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Thermal Decomposition of Co–Cu Double Salicylate Complex under Argon Atmosphere Resulting in Metal–Carbon Compositions

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

Thermal decomposition of double complex (DC) [Co(NH3)6]Cl[Cu(C7H4O3)2] · 3H2O under inert atmosphere (argon) at high (>700°C) temperatures leads to formation of metal–carbon Co–Cu–C compositions. The reaction proceeds by sequential elimination of coordinated ammonia from the cationic portion of DC and decomposition of coordinated salicylate with evolution of phenol and its derivatives.

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Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

    D. P. Domonov, S. I. Pechenyuk & Yu. P. Semushina

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  1. D. P. Domonov
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  2. S. I. Pechenyuk
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  3. Yu. P. Semushina
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Correspondence to D. P. Domonov.

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Translated by I. Kudryavtsev

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Domonov, D.P., Pechenyuk, S.I. & Semushina, Y.P. Thermal Decomposition of Co–Cu Double Salicylate Complex under Argon Atmosphere Resulting in Metal–Carbon Compositions. Russ. J. Inorg. Chem. 67, 555–559 (2022). https://doi.org/10.1134/S0036023622040040

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