Porous organic polymers for CO2 capture, separation and conversion,Chemical Society Reviews

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Porous organic polymers for CO2 capture, separation and conversion
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2022-11-14 , DOI: 10.1039/d2cs00727d
Kyung Seob Song ₁ , Patrick W Fritz ₁ , Ali Coskun ₁

Affiliation

Porous organic polymers (POPs) have long been considered as prime candidates for carbon dioxide (CO₂) capture, separation, and conversion. Especially their permanent porosity, structural tunability, stability and relatively low cost are key factors in such considerations. Whereas heteratom-rich microporous networks as well as their amine impregnation/functionalization have been actively exploited to boost the CO₂ affinity of POPs, recently, the focus has shifted to engineering the pore environment, resulting in a new generation of highly microporous POPs rich in heteroatoms and featuring abundant catalytic sites for the capture and conversion of CO₂ into value-added products. In this review, we aim to provide key insights into structure–property relationships governing the separation, capture and conversion of CO₂ using POPs and highlight recent advances in the field.

中文翻译：

用于 CO2 捕获、分离和转化的多孔有机聚合物

长期以来，多孔有机聚合物 (POP) 一直被认为是二氧化碳 (CO ₂ ) 捕获、分离和转化的主要候选材料。特别是它们的永久孔隙率、结构可调性、稳定性和相对较低的成本是此类考虑的关键因素。尽管富含杂原子的微孔网络及其胺浸渍/功能化已被积极利用来提高 POPs 的 CO ₂亲和力，但最近，重点已转移到孔隙环境工程上，从而产生了新一代高微孔 POPs，富含杂原子并具有丰富的催化位点，用于捕获和转化 CO ₂转化为增值产品。在这篇综述中，我们的目标是提供关于控制使用 POPs 分离、捕获和转化 CO ₂的结构-性质关系的关键见解，并强调该领域的最新进展。

更新日期：2022-11-14

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