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Intramolecular Silanoxy-Michael Reactions with Pendant Nitroalkenes: Racemic and Enantioselective J. Org. Chem. (IF 3.3) Pub Date : 2024-09-21 Harshit Joshi, Shyam Sathyamoorthi
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Ytterbium Triflate-Catalyzed Intramolecular Arylative Ring Opening of Arylaminomethyl-Substituted Donor–Acceptor Cyclopropanes: Access to Tetrahydroquinolines J. Org. Chem. (IF 3.3) Pub Date : 2024-09-20 Thangaraj Devaraj, Kannupal Srinivasan
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TBD-Mediated Diastereoselective Access to Functionalized 3-Alkenyl-2-oxindoles via the Tandem Reaction of Isatins and Allenoates J. Org. Chem. (IF 3.3) Pub Date : 2024-09-20 Athira C. Santhoshkumar, Basavaraja Durugappa, Geethu Venugopal, Mohan Banyangala, Ajay Krishna M. S, Sasidhar B. Somappa
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Probing the Influence of Alkyne Substitution on the Electronic and Magnetic Properties of Diindeno[1,2-b;1′,2′-i]anthracenes J. Org. Chem. (IF 3.3) Pub Date : 2024-09-20 Efrain Vidal, Jr., Lev N. Zakharov, Carlos J. Gómez-García, Michael M. Haley
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“Marriage” of Inorganic to Organic Chemistry as Motivation for a Theoretical Study of Chloroform Hydrolysis Mechanisms J. Org. Chem. (IF 3.3) Pub Date : 2024-09-20 Christina Stamou, Spyros P. Perlepes, Michail M. Sigalas, Dionissios Papaioannou, Athanassios C. Tsipis, Evangelos G. Bakalbassis
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Leap from Diradicals to Tetraradicals by Topological Control of π-Conjugation J. Org. Chem. (IF 3.3) Pub Date : 2024-09-20 Sergi Betkhoshvili, Jordi Poater, Ibério de P. R. Moreira, Josep Maria Bofill
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Cascade Alkynyl Prins Cyclization and Aza-Michael Reaction: En Route to Regioselective Pyrano- and Isochromenoquinoline Scaffolds J. Org. Chem. (IF 3.3) Pub Date : 2024-09-20 Subhamoy Biswas, Anil K. Saikia
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Phototriggered Self-Catalyzed Phosphorylation of 3,4-Dihydroquinoxalin-2(1H)-ones with Diarylphosphine Oxides in EtOH J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Yan-Fang Jiang, Wen-Tao Ouyang, Hong-Tao Ji, Jia-Cheng Hou, Ting Li, Qing-Xia Luo, Chao Wu, Li-Juan Ou, Wei-Min He
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Low-Cost, Safe, and Anion-Flexible Method for the Electrosynthesis of Diaryliodonium Salts J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Anton Scherkus, Aija Gudkova, Jan Čada, Bernd H. Müller, Tomas Bystron, Robert Francke
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Rh(III)- or Ru(II)-Catalyzed C–H Annulation with Vinylene Carbonate and an Unexpected Aerobic Oxidation/Deprotection Cascade to Yield Cinnolin-4(1H)-ones J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Yuqin Wang, Yiling Zeng, Yi Xiao, Jinhua Wang, Shiqing Li
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AcOH-Catalyzed Rearrangements of Benzo[e][1,4]diazepin-2(and 3)-ones: Easy Access to 1,4-Dihydroquinazolines and Their Condensed Analogues J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Vakhid A. Mamedov, Nataliya A. Zhukova, Victor V. Syakaev, Aidar T. Gubaidullin, Aida I. Samigullina, Tat’yana N. Beschastnova, Darya S. Perevalova, Olga B. Babaeva, Il′dar Kh. Rizvanov, Oleg G. Sinyashin
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Decarboxylation of Aza-Annulation Products as a Synthetic Route to 3-Pyrrolin-2-ones and 1,2,3,4-Tetrahydropyridin-2-ones J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Kseniia Petrova, Almaz Kaipov, Lyailya Yussupova, Iliyas Iznat, Davit Hayrapetyan
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2-(1,1-Dicyanomethylene)rhodanine-Functionalized Oligothiophenes: A Structure–Property Investigation of Z/E Photoisomerization Behavior J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Cory T. Kornman, Parag Das, Lei Li, Asmerom O. Weldeab, Ion Ghiviriga, Ronald K. Castellano
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Synthesis of Tetrasubstituted Enamines Using Secondary Amines and In Situ-Generated Allenes from Nitrocyclopropanes J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Zhong-Yang Xu, Jian-Sheng Wei, Li Liu, Qing-Bo Hu, Jin-Yao Zhu, Zhan-Yu Zhou, Ai-Bao Xia, Dan-Qian Xu
