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31P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus Bond Order J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Jingzhen Du, Joseph Hurd, John A. Seed, Gábor Balázs, Manfred Scheer, Ralph W. Adams, Daniel Lee, Stephen T. Liddle
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Revealing the Orientation Selectivity of Tetrapyridyl-Substituted Porphyrins Constrained in Molecular “Klotski Puzzles” J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Zewei Yi, Yuan Guo, Rujia Hou, Zhaoyu Zhang, Yuhong Gao, Chi Zhang, Wei Xu
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Substrate-Controlled Catalysis in the Ether Cross-Link-Forming Radical SAM Enzymes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Suze Ma, Wenhui Xi, Shu Wang, Heng Chen, Sijia Guo, Tianlu Mo, Wenxue Chen, Zixin Deng, Fener Chen, Wei Ding, Qi Zhang
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Large Perpendicular Magnetic Anisotropy Induced by an Intersite Charge Transfer in Strained EuVO2H Films J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Morito Namba, Hiroshi Takatsu, Riho Mikita, Yao Sijia, Kantaro Murayama, Hao-Bo Li, Ryo Terada, Cédric Tassel, Hiroki Ubukata, Masayuki Ochi, Regino Saez-Puche, Elias Palacios Latasa, Naoki Ishimatsu, Daisuke Shiga, Hiroshi Kumigashira, Katsuki Kinjo, Shunsaku Kitagawa, Kenji Ishida, Takahito Terashima, Koji Fujita, Takeaki Mashiko, Keiichi Yanagisawa, Koji Kimoto, Hiroshi Kageyama
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Type-I CdS/ZnS Core/Shell Quantum Dot-Gold Heterostructural Nanocrystals for Enhanced Photocatalytic Hydrogen Generation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Na Jin, Yonglei Sun, Wenwu Shi, Ping Wang, Yasutaka Nagaoka, Tong Cai, Rongzhen Wu, Lacie Dube, Hawi N. Nyiera, Yuzi Liu, Tomoyasu Mani, Xinzhong Wang, Jing Zhao, Ou Chen
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Tripodal Organic Cages with Unconventional CH···O Interactions for Perchlorate Remediation in Water J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Jayanta Samanta, Miao Tang, Mingshi Zhang, Russell P. Hughes, Richard J. Staples, Chenfeng Ke
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Chemical Specification of E3 Ubiquitin Ligase Engagement by Cysteine-Reactive Chemistry J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Roman C. Sarott, Inchul You, Yen-Der Li, Sean T. Toenjes, Katherine A. Donovan, Pooreum Seo, Martha Ordonez, Woong Sub Byun, Muhammad Murtaza Hassan, Franziska Wachter, Edward T. Chouchani, Mikołaj Słabicki, Eric S. Fischer, Benjamin L. Ebert, Stephen M. Hinshaw, Nathanael S. Gray
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Hydrogen Storage with Aluminum Formate, ALF: Experimental, Computational, and Technoeconomic Studies J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Hayden A. Evans, Taner Yildirim, Peng Peng, Yongqiang Cheng, Zeyu Deng, Qiang Zhang, Dinesh Mullangi, Dan Zhao, Pieremanuele Canepa, Hanna M. Breunig, Anthony K. Cheetham, Craig M. Brown
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Strong Solvent and Dual Lithium Salts Enable Fast-Charging Lithium-Ion Batteries Operating from −78 to 60 °C J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Yumeng Zhao, Zhenglin Hu, Zhengfei Zhao, Xinlian Chen, Shu Zhang, Jun Gao, Jiayan Luo
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Sorting of Cluster-Confined Metallic Single-Walled Carbon Nanotubes for Fabricating Atomically Vacant Uranium Oxide J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Xin Zhao, Kun Wang, Guoping Yang, Xiao Wang, Chenguang Qiu, Jian Huang, Yanglin Long, Xiaoxin Yang, Boyuan Yu, Guodong Jia, Feng Yang
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Enantioselective Synthesis of Cyclobutane Derivatives via Cascade Asymmetric Allylic Etherification/[2 + 2] Photocycloaddition J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-28 Pusu Yang, Rui-Xiang Wang, Xu-Lun Huang, Yuan-Zheng Cheng, Shu-Li You
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Topology-Determined Structural Genes Enable Data-Driven Discovery and Intelligent Design of Potential Metal Oxides for Inert C–H Bond Activation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 Chuan Zhou, Chen Chen, P. Hu, Haifeng Wang
