Issue 23, 2022
From the journal:

Chemical Society Reviews

Porous organic polymers for CO2 capture, separation and conversion

Kyung Seob Song,†a   Patrick W. Fritz†a  and  Ali Coskun ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Fribourg, Chemin du Musée 9, 1700 Fribourg, Switzerland
E-mail: ali.coskun@unifr.ch

Abstract

Porous organic polymers (POPs) have long been considered as prime candidates for carbon dioxide (CO2) capture, separation, and conversion. Especially their permanent porosity, structural tunability, stability and relatively low cost are key factors in such considerations. Whereas heteratom-rich microporous networks as well as their amine impregnation/functionalization have been actively exploited to boost the CO2 affinity of POPs, recently, the focus has shifted to engineering the pore environment, resulting in a new generation of highly microporous POPs rich in heteroatoms and featuring abundant catalytic sites for the capture and conversion of CO2 into value-added products. In this review, we aim to provide key insights into structure–property relationships governing the separation, capture and conversion of CO2 using POPs and highlight recent advances in the field.

Graphical abstract: Porous organic polymers for CO2 capture, separation and conversion

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Article information

DOI
https://doi.org/10.1039/D2CS00727D
Article type
Review Article
Submitted
26 Aug 2022
First published
14 Nov 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Soc. Rev., 2022,51, 9831-9852

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Porous organic polymers for CO2 capture, separation and conversion

K. S. Song, P. W. Fritz and A. Coskun, Chem. Soc. Rev., 2022, 51, 9831 DOI: 10.1039/D2CS00727D

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