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The photocatalytic H2O2 production: Design strategies, Photocatalyst advancements, environmental applications and future prospects Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-21 Asif Hayat, Zeeshan Ajmal, Abdullah Yahya Abdullah Alzahrani, Sana Ben Moussa, Manal Khered, Naif Almuqati, Ahmad Alshammari, Yas Al-Hadeethi, Hamid Ali, Yasin Orooji
Hydrogen peroxide (H2O2) is a multipurpose and highly efficient agent that may be used as an oxidizing agent in several fields, including the bleaching industry, pollution control, medical treatments, and chemical synthesis. The existing approach for producing H2O2 is regarded as neither affordable nor environmentally friendly owing to its high energy requirements and the emission of hazardous organic
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Di(2-picolyl)amine appended luminescent probes: Advances in bioimaging and therapeutics Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-20 Bishnu Das, Parna Gupta
Di(2-picolyl)amine appended luminescent probes have been developed as versatile tools for bioimaging and therapeutic applications. These probes offer real-time monitoring and visualization of metal ions, anions, and biomolecules in cellular systems. Specifically, it covers the detection and monitoring of metal ions such as Cu2+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Hg2+, Cd2+, Al3+, Ag+, Pb2+ as well as anions
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Recent advances over the doped g-C3N4 in photocatalysis: A review Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-19 Muhammad Asim Khan, Sadaf Mutahir, Imrana Shaheen, Yuan Qunhui, Mohamed Bououdina, Muhammad Humayun
The fossil fuels energy sources including natural gas, petroleum and coal are the major causes of energy and environmental-related crises. To defend the earth for upcoming generations, the prioritization of renewable energy and sustainability is crucial. To cope with these issues, numerous methodologies have been extensively employed. The most efficient and secondary pollutant-free technology for energy
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Proton conductive polyoxometalates Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-18 Rui-Lan Liu, Yifan Chen, Xiao Su, Wenping Zhu, Zengchen Liu, Yahong Chen, Dan-Yang Wang, Gang Li
Polyoxometalates (POMs), also known as transition metal‑oxygen clusters deliver unique physical and chemical properties such as low effective surface charge density, high thermal stability, and multi-electron acceptance, making them suitable for proton conductors. In recent years, proton conductive POMs have achieved significant progress in high performance (>10−2 S/cm) comparable to conventional materials
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Lanthanide-based photocatalysts for CO2 conversion: Are they a better choice for realizing sustainability? Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-18 Liumei Li, Zicheng Wang, Lina Zhao, Hongbo Liu, Yuxin Li
Employing photocatalysis to diminish CO2 concentrations when exposed to visible spectrum illumination, converting it into energy materials and chemical products, is an effective method to achieve carbon cycling. Among the many catalysts, lanthanide-based metals, with gradually filling 4f orbitals that give them unique electronic structures, have garnered significant focus on the domain of decreasing
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Antimicrobial carbon materials-based quantum dots: From synthesis strategies to antibacterial properties for diagnostic and therapeutic applications in wound healing Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-18 Iman Zare, Shima Zahed Nasab, Amid Rahi, Azadeh Ghaee, Morvarid Koohkhezri, Marzieh Ramezani Farani, Hanna Madadi Gholipour, Amir Hossein Atabaki, Michael R. Hamblin, Ebrahim Mostafavi, Heemin Kang
The emergence of multidrug resistance (MDR) pathogens and the rapid depletion of the antibiotic arsenal have sparked interest in discovering and developing innovative antimicrobial agents. One example of these new agents is antimicrobial nanostructured materials, which have received significant attention due to their intrinsic advantages and unique antibacterial mechanisms. Among such antimicrobial
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Recent advances on visible and near-infrared thermometric phosphors with ambient temperature sensitivity: A review Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-18 Lesole A. Ramolise, Simon N. Ogugua, Hendrik C. Swart, David E. Motaung
The quantification of the exact temperature with precision is fundamentally vital for scientific exploration and industrial production. As a result, the accuracy of regular thermometers is currently questionable for measuring the temperature at sub-micrometric spatial resolution. Hence, there is a high demand for advanced non-contact thermometer sensors, which aid in the alternative fabrication of
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Development of well-defined olefin block (co)polymers achieved by late transition metal catalysts: Catalyst, synthesis and characterization Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-18 Ying Wang, Jingjing Lai, Qingqiang Gou, Rong Gao, Gang Zheng, Randi Zhang, Zhihui Song, Qiang Yue, Zifang Guo