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Controlled Noncovalent Synthesis of Secondary Supramolecular Polymers J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 Souvik Sarkar, Raju Laishram, Darshana Deb, Subi J. George
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Synthetic Control of the Defect Structure and Hierarchical Extra-Large-/Small-Pore Microporosity in Aluminosilicate Zeolite SWY J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 Ruxandra G. Chitac, Vladimir L. Zholobenko, Robin S. Fletcher, Emma Softley, Jonathan Bradley, Alvaro Mayoral, Alessandro Turrina, Paul A. Wright
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Bulky Substituents Promote Triplet–Triplet Annihilation Over Triplet Excimer Formation in Naphthalene Derivatives J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 Axel Olesund, Shima Ghasemi, Kasper Moth-Poulsen, Bo Albinsson
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Pentagon, Hexagon, or Bridge? Identifying the Location of a Single Vanadium Cation on Buckminsterfullerene Surface J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 Jianzhi Xu, Joost M. Bakker, Olga V. Lushchikova, Peter Lievens, Ewald Janssens, Gao-Lei Hou
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1,2-Redox Transpositions of Tertiary Amides J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 Benjamin D. A. Shennan, Sergio Sánchez-Alonso, Gabriele Rossini, Darren J. Dixon
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Spotlights on Recent JACS Publications, Volume 145, Issue 39 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-27 ACS Contributing Correspondents
This article has not yet been cited by other publications.
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High-Entropy Laminates with High Ion Conductivities for High-Power All-Solid-State Lithium Metal Batteries J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-26 Qi Zhao, Zhenjiang Cao, Xingguo Wang, Hao Chen, Yu Shi, Zongju Cheng, Yu Guo, Bin Li, Yongji Gong, Zhiguo Du, Shubin Yang
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Oxophilicity-Controlled CO2 Electroreduction to C2+ Alcohols over Lewis Acid Metal-Doped Cuδ+ Catalysts J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-26 Libing Zhang, Jiaqi Feng, Limin Wu, Xiaodong Ma, Xinning Song, Shunhan Jia, Xingxing Tan, Xiangyuan Jin, Qinggong Zhu, Xinchen Kang, Jun Ma, Qingli Qian, Lirong Zheng, Xiaofu Sun, Buxing Han
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Highly Selective C(sp3)–H Bond Oxygenation at Remote Methylenic Sites Enabled by Polarity Enhancement J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-26 Sergio Sisti, Marco Galeotti, Filippo Scarchilli, Michela Salamone, Miquel Costas, Massimo Bietti
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Selenophene-Based 2D Ruddlesden-Popper Perovskite Solar Cells with an Efficiency Exceeding 19% J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-26 Qiang Fu, Mingqian Chen, Qiaohui Li, Hang Liu, Rui Wang, Yongsheng Liu
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Autophagy Receptor-Inspired Antibody-Fusion Proteins for Targeted Intracellular Degradation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2023-09-25 Ziwen Jiang, Yu-Hsuan Kuo, Michelle R. Arkin
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Mechanistic Studies on the Bismuth-Catalyzed Transfer Hydrogenation of Azoarenes Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-28 Hye Won Moon, Feng Wang, Kalishankar Bhattacharyya, Oriol Planas, Markus Leutzsch, Nils Nöthling, Alexander A. Auer, Josep Cornella
Organobismuth-catalyzed transfer hydrogenation has recently been disclosed as an example of low-valent Bi redox catalysis. However, its mechanistic details have remained speculative. Herein, we report experimental and computational studies that provide mechanistic insights into a Bi-catalyzed transfer hydrogenation of azoarenes using p-trifluoromethylphenol (4) and pinacolborane (5) as hydrogen sources
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Structure and Function of the α-Hydroxylation Bimodule of the Mupirocin Polyketide Synthase. Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-28 Ashley J Winter, Nisha Khanizeman, Abigail M. C. Barker-Mountford, Andrew James Devine, Luoyi Wang, Zhongshu Song, Jonathan A Davies, Paul R Race, Christopher Williams, Thomas James Simpson, Christine L Willis, Matthew Philip Crump
