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Phase Composition and Thermal Properties of Yb-Gd Co-Doped SrZrO 3 Coating Prepared by the Solution Precursor Plasma Spray
Journal of Thermal Spray Technology ( IF 3.2 ) Pub Date : 2021-05-03 , DOI: 10.1007/s11666-021-01201-2
Yuanming Gao , Wen Ma , Xiangfeng Meng , Enbo Li , Yu Bai , Hongying Dong , Weidong Chen , Ruiling Jia

Three different double rare-earth modified SrZrO3 coatings [Sr(Zr0.9Yb0.05Gd0.05)O2.95 (SZYG-1), Sr(Zr0.85Yb0.075Gd0.075)O2.925 (SZYG-2) and Sr(Zr0.8Yb0.1Gd0.1)O2.9 (SZYG-3)] were prepared by solution precursor plasma spray. X-ray diffraction results show that the SZYG-1 coating is composed of SrZrO3 solid solution and ZrO2 solid solution with fluorite structure, while the SZYG-2 and SZYG-3 coatings include SrZrO3 solid solution and rare-earth oxide solid solution with cubic structure. The thermal conductivity of the as-sprayed SZYG-2 coating is 0.69 W m−1 K−1 (1000 °C), which is the lowest among the three modified SrZrO3 coatings and is about 45% lower than that of SrZrO3 coating (1.25 W m−1 K−1, 1000 °C). Among the three modified SrZrO3 coatings, the increase of thermal conductivity of the SZYG-1 coating after heat treatment is the smallest. The thermal expansion coefficients of the as-sprayed SZYG-1, SZYG-2 and SZYG-3 coatings are 10.5 × 10−6 K−1, 10.5 × 10−6 K−1 and 10.1 × 10−6 K−1, respectively. The sintering coefficients of the SZYG-1, SZYG-2 and SZYG-3 coatings are 3.5 × 10−7 s−1, 6.59 × 10−6 s−1 and 8 × 10−6 s−1, respectively. The SZYG-1 coating has the best sintering resistance, followed by the SZYG-2 coating and the SZYG-3 coating. The SZYG-1 coating has good phase stability, low thermal conductivity, better sintering resistance, which is considered as a promising novel TBC material.



中文翻译:

溶液前驱体等离子体喷涂Yb-Gd共掺杂SrZrO 3涂层的相组成和热性能

三种不同的双稀土改性SrZrO 3涂层[Sr(Zr 0.9 Yb 0.05 Gd 0.05)O 2.95(SZYG-1),Sr(Zr 0.85 Yb 0.075 Gd 0.075)O 2.925(SZYG-2)和Sr(Zr 0.8 Yb通过溶液前驱体等离子体喷雾制备0.1 Gd 0.1)O 2.9(SZYG-3)]。X射线衍射结果表明,SZYG-1涂层由具有萤石结构的SrZrO 3固溶体和ZrO 2固溶体组成,而SZYG-2和SZYG-3涂层包含SrZrO 3固溶体和立方结构的稀土氧化物固溶体。喷涂后的SZYG-2涂层的热导率为0.69 W m -1  K -1(1000°C),在三种改性SrZrO 3涂层中最低,且比SrZrO 3涂层低约45%。(1.25 W m -1  K -1,1000 °C)。在三种改性的SrZrO 3涂层中,热处理后SZYG-1涂层的导热系数增加最小。的作为喷涂SZYG-1,SZYG-2和SZYG-3涂层是10.5×10的热膨胀系数-6  ķ -1,10.5×10 -6  ķ -1和分别为10.1×10 -6  K -1。所述SZYG-1的烧结系数,SZYG-2和SZYG-3涂层是3.5×10 -7 小号-1,6.59×10 -6 小号-1和8×10 -6 小号-1,分别。SZYG-1涂层具有最佳的耐烧结性,其次是SZYG-2涂层和SZYG-3涂层。SZYG-1涂层具有良好的相稳定性,低导热性,更好的抗烧结性,被认为是一种有前途的新型TBC材料。

更新日期:2021-05-03
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