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Copper-Catalyzed Oxyfluorosulfonylation of β,γ-Unsaturated Oximes with Sulfur Dioxide and Selectfluor for Isoxazoline-Functionalized Aliphatic Sulfonyl Fluorides J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Hui-Jie Du, Lin Qi, Zhi-Min Yan, Jia-Li Liu, Wei Li, Li-Jing Wang
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Synthesis of Diverse N-Trifluoromethyl Pyrazoles by Trapping of Transiently-Generated Trifluoromethylhydrazine J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Bao Li, Fenglei Xie, Rui Zhang, Yaoyi Wang, Vijaya B. Gondi, Christopher R. H. Hale
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Nickel-Catalyzed, Aminoquinoline-Directed Chemo- and Regioselective Carboamination of Unactivated Olefins with Organoboronic Acids and Anthranils J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Zhongke Xie, Yushan Cui, Jiale Xing, Yang Gao, Yanping Huo, Xianwei Li, Qian Chen
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Mn-Catalyzed Aerobic Oxidative α-Cyanation of Tertiary Amines Using Azo/Hydrazide Redox J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Su Been Kim, Gayeong Park, Eun Sun Park, Santanu Maiti, Jinho Kim
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NCS-Mediated Direct C(sp3)–H Oxygenation of 2-Methylindoles Using Water as the Oxygen Source J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Fan Zhang, Yuling Luo, Xiaoyi Liu, Yaoyao Liu, Jun Xu
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1O2 and Base Assisted Oxidative Conversion of β-Enaminoesters to α-Acyloxy-β-ketoesters under Visible Light Irradiation J. Org. Chem. (IF 3.3) Pub Date : 2024-09-19 Rohit Kumar, Deepak, Nidhi Jain
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Acid-Promoted Amination of Cyclohexenone for the Divergent Synthesis of p-Aminophenols and Tertiary Amines J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Li Liu, Jun Li, Ya Chen, Shanping Chen, Fuhong Xiao, Guo-Jun Deng
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Synthesis of 2,3-Benzobicyclo[3.3.1]non-2-enes via a Cascade of Domino Carbocation Migration/Interrupted Ritter Reaction and Dienone-Phenol Rearrangement J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Zhiwei Sun, Chuanjun Song, Yonggang Meng, Yingchao Dou
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A DFT Mechanistic Study on the Aza-Aldol Reaction of Boron Aza-Enolates: Relative Stability of Six-Membered Transition State and Its Relevance to the Coordination Mode of the Leaving Group J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Sho Miyakawa, Ray Miyazaki, Tomoya Miura, Jun-ya Hasegawa
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Stereoselective Synthesis of Maralixibat via VO(acac)2/Schiff Base-Catalyzed Asymmetric Oxidation of Its Sulfide Intermediate J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Ziyu Peng, Mercy Mpofo, Zheng Jie, Long Ye
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One Pot Synthesis of C3-Sulfurized Imidazolo [1,2-a] Pyridines J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Ya-Dan Zhang, Zhi-Peng Guan, Zhi-Bing Dong
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Spokewise Total Syntheses of Four Erythrina Alkaloids and Telescoped Syntheses of Six Additional Alkaloids J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Yue-Hong Hu, Zhang-Yan Gan, Qin-Tong Li, Yu-Ting Chen, Meng-En Chen, Ling-Hui Zhang, Jin-Chi Zou, Fu-Min Zhang
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Deciphering Asymmetric Brønsted Base-Aminocatalytic Mode in Pudovik/[1,2]-Phospha-Brook Rearrangement/Michael Cascade Reaction J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Ravneet Kaur, Saurabh Singh Rautela, Mubarik Ali, Ravi P. Singh
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Copper-Catalyzed α-Alkylation of Aryl Acetonitriles with Benzyl Alcohols J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Marianna Danopoulou, Leandros P. Zorba, Athanasia P. Karantoni, Demeter Tzeli, Georgios C. Vougioukalakis
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Synthesis of α,α-Difluoromethylene Amines from Thioamides Using Silver Fluoride J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Haixia Song, Qin Wang, Xiaoying Wang, Yu Pan, Jing Li, Xin-Hua Duan, Mingyou Hu
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Polynitro-1,2,4-triazole Energetic Materials with N-Amino Functionalization J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Xinyang Lu, Xiangyang Lin, Haifeng Huang, Jun Yang