Mupirocin is a clinically important antibiotic produced by a trans-AT Type I polyketide synthase (PKS) in Pseudomonas fluorescens. The major bioactive metabolite, pseudomonic acid A (PA-A), is assembled on a tetrasubstituted tetrahydropyran (THP) core incorporating a 6-hydroxyl group proposed to be introduced via α-hydroxylation of the thioester of the acyl carrier protein (ACP) bound polyketide chain
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Stabilization and binding of [V4O12]4–and unprecedented [V20O54(NO3)]n – to lysozyme upon loss of ligands and oxidation of the potential drug VIVO(acetylacetonato)2 Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-28 Giarita Ferraro, Gabriella Tito, Giuseppe Sciortino, Eugenio Garribba, Antonello Merlino
High-resolution crystal structures of lysozyme in the presence of the potential drug VIVO(acetylacetonato)2 under two different experimental conditions have been solved. The crystallographic study reveals the loss of the ligands, the oxidation of VIV to VV and the subsequent formation of adducts of the protein with two different polyoxidovanadates: [V4O12]4–, which interacts with lysozyme non-covalently
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Bacterial Cytochrome P450 Catalyzed Post-translational Macrocyclization of Ribosomal Peptides Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-28 Bei-Bei He, Jing Liu, Zhuo Cheng, Runze Liu, Zheng Zhong, Ying Gao, Hongyan Liu, Zhi-Man Song, Yongqi Tian, Yong-Xin Li
Ribosomally synthesized and post-translationally modified peptides (RiPPs) are a fascinating group of natural products that exhibit diverse structural features and bioactivities. P450-catalyzed RiPPs stand out as a unique but underexplored family. Here, we introduce a rule-based genome mining strategy that harnesses the intrinsic biosynthetic principles of RiPPs, including the co-occurrence, co-conservation
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Boosting CO2 Photoreduction via Regulating Charge Transfer Ability in a One-Dimensional Covalent Organic Framework Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-28 Lei Zou, Zi-Ao Chen, Duan-Hui Si, Shuai-Long Yang, Wen-Qiang Gao, Kai Wang, Yuan-Biao Huang, Rong Cao
Two-dimensional (2D) imine-based covalent organic frameworks (COFs) hold potential for photocatalytic CO2 reduction. However, high energy barrier of imine linkage impede the in-plane photoelectron transfer process, resulting in inadequate efficiency of CO2 photoreduction. Herein, we present a dimensionality induced local electronic modulation strategy through the construction of one-dimensional (1D)
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Stabilization Of The CN35- Anion In Recoverable High-pressure Ln3O2(CN3) (Ln = La, Eu, Gd, Tb, Ho, Yb) Oxoguanidinates Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-28 Andrey Aslandukov, Pascal L. Jurzick, Maxim Bykov, Alena Aslandukova, Artem Chanyshev, Dominique Laniel, Yuqing Yin, Fariia I. Akbar, Saiana Khandarkhaeva, Timofey Fedotenko, Konstantin Glazyrin, Stella Chariton, Vitali Prakapenka, Fabrice Wilhelm, Andrei Rogalev, Davide Comboni, Michael Hanfland, Natalia Dubrovinskaia, Leonid Dubrovinsky
A series of isostructural Ln3O2(CN3) (Ln = La, Eu, Gd, Tb, Ho, Yb) oxoguanidinates was synthesized under high-pressure (25-54 GPa) high-temperature (2000-3000 K) conditions in laser-heated diamond anvil cells. The crystal structure of this novel class of compounds was determined via synchrotron single-crystal X-ray diffraction (SCXRD) as well as corroborated by X-ray absorption near edge structure
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A Journey from Benzoborirene to Benzoborole-Supported 1,2-Diimine and Antiaromatic Borolediide Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Xiaocui Liu, Myron Heinz, Junyi Wang, Leibo Tan, Max C. Holthausen, Qing Ye
The reaction of benzoborirene with one equivalent of isocyanides leads to benzene-fused boretes bearing one imine function, while the reaction with two equivalents of isocyanide affords 2,3-dihydro-2,3-diiminoboroles with perfect regioselectivity. The isocyanide double insertion products represent a novel type of 1,2-diimine with a benzoborole backbone. The reduction chemistry of the benzoborole-supported
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Concentrated Ionic Fluids: Is There a Difference Between Chloride-Based Brines and Deep Eutectic Solvents? Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Guillaume Zante, Christopher E Elgar, Katherine George, Andrew P Abbott, Jennifer M. Hartley