As the saturation rate of the bulk polyolefin market accelerates, the development of high value-added polyolefins becomes increasingly urgent. Particular attention is directed towards advancing olefin block (co)polymers with innovative structures and functions, valued for their exceptional compatibility, mechanical properties, and solubility. The INFUSE from Dow Chemical has achieved significant success
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A review on defect engineered NIR persistent luminescence through transition metal ion (Cr, Mn, Fe and Ni) doping: Wider perspective covering synthesis, characterization, fundamentals and applications Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-17 Reshmi T. Parayil, Santosh K. Gupta, M. Mohapatra
Persistent luminescence is an optical phenomenon where materials continue to emit light after the cessation of the excitation source which leads to different applications in areas like bioimaging, information storage, anticounterfeiting, etc. This review focuses on the latest advancements in near-infrared (NIR) persistent luminescence (PersL) materials doped with Cr3+, Mn4+, Mn2+, Fe3+ and Ni2+along
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Shedding light on Alzheimer's disease: Recent advances in highly selective fluorescent probes Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-16 Jingyun Liu, Yuchen Li, Kulsoom, Fu Wang
Alzheimer's disease (AD) is the predominant neurodegenerative disorder, affecting approximately 60–80 % of all patients diagnosed with dementia globally. Given the intricate nature of AD's pathogenesis, numerous biologically active substances have gained attention, including amyloid-β plaques (Aβ), TAU proteins, metal ions, and reactive oxygen/nitrogen/sulfur species. The development of small-molecule
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Polyoxometalates emerging as multifunctional powerhouses in the battle against cancer Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-16 Xiaotong Xu, Yunfei Guo, Bole Li, Yanfei Lv, Zhaohui Wu, Siyu Liang, Lei He, Yu-Fei Song
A variety of emerging anticancer therapeutic strategies, including chemodynamic, photothermal and combination therapies, are igniting considerable interests due to their precise targetability, minimal side effects, high efficacy and simplified treatment procedures. Polyoxometalates (POMs), as typical metallodrugs, offer many advantages in cancer treatment, including simple synthesis processes, a defined
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Characterizing metal carbide structures: Insights from photoelectron spectroscopy and density functional theory Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-16 Majid Ali, Umar Farooq, Xi-Ling Xu, Hong-Guang Xu, Wei-Jun Zheng
Metal carbides are highly intriguing to researchers due to their diverse properties, including electrical, thermal, magnetic, and mechanical characteristics. They are prized for their high specific surface areas, exceptional biocompatibility, and versatile applications across various fields such as chemical synthesis, catalysis, mechanical components, coatings, electronics, and aerospace materials
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Insights into excitons manipulation in metal chalcogenides based Nano-heterojunction Photocatalysts: A breakthrough in green hydrogen production Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-14 Vempuluru Navakoteswara Rao, Chi Won Ahn, Yonghee Lee, Muthukonda Venkatakrishnan Shankar, Hyunguk Kwon, Kyeounghak Kim, Mashallah Rezakazemi, Sang-jae Kim, Jun-Mo Yang
The advent of nanoscience and technology has ushered in a realm of possibilities in photocatalysis research, offering transformative applications in energy and environmental sustainability. However, the practical utility of unmodified single semiconductor photocatalysts is hampered by limitations such as a restricted absorption spectrum, low intensity, unproductive recombination of photogenerated electrons
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Recent advances in metal-free photosensitizers for dye-sensitized photoelectrochemical cells Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-14 Xiao-Lin Wang, Jian-Feng Huang, Jun-Min Liu, Panagiotis Tsiakaras
Dye-sensitized photoelectrochemical cells (DSPECs), which consist an effective approach to achieve total water splitting, have attracted a lot of attention in recent years. Nowadays, most of the photosensitizers used in DSPECs are noble metal complexes, especially polypyridine‑ruthenium complexes. To avoid the use of noble metal ions, metal-free dyes are emerging as promising candidates for the construction
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Nanostructure-reinforced multifunctional hydrogels for synergistic cancer therapy Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-13 Satar Yousefiasl, Mahsa Ghovvati, Mojdeh Mirshafiei, Fatemeh Hakimi, Amir Azadi, Seyed Mohammad Iman Moezzi, Meng Yuan, Farshid Sefat, Iman Zare, Aziz Maleki, Jun Lin
