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Iron-Catalyzed Synthesis of Sarmentine

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Abstract

Stereoselective synthesis of sarmentine has been achieved via iron-catalyzed cross-coupling of pentylmagnesium bromide with ethyl (2E,4E)-5-chloropenta-2,4-dienoate obtained by one-pot oxidation–olefination of readily available (2E)-3-chloroprop-2-en-1-ol.

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Authors and Affiliations

  1. Ufa State Petroleum Technical University, 450062, Ufa, Russia

    R. N. Shakhmaev, M. G. Ignatishina & V. V. Zorin

Authors
  1. R. N. Shakhmaev
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  2. M. G. Ignatishina
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  3. V. V. Zorin
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Correspondence to R. N. Shakhmaev.

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Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 6, pp. 882–886 https://doi.org/10.31857/S0514749221060112.

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Shakhmaev, R.N., Ignatishina, M.G. & Zorin, V.V. Iron-Catalyzed Synthesis of Sarmentine. Russ J Org Chem 57, 1002–1005 (2021). https://doi.org/10.1134/S1070428021060178

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