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Quantifying F and Cl concentrations in granitic melts from apatite inclusions in zircon
Contributions to Mineralogy and Petrology ( IF 3.5 ) Pub Date : 2021-07-09 , DOI: 10.1007/s00410-021-01813-5
Lillian A. Kendall-Langley 1 , Anthony I. S. Kemp 1 , Chris J. Hawkesworth 2 , Malcolm P. Roberts 3
Affiliation  

Apatite inclusions hosted by zircon offer a means to probe the magmatic history of granitic rocks and better constrain the volatile budgets of crystallising granitic melts. Building on recently developed F–Cl–OH partitioning models for apatite and coexisting melt, we outline an approach for estimating the melt concentrations of F and Cl from the composition of apatite inclusions in zircon, constrained by Ti-in-zircon crystallisation temperatures. The melts in equilibrium with apatite inclusions in zircon for the ‘I-type’ Jindabyne, Why Worry and Cobargo granitic suites of the Lachlan Orogen (eastern Australia), have Cl concentrations of 20–2880 ppm and F concentrations of 65–575 ppm. Variations in melt Cl and F concentrations between the granitic suites is attributed to differences in source compositions, specifically the relative contribution of F-rich turbiditic sediments and Cl-rich juvenile arc magmas. Within individual granitic suites, the calculated melt F and Cl concentrations decrease with magmatic differentiation and falling melt temperatures, and this appears to reflect the partitioning of Cl and F into biotite and hornblende, and into exsolving aqueous fluids. This study demonstrates that apatite-melt exchange coefficients for F, Cl and OH can be applied to apatite inclusions in zircon to quantify the F and Cl content of the melt, without additional context from the host rock samples.



中文翻译:

从锆石磷灰石包裹体中量化花岗岩熔体中的 F 和 Cl 浓度

以锆石为主体的磷灰石包裹体提供了一种探测花岗岩岩浆历史并更好地限制结晶花岗岩熔体的挥发性预算的方法。基于最近开发的磷灰石和共存熔体的 F-Cl-OH 分配模型,我们概述了一种方法,用于从锆石中磷灰石包裹体的组成中估算 F 和 Cl 的熔体浓度,受锆石中钛结晶温度的限制。与 Lachlan Orogen(澳大利亚东部)的“I 型”金德拜恩、Why Worry 和 Cobargo 花岗岩组的锆石中的磷灰石包裹体处于平衡状态的熔体的 Cl 浓度为 20-2880 ppm,F 浓度为 65-575 ppm。花岗岩套件之间熔体 Cl 和 F 浓度的变化归因于源成分的差异,特别是富含 F 的浊流沉积物和富含 Cl 的幼年弧岩浆的相对贡献。在单个花岗岩套内,计算出的熔体 F 和 Cl 浓度随着岩浆分异和熔体温度的下降而降低,这似乎反映了 Cl 和 F 分配为黑云母和角闪石,并进入溶出的含水流体。该研究表明,F、Cl 和 OH 的磷灰石-熔体交换系数可以应用于锆石中的磷灰石包裹体,以量化熔体的 F 和 Cl 含量,而无需来自主岩样品的额外背景。这似乎反映了 Cl 和 F 分配为黑云母和角闪石,以及溶解的水性流体。该研究表明,F、Cl 和 OH 的磷灰石-熔体交换系数可以应用于锆石中的磷灰石包裹体,以量化熔体的 F 和 Cl 含量,而无需来自主岩样品的额外背景。这似乎反映了 Cl 和 F 分配为黑云母和角闪石,以及溶解的水性流体。该研究表明,F、Cl 和 OH 的磷灰石-熔体交换系数可以应用于锆石中的磷灰石包裹体,以量化熔体的 F 和 Cl 含量,而无需来自主岩样品的额外背景。

更新日期:2021-07-09
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