Hydrogel-integrated nanostructures offer a novel approach to cancer therapy by combining hydrogels' biocompatibility and tunable drug release with nanotechnology. These nanoplatforms enhance treatment precision and efficacy while minimizing side effects, providing a sophisticated and targeted delivery system. This comprehensive review explores synergistic cancer therapies utilizing hydrogel-integrated
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Advances in reticular materials for sustainable rare earth element recovery Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-13 Ke Liu, Yang Liu, You Wu, Jiale Liu, Qin Shuai, Lijin Huang, Zhaochu Hu, Yusuke Yamauchi
The rapid growth of the high-tech industry has resulted in an unprecedented demand for rare earth elements (REEs) due to their unique and irreplaceable properties. However, the limited reserves and non-renewable nature of REEs have created a significant imbalance between supply and demand. Recycling and separation of REEs from various industrial and mining wastes are crucial in alleviating the supply
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Alkane functionalization: Recent advances Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-13 Nuno Reis Conceição, Kamran T. Mahmudov, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro
Despite the progress of alternative/renewable energy technologies (solar, wind, hydroelectric, geothermal, nuclear, hydrogen, bio, tidal and wave), still the fossil raw materials such as petroleum (crude oil), natural gas and coal remain the main source of energy. The major constituents of crude oil ( 20–50 %) and natural gas ( 95 % methane, 4 % ethane, 0.2 % propane and 0.02 % butane) are alkanes
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Copper-based nanomaterials for the treatment of bacteria-infected wounds: material classification, strategies and mechanisms Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-11 Wenqi Wang, Peng Gao, Hengshuo Gui, Xiaolong Wei, Hengguo Zhang, Xianwen Wang
Bacterial infection in wounds is a complex and multilayered process, increasing the complexity and challenges of treatment. It often leads to infection, a deeper inflammatory response and a multifaceted slowing down of the wound repair process. Therefore, addressing these unique challenges requires focused and effective treatment strategies aimed at achieving optimal therapeutic outcomes and preventing
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Discrete metallosupramolecular architectures with amino acids Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-11 Shannon Thoonen, Kellie L. Tuck, David R. Turner
Amino acids provide a convenient, economical, and non-toxic route for the synthesis of chiral metallosupramolecular architectures, including coordination cages and metal–organic cages, metallocycles, and metallocatenanes. In this review, we collate recent works on supramolecular coordination complexes assembled with amino acid derivatives, while highlighting the role of the amino acid on the chirality
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Cobalt ferrites: Structural insights with potential applications in magnetics, dielectrics, and Catalysis Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-11 Rohit Jasrotia, Jyoti Prakash, Yasser B. Saddeek, Abdullah H. Alluhayb, Alaa M. Younis, Natrayan Lakshmaiya, Chander Prakash, K.A. Aly, Mika Sillanpää, Yasser A.M. Ismail, Abhishek Kandwal, Pankaj Sharma
Cobalt ferrite, an anomaly among the other spinel ferrites, have continuously captured the consideration of various researchers across the different disciplines due to its inimitable traits and characteristics. In contrast to their spinel ferrite counterparts, the cobalt ferrite exhibits high coercivity, excellent dielectric properties, and significant catalytic behavior, making it a subject of intense
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Persistent luminescence materials for imaging and therapeutic applications Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-11 Yaqiong Wang, Xue-Bo Yin
Persistent luminescence materials (PLMs) are unique as their afterglow emission. The distinctive non-in-situ excitation mechanism could eliminate interference from autofluorescence and scattered light, enabling high sensitivity for optical imaging applications. Additionally, PLMs can be integrated with metal ions, photothermal species, photosensitizers, therapeutic drugs, nucleic acid, or immunological
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Advances in nanotherapeutic strategies for Huntington's disease: Design, delivery, and neuroprotective mechanisms Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-10 Sameera Khan, Nargis Bano, Shakir Ahamad, Nawab John Dar, Aamir Nazir, Shahnawaz Ali Bhat
Huntington's Disease (HD) is a severe neurodegenerative disorder lacking effective diagnostic and treatment options. However, there is increasing interest in the potential of nanotherapeutics to address this challenging condition. Nanotherapeutics, characterized by their distinct capacity for precise targeting and delivery of therapeutic agents to designated sites, exhibit considerable potential in
