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Theoretical prediction and experimental synthesis of a Ba0.5Pb0.5S alloy via the molecular precursor route Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-19 Guoxin Wu, Liang Wang, Kepeng Song, Jiashuo Xu, Jinghai Li, Xinzhuo Fang, Dan Huang, Liqiang Zheng, Qilin Wei, William W. Yu
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Tuning the reactivity of an yttrium complex bearing a functionalized silylamido ligand using solvated KCl Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-14 Qing You, Jiamin Cai, Jie Zhang, Xigeng Zhou
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Synergism between metal single-atom sites and S-vacant two-dimensional nanosheets for efficient hydrogen evolution uncovered by density functional theory and machine learning Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-18 Xinyi Li, Dongxu Jiao, Jingxiang Zhao, Xiao Zhao
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Sulfur, phosphorus and iron codoped nickel oxide as an efficient catalyst for the oxygen evolution reaction Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-18 Zhanqiang Hu, Songsong Zhi, Chen Chen, Jiuli Chang, Dapeng Wu, Kai Jiang, Zhiyong Gao
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Ru nanoparticle-loaded amorphous CoMoP as an efficient electrocatalyst for alkaline water/seawater hydrogen evolution Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-16 Wen-Jing Li, Xin-Jie Tian, Hai-Yi Sun, Xue-Ying Yang, Denghao Ouyang, Guodong Li, Bin Liu, Yong-Ming Chai, Bin Dong
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Halogenated carborane molecular ferroelectric crystals with high-temperature phase transition Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-13 Wenjing Guo, Wenkang Cheng, Yuting Li, Zhenhong Wei, Hu Cai
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Rapid and stable complexation of the α-generators bismuth-212 and lead-212 with a tetraazamacrocyclic chelator bearing thiosemicarbazone pendant arms Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-09 Melyssa L. Grieve, Patrick R. W. J. Davey, Paul V. Bernhardt, Craig M. Forsyth, Brett M. Paterson
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Emerging applications of perovskite oxides in electrochemical reduction of carcinogenic nitrate to ammonia: a recent review Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-12 Sadeeq Ullah, Aftab Ahmad, Hefa Cheng, Amin Ullah Jan, Daxiang Cui, Lu Li
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Variable energy transfer in one-dimensional chiral Mn/Cd-based halides and strong stereo-selective fluorescence for chiral recognition Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-12 Sidan Wang, Pei Wang, Guojun Zhou, Nan Zhang, Yilin Mao, Xian-Ming Zhang
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High performance NIR-I to NIR-II emission of a Cr3+-doped Cs2NaLuCl6 phosphor with an IQE and EQE of up to 92.9% and 60.75% Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-11 Fengmei Zhu, Yuan Gao, Jianbei Qiu
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Atypical hydrogenation selectivity of platinum by reactive environment modulation Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-10 Jurjen Cazemier, Moussa Zaarour, Sarah Komaty, Polina Lavrik, Antonio Aguilar Tapia, Sudheesh Kumar Veeranmaril, Jean-Louis Hazemann, Javier Ruiz-Martinez
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Effects of metal–metal bonding in photosensitizers: red-shifted absorption and oscillator strength enhancement Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-06 Oshan J. Jinarathne, Malkanthi K. Karunananda
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(C13N3H14)2MBr4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-05 Jiajing Wu, Yi-Fan Fu, Wenlong Liu, Sheng-Ping Guo
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Design of a bifunctional Janus structure for high efficiency solar distillation in hypersaline brine Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-10 Yun Han, Yunchen Du, Li Zhu, Yonglei Liu, Bo Hu, Bojing Sun, Fei Han
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Progress and perspectives on the development of inorganic nanofibres/nanowires for functional electrolytes of solid-state lithium metal batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-09 Nanping Deng, Wenwen Duan, Wen Yu, Yang Feng, Zichun Feng, Xiaofan Feng, Zhaozhao Peng, Hengying Xiang, Yong Liu, Weimin Kang
