Russian Journal of Inorganic Chemistry ( IF 1.8 ) Pub Date : 2022-06-08 , DOI: 10.1134/s0036023622050035 G. A. Buzanov , E. A. Stroganova , A. Yu. Bykov , K. Yu. Zhizhin , N. T. Kuznetsov
Abstract
In order to expand the methods of lithium intercalation into layered multicomponent matrices, the reaction of lithium hydride with layered telluride Ni3GaTe2 through the stage of formation of mechanocomposites has been studied. Intercalation compounds LixNi3GaTe2 (0 ≤ x ≤ 0.3) have been shown to form when annealing mechanocomposites of the matrix and intercalating agent (LiH) in argon. The channels of hydride ion conversion have been studied and transformations involving the matrix have been described at various temperatures and molar ratios of the matrix and intercalating agent.
中文翻译:
锂的氢化物嵌入 Ni3GaTe2
摘要
为了将锂嵌入层状多组分基质的方法扩展,研究了氢化锂与层状碲化物Ni 3 GaTe 2在形成机械复合材料阶段的反应。插层化合物 Li x Ni 3 GaTe 2 (0 ≤ x ≤ 0.3) 已显示在氩气中对基体和插层剂 (LiH) 的机械复合材料进行退火时形成。已经研究了氢化物离子转化的通道,并且已经描述了在各种温度和基质与插层剂的摩尔比下涉及基质的转化。