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Nanomaterial-mediated self-calibrating biosensors for ultra-precise detection of food hazards: Recent advances and new horizons Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-10 Lulu Cao, Qinghua Ye, Yuwei Ren, Bao Gao, Yuwei Wu, Xinyu Zhao, Na Ling, Moutong Chen, Yingwang Ye, Qingping Wu
Food safety hazards pose a serious threat to human health and public safety. The development of rapid and accurate detection technologies for food hazards is, therefore, of paramount importance. Nanomaterial-based detection technology has solved the limitations of traditional detection methods, such as long detection time and high cost. However, most current biosensors still rely on single-signal outputs
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Binding- and activity-based small molecule fluorescent probes for the detection of Cu+, Cu2+, Fe2+ and Fe3+ in biological systems Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-07 Yongqing Zhou, Xiaofeng Yang, Won Jun Jang, Mei Yan, Juyoung Yoon
Although transition metals make up less than 0.1 % of the total mass in a human body, they have significant impacts on fundamental biological processes. Among them, copper(I) (Cu), copper(II) (Cu), ferrous ion (Fe) and ferric ion (Fe) exhibited many vital biochemical events. Therefore, precisely monitoring their biological distribution and concentrations modern analytical techniques are urgently required
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The future of alkaline water splitting from the perspective of electrocatalysts-seizing today's opportunities Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-05 Shujie Liu, Yan Wei, Mingkui Wang, Yan Shen
Water electrolysis currently accounts for approximately 4% of the global hydrogen production volume, indicating there is a significant room to provide more low-carbon hydrogen with this technology. At present, alkaline electrolysis of water emerges as the most promising technology to realize large-scale green hydrogen production. Electrocatalysts that can operate efficiently and stably at high current
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Versatile organic fluorescent probes for visualizing the dynamics of lipid droplets Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-05 Mingyue Cao, Yunting Liu, Caihong Xiang, Guangzhen Zheng, Qingping Xiong, Guangle Niu
Lipid droplets (LDs) have recently garnered significant attention due to their pivotal roles in life and diseases. Thus, seeking suitable tools to visualize the dynamics of LDs and reveal their mysterious functions is particularly important. Organic fluorescent probes provide significant advantages in terms of excellent sensitivity, high selectivity, and remarkable spatial resolution for the in situ
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Exploring progress in binary and ternary nanocomposites for photoelectrochemical water splitting: A comprehensive review Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-05 Ala Manohar, Thirukachhi Suvarna, Krishnamoorthi Chintagumpala, Mohd Ubaidullah, Naresh Mameda, Ki Hyeon Kim
Nanocomposites have become increasingly important in photoelectrochemical (PEC) water splitting, considerably improving stability and efficiency. By including nanoscale components, these composites improve light absorption, charge separation, and catalytic activity. Their large surface areas enable effective catalytic reactions, and their electrical characteristics may be precisely controlled. A new
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Rational regulation of Cu species in N-doped carbon-hosted Cu-based single-atom electrocatalysts for the conversion of nitrate to ammonia Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-09-05 Chao Liang, Xiao-Yu Wei, Wei Liu, Yuan-Zheng Zhang, Zu-Ju Ma, Hui-Yun Liu, Cheng-Gang Niu, Li-Sha Jiang
Nitrate (NO) pollution in the ecological environment cause a substantial threat to ecosystem equilibrium and human health. The electrocatalytic nitrate reduction reaction (NORR) emerges as an efficacious method for addressing NO pollution. Single-atom catalysts (SACs) exhibit prominent activity, selectivity, and stability, attributed to their efficient atomic utilization, adaptable coordination environment
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Unveiling the versatile applications of 9-fluorenone: A comprehensive review 2010–2024 Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-31 Neha, Navneet Kaur
Fluorenone, a compound with a fused aromatic ring structure, is widely used in scientific research and technological advancements due to its extensive aromaticity, customizable electron-accepting traits, tuneable luminescence, efficient energy, charge transfer abilities, and unique characteristics. It plays a crucial role in material, medical, and chemical domains due to its broad applicability. Fluorenone
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Recent progress in Pt-based electrocatalysts: A comprehensive review of supported and support-free systems for oxygen reduction Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-30 Narayanamoorthy Bhuvanendran, Sabarinathan Ravichandran, Sanghyun Lee, Fereshteh Dehghani Sanij, Sabariswaran Kandasamy, Puran Pandey, Huaneng Su, Sae Youn Lee
