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Effect of Al 2 O 3 on the viscosity of CaO-SiO 2 -Al 2 O 3 -MgO-Cr 2 O 3 slags
International Journal of Minerals, Metallurgy and Materials ( IF 5.6 ) Pub Date : 2021-05-06 , DOI: 10.1007/s12613-020-2187-9
Chen-yang Xu , Cui Wang , Ren-ze Xu , Jian-liang Zhang , Ke-xin Jiao

We investigated the effect of Al2O3 content on the viscosity of CaO-SiO2-Al2O3-8wt%MgO-1wt%Cr2O3 (mass ratio of CaO/SiO2 is 1.0, and Al2O3 content is 17wt%–29wt%) slags. The results show that the viscosity of the slag increases gradually with increases in the Al2O3 content in the range of 17wt% to 29wt% due to the role of Al2O3 as a network former in the polymerization of the aluminosilicate structure of the slag. With increases in the Al2O3 content from 17wt% to 29wt%, the apparent activation energy of the slags also increases from 180.85 to 210.23 kJ/mol, which is consistent with the variation in the critical temperature. The Fourier-transform infrared spectra indicate that the degree of polymerization of this slag is increased by the addition of Al2O3. The application of Iida’s model for predicting the slag viscosity in the presence of Cr2O3 indicates that the calculated viscosity values fit well with the measured values when both the temperature and Al2O3 content are at relatively low levels, i.e., the temperature range of 1673 to 1803 K and the Al2O3 content range of 17wt%–29wt% in CaO-SiO2-Al2O3-8wt%MgO-1wt%Cr2O3 slag.



中文翻译:

Al 2 O 3对CaO-SiO 2 -Al 2 O 3 -MgO-Cr 2 O 3炉渣粘度的影响

我们研究了Al 2 O 3含量对CaO-SiO 2 -Al 2 O 3 -8wt%MgO-1wt%Cr 2 O 3(CaO / SiO 2的质量比为1.0,Al 2 O 3的粘度)的影响。含量为17wt%–29wt%的炉渣。结果表明,由于Al 2 O 3作为铝硅酸盐结构聚合中的网络形成剂,Al 2 O 3在17wt%至29wt%的范围内随Al 2 O 3含量的增加而逐渐增加。炉渣。随着Al 2 O的增加3含量从17wt%增加到29wt%,炉渣的表观活化能也从180.85 kJ / mol增加到210.23 kJ / mol,这与临界温度的变化是一致的。傅立叶变换的红外光谱表明,通过添加Al 2 O 3可以提高这种炉渣的聚合度。Iida模型在Cr 2 O 3存在下预测炉渣粘度的应用表明,当温度和Al 2 O 3含量均处于较低水平(即温度)时,计算出的粘度值与测量值非常吻合范围为1673至1803 K和Al 2 O 3CaO-SiO 2 -Al 2 O 3 -8wt%MgO-1wt%Cr 2 O 3炉渣中的含量范围为17wt%–29wt%。

更新日期:2021-05-07
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