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Photocontrol of catalysis in CuAAC reactions by air stable Cu(I) complexes of phenylazopyrazole-incorporated ligands Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-25 Debapriya Gupta, Ankit Kumar Gaur, Deepanshu Chauhan, Sandeep Kumar Thakur, Ashish Ashish, Sanjay Singh, Gopalan Rajaraman, Sugumar Venkataramani
Metal complexes containing organic photoswitches modulate the steric and electronic environment around the catalytic center through photoisomerization, enabling their use in photoswitchable metal catalysis. Herein, we design a new class of photoswitchable tripodal tetradentate ligands L1-L3 that can readily form air-stable Cu(I) complexes (C1-PF6, C1-BF4, C2, C3). The design strategy integrates flexible
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Evaluation of Ce-MOFs as Photoanode Materials for the Water Oxidation Reaction: The Effect of Doping with [Ru(bpy)(dcbpy)(H2O)2]2+ Catalyst Inorg. Chem. (IF 4.6) Pub Date : 2024-04-25 Naduvile Purayil Dileep, Jully Patel, Yulia Pushkar
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Unexpected Supramolecular-Induced Redox Switching in Sandwich Gd Bisphthalocyaninate Inorg. Chem. (IF 4.6) Pub Date : 2024-04-25 Anna A. Sinelshchikova, Lyudmila A. Lapkina, Vladimir E. Larchenko, Pavel V. Dorovatovskii, Aslan Yu. Tsivadze, Yulia G. Gorbunova
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Layered Hydride LiH4 with a Pressure-Insensitive Superconductivity Inorg. Chem. (IF 4.6) Pub Date : 2024-04-25 Xing Li, Zixuan Guo, Xiaohua Zhang, Guochun Yang
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Extraction of Uranium by a Pyrazole-Based Porous Organic Polymer Inorg. Chem. (IF 4.6) Pub Date : 2024-04-25 Kai Yu, Lizhen Zhong, Liecheng Guo, Feng Gao, Xuefeng Feng, Feng Luo
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A Water-Soluble Wavy Coordination Polymer of Cu(II) as a Turn-On Luminescent Probe for Histidine and Histidine-Rich Proteins/Peptides Inorg. Chem. (IF 4.6) Pub Date : 2024-04-25 Riya Ghosh, Ratish R. Nair, Shibaji Ghosh, Snehasish Debnath, Pabitra B. Chatterjee
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Modulating Excited State Properties and Ligand Ejection Kinetics in Ruthenium Polypyridyl Complexes Designed to Mimic Photochemotherapeutics Inorg. Chem. (IF 4.6) Pub Date : 2024-04-25 Faith N. Robinette, Nathaniel P. Valentine, Konrad M. Sehler, Andrew M. Medeck, Keylon E. Reynolds, Skylar N. Lane, Averie N. Price, Ireland G. Cavanaugh, Steven M. Shell, Dennis L. Ashford
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Spectroscopy of End-On Copper(II) Superoxido Complexes: A Wave Function-Based Analysis Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Léo Chaussy, Vijay Gopal Chilkuri, Stéphane Humbel, Paola Nava
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Advanced Uranium Removal with Pure, Nonfluorinated Ionic Liquids: Fine-Tuning Hydrophilic and Hydrophobic Properties for Enhanced Selectivity Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Ramzi Zarrougui, Najmeddine Ferhi, Noureddine Raouafi, Ahmed Hichem Hamzaoui, Sabri Messaoudi
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Suppressing the Thermal Quenching Effect via a Cluster Conformer in Copper(I)–Iodide Coordination Polymeric Phosphors for High-Power White LED Lighting Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Bin Wang, Yuzhe Fu, Yi Shen, Pingping Wang, Yang Chen, Fan Feng, Zhong Xu, Wei Huang, Dayu Wu
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Multiscale Modeling of Plutonium Radiation Chemistry in Nitric Acid Solutions. 1. Cobalt-60 Gamma Irradiation of Pu(IV) Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Amy E. Kynman, Travis S. Grimes, Jacy K. Conrad, Simon M. Pimblott, Gregory P. Horne
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Highly Exothermic and Fast Mechanochemical Redox and Intercalation Reactions of V2O5 with Sodium Hydride Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Anna Michaely, Christopher Luckas, Robert Haberkorn, Guido Kickelbick
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Preorganization Effects on Eu(III) Ion Coordination by Dipyridyl-Phenanthroline Ligands: A Combined Experimental and Theoretical Analysis Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Dong Fang, Xiaofan Yang, Jiarui Li, Zhiyuan Zhang, Yang Gao, Chengliang Xiao