In recent years, there has been notable progress in developing advanced catalyst materials and improving the performance of Pt-based catalysts for the oxygen reduction reaction (ORR). ORR is pivotal for achieving high energy conversion efficiency in fuel cells and metal-air batteries. Despite extensive research, balancing the activity and stability of electrocatalysts remains challenging. Due to the
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Tumor vasculature associated nanomedicine strategies Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-29 Xiaorui Wang, Xuejiao Song, Qinglin Wei, Wenjun Wang, Huae Xu, Xiaochen Dong
The tumor vasculature plays a crucial role in promoting tumor growth and metastasis, showcasing heterogeneity in terms of tissue composition, functionality, and structural characteristics. The main limitation of traditional anti-tumor therapy arises from the disordered occlusion and structural abnormalities present within the vascular network of the tumor, which create a bottleneck effect. Hence, the
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S-scheme heterojunction photocatalysts: Mechanism, challenges and opportunities Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-29 Chenhui Wang, Yuanyuan Zhao, Chao Cheng, Qian Li, Changfa Guo, Yong Hu
S-scheme heterojunction photocatalysts hold great promise in sustainable energy production for attractive solar to chemical conversion efficiencies based on designable semiconductor heterostructures. In the past decades, S-scheme heterojunctions were widely investigated in the development of various solar fuels. Conventionally, the concern was mainly focused on the effects of band structure alignment
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Synthesis and application of graphdiyne-based materials for advanced chemical sensors Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-29 Na Zhao, Ji Li, Xiao Chang, Wei Zheng, Jun Zhang, Xianghong Liu
Graphdiyne (GDY), with a highly conjugated and tunable molecular structure, holds great promise in various sensors due to its unique physicochemical features such as high specific surface area, adjustable band gap, excellent conductivity, and superior stability. Although GDY has been investigated both theoretically and experimentally in various sensors, a comprehensive understanding on the structure-property
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A review on the advancements in covalent organic frameworks for photocatalytic reduction of carbon dioxide Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-29 Chien Ing Yeo, Yee Seng Tan, Hafiz Taimoor Ahmed Awan, Abdul Hanan, Weng Pin Wong, Rashmi Walvekar, Bey Hing Goh, Mohammad Khalid
Carbon dioxide (CO) emissions from human activities have raised atmospheric CO levels to unsafe highs, necessitating the development of technologies to capture and utilize this greenhouse gas. Photocatalytic conversion of CO into value-added chemicals and fuels using solar energy has attracted significant research interest as a carbon capture and utilization approach. However, existing photocatalysts
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Metal-organic frameworks for photocatalytical carbon dioxide reduction reaction Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-28 Tianyu Li, Ping Wang, Miao He, Tianbao Zhang, Cheng Yang, Zhenxing Li
Excessive use of carbonaceous fuels causes significant CO emissions so that more environmental issues are occurring. Reduction of CO to Carbonaceous compounds using sunlight is a viable strategy to address this problem. Metal-organic frameworks (MOFs) can effectively increase the interaction between CO₂ molecules and active sites thanks to its extensive specific surface area and adjustable pore configuration
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Advanced optical imaging technology in the near infrared window for cell tracking in vivo Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-28 Xuan Zhao, Yongmin Ma, Zuhai Lei
Recent years, cell-based therapeutics are undergoing explosive growth in the modern biomedical field. The ability for non-invasively and real-timely tracking and understanding the fate and functionality of cells after transplantation is vitally important for safe and effective treatments in cell-based therapeutics or exploring physiological and pathological processes in biological systems. Optical
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Application of polyoxometalates in biomass conversion Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-28 Guoping Yang, Yufeng Liu, Yongge Wei
Biomass has garnered considerable attention as a globally available, low-cost, and renewable carbon-neutral source in recent decades. The inherent complexity and stability of biomass made the efficient utilization of biomass under mild conditions a daunting challenge. Recently, significant progress has been made in biomass conversion by functionalized polyoxometalates (POMs) catalysts. In this review
