Abstract

Ni-Mo sulfide systems generated in situ from precursor salts were used for the hydrodeoxygenation of o-cresol. After the reaction, the catalysts were recovered and analyzed by transmission electron microscopy and X-ray photoelectron spectroscopy. It was shown that the addition of water into the reaction system affects the composition of the o-cresol conversion product due to a change in the texture and phase composition of the surface layer of the in situ sulfide particles.

中文翻译：

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Ni-Mo硫化硫化物存在下加水对邻甲酚转化的影响

摘要

由前体盐原位生成的Ni-Mo硫化物体系用于邻甲酚的加氢脱氧。反应后，回收催化剂并通过透射电子显微镜和X射线光电子能谱分析。结果表明，由于原位硫化物颗粒表面层的织构和相组成的变化，向反应体系中加水会影响邻甲酚转化产物的组成。