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Selecting one out of six stereoisomers
Nature Catalysis ( IF 37.8 ) Pub Date : 2021-06-21 , DOI: 10.1038/s41929-021-00639-5
Damien Bonne , Jean Rodriguez

The design of an original molecular architecture featuring an unusual sterically congested C(sp2)–C(sp3) stereogenic axis with six high rotational barriers results in the formation of six stereoisomers. The configuration of this axis can be controlled by transition metal catalysis and one stereoisomer can be produced selectively.

中文翻译:

从六种立体异构体中选择一种

原始分子结构的设计具有不寻常的空间拥挤 C(sp2)–C(sp3) 立体轴和六个高旋转势垒,导致形成六个立体异构体。该轴的构型可以通过过渡金属催化来控制,并且可以选择性地产生一种立体异构体。
更新日期:2021-06-22
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