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Metal organic and covalent organic framework-based QCM sensors for environmental pollutant detection and beyond Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-26 Zaynab Golshadi, Mohammad Dinari, Alexander Knebel, Johannes Lützenkirchen, Bahram Hosseini Monjezi
Environmental pollution has become a major global issue, worsened by the rapid growth of industries. Traditional pollutant detection methods often require high operational temperatures and exhibit limited sensitivity and selectivity. Quartz crystal microbalance with dissipation monitoring (QCM-D) sensors have emerged as a promising alternative, offering high sensitivity, affordability, and precise
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Transition metal phosphides as noble-metal-alternative co-catalysts for solar hydrogen production Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-25 Tingting Liu, Chen Chen, Sixiang Liu, Zhangsen Chen, Zonghua Pu, Qiufeng Huang, Lei Zhang, Abdullah M. Al-Enizi, Ayman Nafady, Shuhui Sun, Gaixia Zhang
Hydrogen (H) emerges as a highly promising contender for replacing conventional fossil fuels due to its high combustion heat value and net-zero greenhouse gas emission. Photocatalytic H generation through semiconductor-based water splitting represents a clean and sustainable technology in the field. Developing highly efficient and abundant source semiconductor materials, along with co-catalysts, is
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Spying on carbon dioxide with versatile functional materials and small-molecule fluorescent probes Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-24 Zhen Wang, Qian-Hang Niu, Pengjuan Sun, Yanhua Fu, Yong Zheng, Yuanqiang Sun
CO has attracted significant attention due to its effect on global warming. Meanwhile, CO is also essential for the modern agricultural, food, environmental, oil, and chemical industries. Thus, the rapid and selective detection and measurement of CO is urgent. Since the simplicity, sensitivity, and especially non-destructive detection capacities of probes based on fluorescent molecules, fluorescence-based
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Current roles of metals in arming sonodynamic cancer therapy Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-24 Zhuoli Chen, Xianbo Wu, Jinzhe Liang, Hui Chao
Emerging sonodynamic therapy strategies shed light on conquering oxygen dependence and penetration restriction in photodynamic therapy for non-invasive tumor treatments. During the flourishing of novel sonosensitizer construction strategies, the introduction of metals broadens the fabrication modalities of sonosensitizer and perfects the presently insufficient therapeutic effects of single-modality
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Benchmarking stable Electrocatalysts for green hydrogen production: A chemist perspective Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-24 Akhtar Munir, Jamal Abdul Nasir, Tanveer ul Haq, Javed Iqbal, Irshad Hussain, Ahsanulhaq Qurashi
Electro-induced water splitting module is a fascinating strategy for the conversion of electricity into scalable and clean H as a future energy carrier and has significantly attracted the attention of the scientific community. Despite countless research on electrolyzers, cost-effective and durable electrode materials with high conversion efficiency remain a challenge and dream in this quest. This critical
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Emerging tin-based engineering for tumor treatment: Current advances and forward opportunities Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-23 Yaoyu Hu, Lili Feng, Yanlin Zhu, Chenghao Yu, Ruoxi Zhao, He Ding, Piaoping Yang
Nanomaterials have become promising tools in cancer therapy due to their unique physicochemical properties and wide range of applications. Among various nanomaterials, tin-based nanomaterials have attracted much attention for their potential in treating malignant tumors. The presence of multivalent ions gives tin-based nanomaterials multiple enzymatic activities. Attributed to the quantum-confinement
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Recent advances in metal cluster-containing spin-crossover coordination compounds Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-23 Guang Yang, Zhao-Ping Ni, Ming-Liang Tong
Spin crossover (SCO) complexes are classic magnetic bistable materials with various promising potential applications, such as data storage, displays, switches, actuators and sensors. SCO clusters possess intriguing spin state topologies and provide a good platform to study multi-step SCO behavior and quantum cellular automata. This review focuses on the recent developments of discrete SCO clusters
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Oxidase mimicking nanozyme: Classification, catalytic mechanisms and sensing applications Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-22 Ziting Lin, Jinlong Yuan, Lingxi Niu, Yujiao Zhang, Xin Zhang, Mingyang Wang, Yuanyuan Cai, Zihan Bian, Shuqing Yang, Aihua Liu
