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Preparation of polydopamine-coated TiO2 composites for photocatalytic removal of gaseous ammonia under 405 nm violet-blue light
Korean Journal of Chemical Engineering ( IF 2.7 ) Pub Date : 2022-05-21 , DOI: 10.1007/s11814-022-1122-3
Seo-Hyun Pak , Jung Hoon Park , Chan-gyu Park

Although photocatalytic reactions using the ultraviolet (UV) range (particularly UV B (280–320 nm) wavelengths) is well-established, the photocatalytic effect of longer wavelengths (especially that of UVA (≥380 nm) and visible light (≥400 nm)) have only recently been studied and utilized for environmental applications. In this work, we coated polydopamine (PDA) and TiO2 on a support and investigated the synergistic effects of the corresponding composites for the photocatalytic removal of gaseous ammonia under 405 nm violet-blue light. The PDA layer with TiO2 was covalently attached on a ceramic ball using the drop-casting method. The roughness and functional groups of the TiO2-PDA coated ball surfaces were verified using an infrared imaging microscope and field emission scanning electron microscope (FE-SEM). The photocatalytic activity of the obtained hybrid TiO2-PDA coated ball for the removal of ammonia was investigated using a UV C and 405 nm LED lamp at 24 °C. The results showed that both the TiO2 (control sample) and TiO2-PDA coated balls successfully removed ammonia under similar experimental conditions with the 254 nm UV C lamp. Notably, the TiO2-PDA coated ball exhibited an enhanced ammonia removal efficiency of 72% under 405 nm LED light irradiation. Thus, the TiO2-PDA coated ball is a promising indoor air cleaning technique under LED light irradiation.



中文翻译:

405 nm紫蓝光光催化脱除气态氨的聚多巴胺涂层TiO2复合材料的制备

尽管使用紫外 (UV) 范围(特别是 UV B (280–320 nm) 波长)的光催化反应已得到广泛认可,但较长波长(尤其是 UVA(≥380 nm)和可见光(≥400 nm)的光催化效应) )) 直到最近才被研究并用于环境应用。在这项工作中,我们将聚多巴胺 (PDA) 和 TiO 2涂覆在载体上,并研究了相应复合材料在 405 nm 紫蓝光下光催化去除气态氨的协同效应。使用滴注法将具有 TiO 2的 PDA 层共价连接在陶瓷球上。TiO 2的粗糙度和官能团-使用红外成像显微镜和场发射扫描电子显微镜(FE-SEM)验证PDA涂层球表面。使用 UV C 和 405 nm LED 灯在 24 °C 下研究获得的杂化 TiO 2 -PDA 涂层球去除氨的光催化活性。结果表明,在使用 254 nm UV C 灯的类似实验条件下, TiO 2(对照样品)和 TiO 2 -PDA 涂层球均成功去除了氨。值得注意的是,在 405 nm LED 光照射下,TiO 2 -PDA 涂层球的氨去除效率提高了 72%。因此,TiO 2 -PDA 涂层球在 LED 光照射下是一种很有前途的室内空气净化技术。

更新日期:2022-05-22
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