Deep Eutectic Solvents (DESs) have been lauded as novel solvents but is there really a difference between them and concentrated aqueous brines? They provide a method of adjusting the activity of water and chloride ions which can affect mass transport, speciation and reactivity. This study proposes a continuum of properties across concentrated ionic fluids and uses metal processing as an example. Charge
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The Oxygenate-Mediated Conversion of COx to Hydrocarbons─On the Role of Zeolites in Tandem Catalysis Chem. Rev. (IF 62.1) Pub Date : 2023-09-28 Jingxiu Xie, Unni Olsbye
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A Reversible Six-Electron Transfer Cathode for Advanced Aqueous Zinc Batteries Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Zichao Yan, Junwei Li, Hongguang Liu, Hui Zhang, Shibo Xi, Zhiqiang Zhu
The electrochemical reactions for the storage of Zn2+ while embracing more electron transfer is a foundation of the future high-energy aqueous zinc batteries (AZBs). Herein, we report a six-electron transfer electrochemistry of nano-sized TeO2/C (n-TeO2/C) cathode by facilitating the reversible conversion of TeO2↔Te and Te↔ZnTe. Benefitting from the integrated conductive nanostructure and the proton-rich
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Advances in Bioresorbable Triboelectric Nanogenerators Chem. Rev. (IF 62.1) Pub Date : 2023-09-27 Minki Kang, Dong-Min Lee, Inah Hyun, Najaf Rubab, So-Hee Kim, Sang-Woo Kim
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Hyperbranched Polyborosiloxane: Non-traditional Luminescent Polymer with Red Delayed Fluorescence Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Yanyun He, Weixu Feng, Yujie Qiao, Zhixuan Tian, Ben Zhong Tang, Hongxia Yan
Non-traditional fluorescent polymers have attracted significant attention for their excellent biocompatibility and diverse applications. However, designing and preparing non-traditional fluorescent polymers that simultaneously possess long emission wavelengths and long fluorescence lifetime remains challenging. In this study, a series of novel hyperbranched polyborosiloxanes (P1 ~ P4) were synthesized
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Visible Light Responsive Dinuclear Zinc Complex Consisting of Proximally Arranged Two d10-Zinc Centers Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Yoshimasa Wada, Takahiro Maruchi, Reon Ishii, Yusuke Sunada
So far, Zn(II)-based d10 complexes have been known to be colorless unless they are accompanied by chromophoric groups, and therefore both fundamental and advanced photophysical performance of Zn centers of complexes, especially in visible-light regions has been unexplored. Here, we first demonstrate a dinuclear Zn(II) complex that shows visible light absorption using an orbital distributed over closely
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Enantioconvergent Palladium-Catalyzed Alkylation of Tertiary Allylic C−H Bonds Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Zhong-Sheng Nong, Xin-Ran Chen, Pu-Sheng Wang, Xin Hong, Liu-Zhu Gong
Enantioconvergent catalysis enables the conversion of racemic molecules into a single enantiomer in perfect yield and is considered an ideal approach for asymmetric synthesis. Despite remarkable advances in this field, enantioconvergent transformations of inert tertiary C−H bonds remain largely unexplored due to the high bond dissociation energy and the surrounding steric repulsion that pose unparalleled
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A Two-Dimensional Hybrid Perovskite With Heat Switching Birefringence Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Ziyi Wang, Xu Chen, Yipeng Song, Zhipeng Du, Yang Zhou, Minjuan Li, Weiqi Huang, Qianting Xu, Yanqiang Li, Sangen Zhao, Junhua Luo
Birefringent crystals that can switch light polarization have important applications in optoelectronics. In the last decades, birefringence is mostly optimized by chemical strategies. Recently, switching birefringence by physical means has attracted much attention. Here, this work reports the observation of heat switching birefringence in a 2D layered hybrid halide perovskite (C2N3H4)2PbCl4 ([C2N3H4]+
