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Assessment of Corrosion and Scratch Resistance of Plasma Electrolytic Oxidation and Hard Anodized Coatings Fabricated on AA7075-T6
Transactions of the Indian Institute of Metals ( IF 1.5 ) Pub Date : 2021-05-31 , DOI: 10.1007/s12666-021-02289-4
C. Premchand , S. Hariprasad , A. Saikiran , E. Lokeshkumar , P. Manojkumar , B. Ravisankar , B. Venkataraman , N. Rameshbabu

Surface modification of high-strength aluminium alloy 7075-T6 by plasma electrolytic oxidation (PEO) and type II hard anodization (HA) is presented in the current work. PEO-based ceramic oxide coatings were fabricated by employing an alternating current (AC) power source with a current density of 300 mA/cm2. The concentration effect of electrolytes on the alumina coatings was investigated and optimized comprehensively. Three separate aqueous electrolytes with 1:3, 1:1 and 3:1 proportions of sodium silicate (Na2SiO3) and potassium hydroxide (KOH) were utilized to evaluate optimum electrolyte concentration for obtaining desired AC-PEO coatings. X-ray diffraction (XRD) was utilized to investigate the phase composition of the coatings. Field emission scanning electron microscopy (FESEM) was employed to investigate the surface and cross-sectional characteristics of oxide coatings. Scratch testing was used to assess the oxide coatings' adhesion ability, and potentiodynamic polarization (PDP) was utilized to assess the coatings' corrosion behaviour in a 3.5 wt% aqueous NaCl solution. Among the AC-PEO and HA coatings, the AC-PEO specimen fabricated with equal ratios of sodium silicate and KOH concentration (Na2SiO3:KOH 1:1) showed excellent adhesion strength (critical load, Lc = 41.5 N) along with the remarkable corrosion resistance (corrosion current density, icorr = 5.63 × 10–6 mA/cm2).



中文翻译:

在 AA7075-T6 上制造的等离子电解氧化和硬质阳极氧化涂层的耐腐蚀性和耐刮擦性评估

目前的工作介绍了通过等离子体电解氧化 (PEO) 和 II 型硬质阳极氧化 (HA) 对高强度铝合金 7075-T6 进行表面改性。PEO 基陶瓷氧化物涂层是通过使用电流密度为 300 mA/cm 2 的交流 (AC) 电源制造的。综合研究和优化电解液对氧化铝涂层的浓度影响。三种单独的水性电解质,具有 1:3、1:1 和 3:1 比例的硅酸钠 (Na 2 SiO 3) 和氢氧化钾 (KOH) 用于评估获得所需 AC-PEO 涂层的最佳电解质浓度。利用 X 射线衍射 (XRD) 来研究涂层的相组成。场发射扫描电子显微镜(FESEM)被用来研究氧化物涂层的表面和横截面特性。划痕测试用于评估氧化物涂层的附着能力,动电位极化 (PDP) 用于评估涂层在 3.5 wt% NaCl 水溶液中的腐蚀行为。在 AC-PEO 和 HA 涂层中,用等比例的硅酸钠和 KOH 浓度(Na 2 SiO 3 :KOH 1:1)制备的 AC-PEO 样品显示出优异的粘附强度(临界载荷,L c = 41.5 N) 以及显着的耐腐蚀性(腐蚀电流密度,i corr  = 5.63 × 10 –6  mA/cm 2)。

更新日期:2021-06-01
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