Abstract

This work describes the currently known cationic-anionic and complex metal compounds containing the decachloro-closo-decaborate anion [B₁₀Cl₁₀]^2–. The influence of the nature of the cation, solvent, metal and/or organic ligands on the composition and structure of the reaction products is discussed. Salts and complexes containing alkali metal cations, organic cations, and cationic complexes of metals Ag(I), Cu(II), Fe(II), Co(II), Ni(II), and Mn(II) with the decachloro-closo-decaborate anion as a counterion are described. The first examples of silver(I) complexes with the coordinated [B₁₀Cl₁₀]^2– anion are described. The ability of the perchlorinated closo-decaborate anion to participate in additional non-bonded interactions B–Cl…X (X = C, N, O) with alkali metal cations, organic cations, organic ligands, and solvent molecules is discussed; these interactions can be identified by ³⁵Cl NQR spectroscopy and X-ray diffraction. A number of new compounds based on perchlorinated boron clusters [B₁₀Hal₉R]^– containing nine halogen atoms and a functional group R are discussed.

中文翻译：

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含有十氯-近-十硼酸根阴离子的盐类和配合物

摘要

这项工作描述了含有所述decachloro-目前已知阳离子和阴离子复合金属化合物闭合碳-decaborate阴离子[B ₁₀氯₁₀ ] ^2-。讨论了阳离子、溶剂、金属和/或有机配体的性质对反应产物的组成和结构的影响。含有碱金属阳离子、有机阳离子和金属 Ag(I)、Cu(II)、Fe(II)、Co(II)、Ni(II) 和 Mn(II) 与十氯-描述了作为抗衡离子的近十硼酸阴离子。银 (I) 与配位 [B ₁₀ Cl ₁₀ ] ^2-配合物的第一个例子阴离子进行描述。的全氯化的能力闭合碳-decaborate阴离子参与另外的非键合相互作用B-氯... X（X = C，N，O）与碱金属阳离子，有机阳离子，有机配体，和溶剂分子进行了讨论; 这些相互作用可以通过³⁵ Cl NQR 光谱和 X 射线衍射鉴定。讨论了许多基于全氯化硼簇 [B ₁₀ Hal ₉ R]的新化合物^-包含九个卤素原子和一个官能团 R。