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Rapid and Universal Synthesis of 2D Transition Metal (Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W) Sulfides through Oxide Sulfurization in CS2 Vapor Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Vladislav Buravets, Frantisek Hosek, Vasilii Burtsev, Elena Miliutina, Jaroslav Maixner, Ladislav Lapcak, Lucia Bajtosova, Miroslav Cieslar, Michal Procházka, Jan Minar, Zdenka Kolska, Vaclav Svorcik, Oleksiy Lyutakov
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Zinc-Catalyzed Hydroboration of Carbon Dioxide Amplified by Borane-Tethered Heteroscorpionate Bis(Pyrazolyl)methane Ligands Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Tiago F. C. Cruz, Valentin Loupy, Luís F. Veiros
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Luminescent Pt(II) Complexes Using Unsymmetrical Bis(2-pyridylimino)isoindolate Analogues Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Ellie N. Payce, Richard C. Knighton, James A. Platts, Peter N. Horton, Simon J. Coles, Simon J. A. Pope
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Interface Engineering-Modulated Nanoscale Bimetallic CoFe-MIL-88A In-Situ-Grown on 2D V2CTx MXene for Electrocatalytic Nitrogen Reduction Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Shaobin Li, Kun Cheng, Lin Ma, Li Zhang, Fengbo Li, Qingyu Cheng
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(P^N^C) Ligands to Stabilize Gold(III): A Straightforward Access to Hydroxo, Formate, and Hydride Complexes Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Jaime Martín, Johannes Schörgenhumer, Michał Biedrzycki, Cristina Nevado
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NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Huanhuan Zhao, Die Xu, Zhaohui Chen
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Building Nitridic Networks with Phosphorus and Germanium–from GeIIP2N4 to GeIVPN3 Inorg. Chem. (IF 4.6) Pub Date : 2024-04-24 Sebastian J. Ambach, Georg Krach, Elena Bykova, Kristian Witthaut, Nico Giordano, Maxim Bykov, Wolfgang Schnick
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Cd2+-Specific Fluorescence Response of Methoxy-Substituted N,N-Bis(2-quinolylmethyl)-2-methoxyaniline Derivatives Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Yuji Mikata, Nao Tosaka, Saori Yasuda, Yui Sakurai, Sunao Shoji, Hideo Konno, Takashi Matsuo
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β-Phase Yb5Sb3Hx: Magnetic and Thermoelectric Properties Traversing from an Electride to a Semiconductor Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Ashlee K. Hauble, Tanner Q. Kimberly, Kamil M. Ciesielski, Nicholas Mrachek, Maxwell G. Wright, Valentin Taufour, Ping Yu, Eric S. Toberer, Susan M. Kauzlarich
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Synthesis and Photophysical Properties of Silver(I) Coordination Polymers Bridged by Dimethylpyrazine: Comparison of Emissive Excited States between Silver(I) and Copper(I) Congeners Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Taiki Kuwahara, Hideki Ohtsu, Kiyoshi Tsuge
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Rare-Earth Metalloligands for Low-Valent Cobalt Complexes: Fine Electronic Tuning via Co→RE Dative Interactions Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Xiuyan He, Xiaowei Pan, Chunyan Xiong, Yun Zhang, Dongjing Hong, Huayi Fang, Peng Cui
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Searching for Laves Phase Superstructures: Structural and 27Al NMR Spectroscopic Investigations in the Hf–V–Al System Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Elias C. J. Gießelmann, Stefan Engel, Jasper Baldauf, Jutta Kösters, Samir F. Matar, Guido Kickelbick, Oliver Janka
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Diverse Reactivity of Amidinate-Supported Boron Centers with the Hypersilyl Anion and Access to a Monomeric Secondary Boron Hydride Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Sanjukta Pahar, Yara van Ingen, Rasool Babaahmadi, Benson M. Kariuki, Thomas Wirth, Emma Richards, Rebecca L. Melen
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Construction of Nickel Single Atoms by Using the Inherent Confined Space in Template-Occupied Mesoporous Silica Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Xiao-Qin Zheng, Kai Zhang, Yang Wang, Yang Liu, Song-Song Peng, Xiang-Bin Shao, Jiahui Kou, Lin-Bing Sun
