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Synthesis and Metathesis Polymerization of 5-(Triethylsiloxymethyl)norbornene

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Abstract

By the example of the synthesis of 5-(triethylsiloxymethyl)norbornene, a simple, one-step approach to the synthesis of silicon-substituted norbornenes based on the reaction of 5-norbornene-2-methanol with hydrosilanes is proposed. The metathesis polymerization of the synthesized monomer is studied. The resulting polymer is high molecular weight, soluble, noncrystalline, highly elastic, and thermally stable.

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Funding

The study of 5-norbornene-2-methanol polymerization was carried out within the framework of the State task for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences. This work was supported by the Russian Foundation for Basic Research (project no. 19-33-60035).

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    F. A. Andreyanov, D. A. Alent’ev & M. V. Bermeshev

  2. Mendeleev University of Chemical Technology, 125047, Moscow, Russia

    D. A. Alent’ev

Authors
  1. F. A. Andreyanov
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  2. D. A. Alent’ev
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  3. M. V. Bermeshev
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Correspondence to D. A. Alent’ev.

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Andreyanov, F.A., Alent’ev, D.A. & Bermeshev, M.V. Synthesis and Metathesis Polymerization of 5-(Triethylsiloxymethyl)norbornene. Polym. Sci. Ser. B 63, 109–115 (2021). https://doi.org/10.1134/S1560090421020020

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  • DOI: https://doi.org/10.1134/S1560090421020020

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