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Base-Promoted One-Pot Strategy for Expeditious Assembly of Highly Functionalized Benzocoumarin Derivatives J. Org. Chem. (IF 3.3) Pub Date : 2024-09-18 Fataneh Rakaee, Morteza Shiri, Behnaz Farajpour, Serveh Majedi, Mahsa Seraj, Fatemeh Moradkhani, Salman Taheri, Mohammad Reza Sadeghi-Dolatabadi, Soma Majedi
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Syntheses of Phosphonylated Pyrido-Dihydrofurans by Regioselective 5-Exo-dig Addition to Carbon–Carbon Triple Bond Catalyzed by AgNO3 J. Org. Chem. (IF 3.3) Pub Date : 2024-09-17 Xingyu Tu, Bo Jiang, Hongming Fang, Yiyang Qiao, Zhiwei Miao
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Cu/Pd-Catalyzed Tandem Carbonylative Synthesis of Ester-Containing 3,4-Dihydroquinolin-2(1H)-one Derivatives from Alkyne-Tethered α-Bromocarbonyls J. Org. Chem. (IF 3.3) Pub Date : 2024-09-17 Jiajun Zhao, Jianwei Wang, Shangyuan Wang, Jun Ying
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Unexpected E-to-Z Isomerizations during the Negishi-Type Homocoupling of E-Iodoalkenes J. Org. Chem. (IF 3.3) Pub Date : 2024-09-17 Fernanda A. Crovara, Josep Martí, Anna M. Costa, Jaume Vilarrasa
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Manganese(III) Triacetate-Mediated Cross Coupling of Organoboron Compounds with Trichloroethylene (TCE): Synthesis of 1,1-Dichloroalkenes J. Org. Chem. (IF 3.3) Pub Date : 2024-09-17 Liu Xiao, Zhiyuan Xu, Huan Li
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Indium-Mediated Preparation of Bis(α-hydroxyallenes) or α,α′-Dihydroxyallenynes and Further Gold-Catalyzed Cyclizations J. Org. Chem. (IF 3.3) Pub Date : 2024-09-17 Teresa Martínez del Campo, Daniel San Martín, Laura Gamarra, Eva Cerrón, Sara Cembellín, Hikaru Yanai, Pedro Almendros
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Syntheses of 3-(2-Nitrovinyl)-indoles, Benzo[a]carbazoles, Naphtho[2,1-a]carbazoles, and 1-Hydroxy-β-carbolines Lead to Identification of Antiproliferative Compounds Active under Hypoxia J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Nikolai A. Arutiunov, Connor Edvall, Alexander V. Aksenov, Dmitrii A. Aksenov, Igor A. Kurenkov, Inna V. Aksenova, Anna M. Zatsepilina, Nicolai A. Aksenov, Sanku Mallik, Alexander Kornienko
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Organocatalytic Asymmetric (4 + 3) Cycloaddition toward Optically Active Cyclohepta Fused Diindoles J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Kanghua Rui, Hanxiao Shen, Xufeng Lin
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Electrochemical Regioselective C(sp2)–H Bond Chalcogenation of Pyrazolo[1,5-a]pyrimidines via Radical Cross-Coupling at Room Temperature J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Abhinay S. Chillal, Rajesh T. Bhawale, Siddharth Sharma, Umesh A. Kshirsagar
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Cu0-Promoted Truce–Smiles Rearrangement for Aryl-Difluoromethylenation of C═C Bonds via a Reductive Radical–Polar Crossover Process J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Hongxiao Li, Kaiji Hu, Jianhua Zhang, Haizhen Jiang
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Asymmetric Transfer Hydrogenation of gem-Difluorocyclopropenyl Ketones: The Synthesis and Functionalization of Enantioenriched cis gem-Difluorocyclopropyl Ketones J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Olivier Charron, Marharyta Kosiuha, Phannarath Phansavath, Virginie Ratovelomanana-Vidal, Geoffrey Gontard, Christophe Meyer
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RuII–Catalyzed C–H Activated Diverse Cyclization with Transformation of Substrate-DG to Functional Groups: Synthesis of Functionalized Indoles and Indenones J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Ramlal Baidya, Saikat Khamarui, Sabir A. Molla, Pintu Pratihar, Prasenjit Das, Tanmay K. Pati, Dilip K. Maiti
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Benzoimidazolyl Organoseleniums: Antioxidant Activity and Catalysts for Selective Iodination of Arenes and Nitro-Michael Reaction J. Org. Chem. (IF 3.3) Pub Date : 2024-09-16 Monojit Batabyal, Deeksha Chaurasia, Priyanka Rani Panda, Raushan Kumar Jha, Rahul Kadu, Sangit Kumar
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Integrated Approach for Allyl Amine Synthesis Combining the Decarboxylative Coupling of Arylacrylic Acids with the Petasis Reaction J. Org. Chem. (IF 3.3) Pub Date : 2024-09-15 Heeju Lee, Kwang Ho Song, Sunwoo Lee