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Ratiometric Fluorescence Detection of Levofloxacin Based on a Cube-like Zn(II)–Eu(III) Nanocluster: Functionalized Sodium Alginate Film for the Detection in Serum and Medicine Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Huanyin Yu, Jiazhao Lin, Xiaoping Yang, Chengri Wang, Desmond Schipper, Keqin Yang
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Precisely Assembling a CoO Cocatalyst onto Tb4O7/CN and Pt-Tb4O7/CN for Promoting Photocatalytic Overall Water Splitting Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Dedong Zeng, Yuexiang Li
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Dihydrogen Cleavage by a Zinc–Zinc Bond of a Heteroleptic Dizinc(I) Cation Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Pritam Mahawar, Thayalan Rajeshkumar, Thomas P. Spaniol, Laurent Maron, Jun Okuda
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Multiple Functions of l-Thioproline in the Synthesis of Chiral Metal Bromides Showing Second-Harmonic-Generation Responses Inorg. Chem. (IF 4.6) Pub Date : 2024-04-23 Peiqi Qian, Ying Li, Juan Cheng, Jing Li, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin
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Computational Comparative Study of the Binding of Americium with N-Donor Ligands Inorg. Chem. (IF 4.6) Pub Date : 2024-04-22 Xin Yan, Hui Jiang, Ziyi Liu, Dongqi Wang
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Magneto-optical Properties of Chiral Co2Ln and Co3Ln2 (Ln = Dy and Er) Clusters Inorg. Chem. (IF 4.6) Pub Date : 2024-04-22 Mukeremu Aibibula, Yu-Hong Song, Han Xu, Man-Ting Chen, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng
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Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates Inorg. Chem. (IF 4.6) Pub Date : 2024-04-22 Xinyu Tian, Ning Zhao, Kui Wu, Jingjing Xu, Dazhi Lu, Haohai Yu, Huaijin Zhang
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Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups Inorg. Chem. (IF 4.6) Pub Date : 2024-04-22 Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, MengMeng Zhu, Jindan Tian, Haixin Qi, Yaoqing Chu, Jiayue Xu
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Self-Supported WO3@RuO2 Nanowires for Electrocatalytic Acidic Water Oxidation Inorg. Chem. (IF 4.6) Pub Date : 2024-04-21 Xiaozan Zhang, Fei Wu, Qiuju Zhang, Zhiyi Lu, Yueqing Zheng, Yin’an Zhu, Yichao Lin
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Chiral Pyclen-Based Heptadentate Chelates as Highly Stable MRI Contrast Agents Inorg. Chem. (IF 4.6) Pub Date : 2024-04-20 Yong Jian, Gengshen Mo, Weiyuan Xu, Yao Liu, Zhichao Zhang, Yinghui Ding, Ruonan Gao, Jiao Xu, Jiang Zhu, Kun Shu, Zhihan Yan, Fabio Carniato, Carlos Platas-Iglesias, Fangfu Ye, Mauro Botta, Lixiong Dai
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Vegard's law in multivariate libraries of porous interpenetrated zirconia organic frameworks Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-25 Jacob I. Furst, Jacob T. Bryant, Kyle R. Langlois, Shea D. Myers, Azina Rahmani, David C. Fairchild, Rishabh Mehta, Titel Jurca, Jason B. Benedict, Fernando J. Uribe-Romo
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The effect of Sc doping on the electrocatalytic and optoelectronic properties of 2D SiAs single crystal Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-25 Tong Yu, Qiubo Chen, Hailong Qiu, Hongjun Liu, Zhanggui Hu, Yicheng Wu
SiAs with excellent properties have been widely reported in recent years. However, the stubborn p-type conductivity of SiAs itself poses a significant challenge in achieving n-type conductivity. Furthermore, for the two-dimensional (2D) SiAs photodetector, it is also essential to improve its photoelectric performance. SiAs, as one of the representative layer semiconductors of the IV-V group, are considered
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Magnifying turn-on luminescence and electrical conductivity by coupling effect among oxidation, metal ions adhesion and pressure within MnII-MOFs Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-25 Tingchang Shi, Zhihui LI, Zhiyue Dong, Ming-Hua Zeng, Haibing Xu
