located above the stagnant Pacific slab

Most of the world's Zn and Pb is extracted from sediment-hosted Zn-Pb deposits. The Zn-Pb deposits hosted in carbonate rocks are hypothesized to form by mixing of acidic metal-bearing brines with reduced sulfur-bearing fluids while dissolving sedimentary carbonate. To test the role of carbonate in this process, we conducted hydrothermal experiments simulating ore formation by reacting Zn ± Pb ± Ba–bearing

The collapse of a volcanic flank can be destructive and deadly. Hydrothermal alteration is common to volcanoes worldwide and is thought to promote volcano instability by decreasing rock strength. However, some laboratory studies have shown that not all alteration reduces rock strength. Our new laboratory data for altered rhyodacites from Chaos Crags (Lassen volcanic center, California, USA) show that

The end-Permian mass extinction (EPME) has been recorded as the most severe biodiversity crisis in Earth's history, although the timing of the marine and terrestrial extinctions remains debatable. We present a new high-resolution magnetostratigraphic succession across the EPME and the Permian-Triassic boundary (PTB) from the Meishan sections in southeastern China, which contain the global boundary

Many crystalline rocks of the continental crust contain coarse-grained quartz as a main mineral (e.g., granitoids). Incipient deformation of coarse quartz, which likely controls the accumulation of bulk strain in heterogeneously deformed crustal rock volumes, commonly develops microshear zones (MSZs) of localized recrystallization. At mid-crustal conditions, where quartz deformation is mostly accomplished

Paleozoic astrochronologies are limited by uncertainties in past astronomical configurations and the availability of complete stratigraphic sections with precise, independent age control. We show it is possible to reconstruct a robust Paleozoic ~104-yr-resolution astrochronology in the well-preserved and thick Upper Ordovician reference record of Anticosti Island (Canada). The clear imprint of astronomical

Platinum-rich nuggets offer an opportunity for understanding how precious metals accumulate. We analyzed the selenium (Se) isotopic composition of Se-rich (102–103 µg g−1) platinum-palladium (Pt-Pd) nuggets from a recent placer deposit in Minas Gerais, Brazil, for which a biogenic origin has been inferred. We obtained Se isotopic values with a relatively narrow range (δ82/76SeNIST3149 = −17.4 to −15

Alluvial rivers are the most important agents of sediment transport in continental basins, whose fluvial deposits enclose information related to the time when rivers were active. In order to extract the most information from fluvial deposits in the sedimentary record, it is imperative to quantify the natural variability of channel patterns at the global scale, explore what controls may influence their

There is abundant evidence for significant H2O in evolved melts from the platinum-rich UG2 chromitite and the Merensky Reef of the Bushveld Complex (South Africa), but there is no consensus about the source of H2O. We report triple-oxygen and hydrogen isotope ratios of interstitial, late-magmatic phlogopite from three localities of the UG2 layer. The phlogopite yielded δD values of −43 to −23, which

The central nervous system (CNS) presents unique insight into the behaviors and ecology of extant and extinct animal groups. However, neurological tissues are delicate and prone to rapid decay, and thus their occurrence as fossils is mostly confined to Cambrian Burgess Shale–type deposits and Cenozoic amber inclusions. We describe an exceptionally preserved CNS in the horseshoe crab Euproops danae

The Line Islands volcanic chain in the central Pacific Ocean exhibits many characteristics of a hotspot-generated seamount chain; however, the lack of a predictable age progression has stymied previous models for the origin of this feature. We combined plate-tectonic reconstructions with seamount age dates and available geochemistry to develop a new model that involves multiple melt regions and multiple

Variation in δ18O and δ13C values in a speleothem from the Cango Caves in southernmost South Africa enable the construction of coherent regional composite records spanning the past 113,500 yr. Novel for the region in terms of both their length and detail, these records indicate environmental and climatic changes that both are consistent with records from the wider region and show a clear evolution

The tectonic setting of the Australian sector of the eastern Gondwanan margin during the Jurassic and Cretaceous is enigmatic. Whether this involved convergent tectonism and a long-lived continental magmatic arc or rift-related extension unrelated to subduction is debated. The paucity of Australian Jurassic–Cretaceous igneous outcrops makes resolving these competing models difficult. We used the detrital

Primary gypsum represents an excellent paleobiological archive due to its early and fast growth, favoring the preservation of delicate biomineralized structures. The Mediterranean region is renowned for evaporite deposits that formed during the Messinian salinity crisis (MSC), an event that supposedly annihilated most of the marine biota. However, the Messinian evaporites have been scarcely studied

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Loess sequences of the Chinese Loess Plateau (CLP) compose one of the most complete Neogene–Quaternary terrestrial paleoclimatic archives. Understanding the CLP's sediment sources is critical to tracing Asian aridification, atmospheric circulation patterns, and Asian monsoon evolution. Commonly, the sediments that compose the Quaternary strata of the CLP are considered largely homogeneous, and thus

Ediacara-type macrofossils characterize the late Ediacaran Period and are pivotal in understanding the early evolution of animals on the eve of the Cambrian explosion and useful in late Ediacaran biostratigraphy. They have been discovered on almost all major paleocontinents, except the North China and Tarim blocks, as well as on a series of northwest-west–oriented cratonic fragments between the two

Molybdenum (Mo) isotope ratios provide a potential means of tracing material recycling involved in subduction zone processes. However, the geochemical behavior of Mo in subducted oceanic crust remains enigmatic. We analyzed Mo isotope ratios of arc and back-arc basin lavas from the Mariana subduction zone (western Pacific Ocean), combining newly obtained element and Sr-Nd-Pb-Li isotope data to investigate

The location of the West African craton (WAC) has been poorly constrained in the Paleoproterozoic–Mesoproterozoic supercontinent Nuna (also known as Columbia). Previous Nuna reconstruction models suggested that the WAC was connected to Amazonia in a way similar to their relative position in Gondwana. By an integrated paleomagnetic and geochronological study of the Proterozoic mafic dikes in the Anti-Atlas

Whether and how subduction increases the oxidation state of Earth's mantle are two of the most important unresolved questions in solid Earth geochemistry. Using data from the southern Cascade arc (California, USA), we show quantitatively for the first time that increases in arc magma oxidation state are fundamentally linked to mass transfer of isotopically heavy sulfate from the subducted plate into

An accurate reconstruction of the Antarctic Ice Sheet is essential in order to develop an understanding of ice-sheet responses to global climate changes. However, the erosive nature of ice-sheet expansion and the difficulty of accessing much of Antarctica make it challenging to obtain field-based evidence of ice-sheet and sea-level changes before the Last Glacial Maximum. Limited sedimentary records

The Great Unconformity of the Rocky Mountain region (western North America), where Precambrian crystalline basement is nonconformably overlain by Phanerozoic strata, represents the removal of as much as 1.5 b.y. of rock record during 10-km-scale basement exhumation. We evaluate the timing of exhumation of basement rocks at five locations by combining geologic data with multiple thermochronometers.