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An NIR Fluorescence Turn-on and MRl Bimodal Probe for Concurrent Real-time in vivo Sensing and Labeling of β-Galactosidase Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Qiao Yu, Lei Zhang, Mou Jiang, Long Xiao, Yunhui Xiang, Ruifang Wang, Zhaoqing Liu, Rui Zhou, Minghui Yang, Conggang Li, Maili Liu, Xin Zhou, Shizhen Chen
To realize sensing and labeling biomarkers is quite challenging in terms of designing multimodal imaging probes. In this study, we developed a novel β-galactosidase (β-gal) activated bimodal imaging probe that combines near-infrared (NIR) fluorescence and magnetic resonance imaging (MRI) to enable real-time visualization of activity in living organisms. Upon β-gal activation, Gal-Cy-Gd-1 exhibits a
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Neighboring Molecular Engineering in Diels-Alder Chemistry Enabling Easily Recyclable Carbon Fiber Reinforced Composites Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Song Gu, Yan-Fang Xiao, Shi-Huan Tan, Bo-Wen Liu, De-Ming Guo, Yu-Zhong Wang, Li Chen
Although a variety of dynamic covalent bonds have been successfully used in the development of diverse sustainable thermosetting polymers and their composites, solving the trade-off between recovery efficiency and comprehensive properties is still a major challenge. Herein, a “one-stone-two-birds” strategy of lower rotational energy barrier (Er) phosphate-derived Diels-Alder (DA) cycloadditions was
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Electrocatalytic Water Oxidation Activity-Stability Maps for Perovskite Oxides Containing 3d, 4d and 5d Transition Metals Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Xiao Liang, Wensheng Yan, Yinglong Yu, Kexin Zhang, Wei An, Hui Chen, Yongcun Zou, Xiao Zhao, Xiaoxin Zou
Improving catalytic activity without loss of catalytic stability is one of the core goals in search of low-iridium-content oxygen evolution electrocatalysts under acidic conditions. Here, we synthesize a family of 66 SrBO3 perovskite oxides (B = Ti, Ru, Ir) with different Ti:Ru:Ir atomic ratios and construct catalytic activity-stability maps over composition variation. The maps classify the multicomponent
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Visible-light-switchable Chalcone-Flavylium Photochromic Systems in Aqueous Media Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Manik Lal Maity, Samyadeb Mahato, Subhajit Bandyopadhyay
The chalcone-flavylium photochromic system switches in aqueous media. However, the chalconeàflavylium conversion requires detrimental ultra-violet (UV) light for the switching which deters their applications in the biological domain. To address this issue, we have synthesized strategically modified chalcone scaffolds that can be reversibly switched to the flavylium forms with visible light ranging
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A DNA Origami-based Bactericide for Efficient Healing of Infected Wounds Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Tiantian Wu, Hong Wang, Run Tian, Shuang Guo, Yuhui Liao, Jianbing Liu, Baoquan Ding
Bacteria infection is a significant obstacle in the clinical treatment of exposed wounds facing widespread pathogens. Herein, we report a DNA origami-based bactericide for efficient anti-infection therapy of infected wounds in vivo. In our design, abundant DNAzymes (G4/hemin) can be precisely organized on the DNA origami for controllable generation of reactive oxygen species (ROS) to break bacterial
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Activity and Stability of Single- and Di-atom catalysts for O2 reduction reaction. Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2023-09-27 Naiwrit Karmodak, Jens K. Nørskov
Efficient and in-expensive catalysts for the O2 reduction reaction (ORR) is needed for advancement of renewable energy technologies. In this study, we design a computational catalyst screening method to identify single and di-atom metal dopants from first-row transition elements supported on defected nitrogenated graphene surfaces for ORR. Based upon the formation energy calculations and micro-kinetic
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Dispersion Engineering by Hybridizing the Back-Folded Soft Mode of Monomode Elastic Metamaterials with Stiff Acoustic Modes Adv. Mater. (IF 29.4) Pub Date : 2023-09-28 Michael F. Groß, Jonathan L.G. Schneider, Yi Chen, Muamer Kadic, Martin Wegener
