Abstract

By the example of the synthesis of 5-(triethylsiloxymethyl)norbornene, a simple, one-step approach to the synthesis of silicon-substituted norbornenes based on the reaction of 5-norbornene-2-methanol with hydrosilanes is proposed. The metathesis polymerization of the synthesized monomer is studied. The resulting polymer is high molecular weight, soluble, noncrystalline, highly elastic, and thermally stable.

中文翻译：

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5-（三乙基甲硅烷氧基甲基）降冰片烯的合成与复分解聚合

摘要

以5-（三乙基甲硅烷氧基甲基）降冰片烯的合成为例，提出了一种简单的一步法，基于5-降冰片烯-2-甲醇与氢硅烷的反应合成硅取代的降冰片烯。研究了合成单体的复分解聚合。所得聚合物是高分子量的，可溶的，非晶的，高弹性的和热稳定的。