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Ethylation And Allylation Reactions of Pinostrobin from the Rhizome of Kaempferia pandurata
Chemistry of Natural Compounds ( IF 0.8 ) Pub Date : 2023-11-15 , DOI: 10.1007/s10600-023-04197-z
S. D. Marliyana , M. Firdaus , M. W. Wartono , U. W. Apriani , D. I. Utami

This research was designed to isolate pinostrobin from Kaempferia pandurata Roxb. rhizome using a chromatography method and to study its structural modification through ethylation and allylation reactions. Two compounds were afforded from the ethylation reaction that were 5-ethoxy-7-methoxyflavanone and 4′-ethoxy-6′-methoxychalcone and in the case of the allylation, 5-O-allylpinostrobin (5-allyloxy-7-methoxyflavanone) and 6-allylpinostrobin (6-allyl-5-hydroxy-7-methoxyflavanone) were obtained.



中文翻译:

蓬松根茎中松醚酯的乙基化和烯丙基化反应

本研究旨在从山柰中分离松菌素。使用色谱方法研究根茎,并通过乙基化和烯丙基化反应研究其结构修饰。从乙基化反应中得到两种化合物,即 5-乙氧基-7-甲氧基黄烷酮和 4'-乙氧基-6'-甲氧基查尔酮,在烯丙基化的情况下,得到 5-O-烯丙菌酯(5-烯丙氧基-7-甲氧基黄烷酮和获得6-烯丙菌酯(6-烯丙基-5-羟基-7-甲氧基黄烷酮)。

更新日期:2023-11-18
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