In many cases, the hybridization of two or more excitation modes in solids has led to new and useful dispersion relations of waves. Well-studied examples are phonon polaritons, plasmon polaritons, particle-plasmon polaritons, cavity polaritons, and magnetic resonances at optical frequencies. In all of these cases, the lowest propagating mode couples to a finite-frequency localized resonance. Herein
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Injection-on-skin Granular Adhesive for Interactive Human-machine Interface Adv. Mater. (IF 29.4) Pub Date : 2023-09-28 Sumin Kim, Jaepyo Jang, Kyumin Kang, Subin Jin, Heewon Choi, Donghee Son, Mikyung Shin
Realization of interactive human-machine interfaces (iHMI) has been improved with development of soft tissue-like strain sensors beyond hard robotic exosuits, potentially allowing cognitive behavior therapy and physical rehabilitation for patients with brain disorders. Here, we report on a strain-sensitive granular adhesive inspired by the core-shell architectures of natural basil seeds for iHMI as
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Suppressing Bulk Strain and Surface O2 Release in Li-rich Cathodes by Just Tuning the Li Content Adv. Mater. (IF 29.4) Pub Date : 2023-09-28 Zhenkun Hao, Haoxiang Sun, Youxuan Ni, Gaojing Yang, Zhuo Yang, Zhimeng Hao, Ruihan Wang, Pengkun Yang, Yong Lu, Qing Zhao, Weiwei Xie, Zhenhua Yan, Wei Zhang, Jun Chen
Layered oxides represent a prominent class of cathode materials extensively employed in lithium-ion batteries. The structural degradation of layered cathodes causes the capacity decay during battery cycling, which is generally induced by anisotropic lattice strain in the bulk of the cathode particle and undesirable oxygen release at the surface. However, particularly in lithium-rich layered oxides
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Reconfigurable Cascaded Thermal Neuristors for Neuromorphic Computing Adv. Mater. (IF 29.4) Pub Date : 2023-09-28 Erbin Qiu, Yuan-Hang Zhang, Massimiliano Di Ventra, Ivan K. Schuller
While the complementary metal-oxide semiconductor (CMOS) technology is the mainstream for the hardware implementation of neural networks, we explore an alternative route based on a new class of spiking oscillators we call “thermal neuristors”, which operate and interact solely via thermal processes. Utilizing the insulator-to-metal transition in vanadium dioxide, we demonstrate a wide variety of reconfigurable
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18.6% Efficiency All-Polymer Solar Cells Enabled by a Wide Bandgap Polymer Donor Based on Benzo[1,2-d:4,5-d′]bisthiazole Adv. Mater. (IF 29.4) Pub Date : 2023-09-28 Peixi Wu, Yuwei Duan, Yinfeng Li, Xiaopeng Xu, Ruipeng Li, Liyang Yu, Qiang Peng
The limited selection of wide bandgap polymer donors for all-polymer solar cells (all-PSCs) is a bottleneck problem restricting their further development and remains poorly studied. Herein, a new wide bandgap polymer, namely PBBTz-Cl, was designed and synthesized by bridging the benzobisthiazole acceptor block and chlorinated benzodithiophene donor block with thiophene units for application as an electron
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Polarization- and Gate-Tunable Optoelectronic Reverse in 2D Semimetal/Semiconductor Photovoltaic Heterostructure Adv. Mater. (IF 29.4) Pub Date : 2023-09-28 Hanyu Wang, Yan Li, Peng Gao, Jina Wang, Xuefeng Meng, Yin Hu, Yuehan Yang, Zihao Huang, Wei Gao, Zhaoqiang Zheng, Zhongming Wei, Jingbo Li, Nengjie Huo
Polarimetric photodetector can acquire higher resolution and more surface information of imaging targets in complex environments due to the identification of light polarization. To date, the existing technologies yet sustain the poor polarization sensitivity (<10), far from market application requirement. Here, the photovoltaic detectors with polarization- and gate-tunable optoelectronic reverse phenomenon
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Hydrophobicity-Adaptive Polymers Trigger Fission of Tumor Cell-Derived Microparticles for Enhanced Anticancer Drug Delivery Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Haojie Liu, Shiyi Xu, Tuying Yong, Zhaohan Wei, Nana Bie, Xiaoqiong Zhang, Xin Li, Jianye Li, Shiyu Li, Sheng Wang, Yanbing Zhao, Xiangliang Yang, Lu Gan
