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Iron-Catalyzed Synthesis of Sarmentine
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2021-07-18 , DOI: 10.1134/s1070428021060178 R. N. Shakhmaev 1 , M. G. Ignatishina 1 , V. V. Zorin 1
中文翻译:
铁催化合成沙门汀
更新日期:2021-07-19
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2021-07-18 , DOI: 10.1134/s1070428021060178 R. N. Shakhmaev 1 , M. G. Ignatishina 1 , V. V. Zorin 1
Affiliation
Abstract
Stereoselective synthesis of sarmentine has been achieved via iron-catalyzed cross-coupling of pentylmagnesium bromide with ethyl (2E,4E)-5-chloropenta-2,4-dienoate obtained by one-pot oxidation–olefination of readily available (2E)-3-chloroprop-2-en-1-ol.
中文翻译:
铁催化合成沙门汀
摘要
沙门汀的立体选择性合成是通过溴化戊基镁与 (2 E ,4 E )-5-氯五-2,4-二烯酸乙酯的铁催化交叉偶联实现的,通过一锅氧化 - 烯化现成的 (2 E )-3-chloroprop-2-en-1-ol。