Nanozymes are a type of nanomaterials that mimics natural enzymes with biocatalytic functions. Oxidase is a kind of oxidoreductase which oxidizes hydrogen donor substrates in the presence of molecular oxygen. Recently, there have been many reports on various nanomaterials exhibiting oxidase-mimicking activity, which currently became one of the most extensively studied enzymatic property with broad
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Innovative strategies in metal-organic frameworks for enhanced electrochemiluminescence biosensors Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-22 Kai Song, Wei Zhao, Yan Zhou, Duo Liu, Paul K. Chu
Electrochemiluminescence (ECL) is a technique that integrates the benefits of both chemiluminescence and electrochemistry. Early illness diagnosis and hazardous material detection have both benefited greatly from its benefits, which include minimal background signal, high sensitivity, and easy operation. A novel class of porous materials known as metal-organic frameworks (MOFs) is created when organic
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A comprehensive review on the synthesis of ferrite nanomaterials via bottom-up and top-down approaches advantages, disadvantages, characterizations and computational insights Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-22 Muhammad Zain Ul Abidin, Muhammad Ikram, Sawaira Moeen, Ghazanfar Nazir, Mohammed Benali Kanoun, Souraya Goumri-Said
Ferrite nanomaterials (FNMs) have gained much attention due to their vast applications in several areas, such as wastewater treatment, electronics, magnetic, catalysts, biomedical, microwave absorbers, sensors, and biosensors. This review focuses on the synthesis of FNMs and illustrates the advantages and disadvantages of commonly used synthesis techniques, emphasizing the recently published works
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Developments in near-infrared fluorescent probes for G-quadruplexes structures Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-22 Jiaona Han, Jun Li, Xingyu Luo, Guangfu Feng, Jiaheng Zhang
The G-quadruplex (G4) represents a noncanonical guanine-rich nucleic acid secondary structure characterized by the presence of two or more G-quartets stabilized through Hoogsteen hydrogen bonding. These structures play essential roles in various biological processes including DNA replication, gene expression regulation, telomere maintenance, and genomic stability. Effectively visualizing and precisely
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Nano-armor modification of bacteria through supramolecular interactions for disease treatment Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-21 Xinran Cao, Yi Wang, Qirui Wang, Huang Yang, Yuan Ding, Zhengwei Mao
Research on nano-armored bacterial materials (NABM) has attracted considerable attention because of their ability to exert synergistic effects on bacteria and nanomaterials through rational material design. Currently, the predominant methods for preparing NABM involve covalent interactions, supramolecular interactions, and physical encapsulation. Among these mechanisms, supramolecular interaction-based
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Structure regulation of 2D materials by atom confinement for electrocatalysis Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-21 Zhenyu Liu, Longyi Fu, Jijian Liu, Meiling Wang, Jiadong Zhou
Developing highly active and stable electrocatalysts is significant for generating green energy. Ultrahigh exposed active atoms, tunable electronic properties, and high charge migration rate offer a substantial scope of two-dimensional (2D) materials as advanced electrocatalysts but still face limited intrinsic activities and poor stability. Confining metal or non-metal atoms in 2D materials has recently
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Complexation of Gold(I) and Gold(III) in solutions Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-20 George A. Gamov
The present review critically observes literature data on stability constants of gold(I) and gold(III) complexes in aqueous and non-aqueous medium. The equilibrium constants of complexation or ligand exchange as well as the values of E for the redox processes [AuL] + 3e = Au + xL and [AuL] + e = Au + xL are reported or calculated using the results of other researchers. Information about the composition
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Fundamental understanding of Prussian blue and its analogues for superior capacitive deionization: A perspective from nanoarchitectonics Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-20 Changle Li, Yuecheng Xiong, Xiaojie Shen, Dan Luo, Wenjie Wu, Zhengtong Li, Mohamed H. Helal, Zeinhom M. El-Bahy, Yiyong Mai, Zhong Liu, Yusuke Yamauchi, Xingtao Xu
Capacitive deionization (CDI) offers an appealing electrochemical solution for water treatment, where electrode materials play a crucial role in ensuring the efficiency of CDI devices. The quest for novel electrode materials is driven by the need to enhance desalination capacity, cycling stability, ion selectivity, and energy efficiency, given that traditional carbon materials relying on electric double
