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Pt and Ru Catalysts Based on Porous Aromatic Frameworks for Hydrogenation of Lignin Biofuel Components
Petroleum Chemistry ( IF 1.4 ) Pub Date : 2021-07-13 , DOI: 10.1134/s0965544121070045
L. A. Kulikov 1 , D. A. Makeeva 1 , M. A. Kalinina 1 , A. L. Maximov 1, 2 , E. A. Karakhanov 1 , K. A. Cherednichenko 3
Affiliation  

Abstract

A platinum catalyst and a ruthenium catalyst were synthesized from a porous aromatic framework, namely PAF-30. The catalyst properties were examined in hydrogenation of phenol and guaiacol at 80–250°C and at a hydrogen pressure of 30 atm in the presence of various solvents. Significant effects of the reaction medium, process conditions, and catalyst morphology on the reaction mechanism were demonstrated. Reaction conditions optimal for complete conversion of phenol and guaiacol to hydrogenation products were selected for both catalysts.



中文翻译:

基于多孔芳烃骨架的 Pt 和 Ru 催化剂用于木质素生物燃料组分的加氢

摘要

铂催化剂和钌催化剂由多孔芳族骨架合成,即PAF-30。在各种溶剂存在下,在 80-250°C 和 30 个大气压的氢气压力下,苯酚和愈创木酚的加氢反应检测了催化剂的性质。证明了反应介质、工艺条件和催化剂形态对反应机理的显着影响。为两种催化剂选择了对于苯酚和愈创木酚完全转化为氢化产物的最佳反应条件。

更新日期:2021-07-14
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