Tumor cell-derived microparticles (MPs) can function as anticancer drug delivery carriers. However, short blood circulation time, large size-induced insufficient tumor accumulation and penetration into tumor parenchyma as well as limited cellular internalization by tumor cells and cancer stem cells (CSCs), and difficult intracellular drug release restrict the anticancer activity of tumor cell-derived
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Stochastic Electrical Detection of Single Ion-Gated Semiconducting Polymers Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Ab F. Nieuwenhuis, Daniel F. Duarte Sánchez, Jin Z. Cui, Serge G. Lemay
Semiconducting polymer chains constitute the building blocks for a wide range of electronic materials and devices. However, most of their electrical characteristics at single-molecule level have received little attention. Elucidating these properties could help understanding performance limits and enable new applications. Here we exploit coupled ionic-electronic charge transport to measure the quasi-one-dimensional
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Scaling-Up Insights for Zinc–Air Battery Technologies Realizing Reversible Zinc Anodes Adv. Mater. (IF 29.4) Pub Date : 2023-09-26 Sambhaji S. Shinde, Nayantara K. Wagh, Chi Ho Lee, Dong-Hyung Kim, Sung-Hae Kim, Han-Don Um, Sang Uck Lee, Jung-Ho Lee
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Imaging Field-Driven Melting of a Molecular Solid at the Atomic Scale (Adv. Mater. 39/2023) Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Franklin Liou, Hsin-Zon Tsai, Zachary A. H. Goodwin, Andrew S. Aikawa, Ethan Ha, Michael Hu, Yiming Yang, Kenji Watanabe, Takashi Taniguchi, Alex Zettl, Johannes Lischner, Michael F. Crommie
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Combining PEDOT:PSS Polymer Coating with Metallic 3D Nanowires Electrodes to Achieve High Electrochemical Performances for Neuronal Interfacing Applications (Adv. Mater. 39/2023) Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Ines Muguet, Ali Maziz, Fabrice Mathieu, Laurent Mazenq, Guilhem Larrieu
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4D Additive–Subtractive Manufacturing of Shape Memory Ceramics (Adv. Mater. 39/2023) Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Guo Liu, Xiaofeng Zhang, Xinya Lu, Yan Zhao, Zhifeng Zhou, Jingjun Xu, Jianan Yin, Tao Tang, Peiyu Wang, Shenghui Yi, Jiafeng Fan, Xueshi Zhuo, Yu Hin Chan, Wui Leung Wong, Haidong Bian, Jun Zuo, Yu Dai, Jian Wu, Jian Lu
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Macrocyclic Engineering of Thermally Activated Delayed Fluorescent Emitters for High-Efficiency Organic Light-Emitting Diodes (Adv. Mater. 39/2023) Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Yu Fu, Zecong Ye, Denghui Liu, Yingxiao Mu, Jingping Xiao, Dehua Hu, Shaomin Ji, Yanping Huo, Shi-Jian Su
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Short-Wavelength Infrared Organic Light-Emitting Diodes from A–D–A′–D–A Type Small Molecules with Emission beyond 1100 nm (Adv. Mater. 39/2023) Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Wansheng Liu, Suinan Deng, Lianjie Zhang, Cheng-Wei Ju, Yuan Xie, Wanyuan Deng, Junwu Chen, Hongbin Wu, Yong Cao
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Probing Optical Multi-Level Memory Effects in Single Core-Shell Quantum Dots and Application Through 2D–0D Hybrid Inverters (Adv. Mater. 39/2023) Adv. Mater. (IF 29.4) Pub Date : 2023-09-27 Hyun-Soo Ra, Tae Wook Kim, Derrick Allan Taylor, Je-Jun Lee, Seungho Song, Jongtae Ahn, Jisu Jang, Takashi Taniguchi, Kenji Watanabe, Jae Won Shim, Jong-Soo Lee, Do Kyung Hwang
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Multifunctional Solid Additive Enabling All-Polymer Solar Cells with Improved Efficiency, Photostability and Mechanical Durability Energy Environ. Sci. (IF 32.5) Pub Date : 2023-09-27 Jiali Song, Linglong Ye, Chunhui Liu, Yunhao Cai, Guichu Yue, Yun Li, Min Hun Jee, Chen Zhang, Yong Zhao, Donghui Wei, Han Young Woo, Yanming Sun
All-polymer solar cells (all-PSCs) have recently made remarkable progress owing to the emergence of polymerized small molecule acceptors. However, the fabrication of all-PSCs featuring high efficiency, desirable photostability and excellent mechanical durability remains challenging. Herein, we designed and synthesized a series of novel non-volatile solid additives, namely DTC-Cn (n represents 8, 12
更新日期：2023-09-29
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