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Photoinduced Deconstructive Alkylation Approach Enabled by Oxy-Radicals from Alcohols J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Yiman Gao, Yan Li, Wenxuan Yan, Kui Zhang, Lingchao Cai
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Computational Study on Flavin-Catalyzed Aerobic Dioxygenation of Alkenyl Thioesters: Decomposition of Anionic Peroxides J. Org. Chem. (IF 3.3) Pub Date : 2024-09-14 Yuan-Ye Jiang, Yu Li, Chao Chen, Yi-Xuan Xin
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Acid-Mediated Intramolecular Cyclizations of (N-Aryl)-acetylenic Sulfonamides: Synthesis of Fused and Spirocyclic Sultams J. Org. Chem. (IF 3.3) Pub Date : 2024-09-14 Chada Raji Reddy, Anjali Rathaur, Banoth Karuna Sagar
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Thioarylation of Alkynes to Generate Dihydrothiopheniums through Gold(I)/(III)-Catalyzed Cyclization–Cross-Coupling J. Org. Chem. (IF 3.3) Pub Date : 2024-09-14 Joseph A. Kaplan, Jonghyun Won, Suzanne A. Blum
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B/Pd Synergistic Catalysis for the Decarboxylative Allylation of 2-(2-Azaaryl)acetic Acids J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Chicheng Ma, Chao Fu, Zhihe Cen, Kai Huang, Xuehe Lu, Xiaoyu Wu
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Highly Reactive Glycosylation with 1-O-(Methylthio)thiocarbonyl Glycosyl Donors under Acidic to Neutral Reaction Conditions J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Tao Luo, Guo-Hui Zhang, Yang-Fan Guo, Hai Dong
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Correction to “3-Formylpyrazolo[1,5-a]pyrimidines as Key Intermediates for the Preparation of Functional Fluorophores” J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Juan-Carlos Castillo, Alexis Tigreros, Carlos Cifuentes, Jaime Portilla
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Highly Enantioselective Synthesis of Polycyclic Dihydroisoquinolinones via NHC-Catalyzed [4 + 2] Annulations J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Xiaojie Ren, Xiao-Yong Duan, Yuxuan Feng, Yanting Li, Jiahan Li, Jing Qi
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De Novo Enantioselective Synthesis of Hexafluorinated d-Glucose J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Sébastien Depienne, Clément Q. Fontenelle, Mark E. Light, Kristof Van Hecke, Bruno Linclau
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Three-Component Synthesis of 1-Substituted 5-Aminotetrazoles Promoted by Bismuth Nitrate J. Org. Chem. (IF 3.3) Pub Date : 2024-09-13 Iva S. de Jesus, Amenson Trindade Gomes, Igor Sande, Silvio Cunha
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Gold(I)-Catalyzed Rautenstrauch/Hetero-Diels–Alder/Retro-aza-Michael Cascade Reaction for the Synthesis of α-Hydrazineyl-2-cyclopentenones J. Org. Chem. (IF 3.3) Pub Date : 2024-09-12 Dina Scarpi, Claudia Capanni, Samuele Visi, Cristina Faggi, Ernesto G. Occhiato
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Synthesis of Aryl Alkyl Thioethers via a Copper-Catalyzed Three-Component Reaction with DABSO, Aryldiazonium Salts, and Alkyl Bromides J. Org. Chem. (IF 3.3) Pub Date : 2024-09-11 Nithin Pootheri, Sunwoo Lee
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Metal-Free Synthesis of 2-(per)Fluoroalkyl-3-nitro Indoles via Intramolecular Cyclization of Amides J. Org. Chem. (IF 3.3) Pub Date : 2024-09-12 Grigorii K. Sterligov, Maria A. Rasskazova, Egor A. Drokin, Dilshodakhon K. Isaeva, Alexandra A. Ageshina, Sergey A. Rzhevskiy, Olga V. Shurupova, Maxim A. Topchiy, Lidiya I. Minaeva, Andrey F. Asachenko
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Benzoylation of Tetrols: A Comparison of Regioselectivity Patterns for O- and S-Glycosides of d-Galactose J. Org. Chem. (IF 3.3) Pub Date : 2024-09-12 Jack Porter, Jacob Roberts, Gavin J. Miller
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Palladium-Catalyzed [3 + 2] Cycloaddition of 4-Vinyl-4-Butyrolactones with Alkenes: Synthesis of Spirocyclopentane Compounds J. Org. Chem. (IF 3.3) Pub Date : 2024-09-12 Honghao Sun, Aoran Song, Shuang Gu, Yi Tang, Sen Yang, Wenhui Li, Hongchao Guo
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Photoinduced HCl-Mediated Cross-Dehydrogenative Coupling of Quinolines with Alcohols and Ethers J. Org. Chem. (IF 3.3) Pub Date : 2024-09-12 Feixiang Guo, Yingchang Guo, Qianqian Sun, Tao Zhang, Yakun Wang, Lizhen Fang