The synthetic nosean- and haüyne-like aluminosilicates with (MoO₄)²⁻ and (WO₄)²⁻ extra-framework anions were synthesized in H₂O-bearing systems (3 kbar, 750 °C) and studied by means of electron microprobe analysis, Raman spectroscopy, powder and single-crystal X-ray diffraction. The nosean-like phase contains up to 10.6 wt% MoO₃ and up to 5.1 wt% WO₃; the maximum content of MoO₃ in the haüyne-like phase is 22.5 wt%. The nosean-like phase with (MoO₄)²⁻ and (WO₄)²⁻ is cubic, P-43m, a = 9.1278(10) Å, V = 760.498(14) ų, Z = 1. This compound with the crystal chemical formula Na_7.68[(Al,Si)₁₂O₂₄] {[(Mo_0.65W_0.35)O₄]_0.78□_0.22}·H₂O has a disordered Al/Si framework, that is caused by the high temperature of crystallization (t = 750 °C) with further quenching at room temperature. Despite the same conditions of synthesis, the haüyne-like phase with (MoO₄)²⁻, Na_5.12Ca_1.92[Al₆Si₆O₂₄](MoO₄)_1.52 has an Al/Si-ordered framework. Its space group is P-43n, a = 9.1516(4) Å, V = 766.46(6) ų, Z = 1. In both synthesized sodalite-type aluminosilicates the anion groups (MoO₄)²⁻ and (WO₄)²⁻ are dynamically disordered. The polarized Raman spectra of both aluminosilicates show that Raman-active modes of (MoO₄)²⁻ and (WO₄)²⁻ correspond to vibrations of tetrahedral anions with symmetry T_d. The presence of H₂O was fixed only in the nosean-like compound and no preferred orientation of water molecule was detected.

在（H ₂ O）轴承体系（3 kbar，750°C）下合成具有（MoO ₄）²⁻和（WO ₄）²⁻骨架外阴离子的合成的类似鼻和Haüyne的铝硅酸盐，并通过电子进行研究微探针分析，拉曼光谱，粉末和单晶X射线衍射。鼻状样相含有至多10.6重量％的MoO ₃和至多5.1重量％的WO ₃。类Haüyne相中MoO ₃的最大含量为22.5 wt％。（MoO ₄）²⁻和（WO ₄）²⁻的鼻状相为立方，P -43 m，一个 = 9.1278（10）A，V  = 760.498（14）一种³，ž  = 1。这化合物与晶体化学式的Na _7.68 [（铝，硅）₁₂ ö ₂₄ ] {[（沫_0.65 w ^ _0.35）O ₄ ] _0.78 □ _0.22 }·H ₂ O具有无序的Al / Si骨架，这是由高温结晶（t  = 750°C）并在室温下进一步淬火引起的。尽管具有相同的合成条件，但具有（MoO ₄）²⁻，Na _5.12 Ca _1.92的类哈伊恩相[Al ₆ Si ₆ O ₂₄ ]（MoO ₄）_1.52具有Al / Si有序框架。其空间群为P -43 Ñ，一个 = 9.1516（4），V  = 766.46（6）³，ž  = 1。在这两种合成方钠石型铝硅酸盐的阴离子基团（的MoO ₄）^2-和（WO ₄）²⁻是动态无序的。两种硅铝酸盐的极化拉曼光谱均显示（MoO ₄）²⁻和（WO ₄）^2−的拉曼活性模式对应于对称性为T _d的四面体阴离子的振动。H ₂ O的存在仅在鼻状化合物中固定，并且未检测到水分子的优选取向。