Environmental Science and Pollution Research Pub Date : 2021-06-22 , DOI: 10.1007/s11356-021-15014-x Sacha Moretti 1 , Antonella Tassone 1 , Virginia Andreoli 1 , Francesco Carbone 1 , Nicola Pirrone 1 , Francesca Sprovieri 1 , Attilio Naccarato 1
This study provides a thorough investigation of the trends of organic carbon (OC) and elemental carbon (EC) in particulate matter (PM)10 and PM2.5 samples collected at the Monte Curcio Observatory (1780 m a.s.l.), a station of the Global Atmosphere Watch (GAW) program and Global Mercury Observation System (GMOS) network. Although the drawn attention toward these pollutants, there is still a lack of data for southern Italy, and this work is a contribution toward the filling of this gap. PM was sampled daily in 2016 and analyzed by thermo-optical transmittance method, while equivalent black carbon (eBC) concentrations in PM10 were simultaneously measured using a multiangle absorption photometer. The results showed that in PM10, the average values of OC and EC were 1.43 μgC/m3 and 0.12 μgC/m3, whereas in PM2.5, these concentrations were 1.09 μgC/m3 and 0.12 μgC/m3, respectively. We detected a clear seasonal variability in OC and EC with higher concentrations during the warm period. Moreover, the analysis of the OC/EC ratio revealed that most of the carbonaceous aerosol was transported by long-range air masses, as further confirmed by the use of the concentration-weighed trajectory (CWT) model. The mass absorption cross-section at 632 nm of EC (MACEC) over the entire period was 9.67 ± 4.86 m2/g and 8.70 ± 3.18 m2/g in PM2.5 and PM10, respectively, and did not exhibit a clear seasonal variation. The concentrations for OC and EC were also used for the computation of the secondary organic carbon (SOC) content, whose outcomes resulted in a seasonal trend similar to those obtained for OC and EC. As regards the eBC, its weekly pattern showed a slight increase during the weekend in the warm period, consistent with the anthropic activities in the touristic area surrounding the observatory.
中文翻译:
意大利高海拔Monte Curcio GAW站颗粒物中一次次生有机碳和元素碳的分析研究
本研究对在全球大气站 Monte Curcio 天文台 (1780 m asl) 收集的颗粒物 (PM) 10和 PM 2.5样品中有机碳 (OC) 和元素碳 (EC) 的趋势进行了彻底调查Watch (GAW) 计划和全球汞观测系统 (GMOS) 网络。尽管这些污染物引起了人们的关注,但意大利南部仍然缺乏数据,这项工作有助于填补这一空白。2016 年每天对 PM 进行采样并通过热光透射率方法进行分析,同时使用多角度吸收光度计同时测量PM 10中的等效黑碳 (eBC) 浓度。结果表明,在 PM 10,OC 和EC 的平均值分别为1.43 μgC/m 3和0.12 μgC/m 3,而在PM 2.5 中,这些浓度分别为1.09 μgC/m 3和0.12 μgC/m 3。我们检测到 OC 和 EC 的明显季节性变化,在温暖时期浓度较高。此外,OC/EC 比率的分析表明,大多数含碳气溶胶是通过远程气团运输的,这通过使用浓度加权轨迹 (CWT) 模型进一步证实。在 PM 2.5 中,整个期间EC (MAC EC )在 632 nm 处的质量吸收截面为 9.67 ± 4.86 m 2 /g 和 8.70 ± 3.18 m 2 /g和 PM 10,并没有表现出明显的季节性变化。OC 和 EC 的浓度也用于计算次生有机碳 (SOC) 含量,其结果导致季节性趋势类似于 OC 和 EC 获得的那些。至于eBC,其每周模式在温暖时期的周末略有增加,与天文台周围旅游区的人类活动一致。