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Photosensitizing metal–organic polyhedra combined with Co catalytic sites for CO2 photoreduction Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-05 Jixin Li, Yaming Liu, Kaiyue Ma, Chunguang Li, Zhan Shi
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Tuning photoluminescence properties of Au clusters by surface modification and doping: lessons from case studies of icosahedral Au13 Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-09 Dennis Alexander Buschmann, Haru Hirai, Tatsuya Tsukuda
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Targeting protein aggregation: the promising application of polyoxometalates in neurodegenerative diseases Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-07 Junyi Chen, Wen-Zhu Yang, Huilan Chen, Xiuxia Ding, Hongxu Chen, Cai-Hong Zhan, Zhigang Jin
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Exchange of equatorial ligands in protein-bound paddlewheel Ru25+ complexes: new insights from X-ray crystallography and quantum chemistry Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-06 Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
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Interface engineering of Co2B–MoO3/MOF heterojunctions with rich cobalt defects for highly enhanced NaBH4 hydrolysis Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-06 Chenxi Shang, Luyan Shi, Shuqing Zhou, Sheraz Muhammad, Tayirjan Taylor Isimjan, Huancheng Hu, Xiulin Yang
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Hypercoordinated Si/Ge driving excellent HER catalytic performance in new TM2X (X = Si and Ge) monolayers: a high-throughput investigation by screening transition metal elements Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-31 Tianya Li, Guangtao Yu, E. Yang, Wei Chen
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Bimetallic MOF-based catalysts with enhanced activity for electrochemical hydrogen evolution in acid and alkaline electrolytes Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-05 Rui-Zhe Zhang, Lele Lu, Peng Cheng, Wei Shi
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Boosting the oxygen reduction activity of silver nanoclusters via selective exposure of solvent-coordinated sites Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-05 Zhao-Di Wang, Ye Han, Wen-Yan Sun, Peng Peng, Shuang-Quan Zang
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Binary Ni–W metal sulfides with polyhedral nanostructures towards efficient hydrogen evolution Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-05 Zi-Zhang Liu, Ruo-Yao Fan, Ya-Nan Zhou, Ning Yu, Bin Dong, Zi-Feng Yan
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Thermal-induced coloration and photothermal conversion of an Ag-based coordination polymer with stable radicals Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-30 Hua Ke, Tong Xie, Jian-Zhen Liao
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Bifunctional Sn-Y zeolite triggers tandem catalytic conversion of glucose into 5-hydroxymethylfurfural Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-04 Zhiguo Zhu, Xiaolong Liu, Xue Liu, Songcheng Bo, Kaixuan Yang, Ting Su, Yuchao Zhao, Hongying Lü
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A 3D-assembled endohedral nitrogen fullerene in a metal–organic framework toward spin qubit and quantum sensors Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-04 Xin-Yu Hui, Yu-Shuang Zhang, Qi Xiong, Zhi-Rong Wu, Song Gao, Shen Zhou, Shang-Da Jiang
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Excellent temperature sensitivities based on the FIR technique of up-conversion luminescence in a novel NaLaTi2O6:Yb3+,Tm3+ material Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-04 Kai Li, Zhiyu Zhang, Daiman Zhu, Changtao Yue
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Octahedral CoS2 electrocatalysts for efficient nitrate reduction to ammonia Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-04 Weili Li, Pai Wang, Peng Wang, Hongxian Liu, Chunyang Wu, Yuqing Liu, Jianwen Huang, Zhenxing Fang, Huanmei Guo, Yanning Zhang, Fei Li, Tongwei Wu, Xuping Sun
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Divergent reactivity of U(III) and U(II) complexes with organoazides via isolable diazenylimido intermediates Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-04 Chong Deng, Yihu Yang, Yi Wang, Wenliang Huang
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A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-30 Hao Fu, Xiaohui Zhang, Peiyu Liu, Bo Li, Baolin Wu, Ye Tao, Qianshuang Lu, Yingjie Li, Jiaxi Huang, Fangfang Zhang, Tingchao He, Zhi Chen, Heng Wang, Chenliang Su, Hong-Ying Zang, Xiujun Yu, Xiaopeng Li
