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Effects of Water Addition on the Conversion of o-Cresol in the Presence of In Situ Ni–Mo Sulfide Catalysts

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Abstract

Ni-Mo sulfide systems generated in situ from precursor salts were used for the hydrodeoxygenation of o-cresol. After the reaction, the catalysts were recovered and analyzed by transmission electron microscopy and X-ray photoelectron spectroscopy. It was shown that the addition of water into the reaction system affects the composition of the o-cresol conversion product due to a change in the texture and phase composition of the surface layer of the in situ sulfide particles.

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Funding

This work was carried out within the State Program of TIPS RAS.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    M. I. Kniazeva, T. S. Kuchinskaya & A. S. Erasheva

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  1. M. I. Kniazeva
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  2. T. S. Kuchinskaya
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  3. A. S. Erasheva
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Correspondence to T. S. Kuchinskaya.

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Kniazeva, M.I., Kuchinskaya, T.S. & Erasheva, A.S. Effects of Water Addition on the Conversion of o-Cresol in the Presence of In Situ Ni–Mo Sulfide Catalysts. Pet. Chem. 61, 682–687 (2021). https://doi.org/10.1134/S0965544121040034

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