当前位置: X-MOL 学术Iran. Polym. J. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Carbon nanotube functional group-dependent compatibilization of polyamide 6 and poly(methyl methacrylate) nanocomposites
Iranian Polymer Journal ( IF 2.4 ) Pub Date : 2021-05-07 , DOI: 10.1007/s13726-021-00930-z
Nampally Bikshamaiah , Nandru Mohan Babu , Danikonda Suresh Kumar , Suramoni Ramesh , Dumpala Madhuri , Annadanam V. Sesha Sainath , Katakam Madhukar

Nanocomposites of polyamide 6 (PA6)–poly(methyl methacrylate) (PMMA)–functionalized single-wall carbon nanotubes (f-SWCNTs) with hydroxyl (SWCNTOH) and carboxylic acid (SWCNTCOOH) in weight ratios of 79.5–19.5–1, 49.5–49.5–1, and 19.5–79.5–1 were fabricated and investigated in terms of morphology, mechanical and XRD studies. Blends of 80–20, 50–50, and 20–80 weight ratios of PA6–PMMA have functioned as references. The scanning electron microscopy images of nanocomposites showed a relatively uniform dispersion of PMMA domains as co-continuous phase morphology in the continuous phase of PA6 compared to their respective blends. The f-SWCNTs acted as functional group-dependent compatibilizers for the PA6–PMMA blend system. Compatibilization of PA6-PMMA blends was higher in the presence of functionalized SWCNTs. XRD analysis indicated that the αI and αII phases of the PA6 were dependent on the weight ratio of the PA6 and PMMA and the nature of the f-SWCNTs. The PMMA-rich blends and nanocomposites exhibited the rich αI phase. The melt strength of the nanocomposites was higher compared to that of the PA6–PMMA blends. All the nanocomposites exhibited higher tensile strength than their corresponding blends. Tensile modulus increased with increasing weight percent of PMMA in blends (from 810 to 1135 MPa) and in nanocomposites (from 854 to 1298 MPa). PA6–PMMA–SWCNTOH19.5–79.5–1 nanocomposites exhibited higher tensile modulus (1298 MPa) compared to all the blends and PA6–PMMA–SWCNTCOOH nanocomposites.



中文翻译:

碳纳米管对聚酰胺6和聚甲基丙烯酸甲酯纳米复合材料的官能团依赖性

聚酰胺6(PA6)-聚(甲基丙烯酸甲酯)(PMMA)-官能化的单壁碳纳米管(f -SWCNTs)与羟基(SWCNT OH)和羧酸(SWCNT COOH)的纳米复合材料,重量比为79.5-19.5-1 ,49.5–49.5–1和19.5–79.5–1是通过形态学,力学和XRD研究制成的,并进行了研究。重量比为80–20、50–50和20–80的PA6-PMMA的混合物已作为参考。纳米复合材料的扫描电子显微镜图像显示,与它们各自的共混物相比,PMMA域相对均匀地分散在PA6连续相中作为共连续相形态。该˚F-SWCNT充当PA6-PMMA共混体系的官能团依赖性增容剂。在存在功能化SWCNT的情况下,PA6-PMMA共混物的相容性更高。XRD分析表明,α和α II的PA6的相是依赖于PA6和PMMA和性质的重量比˚F -SWCNTs。富含PMMA共混物和纳米复合材料表现出丰富的α相中。纳米复合材料的熔体强度高于PA6-PMMA共混物的熔体强度。所有纳米复合材料均显示出比其相应的共混物更高的拉伸强度。拉伸模量随着共混物(从810到1135 MPa)和纳米复合材料(从854到1298 MPa)中PMMA重量百分比的增加而增加。PA6–PMMA–SWCNT与所有共混物和PA6-PMMA-SWCNT COOH纳米复合材料相比,OH 19.5–79.5–1纳米复合材料表现出更高的拉伸模量(1298 MPa)。

更新日期:2021-05-07
down
wechat
bug