A metal-organic framework (MOFs), Mn2II-BTDB-MOFs (Mn1, BTDB = 4,4’-(1,2,5-benzothiadiazole-4,7-diyl)bis-benzoic acid) exhibits enhancement of turn-on luminescence through restricting intramolecular vibration (RIV) mechanism, retaining its crystallinity and porosity under oxidization, metal ions attachment, or pressure. As expected, 1.8-, 3.6-, 45.5-, and 164.4-folds emission enhancement respect to
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Novel triphenyltin(IV) compounds with carboxylato N-functionalized 2-quinolones as promising potential anticancer drug candidates: in vitro and in vivo evaluation Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Marijana P. Kasalović, Sanja Jelača, Žiko Milanović, Danijela Maksimović-Ivanić, Sanja Mijatović, Jelena Lađarević, Bojan Božić, Zoran Marković, Duško Dunđerović, Tobias Rüffer, Robert Kretschmer, Goran N. Kaluđerović, Nebojša Đ. Pantelić
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Expression of concern: Enhanced photocatalytic activity of g-C3N4/MnO composites for hydrogen evolution under visible light Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Na Mao, Xiaomin Gao, Chong Zhang, Chang Shu, Wenyan Ma, Feng Wang, Jia-Xing Jiang
Expression of concern for ‘Enhanced photocatalytic activity of g-C3N4/MnO composites for hydrogen evolution under visible light’ by Na Mao et al., Dalton Trans., 2019, 48, 14864–14872, https://doi.org/10.1039/C9DT02748C.
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DLPNO-CCSD(T) and DFT study of the acetate-assisted C-H activation of benzaldimine at [RuCl2(p-cymene)]2: the relevance of ligand exchange processes at ruthenium(II) complexes in polar protic media Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Vicente Ojea, María Ruiz
To gain mechanistic insight into the acetate-assisted cyclometallations of arylimines promoted by [RuCl2(p-cymene)]2 in polar protic media, DFT geometry optimizations (with M06 and ωB97X-D3 functionals and cc-pVDZ-PP[Ru] basis set) followed by DLPNO-CCSD(T)/CBS energy evaluations have been performed with benzaldimine as model substrate and methanol as solvent (using CPCM and SMD solvation models).
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Transition metal and lanthanide modified MOF-808 for barcode design Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Nele Marquardt, Frederike von der Haar, Andreas Schaate
This study explores the utilization of metal-organic frameworks (MOFs), particularly those incorporating lanthanide-based elements for their fluorescence capabilities, to create an advanced barcode system. By exploiting the modular nature of MOFs, we have developed a material capable of dynamic information encoding and robust against counterfeiting eff orts. We introduce a novel barcode prototype that
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Influence of acid–base equilibrium on interactions of some monofunctional coumarin Pd(II) complexes with biologically relevant nucleophiles-comprehensive kinetic study Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Žiko Milanović, Zoran Marković, Ana Kesić, Snežana Jovanović Stević, Biljana Petrović, Edina Avdović
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Synthesis and Structures of Cobalt-Expanded Zirconium- and Cerium-Oxo Clusters as Precursors for Mixed-Metal Oxide Thin Films Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Maximilian Seiß, Jonas Lorenz, Sebastian Schmitz, Marco Moors, Martin Börner, Kirill Monakhov
Transforming current complementary metal-oxide-semiconductor (CMOS) technology to fabricate memory chips and microprocessors into environmentally friendlier electronics requires the development of new approaches to resource- and energy-efficient electron transport and switching materials. Metal and multi-metal oxide layers play a key role in high-end technical applications. However, these layers are
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Insights into surface-modified Li(Ni0.80Co0.15Al0.05)O2 cathode by atomic layer fluorination for improved cycling behaviour Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Youn Charles-Blin, Oumaima Hatim, Mélissa Clarac, Anne-Marie Perbost, Solveine Liminana, Laura Lopez, Olinda Gimello, Katia Guerin, Marc Dubois, Michael Deschamps, Delphine Flahaut, Herve Martinez, Laure Monconduit, Nicolas Louvain
