Thermal Decomposition of Co–Cu Double Salicylate Complex under Argon Atmosphere Resulting in Metal–Carbon Compositions,Russian Journal of Inorganic Chemistry

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Thermal Decomposition of Co–Cu Double Salicylate Complex under Argon Atmosphere Resulting in Metal–Carbon Compositions
Russian Journal of Inorganic Chemistry ( IF 1.8 ) Pub Date : 2022-04-18 , DOI: 10.1134/s0036023622040040
D. P. Domonov ₁ , S. I. Pechenyuk ₁ , Yu. P. Semushina ₁

Affiliation

Abstract

Thermal decomposition of double complex (DC) [Co(NH₃)₆]Cl[Cu(C₇H₄O₃)₂] · 3H₂O under inert atmosphere (argon) at high (>700°C) temperatures leads to formation of metal–carbon Co–Cu–C compositions. The reaction proceeds by sequential elimination of coordinated ammonia from the cationic portion of DC and decomposition of coordinated salicylate with evolution of phenol and its derivatives.

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