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State-of-the-art strategies of surface plasmon resonance biosensors in clinical analysis: A comprehensive review Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-17 Jie Zhou, Yue Wang, Guo-Jun Zhang
The pursuit of more sensitive, selective, multifunctional, portable and cost-effective diagnostic tools has propelled biosensing technology to the forefront of clinical research. Surface plasmon resonance (SPR) biosensors could achieve label-free, sensitive, real-time monitoring of biomolecular interactions, thus providing a suitable and reliable platform for clinical analysis. However, to maximize
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AIEgen-functionalized nanoprobes and nanomedicines for cancer diagnosis and therapy Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-16 Chen Wang, Shuailin Li, Bosi Qian, Jin Sun, Zhonggui He, Yuequan Wang, Shenwu Zhang, Cong Luo
The development of functional nanoprobes and nanomedicines has long been a focal point in the realm of precision cancer therapeutics. A particularly noteworthy and promising trend in current research involves integrating diagnostic methods and treatment techniques within a single nanosystem. The luminescence phenomenon known as aggregation-induced emission (AIE) has garnered substantial attention in
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Advances of W-based catalysts from material to electrocatalysis Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-15 Jiayu Xu, Fulin Yang, Ligang Feng
Electrocatalysis technology plays a significant role in promoting efficient energy conversion, where the performance of the catalyst directly determines the efficiency and feasibility of the electrochemical reactions. Among the many studied catalytic materials, tungsten-based catalysts have attracted widespread attention due to their tunable oxidation states and complex chemical states, making significant
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Sulfur-modified MOFs as efficient electrocatalysts for overall water splitting Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-14 Shudi Yu, Jie Li, Yukou Du, Yong Wang, Yangping Zhang, Zhengying Wu
In order to alleviate the shortage of fossil energy, it is an effective way to explore superior electrocatalysts for overall water splitting (OWS) to obtain hydrogen energy. Metal–organic frameworks (MOFs) and their derivatives have become one of the most promising candidates for OWS due to their diversified chemical composition, high specific surface area and porosity, accessible catalytic sites as
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Organoiridium-catalyzed bioorthogonal chemistry Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-14 Deepika Chauhan, Puja Prasad, Pijus K. Sasmal
“Bioorthogonal chemistry” refers to chemical reactions between functional groups not generally present in biological systems and can occur under physiological conditions without interfering with or affecting the surrounding biochemical processes. Metal-catalyzed bioorthogonal chemistry has emerged as a powerful tool in chemical biology, and biomedicine to establish new-to-nature reactions in living
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Transition metal complexes: A new era of photosensitizers for Dearomative photocycloaddition/annulation via energy and Electron transfer Photocatalysis Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-14 Ram N. Yadav, Ashok Kumar Srivastava, Sovan Dey, Arindam Das, Bimal K. Banik, Md. Firoj Hossain
Dearomative photocycloaddition reactions offer a powerful strategy to construct sp-rich 3D frameworks adorned with diverse functionalities from readily available 2D feedstocks. This method leverages visible light to drive cascades of energy transfer (EnT) or single electron transfer (SET) mediated by organic or transition metal photosensitizers (e.g., ruthenium (Ru), chromium (Cr), and iridium (Ir))
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Selective separation of CO2/CH4 gases by metal-organic framework-based composites Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-14 Xiao-Wei Yan, Fahime Bigdeli, Mahsa Abbasi-Azad, Su-Juan Wang, Ali Morsali
In natural gas refining, separation of CO from methane is an important research issue, because CO wastes natural gas energy and causes pipeline corrosion. Compared to common technologies, adsorption-based processes are noteworthy for gas separation because they are inexpensive and have high efficiency. A type of composite consists of a polymer matrix and organic or inorganic fillers. By integrating
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Synthesis, properties, and applications of carbon-encapsulated metal nanoparticles Coord. Chem. Rev. (IF 20.3) Pub Date : 2024-08-14 Santosh K. Tiwari, Michał Bystrzejewski, Yanqiu Zhu
Carbon nano allotropes, comprising zero to three dimensional nanostructures have ushered in a transformative era in materials science and engineering. Their unique properties have transcended classical boundaries in physics and chemistry, displaying exceptional quantum hall effects and challenging the conventional notions of atomic interactions. This article offers a comprehensive analysis of carbon