Li(Ni0.80Co0.15Al0.05)O2 is a lithium-ion battery cathode, commercially available for more than twenty years, that is associated with high energy capacity and high energy density, with moderate power. Atomic layer fluorination (ALF) of Li(Ni0.80Co0.15Al0.05)O2 with XeF2 is performed in order to improve its cyclability. The ALF method aims at forming an efficient protecting fluorinated layer at the
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Synthesis and proton-conductive behaviour of two MOFs with covalently bonded imidazoles in the channels Dalton Trans. (IF 4.0) Pub Date : 2024-04-25 Kun-Peng Chen, Yue Ma, Hong-Xia Ren, Chenxi Zhang, Qing-Lun Wang
Immobilization of imidazole molecules as the proton carriers into MOFs to facilitate the proton conduction is a general strategy for developing high proton conductive materials. Here in, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr6(OH)16(H3L1)4]Cl8∙20H2O}n [Zr-MOF; H3L1= 2-(1H-imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H2L2)2}n [Gd-MOF;
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Interfacial charge transfer in sheet Ni2P–FePx heterojunction to promote the study of electrocatalytic oxygen evolution Dalton Trans. (IF 4.0) Pub Date : 2024-04-23 Qiangqiang Wang, Xuejing Liu, Xiang Ren, Xu Sun, Xuan Kuang, Dan Wu, Qin Wei
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Molecular Two-Point Recognition of Fructosyl Valine and Fructosyl Glycyl Histidine in Water by Fluorescent Zn(II)-Terpyridine Complexes Bearing Boronic Acids Dalton Trans. (IF 4.0) Pub Date : 2024-04-24 María Karina Salomón-Flores, Josue Valdes-García, Alejandro O. Viviano-Posadas, Diego Martínez-Otero, Joaquín Barroso-Flores, Iván J. Bazany-Rodríguez, Alejandro Dorazco-González
Selective recognition in water of fructosyl amino acids by arylboronic acid-based receptors is a central field of modern supramolecular chemistry that impacts biological and medicinal chemistry. Fructosyl valine (FV) and fructosyl glycyl histidine (FGH) occur as N-terminal moieties of human glycated hemoglobin; therefore, the molecular design of biomimetic receptors is an attractive, but very challenging
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Correction: Simple synthetic access to [Au(IBiox)Cl] complexes Dalton Trans. (IF 4.0) Pub Date : 2024-04-24 Ekaterina A. Martynova, Marco Zuccarello, Domenic Kronenberg, Marek Beliš, Agnieszka Czapik, Ziyun Zhang, Kristof Van Hecke, Marcin Kwit, Olivier Baudoin, Luigi Cavallo, Steven P. Nolan
Correction for ‘Simple synthetic access to [Au(IBiox)Cl] complexes’ by Ekaterina A. Martynova et al., Dalton Trans., 2023, 52, 7558–7563, https://doi.org/10.1039/D3DT01357J.
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Control of the geometry and anisotropy driven by the combination of steric and anion coordination effects in CoII complexes with N6-tripodal ligands: The impact of the size of the ligand on the magnetization relaxation time Dalton Trans. (IF 4.0) Pub Date : 2024-04-24 Aritz Landart Gereka, María Mar Quesada-Moreno, Maria A. Palacios, Yanling Li, Mykhaylo Ozerov, Jurek Krzystek, Enrique Colacio
Four mononuclear CoII complexes of formula [[Co(L)(SCN)2(H2O)0.5(CH3OH)0.5]·1.5H2O·0.75CH3OH (1), [Co(L1)Cl2]·H2O·2CH3CN (2), [Co(L1)(SCN)2]· 1.5H2O·CH3OH (3) and [Co(L1)]ClO4·2CH3OH (4) were prepared from the N6-tripodal Schiff bases ligands (S)P[N(Me)N=C(H)2-Q]3 (L) and (S)P[N(Me)N=C(H)1-ISOQ]3 (L1), where Q and ISOQ represent quinolyl and isoquinolyl moieties, respectively. In 1, the L ligand does
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Aggregation-induced enhanced fluorescence emission of chiral Zn(II) complexes coordinated by Schiff-base type binaphthyl ligands Dalton Trans. (IF 4.0) Pub Date : 2024-04-24 Daiki Tauchi, Katsuya Kanno, Masashi Hasegawa, Yasuhiro Mazaki, Kazunori Tsubaki, Ken-ichi Sugiura, Takuya Shiga, Seiji Mori, Hiroyuki Nishikawa
A pair of novel chiral Zn(II) complexes coordinated by Schiff-base type ligands derived from BINOL (1,1’-bi-2-naphthol), R-/S-Zn, were synthesized. X-ray crystallography revealed the presence of two crystallographically independent complexes; one has a distorted trigonal-bipyramidal structure coordinated by two binaphthyl ligands and one disordered methanol molecule (molecule A), while the other has
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A series of four-substituted polyoxometalate-thiacalix[4]arene-based materials for the efficient photocatalytic reduction of Cr(VI) Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-24 Jia-Yi Zhang, Yuting Song, Jin Yang, Wen-Yuan Pei, Jian-Fang Ma