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Oxygen vacancy assisted Ru–Ni(OH)2 for efficient ethylene glycol electrooxidation reaction Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-02 Yanyan Li, Xiaobin Liu, Ketao Wang, Jingqi Chi, Haifeng Lin, Lei Wang
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Stabilization of lattice oxygen in lithium rich cathode materials via manipulating Ni content Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-02 Xiaoyuan Zhang, Xiangnan Li, Wenfeng Liu, Huishuang Zhang, Hongyun Yue, Hongyu Dong, Yongfang Li, Shuting Yang, Yanhong Yin
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Synthesis of a cubane-like anion [Re4As2S2(CN)12]6− for coordinate regulation of Na+ ion transport Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-02 Hongyang Li, Andrey V. Ermolaev, Aleksei S. Pronin, Jingang Zheng, Hao Huang, Han Zhang, Lixiang Li, Baigang An, Yuri V. Mironov, Chengguo Sun
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Synergistic effect of ionic liquid-doped spiro-OMeTAD: simultaneous management of energy level alignment and interfacial traps in perovskite solar cells Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-02 Qingshui Zheng, Fengxian Cao, Yuhong Wang, Anling Tong, Shibo Wang, Pengxu Chen, Zeyuan Zhao, Yang Wang, Weihai Sun, Weichun Pan, Yunlong Li, Jihuai Wu
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Building continuous Li-ion transport channels from cathode to anode in solid-state lithium-metal batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-03 Xianxi Liu, Hongying Hou, Yixuan Wang, Sen Ming, Yutao Niu, Xiaohua Yu, Ju Rong, Shizhao Xiong
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Self-assembly of a giant molybdenum titanium-oxo cluster [Mo42Ti12(O2)24] for bifunctional oxidation catalysis Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-03 Ming Xu, Ting Wang, Wenjing Zhang, Keke Guo, Ping Wang, Chao Qin, Lin Xu, Zhongmin Su, Xinlong Wang
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An interplay between metal–fullerene and metal–metal bonding in molecular magnetism of erbium metallofullerenes Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-02 Ruslan B. Zaripov, Fupin Liu, Marco Rosenkranz, Matheus Felipe de Souza Barbosa, Yuri E. Kandrashkin, Vladislav Kataev, Stanislav M. Avdoshenko, Alexey A. Popov
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Photoredox catalysis enabled by atomically precise metal nanoclusters Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-09-02 Junyi Zhang, Linjian Zhan, Boyuan Ning, Yunhui He, Guangcan Xiao, Zhixin Chen, Fang-Xing Xiao
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Excitation wavelength-dependent emission of Mn2+/Sn2+ co-doped Cs3ZnI5 for optical fluorescence anti-counterfeiting applications Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-31 Xiunan Li, Shuang Zhao, Hailong Yu, Jing Liu, Bing Hu, Qiuju Han, Wenzhi Wu
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Highly efficient utilization of polypyrrole enabled by dispersed buckypaper tape for high-performance flexible energy storage Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-30 Haihan Zhou, Shaozhen Liu, Mengyao Ren, Hua-Jin Zhai
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Size matters: altering the metal-surface coordination in micropores via structural confinement effects Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-30 Scott A. Southern, Austin Thompson, Aaron D. Sadow, Frédéric A. Perras
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Constructing built-in electric fields in 2D/2D Schottky heterojunctions for efficient alkaline seawater electrolysis Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-30 Hongjun Chen, Liming Deng, Sheng Zhao, Shuyi Liu, Feng Hu, Linlin Li, Jianwei Ren, Shengjie Peng
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Modulation of the near-infrared-I and -II luminescence of thulium-incorporated lead-free double perovskites Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-30 Jingheng Nie, Weitao Ying, Renping Cao, Sijie Liu, Shaobin Qiu, Chaohong Liao, Xiangyan Yun, Bang Lan, Jing Wang
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Recent advances in rational design, synthesis and application of metal–organic frameworks as visible-light-driven photocatalysts Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-29 Xu-Sheng Li, Yu-Jie He, Jiao Chen, Quan-Quan Li, Ping Liu, Jian-Li Li
