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Nickel nanoparticles anchored over porous triazine-thiourea-sulfonamide to explore the reduction of carbonyl compounds
Journal of Porous Materials ( IF 2.5 ) Pub Date : 2021-06-25 , DOI: 10.1007/s10934-021-01104-1
Abumuslim Rahimi , Ramin Ghorbani-Vaghei , Sedigheh Alavinia

In the recent few years, polymer based nanomaterials are emerged as promising candidates in new generation catalysis. In this regard, we report the synthesis of nickel nanoparticles at mild conditions using porous triazine-thiourea-sulfonamide support (TTSA). The novel heterogeneous polymer support was synthesized by silica template method. The synthetically modified porous material (TTSA@Ni NPs) was analyzed in details over a number of physicochemical methods like, FT-IR, FE-SEM, HR-TEM, EDX, XRD, TGA and ICP-OES. In catalytic exploration we aimed the synthesis of alochohols from the reduction of aldehydes/ketones in water. Furthermore, the prepared green heterogeneous catalyst can be recycled and recovered six times without significant loss in the catalytic activity



中文翻译:

镍纳米粒子锚定在多孔三嗪-硫脲-磺酰胺上以探索羰基化合物的还原

近年来,基于聚合物的纳米材料成为新一代催化的有前途的候选材料。在这方面,我们报告了使用多孔三嗪-硫脲-磺酰胺载体 (TTSA) 在温和条件下合成镍纳米颗粒。采用二氧化硅模板法合成了新型多相聚合物载体。通过FT-IR、FE-SEM、HR-TEM、EDX、XRD、TGA和ICP-OES等多种物理化学方法对合成改性的多孔材料(TTSA@Ni NPs)进行了详细分析。在催化探索中,我们的目标是通过还原水中的醛/酮来合成醇类。此外,所制备的绿色多相催化剂可循环回收6次,催化活性没有明显损失。

更新日期:2021-06-25
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