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Tailoring supertetrahedral cadmium/tin selenide clusters into a robust framework for efficient elimination of Cs+, Co2+, and Ni2+ ions Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-24 Kai-Yao Wang, Meng-Yu Li, Lin Cheng, Xin Hao, Cheng Wang
The long-lived 137Cs/134Cs, 60Co, 63Ni with high-energy β/γ emissions are primary toxic fission/activation products in nuclear-contaminated water, causing irreversible damage to the ecological environment and human health. Rapid remediation of these radionuclides emerges as an urgent task, while the deficiencies in adsorption kinetics, selectivity and acid resistance hinder the material innovation
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Surface functionalization of metal-organic framework nanoparticle for overcoming biological barrier in cancer therapy Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-24 Jun Yong Oh, Youjung Sim, Gyeongseok Yang, Myoung-Hwan Park, Kibeom Kim, Ja-Hyoung Ryu
Nanomedicine, which merges the realms of nanotechnology and medicine, presents transformative strategies for advancing healthcare through nanoscale manipulation of materials. Among these, metal–organic frameworks (MOFs), with a unique hybrid structure of metal ions interconnected by organic ligands, have emerged as a novel class of inorganic nanoparticles with significant potential in drug delivery
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Bimetallic CoZn Metal-Organic-Framework Derived CoZnS@NSC Co-Catalyst Loaded on g-C3N4 for Significantly Augmented Photocatalytic H2 Evolution Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-24 Xiao-Jie Lu, Ikram Ullah, Jing-Han Li, Shuai Chen, Cheng-Zong Yuan, An-Wu Xu
The main existing issues in graphitic carbon nitride (g-C3N4) based photocatalytic hydrogen (H2) production include poor separation and transfer of photogenerated charge carriers and low optical absorption. Thus, the construction of a multicomponent co-catalyst and its integration with g-C3N4 to facilitate the transport and separation of photoexcited charge carriers is regarded as a promising approach
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Unveiling the Surface Hydroxylation and Selenite Modification of In Situ Generated Nickel for Promoting the Hydrogen Evolution Reaction Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-24 Kailu Guo, Jinzhi Jia, huijiao wang, Cailing Xu
Revealing structural reconstruction of Ni-based materials under the electro-reduction conditions and identifying real active species in alkaline hydrogen evolution reaction (HER) are significant for developing low-cost and efficient electrocatalysts. Moreover, the role of surface-adsorbed ions has not been fully elucidated after electrochemical reconstruction and severe leaching. Herein, taking (N
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Prussian Blue Analogues Derived Materials for Photocatalysis Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-23 Xu Han, Wen-Wen He, Tao Zhou, Shengqian Ma
Prussian Blue (PB) and Prussian Blue analogues (PBAs) as coordination polymers (CPs) are excellent catalysts, which have already been widely studied in the field of electrocatalysis. A large number of excellent researches for PBA-derived electrocatalysts have been reported successively. In the field of photocatalysis, the exploration and report of PBA and its derivatives is relatively less compared
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A sustainable strategic approach for N-alkylation of amines with activation of alcohols triggered via hydrogen auto-transfer reaction using Pd(II) complex: Evidences for metal-ligand cooperativity Dalton Trans. (IF 4.0) Pub Date : 2024-04-23 Virendra Kumar Chaudhary, Prashant Kukreti, Keshav Sharma, Kapil Kumar, Sain Singh, Sheela Kumari, Kaushik Ghosh
This work describes a new well-defined, air-stable, phosphine free palladium(II) [Pd(L)Cl] (1) catalyst. This catalyst was utilized for N-alkylation of amines and indole synthesis where H2O was found to be by-product. A broad range of aromatic amines were alkylated using this homogeneous catalyst with catalyst loading of 0.1 mol%. Greener aromatic and aliphatic primary alcohols were utilized and hydrogen