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Amorphous heterojunction and fluoride-induced effects enable a F-Ni(OH)2/Ni–B electrocatalyst for efficient and stable alkaline freshwater/seawater hydrogen evolution at a high current density Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-28 Shenyi Chen, Haoming Chu, Ziyin Xie, Lihui Dong, Bin Li, Minguang Fan, Huibing He, Zhengjun Chen
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Insights into the application of cerium dioxide nanoparticle-modified cobalt phosphide as an efficient electrocatalyst for high-performance lithium–sulfur batteries Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-28 Xiaofei Wang, Ganfan Zhang, Yue Li, Yuanting Wu, Wei Luo
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Assembly of Si-substituted heteropolyoxotantalate architecture Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-28 Hanhan Chen, Haojie Xu, Xinyi Ma, Pengtao Ma, Jingping Wang, Jingyang Niu
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A redox-active ligand combines a PCP pincer site with a bidentate N–N donor in opposition Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-28 Derek W. Leong, Yanwu Shao, Nattamai Bhuvanesh, Oleg V. Ozerov
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Activating S surfaces by reversing the electron supply direction for fast hydrogen sensing Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-22 Xin Jia, Musen Li, Yurou Li, Panzhe Qiao, Xiaowu Wang, Yi Jiang, Mengmeng Guo, Pengfei Hu, Bo Lu, Bao-Li An, Zhenggang Xue, Jiaqiang Xu
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Superior-performance lithium–sulfur batteries: a face-centered-cubic-structure high-entropy alloy improves the bidirectional catalytic conversion of polysulfides/sulfides Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-27 Xueyu Wang, Peirong Lin, Chuanhuang Wu, Yuchuan Zhu, Cong Wang, Daying Guo, Xi'an Chen, Shun Wang
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A Co-containing polyoxogermanotungstate for alkaline electrocatalytic water oxidation Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-24 Da-Huan Li, Lei Jia, Yi-Xin Liu, Cai Sun, Xin-Xiong Li, Ping-Wei Cai, Yan-Qiong Sun, Shou-Tian Zheng
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An organic–inorganic hybrid photoluminescent ferroelastic with high phase transition temperature Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-24 Wen-Li Yang, Xin Yan, Miao Wang, Hao Yuan, Yuan-Yuan Tang, Yan Qin, Xian-Jiang Song
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Carbon dioxide affinity (“carboxophilicity”) of trivalent light metal pyrazolates Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-23 Felix Kracht, Philipp Rolser, Klaus Eichele, Cäcilia Maichle-Mössmer, Reiner Anwander
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Unusual singlet oxygen-dependent hydroxyl radical production by a unique ruthenium-polypyridyl-hydroxamate complex under visible light irradiation Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-22 Tian-Shu Tang, Li Mao, Chun-Hua Huang, Chuan-Fang Zhao, Zhi-Sheng Liu, Jing Chen, Ben-Zhan Zhu
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Structural and vacancy assisted engineering of cobalt selenide for ultrahigh energy density sodium ion pouch cell Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-17 Ziling Huang, Jing Liu, Kang Xu, Yue Li, Yajun Tan, Chencheng Sun, Jun Yang, Hongbo Geng
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A bis-aromatic MOF system constructed with a copper iodine cluster and porphyrinic ligand for enhancing near-infrared photothermal conversion Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-22 Man Cao, Qian-You Wang, Run-Meng Li, Fangfang Dai, Shan Wang, Peng Luo, Jia-Hua Hu, Xi-Yan Dong, Ren-Wu Huang
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Cobalt and lithium recovery from spent LiCoO2 using a free-standing potassium zinc hexacyanoferrate/carbon cloth composite electrode Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-22 Mengxiang Ye, Huaimeng Li, Xi Wu, Guofeng Zhang, Yunxia Zhang
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Halogen regulation of multifunctional hybrid materials with photoluminescence and dielectric response Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-22 Jiu-Yang Liu, Ming Zhu, Feng-Wen Zhang, Hao-Fei Ni, Zhi-Long Li, Bo Zhuang, Kun Ding, Da-Wei Fu, Hai-Feng Lu, Meng-Meng Lun
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Thermally stable NIR broad emission of Cr3+ doping phosphor with a high output power Inorg. Chem. Front. (IF 6.1) Pub Date : 2024-08-22 Zhishan Chen, Shaoan Zhang, Zhenzhang Li, Huacong Ye, Haoran Yan, Jialong Xu, Ling Gao, Yang Li, Shizhen Zhang